Electrical contact outlet for anodes
    92.
    发明授权
    Electrical contact outlet for anodes 失效
    阳极电接点

    公开(公告)号:US5415954A

    公开(公告)日:1995-05-16

    申请号:US52833

    申请日:1993-04-27

    摘要: Electrical contact outlet for an anode sheet of a lithium generator with polymer electrolyte, consisting of one or more multilayer electrochemical cells. The cell comprises at least one lithium base sheet having a thickness between about 1 and 50 microns to constitute the anode and its collector and additionally includes a cathode and its collector as well as the polymer electrolyte. A lateral end of the anode sheet extends beyond corresponding ends of the cathode and the collector to constitute a projecting zone. A metallic layer consisting of at least one rigid metal which is compatible with lithium is in electrical contact with the lateral end of the anode sheet but without electronic contact with the other components of the cell. The metallic layer constitutes the external terminal of the generator when the latter is in non-finished condition. According to a variant, a conductive and cohesive intermediate metallic zone, which consists of lithium or lithium rich ductile alloys is in intimate contact with the lateral end of the anode sheet and the metallic layer mentioned above is therefore in electrical contact with the lateral end of the anode sheet by means of the intermediate zone of lithium. Generators provided with such contact outlet as well as a process for the preparation of these contact outlets are described.

    摘要翻译: 具有聚合物电解质的锂发生器的阳极片的电接触出口,由一个或多个多层电化学电池组成。 电池包括至少一个厚度在约1微米至50微米之间的锂基片,以构成阳极及其集电体,另外还包括阴极及其集电体以及聚合物电解质。 阳极片的横向端部延伸超过阴极和集电器的相应端部以构成突出区域。 由与锂相容的至少一种刚性金属组成的金属层与阳极片的侧端电接触,但与电池的其它部件没有电接触。 当后者处于未完成状态时,金属层构成发电机的外部端子。 根据一个变型,由富含锂或锂的延性合金构成的导电和内聚中间金属区域与阳极片的侧端紧密接触,因此上述金属层与外部端部电接触 通过锂的中间区形成阳极片。 描述了提供有这种接触插座的发电机以及用于制备这些接触插座的工艺。

    Production of organic cation radicals in an electrochemical cell
    93.
    发明授权
    Production of organic cation radicals in an electrochemical cell 失效
    在电化学电池中生产有机阳离子自由基

    公开(公告)号:US5260145A

    公开(公告)日:1993-11-09

    申请号:US941555

    申请日:1992-09-08

    IPC分类号: H01M6/16

    CPC分类号: H01M6/166

    摘要: Process for producing organic cation radicals using anodic oxidation of an organic molecule in an electrochemical cell containing two electrodes upon which opposite polarity may be established and a liquid electrolyte which is an ion conductive material comprising a salt in solution in a liquid consisting essentially of at least one polar aprotic solvent selected from the group consisting of linear ethers, cyclic ethers, esters, carbonates, lactones, nitrate derivatives, amides, sulfones and sulfolanes, wherein said salt is represented by one of the following formulas: ##STR1## wherein M is an alkaline or alkaline earth metal, a transition metal or a rare earth metal,RF and R'F are identical or different and each represent a perhalogen radical having from 1 to 12 carbon atoms,QF is a perfluorinated bivalent radical having from 2 to 6 carbon atoms.

    摘要翻译: 在含有两个电极的电化学电池中使用有机分子的阳极氧化制备有机阳离子自由基的方法,其中可以建立相反极性的电极,以及作为离子导电材料的液体电解质,所述液体电解质包含基本上至少由 一种选自直链醚,环醚,酯,碳酸酯,内酯,硝酸酯衍生物,酰胺,砜和环丁砜的极性非质子溶剂,其中所述盐由下式表示:M [RFSO 2 NSO 2 R'F]( I)M [RFSO2NCOR'F](II)M [RFCONCOR'F](III)其中M是碱金属或碱土金属,过渡金属或稀土金属,RF和R'F 相同或不同,并且各自表示具有1至12个碳原子的全卤基团,QF是具有2至6个碳原子的全氟化二价基团。

    Laser production of carbon-13 based on CF.sub.2 HCl
    97.
    发明授权
    Laser production of carbon-13 based on CF.sub.2 HCl 失效
    基于CF2HCl的碳-13激光生产

    公开(公告)号:US4436709A

    公开(公告)日:1984-03-13

    申请号:US350741

    申请日:1982-02-22

    IPC分类号: B01D59/34 B01D59/00

    CPC分类号: B01D59/34

    摘要: A method of producing carbon-13 using CF.sub.2 HCl as the feedstock (substrate) material in which the CF.sub.2 HCl is enriched up to a first level of C-13 by I.R. laser photodissociation and then to 90-99% C-13 by a second exchange process. In the preferred arrangement the second stage is a chemical exchange process.

    摘要翻译: 使用CF2HCl作为原料(基质)材料生产碳-13的方法,其中CF2HCl由I.R.富集至第一级C-13。 激光光解,然后通过第二次交换进行到90-99%C-13。 在优选的布置中,第二阶段是化学交换过程。

    Solid sensor for anhydrides
    98.
    发明授权
    Solid sensor for anhydrides 失效
    固体传感器用于酸酐

    公开(公告)号:US4388155A

    公开(公告)日:1983-06-14

    申请号:US174186

    申请日:1980-07-31

    CPC分类号: G01N27/4074

    摘要: The invention concerns a detector for anhydrides, present in the air or stack gases, which comprises a solid state electrolyte element containing oxy-anions of the particular anhydride to be detected. This solid state element is provided with metal areas to which potentiometric measuring means are connected. The detecting element is, preferably, sintered and may consist of one or several juxtaposed solid state compounds, according as the reference source is a gas or a solid state electrode, respectively. The electrolyte element is heated to a temperature not exceeding its fusion point. In addition, particular arrangements are provided to compensate for the oxygen content variations in air due to varying measurement conditions.

    摘要翻译: 本发明涉及存在于空气或烟道气体中的酸酐检测器,其包含含有要检测的特定酸酐的氧阴离子的固态电解质元件。 该固体元件设置有连接有电位计测量装置的金属区域。 检测元件优选地被烧结并且可以由一个或多个并置的固态化合物组成,根据参考源分别是气体或固态电极。 将电解质元件加热到不超过其熔点的温度。 此外,提供了特定的布置以补偿由于变化的测量条件而导致的空气中的氧含量变化。

    Solid state sensor for anhydrides
    99.
    发明授权
    Solid state sensor for anhydrides 失效
    用于酸酐的固态传感器

    公开(公告)号:US4282078A

    公开(公告)日:1981-08-04

    申请号:US718511

    申请日:1976-08-30

    CPC分类号: G01N27/417 G01N27/4074

    摘要: The invention concerns a detector for anhydrides, present in the air or stack gases, which comprises a solid state electrolyte element containing oxy-anions of the particular anhydride to be detected. This solid state element is provided with metal areas to which potentiometric measuring means are connected. The detecting element is, preferably, sintered and may consist of one or several juxtaposed solid state compounds, according as the reference source is a gas or a solid state electrode, respectively. The electrolyte element is heated to a temperature not exceeding its fusion point. In addition, particular arrangements are provided to compensate for the oxygen content variations in air due to varying measurement conditions.

    摘要翻译: 本发明涉及存在于空气或烟道气体中的酸酐检测器,其包含含有要检测的特定酸酐的氧阴离子的固态电解质元件。 该固体元件设置有连接有电位计测量装置的金属区域。 检测元件优选地被烧结并且可以由一个或多个并置的固态化合物组成,根据参考源分别是气体或固态电极。 将电解质元件加热到不超过其熔点的温度。 此外,提供了特定的布置以补偿由于变化的测量条件而导致的空气中的氧含量变化。