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1.发明授权Process for desorbing CO2 capture from ion-rich mixture with micro-particles comprising biocatalysts 有权从含有生物催化剂的微粒子的离子浓缩混合物解吸二氧化碳捕获的方法公开(公告)号：US09480949B2
公开(公告)日：2016-11-01
申请号：US14458779
申请日：2014-08-13
申请人： CO2 SOLUTIONS INC.
发明人： Sylvie Fradette , Julie Gingras , Norman Voyer , Jonathan Carley , Glenn R. Kelly , Olivera Ceperkovic
CPC分类号： B01D53/83 , B01D53/1425 , B01D53/1475 , B01D53/1493 , B01D53/62 , B01D53/96 , B01D2251/304 , B01D2251/306 , B01D2251/606 , B01D2252/20405 , B01D2252/20431 , B01D2252/20489 , B01D2252/20494 , B01D2252/205 , B01D2252/504 , B01D2252/602 , B01D2255/804 , B01D2257/504 , B01D2258/0283 , C01B32/50 , Y02C10/04 , Y02C10/06 , Y02P20/152
摘要： A process for desorbing CO2 gas from an ion-rich aqueous mixture comprising bicarbonate and hydrogen ions, includes providing micro-particles in the ion-rich aqueous mixture; and feeding the ion-rich aqueous mixture into a desorption reactor; the micro-particles comprising a support material and biocatalysts supported and stabilized by the support material and being sized and provided in a concentration in the desorption reactor such that the micro-particles are carried with the ion-rich aqueous mixture to promote transformation of the bicarbonate and hydrogen ions into CO2 gas and water, thereby producing a CO2 gas stream and an ion-depleted solution.
摘要翻译： 从含有碳酸氢盐和氢离子的离子富集的含水混合物中解吸CO 2气体的方法包括在富含离子的含水混合物中提供微粒子; 并将离子富集的含水混合物进料到解吸反应器中; 微粒包含载体材料和由载体材料负载和稳定的生物催化剂，其尺寸和浓度以解吸反应器的形式提供，使得微粒携带离子富含水的混合物以促进碳酸氢盐的转化 并将氢离子分解成二氧化碳气体和水，从而产生二氧化碳气流和离子耗尽溶液。
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2.发明申请PROCESS FOR CO2 ABSORPTION WITH CARBONIC ANHYDRASE ENTRAPPED IN POROUS SUPPORTS 审中-公开二氧化碳吸收与多孔支持物中碳纳米管的过程公开(公告)号：US20130224842A1
公开(公告)日：2013-08-29
申请号：US13845268
申请日：2013-03-18
申请人： CO2 Solutions Inc.
发明人： Carmen PARENT , Frederic DUTIL
IPC分类号： B01D53/85
CPC分类号： B01D53/85 , B01D53/84 , B01D2257/504 , Y02A50/2358 , Y02C10/02 , Y02C10/04 , Y02E50/343
摘要： A carbonic anhydrase bioreactor for treating a CO2-containing gas includes a reaction chamber for receiving a liquid; porous particles with carbonic anhydrase entrapped therein provided in the reaction chamber for catalyzing a reaction of CO2 into bicarbonate and hydrogen ions to obtain a treated gas and an ion-rich solution; a retention device for retaining the porous particles within the reaction chamber; a liquid inlet for providing the liquid; a gas inlet for providing the CO2-containing gas; a liquid outlet for releasing the ion-rich solution; and a gas outlet to release the treated gas. Processes are also described for treating a CO2-containing gas, where particles comprising porous material with entrapped carbonic anhydrase catalyze the reaction and the particles are retained in the reaction chamber.
摘要翻译： 用于处理含CO 2气体的碳酸酐酶生物反应器包括用于接收液体的反应室; 在反应室中设置有碳酸酐酶的多孔颗粒，用于催化CO 2与碳酸氢盐和氢离子的反应，以获得处理气体和富含离子的溶液; 用于将多孔颗粒保持在反应室内的保持装置; 用于提供液体的液体入口; 用于提供含CO 2气体的气体入口; 用于释放离子富溶液的液体出口; 和气体出口以释放经处理的气体。 还描述了处理含CO 2气体的方法，其中包含含有碳酸酐酶的多孔材料的颗粒催化反应并且颗粒保留在反应室中。
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公开(公告)号：US20130203155A1
公开(公告)日：2013-08-08
申请号：US13503808
申请日：2011-10-28
CPC分类号： B01D53/84 , B01D53/1425 , B01D53/1475 , B01D53/62 , B01D2251/304 , B01D2251/306 , B01D2251/606 , B01D2252/10 , B01D2252/102 , B01D2252/2026 , B01D2252/20442 , B01D2252/20447 , B01D2252/20484 , B01D2252/20489 , B01D2252/20494 , B01D2252/602 , B01D2256/22 , B01D2256/245 , B01D2257/504 , B01D2258/0283 , B01D2258/05 , B01D2258/06 , C12F3/02 , Y02C10/02 , Y02C10/04 , Y02C10/06
摘要： An enzyme-catalyzed desorption process for releasing CO2 gas from an ion-rich solution containing bicarbonate ions includes providing carbonic anhydrase in the ion-rich solution such that in a desorption unit the carbonic anhydrase is allowed to flow with the ion-rich solution while promoting conversion of the bicarbonate ions into CO2 gas and generating an ion-depleted solution and releasing the CO2 gas and the ion-depleted solution from the desorption unit. A CO2 capture process includes contacting a CO2-containing gas with a solution in an absorption unit, to convert CO2 into ions; feeding an ion-rich solution to a desorption unit wherein carbonic anhydrase is present within the ion-rich solution to generate an ion-depleted solution and, preferably, recycling the ion-depleted solution. Methods of decreasing the CO2 desorption temperature in a desorption unit, decreasing the CO2 desorption reactor size, and decreasing the CO2 desorption energy input in a desorption unit, are also described.
摘要翻译： 用于从含有碳酸氢根离子的离子富集溶液中释放CO 2气体的酶催化脱附方法包括在离子富集溶液中提供碳酸酐酶，使得在解吸单元中允许碳酸酐酶与富含离子的溶液一起流动，同时促进 将碳酸氢根离子转化成CO 2气体并产生离子耗尽的溶液，并从解吸单元释放二氧化碳气体和离子消耗溶液。 CO 2捕获方法包括将含CO 2的气体与吸收单元中的溶液接触，以将CO 2转化为离子; 将离子富集溶液供给到解吸单元，其中碳酸酐酶存在于离子富集溶液中以产生离子贫化溶液，并且优选地循环耗尽离子的溶液。 还描述了在解吸单元中降低CO 2解吸温度，降低CO 2解吸反应器尺寸以及降低在解吸单元中输入的CO 2解吸能的方法。
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公开(公告)号：US08273155B2
公开(公告)日：2012-09-25
申请号：US13077316
申请日：2011-03-31
IPC分类号： B01D53/14
CPC分类号： B01D53/1493 , B01D53/1475 , B01D2252/20421 , B01D2252/20431 , Y02C10/06
摘要： Disclosed is a formulation for the absorption of CO2, which comprises water, at least one CO2 absorption compound and a carbonic anhydrase as an activator to enhance the absorption capacity of the CO2 absorption compound. The invention also concerns the use of carbonic anhydrase, in a CO2 absorption solution to increase the CO2 absorption rate of such solution.
摘要翻译： 公开了一种用于吸收CO 2的制剂，其包括水，至少一种CO 2吸收化合物和碳酸酐酶作为活化剂，以增强CO 2吸收化合物的吸收能力。 本发明还涉及在CO 2吸收溶液中使用碳酸酐酶以增加这种溶液的CO 2吸收速率。
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5.发明申请FORMULATION AND PROCESS FOR CO2 CAPTURE USING AMINO ACIDS AND BIOCATALYSTS 审中-公开使用氨基酸和生物水解二氧化碳捕获的配方和方法公开(公告)号：US20120129236A1
公开(公告)日：2012-05-24
申请号：US13388854
申请日：2010-08-04
CPC分类号： B01D53/62 , B01D53/1493 , B01D53/96 , B01D2252/20494 , B01D2252/205 , B01D2252/504 , B01D2252/602 , B01D2255/804 , B01D2257/504 , Y02A50/2342 , Y02C10/04 , Y02C10/06
摘要： A formulation and a process for CO2 capture, where a CO2-containing gas in contacted with water, biocatalyst and an amino acid compound, enabling the dissolution and transformation of the CO2 into bicarbonate ions and hydrogen ions, producing an ion-rich solution and a CO2-depleted gas. The amino acids may present slow absorption kinetics and having elevated stability such that absorption is enhanced in combination with the biocatalyst. The amino acid compound and the biocatalyst may be selected such that the active sites of the biocatalyst benefit from proton removal facilitated by the amino acid compounds, thus improving the CO2 absorption.
摘要翻译： 一种用于CO 2捕获的制剂和方法，其中与水接触的含CO 2气体，生物催化剂和氨基酸化合物能够将CO 2溶解和转化成碳酸氢根离子和氢离子，产生离子富集溶液和 二氧化碳耗尽气体。 氨基酸可以呈现缓慢的吸收动力学并且具有提高的稳定性，使得吸收与生物催化剂组合增强。 可以选择氨基酸化合物和生物催化剂，使得生物催化剂的活性位点受益于由氨基酸化合物促进的质子去除，从而改善了CO 2吸收。
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6.发明申请IMMOBILIZED BIOLOGICAL MATERIAL WITH IMPROVED FUNCTIONALITY AND METHOD FOR PRODUCING THE SAME 审中-公开具有改进功能的固定生物材料及其生产方法公开(公告)号：US20110097781A1
公开(公告)日：2011-04-28
申请号：US12984852
申请日：2011-01-05
申请人： Carmen Parent , Anne Belzil , Michelle Plante , Richard Lacasse
发明人： Carmen Parent , Anne Belzil , Michelle Plante , Richard Lacasse
IPC分类号： C12P3/00
CPC分类号： B01D53/84 , B01D2257/504 , C12N9/88 , C12N11/06 , Y02A50/2358 , Y02C10/02
摘要： The present invention provides methods and systems for performing biological reactions with biologically active entities immobilized on a solid support. Particularly, the invention provides a biologically active entity immobilized a support through a spacer linked to a first linker. The spacer gives the biologically active entity a certain level of free movement relatively to the support surface to which it is fixed, thereby allowing the biological reaction to take place.
摘要翻译： 本发明提供用于与固体支持物上固定的生物活性物质进行生物反应的方法和系统。 特别地，本发明提供通过与第一接头连接的间隔基固定支持体的生物活性实体。 间隔物使生物活性物质相对于其固定的支撑表面具有一定程度的自由运动，从而允许发生生物反应。
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公开(公告)号：US10220348B2
公开(公告)日：2019-03-05
申请号：US15281847
申请日：2016-09-30
申请人： CO2 SOLUTIONS INC.
发明人： Sylvie Fradette , Julie Gingras , Norman Voyer , Jonathan Carley , Glenn R. Kelly , Olivera Ceperkovic
摘要： A process for desorbing CO2 gas from an ion-rich aqueous mixture comprising bicarbonate and hydrogen ions, includes providing micro-particles in the ion-rich aqueous mixture; and feeding the ion-rich aqueous mixture into a desorption reactor; the micro-particles comprising a support material and biocatalysts supported and stabilized by the support material and being sized and provided in a concentration in the desorption reactor such that the micro-particles are carried with the ion-rich aqueous mixture to promote transformation of the bicarbonate and hydrogen ions into CO2 gas and water, thereby producing a CO2 gas stream and an ion-depleted solution.
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8.发明申请FORMULATION AND PROCESS FOR BIOCATALYTIC CO2 CAPTURE USING ABSORPTION COMPOUNDS SUCH AS DIMETHYLMONOETHANOLAMINE, DIETHYLMONOETHANOLAMINE OR DIMETHYLGLYCINE 有权使用吸收化合物如二甲基三乙醇胺，二乙氧基乙醇胺或二甲基乙酰胺的生物二氧化碳捕获的配方和方法公开(公告)号：US20140099701A1
公开(公告)日：2014-04-10
申请号：US14106102
申请日：2013-12-13
申请人： CO2 SOLUTIONS INC.
发明人： Sylvie FRADETTE , Julie GINGRAS , Jonathan CARLEY , Glenn R. KELLY , Olivera CEPERKOVIC , Geert F. VERSTEEG
IPC分类号： B01D53/62
CPC分类号： B01D53/1425 , B01D53/1475 , B01D53/1493 , B01D53/62 , B01D53/84 , B01D53/96 , B01D2251/206 , B01D2251/304 , B01D2251/306 , B01D2251/606 , B01D2252/20494 , B01D2252/205 , B01D2252/602 , B01D2255/804 , B01D2257/504 , C12N9/88 , C12Y402/01001 , Y02C10/04 , Y02C10/06 , Y02P20/59
摘要： A formulation and process for capturing CO2 use an absorption mixture containing water, biocatalysts and an absorption compound selected from dimethylmonoethanolamine (DMMEA), diethylmonoethanolamine (DEMEA), and dimethylglycine. The process may include contacting a CO2-containing gas with the absorption mixture to enable dissolution and transformation of CO2 into bicarbonate and hydrogen ions, thereby producing a CO2-depleted gas and an ion-rich solution, followed by subjecting the ion-rich solution to desorption.
摘要翻译： 用于捕获CO 2的制剂和方法使用含有水，生物催化剂和选自二甲基单乙醇胺（DMMEA），二乙基单乙醇胺（DEMEA）和二甲基甘氨酸的吸收化合物的吸收混合物。 该方法可以包括使含CO 2的气体与吸收混合物接触以使CO 2溶解和转化成碳酸氢盐和氢离子，从而产生贫CO 2的气体和富含离子的溶液，随后将富含离子的溶液 解吸。
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9.发明申请ENZYMATIC PROCESS AND BIOREACTOR USING ELONGATED STRUCTURES FOR CO2 CAPTURE TREATMENT 审中-公开使用延长结构的二氧化碳捕集处理的酶法和生物反应器公开(公告)号：US20130052720A1
公开(公告)日：2013-02-28
申请号：US13508246
申请日：2010-11-04
申请人： Sylvie Fradette , Anne Belzil , Melanie Dion , Romain Parent
发明人： Sylvie Fradette , Anne Belzil , Melanie Dion , Romain Parent
CPC分类号： C12P3/00 , B01D53/1475 , B01D53/1493 , B01D53/18 , B01D53/62 , B01D2251/606 , B01D2252/204 , B01D2252/20478 , B01D2252/20494 , B01D2252/602 , B01D2255/804 , B01D2257/504 , C12M21/18 , C12M29/00 , Y02C10/04 , Y02C10/06 , Y02P20/152 , Y02P20/59
摘要： An enzymatic process and bioreactor use elongated structures to enhance CO2 capture treatments. The enzymatic process and bioreactor treat a fluid by catalyzing reaction (I) with carbonic anhydrase, CO2+H2OHCO−3+H+ (|) by feeding the fluid into a reaction zone wherein a plurality of elongated structures extend through the reaction zone. Each elongated structure supports a flowing liquid layer comprising droplets. Reaction (I) occurs within the flowing liquid layer in the presence of the carbonic anhydrase, to produce a gas stream and a liquid stream which are released. The process and bioreactor can be used in an absorption, desorption or combined treatment context.
摘要翻译： 酶法和生物反应器使用细长结构来增强CO2捕获处理。 催化过程和生物反应器通过将流体进料到多个细长结构延伸穿过反应区的反应区中，通过用碳酸酐酶CO 2 + H 2 OHCO 3 + H +（|）催化反应（I）来处理流体。 每个细长结构支撑包含液滴的流动液体层。 反应（I）在碳酸酐酶的存在下在流动的液体层内发生，产生释放的气流和液体流。 该方法和生物反应器可用于吸收，解吸或组合处理。
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公开(公告)号：US10226733B2
公开(公告)日：2019-03-12
申请号：US15359868
申请日：2016-11-23
申请人： CO2 SOLUTIONS INC.
摘要： A formulation and process for capturing CO2 use an absorption mixture containing water, biocatalysts and a carbonate compound. The process includes contacting a CO2-containing gas with the absorption mixture to enable dissolution and transformation of CO2 into bicarbonate and hydrogen ions, thereby producing a CO2-depleted gas and an ion-rich solution, followed by subjecting the ion-rich solution to desorption. The biocatalyst improves absorption of the mixture comprising carbonate compounds and the carbonate compound promotes release of the bicarbonate ions from the ion-rich solution during desorption, producing a CO2 gas stream and an ion-depleted solution.
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