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公开(公告)号:US20180327646A1
公开(公告)日:2018-11-15
申请号:US15569404
申请日:2016-04-25
Applicant: THE CHEMOURS COMPANY FC, LLC
Inventor: KONSTANTINOS KONTOMARIS , MARIO JOSEPH NAPPA , TOM SPOORMAKER , KARL R KRAUSE , MICHAEL A SISK
IPC: C09K5/04
CPC classification number: C09K5/045 , C09K2205/122 , C09K2205/124 , C09K2205/126 , C09K2205/22 , C09K2205/40
Abstract: The present disclosure relates to compositions comprising 1,1,2,2-tetrafluoroethane and at least one additional compound selected from the group consisting of 1,1-difluoroethane, 1,2-difluoroethane, 1,1,1-trifluoroethane, difluoromethane, octafluorocyclobutane, 1,1,1,2,3,4,4,4-octafluoro-2-butene, 1,1,1,2,3,3,3-heptafluoropropane, 1,1,3,3,3-pentafluoropropene, 1,1,1,2,2-pentafluoropropane, 1,2,3,3,3-pentafluoropropene, pentafluoroethane, chlorodifluoromethane, 2-chloro-1,1,1,2-tetrafluoroethane, 1-chloro-1,1,2,2-tetrafluoroethane, methyl chloride, chlorofluoromethane, 1,2-dichloro-1,1,2,2-tetrafluoroethane, 1,1-dichloro-1,2,2,2-tetrafluoroethane, 1,1-difluoroethylene, and 1,1,2-trifluoroethylene and combinations thereof. These compositions are useful as refrigerants, heat transfer compositions, thermodynamic cycle (e.g. heating or cooling cycle) working fluids, aerosol propellants, foaming agents (blowing agents), solvents, cleaning agents, carrier fluids, displacement drying agents, buffing abrasion agents, polymerization media, foaming agents for polyolefins and polyurethane, gaseous dielectrics, power cycle working fluids, extinguishing agents, and fire suppression agents in liquid or gaseous form.
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公开(公告)号:US20180282514A1
公开(公告)日:2018-10-04
申请号:US15764901
申请日:2016-09-30
Applicant: THE CHEMOURS COMPANY FC, LLC
Inventor: GERALD ORONDE BROWN , JOHN CHRISTOPHER SWOREN
IPC: C08K5/1535 , B29C45/00 , B29C45/14 , H01B7/02 , H01B3/30
Abstract: The present invention relates to a three-dimensional solid polymeric article having surface effects comprising a polymer composition and 0.1 to 20% by weight of a hydrophobic compound, based on the total weight of the solid polymeric article, where the hydrophobic compound is intermixed throughout the polymer composition and throughout three-dimensional solid polymeric article; and where the hydrophobic compound is selected from a cyclic alcohol which is substituted with at least two hydrophobic groups.
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公开(公告)号:US20180231281A1
公开(公告)日:2018-08-16
申请号:US15939644
申请日:2018-03-29
Applicant: THE CHEMOURS COMPANY FC, LLC
Inventor: DENIS CLODIC , Youssef Riachi , Mary E. Koban
CPC classification number: F25B40/02 , F25B40/00 , F25B49/027 , F25B2339/046 , F25B2400/121 , F28D1/0452 , F28D1/05333 , F28D1/05383 , F28D1/05391 , F28D2021/007 , F28D2021/0071
Abstract: A multi-step method is disclosed for exchanging heat in a vapor compression heat transfer system having a working fluid circulating therethrough. The method includes the step of circulating a working fluid comprising a fluoroolefin to an inlet of a first tube of an internal heat exchanger, through the internal heat exchanger and to an outlet thereof. Also disclosed are vapor compression heat transfer systems for exchanging heat. The systems include an evaporator, a compressor, a dual-row condenser and an intermediate heat exchanger having a first tube and a second tube. A disclosed system involves a dual-row condenser connected to the first and second intermediate heat exchanger tubes. Another disclosed system involves a dual-row evaporator connected to the first and second intermediate heat exchanger tubes.
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公开(公告)号:US10011617B2
公开(公告)日:2018-07-03
申请号:US14847199
申请日:2015-09-08
Applicant: THE CHEMOURS COMPANY FC LLC
Inventor: John Christopher Sworen , Gerald Oronde Brown , Tatsiana Haidzinskaya , Ewa Kohler
CPC classification number: C07F7/10 , C01P2004/64 , C07F7/1804 , C07F7/28 , C09C1/043 , C09C1/3072 , C09C1/3081 , C09C1/309 , C09C1/3669 , C09C1/3684 , C09C1/3692 , C09C1/407 , C09C3/12
Abstract: The invention relates to isocyanate derived organosilanes and the use thereof. The isocyanate derived organosilanes can be reacted with inorganic substrates, such as oxide particles, to result in a surface modified inorganic substrate.
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公开(公告)号:US20180127338A1
公开(公告)日:2018-05-10
申请号:US15575526
申请日:2016-05-20
Applicant: THE CHEMOURS COMPANY FC, LLC
Inventor: Xuehui SUN , Mario Joseph NAPPA , Karl KRAUSE
IPC: C07C17/087 , C07C17/20 , C07C19/10
CPC classification number: C07C17/087 , C07C17/206 , C07C19/10 , C07C2527/12 , C07C2527/133
Abstract: The disclosure relates to a method for hydrofluorination of an olefin of the formula: RCX=CYZ to produce a hydrofluoroalkane of formula RCXFCHYZ or RCHXCFYZ, wherein X, Y, and Z are independently the same or different and are selected from the group consisting of H, F, Cl, Br, and C1-C6 alkyl which is partially or fully substituted with chloro or fluoro or bromo; and R is a C1-C6 alkyl which is unsubstituted or substituted with chloro or fluoro or bromo, comprising reacting the olefin with HF in the liquid-phase, in the presence of SbF5, at a temperature ranging from about −30° C. to about 65° C.
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公开(公告)号:US09879165B2
公开(公告)日:2018-01-30
申请号:US15005743
申请日:2016-01-25
Applicant: THE CHEMOURS COMPANY FC, LLC
Inventor: Barbara Haviland Minor , Velliyur Nott Mallikarjuna Rao
IPC: C09K5/04 , A62D1/00 , A62D1/02 , B60H1/32 , C08J9/12 , C08J9/14 , C09K3/30 , C10M171/00 , B01F17/00 , F25B45/00
CPC classification number: C09K5/045 , A62D1/0057 , A62D1/0071 , B01F17/0035 , B60H1/3204 , C08J9/127 , C08J9/146 , C08J9/149 , C08J2203/06 , C08J2203/12 , C08J2203/14 , C08J2203/142 , C08J2203/162 , C08J2203/182 , C08J2207/04 , C08J2375/04 , C09K3/30 , C09K2205/106 , C09K2205/11 , C09K2205/12 , C09K2205/122 , C09K2205/126 , C09K2205/132 , C09K2205/134 , C09K2205/22 , C09K2205/32 , C10M171/008 , C10M2203/022 , C10M2203/024 , C10M2203/065 , C10M2203/1006 , C10M2205/0206 , C10M2207/2835 , C10M2209/043 , C10M2209/1033 , C10N2220/302 , C10N2220/303 , C10N2240/30 , F25B45/00
Abstract: The present invention relates to compositions for use in refrigeration, air-conditioning, and heat pump systems wherein the composition comprises a fluoroolefin and at least one other component. The compositions of the present invention are useful in processes for producing cooling or heat, as heat transfer fluids, foam blowing agents, aerosol propellants, and fire suppression and fire extinguishing agents.
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公开(公告)号:US20170342177A1
公开(公告)日:2017-11-30
申请号:US15532063
申请日:2015-12-01
Applicant: THE CHEMOURS COMPANY FC, LLC
Inventor: SHENG PENG , PHAN LINH TANG , MING HONG HUNG , RONALD EARL USCHOLD
IPC: C08F214/18 , C08F214/20 , C08F214/26
CPC classification number: C08F214/182 , C08F214/20 , C08F214/22 , C08F214/26 , C08F214/265 , C08J5/18 , C08J2327/12 , C08J2327/18 , C09D127/12
Abstract: The present invention provides 1,3,3,3-tetrafluoropropene (HFO-1234ze) copolymers comprising 1,3,3,3-tetrafluoropropene and one or more comonomers selected from the group consisting of vinyl fluoride (VF), vinylidene fluoride (VF2), tetrafluoroethylene (TFE), chlorotrifluoroethylene (CTFE), hexafluoropropylene (HFP), and perfluoro(alkyl vinyl ether) (PAVE), wherein said alkyl contains 1 to 5 carbon atoms, the copolymers being a fluoroplastic or a fluoroelastomer, depending upon monomer content.
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公开(公告)号:US09758452B2
公开(公告)日:2017-09-12
申请号:US15114944
申请日:2015-02-06
Applicant: THE CHEMOURS COMPANY FC, LLC
Inventor: Ivan Sergeyevich Baldychev , Stephan M Brandstadter , Patricia Cheung , Mario Joseph Nappa
IPC: C07C17/25 , C07C17/23 , C07C17/281 , C07C21/18 , C07C17/357 , C07C17/354
CPC classification number: C07C17/25 , C07C17/23 , C07C17/281 , C07C17/354 , Y02P20/125 , Y02P20/582 , C07C21/18
Abstract: Disclosed is a process for the preparation of cis-1,1,1,4,4,4-hexafluoro-2-butene comprising contacting 1,1,1-trifluorotrichloroethane with hydrogen in the presence of a catalyst comprising ruthenium to produce a product mixture comprising 1316mxx, recovering said 1316mxx as a mixture of Z- and E-isomers, contacting said 1316mxx with hydrogen, in the presence of a catalyst selected from the group consisting of copper on carbon, nickel on carbon, copper and nickel on carbon and copper and palladium on carbon, to produce a second product mixture, comprising E- or Z-CFC-1326mxz, and subjecting said second product mixture to a separation step to provide E- or Z-1326mxz. The E- or Z-1326mxz can be dehydrochlorinated in an aqueous basic solution with an alkali metal hydroxide in the presence of a phase transfer catalyst to produce hexafluoro-2-butyne, which can then be selectively hydrogenated to produce Z-1,1,1,4,4,4-hexafluoro-2-butene using either Lindlar's catalyst, or a palladium catalyst further comprising a lantanide element or silver.
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公开(公告)号:US20170210869A1
公开(公告)日:2017-07-27
申请号:US15405374
申请日:2017-01-13
Applicant: THE CHEMOURS COMPANY FC, LLC
Inventor: ERNEST BYRON WYSONG , BRUCE P. HITCHENS
CPC classification number: C08J9/146 , C08G18/1833 , C08G18/42 , C08G18/76 , C08J2201/022 , C08J2203/142 , C08J2203/162 , C08J2203/182 , C08J2205/046 , C08J2205/052 , C08J2205/10 , C08J2207/04 , C08J2375/04 , C08J2375/06
Abstract: A composition is provided comprising 55 to 75 wt % Z-1,1,1,4,4,4-hexafluoro-2-butene and 45 to 25 wt % E-1,1,1,4,4,4-hexafluoro-2-butene, the combined weight of these isomers totaling 100 wt %, along with a process comprising forming a foamed reaction product obtained by reacting polyisocyanate with active hydrogen-containing compound such as polyol in the presence of this composition as a blowing agent to obtain the foamed reaction product, such as polyurethane or polyisocyanurate.
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公开(公告)号:US20170198070A1
公开(公告)日:2017-07-13
申请号:US15461768
申请日:2017-03-17
Applicant: THE CHEMOURS COMPANY FC, LLC
Inventor: PAUL DOUGLAS BROTHERS , SUBHASH VISHNU GANGAL
CPC classification number: C08F14/26 , C08F14/18 , C08F214/262 , C08K3/20 , C08L27/18 , C08L2201/54 , C08F2/16
Abstract: A process comprising polymerizing at least one fluorinated monomer in an aqueous medium containing initiator and polymerization agent to form an aqueous dispersion of particles of fluoropolymer, the polymerization agent comprising: fluoropolyether acid or salt thereof having a number average molecular weight of at least about 800 g/mol; and fluorosurfactant having the formula: [R1—On-L-A−]Y+ wherein: R1 is a linear or branched partially or fully fluorinated aliphatic group which may contain ether linkages; n is 0 or 1; L is a linear or branched alkylene group which may be nonfluorinated, partially fluorinated or fully fluorinated and which may contain ether linkages; A− is an anionic group selected from the group consisting of carboxylate, sulfonate, sulfonamide anion, and phosphonate; and Y+ is hydrogen, ammonium or alkali metal cation; with the proviso that the chain length of R1—On-L- is not greater than 6 atoms.
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