Thermoplastic polyurethane
    93.
    发明授权

    公开(公告)号:US12060450B2

    公开(公告)日:2024-08-13

    申请号:US16478701

    申请日:2018-02-13

    Applicant: BASF SE

    CPC classification number: C08G18/3215 C08G18/4854 C08G18/6674 C08G18/7671

    Abstract: The present invention relates to thermoplastic polyurethanes obtainable or obtained by reaction of at least one polyisocyanate composition which comprises 4,4′-MDI and at least one further polyisocyanate, at least one chain extender of general formula (I) and at least one polyol composition. The present invention further relates to a production process for such thermoplastic polyurethanes and to the use of a thermoplastic polyurethane according to the invention or of a thermoplastic polyurethane obtainable or obtained by a process according to the invention for producing extrusion products, films and molded articles.

    METHODS FOR THE PURIFICATION OF L-GLUFOSINATE

    公开(公告)号:US20240247013A1

    公开(公告)日:2024-07-25

    申请号:US18628116

    申请日:2024-04-05

    Applicant: BASF SE

    CPC classification number: C07F9/535 C07F9/301

    Abstract: Compositions and methods for isolating L-glufosinate from a composition comprising L-glufosinate and glutamate are provided. The method comprises converting the glutamate to pyroglutamate followed by the isolation of L-glufosinate from the pyroglutamate and other components of the composition to obtain substantially purified L-glufosinate. The composition comprising L-glufosinate and glutamate is subjected to an elevated temperature for a sufficient time to allow for the conversion of glutamate to pyroglutamate, followed by the isolation of L-glufosinate from the pyroglutamate and other components of the composition to obtain substantially purified L-glufosinate. The glutamate alternatively may be converted to pyroglutamate by enzymatic conversion. The purified L-glufosinate is present in a final composition at a concentration of 90% or greater of the sum of L-glufosinate, glutamate, and pyroglutamate. In some embodiments, a portion of the glutamate in the starting composition may be separated from the L-glufosinate using a crystallization step. Solid forms of L-glufosinate materials, including crystalline L-glufosinate ammonium, are also described.

    (Co)polymers of hydrophobic monomers and methods of making and use thereof

    公开(公告)号:US12037433B2

    公开(公告)日:2024-07-16

    申请号:US16970392

    申请日:2019-02-14

    Applicant: BASF SE

    Abstract: Described herein are methods of making a composition, the method comprising polymerizing monomers comprising a hydrophobic monomer in the presence of a solid grade oligomer, thereby forming a (co)polymer derived from the hydrophobic monomer, wherein the (co)polymer is derived from 5% by weight to 100% by weight of the hydrophobic monomer based on the total monomer weight. The hydrophobic monomer has a solubility in water of 0.2 g/100 g or less as measured at 20° C. The hydrophobic monomer comprises a substituted or unsubstituted C10-C22 alkyl (meth)acrylate, a substituted or unsubstituted C8-C20 alkenyl (meth)acrylate, a substituted or unsubstituted C5-C12 cycloalkyl (meth)acrylate, or a combination thereof. In some examples, the hydrophobic monomer can comprise lauryl (meth)acrylate, stearyl (meth)acrylate, heptadecyl (meth)acrylate, linoleyl (meth)acrylate, behenyl acrylate, cyclohexyl (meth)acrylate, isodecyl (meth)acrylate), nonyl (meth)acrylate, tridecyl (meth)acrylate, pentadecyl (meth)acrylate, 3-methylbut-2-enyl methacrylate, 3,7-dimethylocta-2,6-dienyl (meth)acrylate, or a combination thereof.

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