公开(公告)号：US20230332348A1

公开(公告)日：2023-10-19

申请号：US18025427

申请日：2021-09-07

Applicant: THE CHEMOURS COMPANY FC, LLC

Inventor： JOHN CHRISTOPHER SWOREN ,  GERALD ORONDE BROWN ,  CHARLES K. KARANJA ,  AMY LIZABETH WARREN

IPC: D06M15/647 ,  C08G77/46 ,  C08L83/12 ,  D06M13/328 ,  D06M13/188 ,  D06M15/263 ,  D06M15/248

CPC classification number: D06M15/647 ,  C08G77/46 ,  C08L83/12 ,  D06M13/328 ,  D06M13/188 ,  D06M15/263 ,  D06M15/248 ,  D06M2200/12 ,  D06M2200/01 ,  D06M2101/06

Abstract: Described is a fibrous substrate treatment composition having a) 20-99.5% by weight of a silicone polyether polymer and b) 0.5-4% by weight of a cationic surfactant or a mixture of cationic and nonionic surfactant; wherein the silicone polyether polymer has 6-100% by weight of formula (I) or (II) and 0-94% by weight of repeat units from ethylenically unsaturated comonomers;




wherein a and b are integers of 1 to 40 where a+b is an integer of at least 2; c and d are integers of 0 to 20; e is an integer of 1 to 40; X is a linear or branched C1-C4 alkylene group; R1 is a C1-C4 alkyl group; and R2 is —C(R1)═CH2 or polymer backbone unit —[C(R1)—CH2]— bonded at C(R1). Treatments exhibit improved balance of water repellency and oily stain release performance.

公开(公告)号：US20190256729A1

公开(公告)日：2019-08-22

申请号：US16344194

申请日：2017-10-31

Applicant: THE CHEMOURS COMPANY FC, LLC

Inventor： GERALD ORONDE BROWN ,  TESS CROSETTO ,  EWA KOHLER ,  JOHN CHRISTOPHER SWOREN

IPC: C09D133/10 ,  C09D133/02 ,  C09D7/65 ,  C08L83/10

Abstract: The present invention relates to a coating composition having a coating base and 0.1 to 10% by weight of an additive compound, based on the total solids weight of the coating, where the additive compound is at least one of an alkali metal salt of poly(meth)acrylic acid or copolymer thereof, ammonium compound or amine salt of poly(meth)acrylic acid or copolymer thereof, silicone polyether, alkali metal salt of silicone polyether carboxylate, ammonium compound or amine salt of silicone polyether carboxylate, salt of hydrolyzed α-olefin/maleic anhydride copolymer, salt of esterified α-olefin/maleic anhydride copolymer, α-olefin/maleic anhydride copolymer amic acid resin or salt thereof, polycarboxylate calcium sequestrants, or mixtures thereof; and where the coating base is an architectural paint, architectural stain, or architectural clear coating. Such coatings exhibit improved stain cleaning performance.

公开(公告)号：US20160090560A1

公开(公告)日：2016-03-31

申请号：US14851484

申请日：2015-09-11

Applicant: THE CHEMOURS COMPANY FC LLC

Inventor： JOHN CHRISTOPHER SWOREN ,  GERALD ORONDE BROWN ,  SARA LYONS ,  EWA KOHLER

IPC: C11D3/32 ,  D06M13/144 ,  C11D3/00

CPC classification number: C11D3/323 ,  C11D3/0005 ,  C11D3/0036 ,  C11D3/32 ,  C11D3/3454 ,  C11D3/349 ,  C11D3/3726 ,  D06M13/144 ,  D06M15/564 ,  D06M15/568 ,  D06M15/572 ,  D06M2200/12

Abstract: The present invention discloses a method of imparting water repellency and optionally stain release to fibrous substrates by contacting a fibrous substrate with a non-fluorinated laundry treatment composition inside a laundry machine. The laundry treatment composition contains a hydrophobic organic urethane compound having a urethane linkage and the residue of a substituted cyclic or acyclic sugar alcohol. Laundry additive compositions containing a first laundry treatment composition, having a hydrophobic organic urethane compound, and a second laundry treatment composition are also included.

Abstract translation: 本发明公开了一种通过使纤维基材与洗衣机内部的非氟化衣物处理组合物接触来赋予防水性和任选的将纤维基材去污的方法。 衣物处理组合物含有具有氨基甲酸酯键的疏水性有机聚氨酯化合物和取代的环状或无环状糖醇的残基。 还包括含有具有疏水性有机聚氨酯化合物的第一衣物处理组合物和第二衣物处理组合物的洗衣添加剂组合物。

公开(公告)号：US20190040270A1

公开(公告)日：2019-02-07

申请号：US15764908

申请日：2016-09-30

Applicant: THE CHEMOURS COMPANY FC, LLC

Inventor： GERALD ORONDE BROWN ,  JOHN CHRISTOPHER SWOREN

IPC: C09D7/63 ,  C09D4/00

Abstract: The present invention relates to a coated article comprising a partial or complete coating on the surface of an article, wherein the coating comprises a coating base and 0.1 to 5% by weight of a hydrophobic compound, based on the total solids weight of the coating, selected from a hydrophobic cyclic or acyclic alcohol, and the coating has a film thickness of at least 0.1 mils.

公开(公告)号：US20180282514A1

公开(公告)日：2018-10-04

申请号：US15764901

申请日：2016-09-30

Applicant: THE CHEMOURS COMPANY FC, LLC

Inventor： GERALD ORONDE BROWN ,  JOHN CHRISTOPHER SWOREN

IPC: C08K5/1535 ,  B29C45/00 ,  B29C45/14 ,  H01B7/02 ,  H01B3/30

Abstract: The present invention relates to a three-dimensional solid polymeric article having surface effects comprising a polymer composition and 0.1 to 20% by weight of a hydrophobic compound, based on the total weight of the solid polymeric article, where the hydrophobic compound is intermixed throughout the polymer composition and throughout three-dimensional solid polymeric article; and where the hydrophobic compound is selected from a cyclic alcohol which is substituted with at least two hydrophobic groups.

公开(公告)号：US20160090687A1

公开(公告)日：2016-03-31

申请号：US14852842

申请日：2015-09-14

Applicant: THE CHEMOURS COMPANY FC LLC

Inventor： JOHN CHRISTOPHER SWOREN ,  GERALD ORONDE BROWN ,  TATSIANA HAIDZINSKAYA ,  EWA KOHLER

IPC: D06M15/277 ,  D06M15/273

CPC classification number: D06M15/277 ,  C08F220/24 ,  C08G18/283 ,  C08G18/284 ,  C08G18/2885 ,  C08G18/6283 ,  C08G18/7831 ,  C08G18/791 ,  C08G18/8108 ,  C08G18/8116 ,  C09D133/066 ,  C09D133/14 ,  C09D175/04 ,  D06M15/263 ,  D06M15/273 ,  D06M15/285 ,  D06M15/564 ,  D06M15/576 ,  D06M2101/06 ,  D06M2101/32 ,  D06M2200/01 ,  D06M2200/12 ,  C08F2220/283 ,  C08F2220/1891 ,  C08F220/58 ,  C08F220/20 ,  C08F214/06 ,  C08F2220/346 ,  C08F212/14

Abstract: Polymers are described having repeat units of Formula (I): wherein R3 is H or alkyl group; x and t are positive integers; Q is C(O)O, C(O)NH, or direct bond; D is alkylene, arylene, or (CH2CH2O)n(CH(CH3)CH2O)m; E is O, S, NR5, or direct bond; R5 is H or alkyl; G is the residue of a polyisocyanate; V is a urethane, urea, or thiourea that bonds to other parts of the polymer compound or to a monovalent blocking group; s is 1 to 5; Y is O or a substituted or unsubstituted arylene group; A is an alkylene group; w, v, and y are 0 or 1; X is the residue of a cyclic or acyclic sugar alcohol which is substituted with —R1, —C(O)R1, —(CH2CH2O)n(CH(CH3)CH2O)mR2, —(CH2CH2O)n(CH(CH3)CH2O)mC(O)R1, or mixtures thereof; n and m are independently 0 to 20; R1 is independently an alkyl group; and R2 is independently —H or alkyl group.

Abstract translation: 描述具有式（I）的重复单元的聚合物：其中R 3是H或烷基; x和t是正整数; Q是C（O）O，C（O）NH或直接键; D是亚烷基，亚芳基或（CH 2 CH 2 O）n（CH（CH 3）CH 2 O）m; E是O，S，NR5或直接键; R5是H或烷基; G是多异氰酸酯的残基; V是与聚合物化合物的其它部分键合或单价封闭基团的氨基甲酸酯，脲或硫脲; s是1到5; Y是O或取代或未取代的亚芳基; A是亚烷基; w，v和y分别为0或1; X是被-R1，-C（O）R 1， - （CH 2 CH 2 O）n（CH（CH 3）CH 2 O）m R 2， - （CH 2 CH 2 O）n（CH（CH 3）CH 2 O）取代的环状或非环状糖醇的残基 ）mC（O）R 1，或其混合物; n和m独立地为0至20; R1独立地是烷基; R2独立地为-H或烷基。

公开(公告)号：US20160090505A1

公开(公告)日：2016-03-31

申请号：US14862293

申请日：2015-09-23

Applicant: THE CHEMOURS COMPANY FC LLC

Inventor： JOHN CHRISTOPHER SWOREN ,  GERALD ORONDE BROWN ,  TATSIANA HAIDZINSKAYA

IPC: C09D175/04 ,  D06M15/273 ,  D06M15/564

CPC classification number: C09D175/04 ,  C08G18/3221 ,  C08G18/7831 ,  C08G18/792 ,  D06M15/273 ,  D06M15/564 ,  D10B2201/02 ,  D10B2331/04

Abstract: A polymer composition with (A) a first poly(meth)acrylate polymer or urethane polymer; and (B) a second poly(meth)acrylate polymer or urethane polymer which has a residue X incorporated therein, where X is the residue of a cyclic or acyclic sugar alcohol which is substituted with at least one —R1; —C(O)R1; —(CH2CH2O)n(CH(CH3)CH2O)mR2; —(CH2CH2O)n(CH(CH3)CH2O)mC(O)R1; or mixtures thereof; where the cyclic or acyclic sugar alcohol is selected from a saccharide, reduced sugar, aminosaccharide, aldonic acid, or aldonic acid lactone; wherein each n is independently 0 to 20; each m is independently 0 to 20; m+n is greater than 0; each R1 is independently a linear or branched alkyl group having 5 to 29 carbons optionally comprising at least 1 unsaturated bond; and each R2 is independently —H, a linear or branched alkyl group having 6 to 30 carbons optionally comprising at least 1 unsaturated bond, or mixtures thereof.

Abstract translation: 具有（A）第一聚（甲基）丙烯酸酯聚合物或聚氨酯聚合物的聚合物组合物; 和（B）其中含有残基X的第二聚（甲基）丙烯酸酯聚合物或氨基甲酸酯聚合物，其中X是被至少一个-R 1取代的环状或非环状糖醇的残基; -C（O）R 1; - （CH 2 CH 2 O）n（CH（CH 3）CH 2 O）m R 2; - （CH 2 CH 2 O）n（CH（CH 3）CH 2 O）m C（O）R 1; 或其混合物; 其中环状或非环状糖醇选自糖，还原糖，氨基糖，醛糖酸或醛糖酸内酯; 其中每个n独立地为0至20; 每个m独立地为0至20; m + n大于0; 每个R 1独立地是具有5至29个碳的直链或支链烷基，任选地包含至少1个不饱和键; 并且每个R 2独立地为-H，具有6至30个碳的直链或支链烷基，任选地包含至少1个不饱和键，或其混合物。

公开(公告)号：US20190256739A1

公开(公告)日：2019-08-22

申请号：US16344199

申请日：2017-10-31

Applicant: THE CHEMOURS COMPANY FC, LLC

Inventor： GERALD ORONDE BROWN ,  TESS CROSETTO ,  EWA KOHLER ,  JOHN CHRISTOPHER SWOREN

IPC: C09D183/12 ,  C09D133/02 ,  C09D7/63 ,  D06M15/267 ,  D06M15/647 ,  C09D7/65

Abstract: The present invention relates to a coating composition with 10 to 100% by weight of a non-fluorinated compound mixture, which comprises at least one compound b and at least one compound a, c, or d: a) alkali metal salt of poly(meth)acrylic acid, alkali metal salt of poly(meth)acrylic acid copolymer, ammonium compound or amine salt of poly(meth)acrylic acid, ammonium compound or amine salt of poly(meth)acrylic acid copolymer, or mixtures thereof; b) silicone polyether, alkali metal salt of silicone polyether carboxylate, ammonium compound or amine salt of silicone polyether carboxylate, or mixtures thereof; c) salt of hydrolyzed α-olefin/maleic anhydride copolymer, salt of esterified α-olefin/maleic anhydride copolymer, α-olefin/maleic anhydride copolymer amic acid resin or salt thereof, or mixtures thereof; or d) polycarboxylate calcium sequestrants or mixtures thereof. Such coatings exhibit improved soil and stain cleaning performance.

公开(公告)号：US20170268165A1

公开(公告)日：2017-09-21

申请号：US15617272

申请日：2017-06-08

Applicant: THE CHEMOURS COMPANY FC, LLC

Inventor： JOHN CHRISTOPHER SWOREN ,  GERALD ORONDE BROWN ,  TATSIANA HAIDZINSKAYA ,  EWA KOHLER

IPC: D06M15/277 ,  D06M15/576 ,  C09D133/14 ,  C09D133/06 ,  C08F220/24 ,  C08G18/28 ,  C08G18/81 ,  C08G18/79 ,  C08G18/62 ,  D06M15/564 ,  C09D175/04 ,  C08G18/78 ,  D06M15/273 ,  D06M15/263 ,  D06M15/285

CPC classification number: D06M15/277 ,  C08F220/24 ,  C08G18/283 ,  C08G18/284 ,  C08G18/2885 ,  C08G18/6283 ,  C08G18/7831 ,  C08G18/791 ,  C08G18/8108 ,  C08G18/8116 ,  C09D133/066 ,  C09D133/14 ,  C09D175/04 ,  D06M15/263 ,  D06M15/273 ,  D06M15/285 ,  D06M15/564 ,  D06M15/576 ,  D06M2101/06 ,  D06M2101/32 ,  D06M2200/01 ,  D06M2200/12 ,  C08F2220/283 ,  C08F2220/1891 ,  C08F220/58 ,  C08F220/20 ,  C08F214/06 ,  C08F2220/346 ,  C08F212/14

Abstract: Polymers are described having repeat units of Formula (I): wherein R3 is H or alkyl group; x and t are positive integers; Q is C(O)O, C(O)NH, or direct bond; D is alkylene, arylene, or (CH2CH2O)n(CH(CH3)CH2O)m; E is O, S, NR5, or direct bond; R5 is H or alkyl; G is the residue of a polyisocyanate; V is a urethane, urea, or thiourea that bonds to other parts of the polymer compound or to a monovalent blocking group; s is 1 to 5; Y is O or a substituted or unsubstituted arylene group; A is an alkylene group; w, v, and y are 0 or 1; X is the residue of a cyclic or acyclic sugar alcohol which is substituted with —R1, —C(O)R1, —(CH2CH2O)n(CH(CH3)CH2O)mR2, —(CH2CH2O)n(CH(CH3)CH2O)mC(O)R1, or mixtures thereof; n and m are independently 0 to 20; R1 is independently an alkyl group; and R2 is independently —H or alkyl group.

公开(公告)号：US20160090438A1

公开(公告)日：2016-03-31

申请号：US14863830

申请日：2015-09-24

Applicant: THE CHEMOURS COMPANY FC LLC

Inventor： JOHN CHRISTOPHER SWOREN ,  GERALD ORONDE BROWN ,  TATSIANA HAIDZINSKAYA

IPC: C08G18/73 ,  C08G18/48 ,  C08G18/34 ,  D06M15/19 ,  D06M15/576 ,  D06M15/564 ,  D06M15/21 ,  C09D175/08 ,  C08G18/22

CPC classification number: C08G18/73 ,  C08G18/0828 ,  C08G18/222 ,  C08G18/225 ,  C08G18/284 ,  C08G18/2885 ,  C08G18/345 ,  C08G18/36 ,  C08G18/4833 ,  C08G18/792 ,  C08G18/83 ,  C08G2150/00 ,  C09D175/04 ,  C09D175/08 ,  D06M15/195 ,  D06M15/21 ,  D06M15/564 ,  D06M15/576 ,  D06M2200/01

Abstract: The invention relates to a compound prepared by (i) reacting (a) at least one compound selected from diisocyanate, polyisocyanate, or mixture thereof; (b) at least one isocyanate-reactive compound selected from a fluorinated alcohol; a cyclic or acyclic sugar alcohol which is substituted with at least one —R1, —C(O)R1, −(CH2CH2O)n(CH(CH3)CH2O)mR2, —(CH2CH2O)n(CH(CH3)CH2O)mC(O)R1, or mixtures thereof; or mixtures of a fluorinated alcohol and a substituted cyclic or acyclic sugar alcohol; and (c) at least one isocyanate-reactive ethylenically unsaturated compound; wherein each n is independently 0 to 20; each m is independently 0 to 20; m+n is greater than 0; each R1 is independently a linear or branched alkyl group having 5 to 29 carbons optionally comprising at least 1 unsaturated bond; each R2 is independently —H, or a linear or branched alkyl group having 6 to 30 carbons optionally comprising at least 1 unsaturated bond, or mixtures thereof; and (ii) reacting the reaction product of step (i) with a bisulfate source.

Abstract translation: 本发明涉及通过（i）使（a）至少一种选自二异氰酸酯，多异氰酸酯或其混合物的化合物反应制备的化合物; （b）至少一种选自氟化醇的异氰酸酯反应性化合物; 被至少一个-R1，-C（O）R 1， - （CH 2 CH 2 O）n（CH（CH 3）CH 2 O）m R 2， - （CH 2 CH 2 O）n（CH（CH 3）CH 2 O）m C取代的环状或非环状糖醇 （O）R 1，或其混合物; 或氟化醇和取代的环状或非环状糖醇的混合物; 和（c）至少一种异氰酸酯反应性烯属不饱和化合物; 其中每个n独立地为0至20; 每个m独立地为0至20; m + n大于0; 每个R 1独立地是具有5至29个碳的直链或支链烷基，任选地包含至少1个不饱和键; 每个R 2独立地为-H，或具有6至30个碳的直链或支链烷基，任选地包含至少1个不饱和键，或其混合物; 和（ii）使步骤（i）的反应产物与硫酸氢盐源反应。