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    Catalyst composition II
    1.
    发明申请
    Catalyst composition II 失效
    催化剂组合物II

    公开(公告)号：US20040266961A1

    公开(公告)日：2004-12-30

    申请号：US10855585

    申请日：2004-05-27

    Inventor： Gregory Adam Solan ,  Christopher James Davies

    IPC: C08F004/44 ,  B01J031/00 ,  C07F015/02 ,  C07F015/06

    CPC classification number: C07C2/32 ,  B01J31/143 ,  B01J31/146 ,  B01J31/1805 ,  B01J31/1815 ,  B01J2231/122 ,  B01J2231/20 ,  B01J2531/0258 ,  B01J2531/16 ,  B01J2531/72 ,  B01J2531/842 ,  B01J2531/845 ,  B01J2531/847 ,  C07C2531/26 ,  C07F13/005 ,  C07F15/025 ,  C07F15/045 ,  C07F15/065 ,  C08F10/00 ,  C08F110/02 ,  C07C11/02 ,  C08F2500/02 ,  C08F4/60089 ,  C08F4/7042 ,  C08F4/50 ,  C08F4/7081

    Abstract: This invention relates to a transition metal catalyst compound represented by the formula: LMX2 or (LMX2)2 wherein each M is independently a Group 7 to 11 metal, preferably a Group 7, 8, 9, or 10 metal; each L is, independently, a tridentate or tetradentate neutrally charged ligand that is bonded to M by three or four nitrogen atoms, (where at least one of the nitrogen atoms is a central nitrogen atom and at least two of the nitrogen atoms are terminal nitrogen atoms), and at least two terminal nitrogen atoms are substituted with one C3-C50 hydrocarbyl and one hydrogen atom or two hydrocarbyls wherein at least one hydrocarbyl is a C3-C50 hydrocarbyl, and the central nitrogen atom is bonded to three different carbon atoms or two different carbon atoms and one hydrogen atom; X is independently a monoanionic ligand, or two X may join together to form a bidentate dianionic ligand.

    Abstract translation: 本发明涉及由下式表示的过渡金属催化剂化合物：LMX2或（LMX2）2，其中每个M独立地是7-11族金属，优选第7,8,9或10族金属; 每个L独立地是三齿或四齿中性带电的配体，其通过三个或四个氮原子（其中至少一个氮原子是中心氮原子，并且至少两个氮原子是末端氮）键合到M上 原子），并且至少两个末端氮原子被一个C 3 -C 50烃基和一个氢原子或两个烃基取代，其中至少一个烃基是C 3 -C 50烃基，并且中心氮原子键合到三个不同的碳原子或 两个不同的碳原子和一个氢原子; X独立地是单阴离子配体，或两个X可以连接在一起以形成二齿二离子配体。

    Solid titanium catalyst component for olefin polymerization, catalyst for olefin polymerization, and process for olefin polymerization
    2.
    发明申请
    Solid titanium catalyst component for olefin polymerization, catalyst for olefin polymerization, and process for olefin polymerization 有权
    用于烯烃聚合的固体钛催化剂组分，用于烯烃聚合的催化剂和烯烃聚合方法

    公开(公告)号：US20040259721A1

    公开(公告)日：2004-12-23

    申请号：US10501888

    申请日：2004-07-20

    Inventor： Kazuhisa Matsunaga ,  Masao Nakano ,  Masaaki Ohgizawa ,  Toshiyuki Tsutsui

    IPC: B01J031/00 ,  C08F004/44

    CPC classification number: C08F110/06 ,  C08F10/00 ,  C08F4/6492 ,  C08F4/651 ,  C08F4/6545 ,  C08F2500/18 ,  C08F2500/15 ,  C08F2500/12

    Abstract: Disclosed is a catalyst for olefin polymerization comprising nullInull a solid titanium catalyst component nullSnull comprising titanium, magnesium, halogen and an electron donor (b), which is obtained by bringing a solid adduct consisting of a magnesium compound and an electron donor (a) into contact with an electron donor (b) and a liquid titanium compound by at least one method selected from (A) a method of contacting the materials in a suspended state in the coexistence of an inert hydrocarbon solvent and (B) a method of contacting the material plural times individed portions and nullIInull an organometallic compound catalyst component nullMnull containing a metal selected from the groups I to III in the periodic table. By olefin polymerization with this polymerization catalyst, an olefinic (co)polymer having high stereospecificity can be obtained with high activity.

    Abstract translation: 公开了一种用于烯烃聚合的催化剂，其包含[I]包含钛，镁，卤素和电子给体（b）的固体钛催化剂组分[S]，其通过使由镁化合物和电子给体 （a）通过选自以下的至少一种方法与电子给体（b）和液体钛化合物接触：（A）在惰性烃溶剂共存下使悬浮状态的材料接触的方法和（B） 将该材料多次接触的方法和[II]含有选自元素周期表中I〜III族的金属的有机金属化合物催化剂组分[M]。 通过与该聚合催化剂的烯烃聚合，可以获得高活性的具有高立体定向性的烯属（共）聚合物。

    Metal complexes and polymerization process using same
    4.
    发明申请
    Metal complexes and polymerization process using same 有权
    金属络合物和聚合方法使用相同

    公开(公告)号：US20040249092A1

    公开(公告)日：2004-12-09

    申请号：US10855815

    申请日：2004-05-27

    Inventor： Shaoguang Feng ,  Ravi B. Shankar ,  Francis J. Timmers

    IPC: C08F004/44

    CPC classification number: C07F17/00 ,  C08F4/65908 ,  C08F10/00 ,  C08F2420/02 ,  C08F2420/06 ,  C08F4/6592

    Abstract: A metal complex useful as a component of a catalyst composition for addition polymerizations comprising an anionic, polycyclic, fused ring ligand system containing at least 4 fused rings, at least one such ring comprising at least one heteroatom, said ligand being bonded to M by means of delocalized null-electrons and an addition polymerization process using the same.

    Abstract translation: 可用作加成聚合反应催化剂组合物的组分的金属络合物，其包含含有至少4个稠环的阴离子，多环，稠环配体体系，至少一个这样的环包含至少一个杂原子，所述配体通过 的离域π电子和使用其的加成聚合方法。

    TRIPLE-DECKER CATALYSTS BASED ON DELOCALIZED DIANIONIC LIGANDS
    6.
    发明申请
    TRIPLE-DECKER CATALYSTS BASED ON DELOCALIZED DIANIONIC LIGANDS 失效
    基于DELOCALIZED DIANIONIC LIGANDS的三重催化剂

    公开(公告)号：US20040214716A1

    公开(公告)日：2004-10-28

    申请号：US10421062

    申请日：2003-04-23

    Inventor： Sandor Nagy ,  Joel A. Mutchler

    IPC: B01J031/00 ,  C08F004/44

    CPC classification number: C08F10/00 ,  C08F4/65912 ,  C08F4/6592

    Abstract: Catalysts useful for polymerizing olefins are disclosed. The catalysts comprise an activator and a triple-decker bimetallic complex. The complex includes two Group 3-10 transition metals and a delocalized dianionic ligand that is pi-bonded to each of the metals. The behavior of the catalysts can be modified by choice of each metal, by the choice of the dianionic ligand, or by choice of the ancillary ligands. The invention provides a new way to make a large variety of catalyst systems.

    Abstract translation: 公开了可用于聚合烯烃的催化剂。 催化剂包括活化剂和三层双金属络合物。 络合物包括两个3-10族过渡金属和与每种金属π键合的离域二离子配位体。 可以通过选择每种金属，通过选择二阴离子配体或通过选择辅助配体来修饰催化剂的行为。 本发明提供了一种制造各种催化剂体系的新方法。

    Supported metallocene catalysts
    9.
    发明申请
    Supported metallocene catalysts 有权
    负载金属茂催化剂

    公开(公告)号：US20040204310A1

    公开(公告)日：2004-10-14

    申请号：US10412372

    申请日：2003-04-11

    Inventor： William J. Gauthier ,  Margaret Kerr ,  Jun Tian ,  David J. Rauscher ,  Constance Hayworth Patrick ,  Shady Henry

    IPC: B01J031/00 ,  C08F004/44

    CPC classification number: C08F10/00 ,  C08F4/65912 ,  C08F4/65927 ,  C08F110/06 ,  Y10S526/943 ,  C08F4/65916 ,  C08F2500/18 ,  C08F2500/03 ,  C08F2500/12 ,  C08F2500/17 ,  C08F2500/15

    Abstract: Supported metallocene catalysts and processes for the use of such catalysts in isotactic polymerization of a C3nullethylenically unsaturated monomer. The supported catalysts comprise a particulate silica support, an alkyl alumoxane component, and a metallocene catalyst component. The support has an average particle size of 10-50 microns, a surface area of 200-800 m2/g and a pore volume of 0.9-2.1 milliliters per gram (ml/g). Alumoxane is incorporated onto the support to provide a weight ratio of alumoxane to silica of at least 0.8:1. The metallocene is present in an amount of at least 1 weight percent of the silica and the alumoxane and is of the formula B(CpRaRb)(Flnull)MQ2 in which Flnull is an unsubstituted fluorenyl group or a fluorenyl group symmetrically substituted at the 3 and 6 positions, B is a structural bridge between Cp and Flnull, Ra is a bulky substituent in a distal position, Rb is a less bulky substituent proximal to the bridge and non-vicinal to the distal substituent, M is a Group IVB transition metal or vanadium, and Q is a halogen or a Cl-C4 alkyl group.

    Abstract translation: 负载型金属茂催化剂和在C3 +烯属不饱和单体的全同立构聚合中使用这种催化剂的方法。 载体催化剂包括颗粒二氧化硅载体，烷基铝氧烷组分和茂金属催化剂组分。 载体的平均粒度为10-50微米，表面积为200-800平方米/克，孔体积为0.9-2.1毫升/克（毫升/克）。 将Alumoxane加入到载体上以提供至少0.8:1的铝氧烷与二氧化硅的重量比。 金属茂的存在量为二氧化硅和铝氧烷的至少1重量％，并且具有式B（CpRaRb）（F1'）MQ2，其中F1'是未取代的芴基或在该位置上对称取代的芴基 3和6位，B是Cp和Fl'之间的结构桥，Ra是远端位置的大体积取代基，Rb是靠近桥的较不庞大的取代基，而与远端取代基不相邻，M是IVB族 过渡金属或钒，Q是卤素或C 1 -C 4烷基。

    Process for the polymerization of 1-butene
    10.
    发明申请
    Process for the polymerization of 1-butene 有权
    1-丁烯聚合方法

    公开(公告)号：US20040198932A1

    公开(公告)日：2004-10-07

    申请号：US10479328

    申请日：2003-12-02

    Inventor： Luigi Resconi

    IPC: C08F004/44

    CPC classification number: C08F10/08 ,  C08F4/65912 ,  C08F110/08 ,  C08F210/08 ,  Y10S526/943 ,  C08F4/65927 ,  C08F2500/17 ,  C08F2500/12 ,  C08F2500/15 ,  C08F2500/03 ,  C08F2500/20 ,  C08F210/16

    Abstract: A process for polymerizing I-butene comprising the step of contacting under polymerization null conditions 1-butene and optionally from 0 to 20% by mol of an alpha olefin with a catalyst system obtainable by contacting a bridged metallocene compound of formula (I) wherein R1 and R2 are an hydrocarbon radical A is a carbon atom, a germanium atom or a silicon atom; m is 1, 2; M is a metal of group 4 of the Periodic Table of the Elements; X, is hydrogen, a halogen atom, or a group R, OR, OS02CF2, OCOR, SR, NR2 or PR2, wherein the substituents R are hydrocarbon radical; L is a moiety of formula (IIa), (IIb), or (IIc) wherein T is an oxygen (0) or sulphur (S) atom or a CH2 group; and R3, R4, R5, R6, R7, R8 are hydrogen or hydrocarbon radicals; one or more alumoxanes or compounds able to form an alkylmetallocene cation; and optionally an organo aluminum compound.

    Abstract translation: 一种聚合1-丁烯的方法，包括在聚合条件下使“α-丁烯和任选的0至20％（摩尔）的α-烯烃与催化剂体系接触的步骤，该催化剂体系可通过将式（I）的桥接茂金属化合物 1和R 2是烃基A是碳原子，锗原子或硅原子; m是1,2; M是元素周期表第4族的金属; X是 氢，卤素原子或基团R，OR，OSO 2 CF 2，OCOR，SR，NR 2或PR 2，其中取代基R为烃基; L为式（IIa），（IIb）或（IIc） T是氧（O）或硫（S）原子或CH 2基; R 3，R 4，R 5，R 6，R 7，R 8是氢 或烃基;一种或多种能够形成烷基茂金属阳离子的铝氧烷或化合物;以及任选的有机铝化合物。

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