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公开(公告)号：US06254797B1
公开(公告)日：2001-07-03
申请号：US09274883
申请日：1999-03-23
IPC分类号： C08L702
CPC分类号： H01G9/038 , C01B21/0935 , C07C307/00 , H01B1/122 , H01G11/20 , H01G11/56 , H01M6/181 , H01M10/052 , H01M10/0525 , H01M10/0565 , H01M10/0567 , H01M10/0568 , H01M10/0569 , Y02E60/13
摘要： The invention relates to an ionically conductive material, to its preparation and to its uses. The material includes at least one ionic compound in solution in an aprotic solvent, chosen from the compounds (1/mM)+[(ZY)2N]−, (1/mM)+[(ZY)3C]− and (1/mM)+[(ZY)2CQ]−, in which Y denotes SO2 or POZ, Q denotes —H, —COZ or Z, each substituent Z independently denotes a fluorine atom or an optionally perfluorinated organic group which optionally contains at least one polymerizable functional group, at least one of the substituents Z denoting a fluorine atom, and M denotes a cation. Application to electrochemical generators, supercapacities, to the doping of polymers and to electrochromic devices.
摘要翻译： 本发明涉及离子导电材料及其制备及其用途。该材料包括选自化合物（1 / mM）+ [（ZY）2 N] - 的非质子溶剂中的溶液中的至少一种离子化合物， （1 / mM）+ [（ZY）3C] - 和（1 / mM）+ [（ZY）2CQ] - ，其中Y表示SO2或POZ，Q表示-H，-COZ或Z， 表示任选含有至少一个可聚合官能团的氟原子或任选的全氟化有机基团，表示氟原子的取代基Z中的至少一个，M表示阳离子。应用于电化学发生器，超电容，掺杂聚合物 和电致变色器件。
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公开(公告)号：US06682855B2
公开(公告)日：2004-01-27
申请号：US09837274
申请日：2001-04-19
IPC分类号： H01M618
CPC分类号： H01G9/038 , C01B21/0935 , C07C307/00 , H01B1/122 , H01G11/20 , H01G11/56 , H01M6/181 , H01M10/052 , H01M10/0525 , H01M10/0565 , H01M10/0567 , H01M10/0568 , H01M10/0569 , Y02E60/13
摘要： The invention relates to an tonically conductive material, to its preparation and to its uses. The material includes at least one ionic compound in solution in an aprotic solvent, chosen from the compounds (1/mM)+[(ZY)2N]−, (1/mM)+[(ZY)3C]− and (1/mM)+[(ZY)2CQ]−, in which Y denotes SO2 or POZ, Q denotes —H, —COZ or Z, each substituent Z independently denotes a fluorine atom or an optionally perfluorinated organic group which optionally contains at least one polymerizable functional group, at least one of the substituents Z denoting a fluorine atom, and M denotes a cation. Application to electrochemical generators, supercapacities, to the doping of polymers and to electrochromic devices.
摘要翻译： 本发明涉及一种导电材料，其制备及其用途。该材料包括选自化合物（1 / mM）+ [（ZY）2 N]的非质子溶剂中的至少一种离子化合物， 其中Y表示SO2或POZ，Q表示（1 / mM）+（（ZY）3C] - 和（1 / mM）+ [（ZY）2CQ] -H，-COZ或Z，每个取代基Z独立地表示任选含有至少一个可聚合官能团的氟原子或任选的全氟化有机基团，至少一个取代基Z表示氟原子，M表示阳离子。 应用于电化学发生器，超电容，掺杂聚合物和电致变色器件。
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公开(公告)号：US5916475A
公开(公告)日：1999-06-29
申请号：US537944
申请日：1995-11-21
IPC分类号： C01B21/093 , C07C307/00 , C07C311/48 , C07C317/04 , C07C317/24 , C07F9/36 , C07F9/53 , H01B1/12 , H01B1/20 , H01G9/02 , H01G9/025 , H01G11/02 , H01G11/20 , H01G11/54 , H01G11/56 , H01G11/60 , H01G11/62 , H01M4/66 , H01M6/16 , H01M6/18 , H01M10/05 , H01M10/052 , H01M10/0525 , H01M10/0565 , H01M10/0567 , H01M10/0568 , H01M10/0569 , H01M10/36 , C08L7/02
CPC分类号： H01G9/038 , C01B21/0935 , C07C307/00 , H01B1/122 , H01G11/20 , H01G11/56 , H01M10/052 , H01M10/0565 , H01M10/0567 , H01M10/0568 , H01M10/0569 , H01M6/181 , H01M10/0525 , Y02E60/13
摘要： An ionically conductive material which contains at least one ionic compound in solution in an aprotic solvent, wherein the ionic compound is selected from the group consisting of compounds of the formulae (1/mM).sup.61 ((ZY)2N).sup..crclbar., (1/mM).sup..sym. ((ZY).sub.3 C).sup..crclbar., or (1/mM).sup..sym. ((ZY).sub.2 CQ).sup..crclbar., wherein M, Z, Y and Q are as defined herein.
摘要翻译： PCT No.PCT / FR95 / 00343 Sec。 371日期：1995年11月21日 102（e）1995年11月21日日期PCT 1995年3月21日PCT PCT。 公开号WO95 / 26056 日期1995年9月28日在非质子溶剂中含有溶液中的至少一种离子化合物的离子导电材料，其中离子化合物选自式（1 / mM）61（（ZY）2 N）化合物， （ - ），（1）/（+）（（ZY）3C）（ - ）或（1 / mM）（+）（（ZY）2CQ）（ - ），其中M，Z，Y和Q为 如本文所定义。
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4.发明授权
公开(公告)号：US5883220A
公开(公告)日：1999-03-16
申请号：US915790
申请日：1997-08-21
IPC分类号： C08G65/333 , C08G73/10 , G02F1/15 , H01B1/12 , H01G9/02 , H01G9/022 , H01M4/36 , H01M4/60 , H01M4/62 , H01M6/18
CPC分类号： H01G9/022 , C08G65/33317 , C08G73/10 , G02F1/15 , H01B1/122 , H01M4/36 , H01M4/364 , H01M4/60 , H01M6/181 , Y10S430/10
摘要： The copolymer described is a segmented copolymer consisting essentially of organic segments A which have a number i of reactive ends such that i is from 1 to 6 inclusive, and segments B which have a number j of reactive ends such that j is from 1 to 6 inclusive. The segments B have redox properties and each segment A is connected to at least one segment B by a group Y and vice versa, the group Y being an ether, thioether, secondary amine, tertiary amine, secondary amide, tertiary amide, imide, quarternary ammonium group, or a group having a carbon--carbon bond. The respective weighted molar mean of i and j is 2 or more. Application to electrochemical generators and electrochromic systems.
摘要翻译： 所述的共聚物是基本上由有机区段A组成的分段共聚物，其具有数目i的反应性末端，使得i为1至6，其中包含数目j的反应性末端，使得j为1至6 包括的。 段B具有氧化还原性质，并且每个区段A通过基团Y连接至至少一个区段B，反之亦然，基团Y为醚，硫醚，仲胺，叔胺，仲酰胺，叔酰胺，酰亚胺，季胺 铵基或具有碳 - 碳键的基团。 i和j的相应加权摩尔平均值为2以上。 适用于电化学发生器和电致变色系统。
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5.发明授权Oxirane and dioxolane copolymers, process for their preparation and ionic conduction materials containing same 失效环氧乙烷和二氧戊环共聚物，其制备方法和含有它们的离子导电材料
公开(公告)号：US5552510A
公开(公告)日：1996-09-03
申请号：US193134
申请日：1994-05-27
IPC分类号： C08F299/02 , C08F283/06 , C08F290/00 , C08G4/00 , C08G65/06 , C08G65/14 , H01M6/18 , C08G2/22 , C08G2/26
CPC分类号： H01M6/181 , C08F283/065 , C08G4/00 , C08G65/06
摘要： The present invention relates to copolymers, to a process for their preparation and to their use for the production of ionically conductive materials. A copolymer according to the invention consists of monomer units corresponding to the formula --CH.sub.2 --O--CHR--CH.sub.2 O (I) and monomer units corresponding to the formula --CH.sub.2 --CHR'--O-- (II), in which: R denotes a hydrogen atom, a linear or branched alkyl radical containing from 1 to 8 carbon atoms or a radical CH.sub.3 (--O--CH.sub.2 --CH.sub.2).sub.n --O--CH.sub.2 --, in which 1.ltoreq.n.ltoreq.10; R' denotes an aliphatic radical containing an unsaturation which can be polymerized by a radical route and inert in the conditions of cationic polymerization. The copolymers can be obtained by cationic polymerization of the appropriate oxirane and dioxolane. Application to the production of ionically conductive materials.
摘要翻译： PCT No.PCT / FR93 / 00701 Sec。 371日期：1994年5月27日 102（e）日期1994年5月27日PCT提交1993年7月7日PCT公布。 第WO94 / 02534号公报 日期1994年2月3日本发明涉及共聚物，其制备方法及其用于制备离子导电材料的用途。 根据本发明的共聚物由对应于式-CH 2 -O-CHR-CH 2 O（I）的单体单元和对应于式-CH 2 -CHR'-O-（II）的单体单元组成，其中：R表示 氢原子，含有1至8个碳原子的直链或支链烷基或基团CH 3（-O-CH 2 -CH 2）n O-CH 2 - ，其中1 = n = 10; R'表示含有不饱和键的脂族基团，其可以通过自由基途径聚合并在阳离子聚合条件下是惰性的。 共聚物可以通过合适的环氧乙烷和二氧戊环的阳离子聚合得到。 适用于生产离子导电材料。
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公开(公告)号：US5350646A
公开(公告)日：1994-09-27
申请号：US945639
申请日：1992-11-06
申请人： Michel Armand , Jean-Yves Sanchez , Daniel Deroo
发明人： Michel Armand , Jean-Yves Sanchez , Daniel Deroo
IPC分类号： C08K5/00 , C08G75/32 , C08G79/02 , C08L71/02 , H01B1/06 , H01B1/12 , H01M6/16 , H01M6/18 , H01M10/40
CPC分类号： H01M6/166 , C08G75/32 , C08G79/025 , H01B1/122 , H01M6/181
摘要： The present invention relates to ionically conductive polymeric materials, to their preparation and to their use as a solid electrolyte. The materials comprise a solid solution of one or more salts in a polymer and are characterized in that the transport and the mobility of a metal cation M.sup.n+ which has the valency n, 1.ltoreq.n.ltoreq.5, are provided by at least one complex anion, corresponding to the general formula [MZ.sub.n Y.sub.p ].sup.p- formed between an anionic ligand Z.sup.-, an anionic ligand Y.sup.- and the cation M.sup.n+, with 1.ltoreq.p.ltoreq.3. Application to the formation of electrochemical generators and of electrochemical systems which make it possible to affect the transmission of light.
摘要翻译： PCT No.PCT / FR92 / 00198 Sec。 371日期：1992年11月6日 102（e）日期1992年11月6日PCT 1992年3月4日PCT公布。 出版物WO92 / 日本1992年9月17日。本发明涉及离子导电聚合物材料，其制备方法及其作为固体电解质的用途。 这些材料包括聚合物中一种或多种盐的固溶体，其特征在于具有化合价n 1，n = 5的金属阳离子Mn +的迁移率和迁移率至少由 对应于在阴离子配体Z-，阴离子配体Y-和阳离子Mn +之间形成的通式[MZnYp] p-对应于1≤n≤3的一个复合阴离子。 应用于电化学发生器和电化学系统的形成，这使得可能影响光的透射。
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7.发明授权Proton conducting polymer, and application thereof as electrolyte in electrochemical devices 失效质子导电聚合物及其在电化学装置中作为电解质的应用
公开(公告)号：US5283310A
公开(公告)日：1994-02-01
申请号：US944094
申请日：1992-09-11
IPC分类号： C08G77/26 , C08G77/22 , C08G77/28 , C08L83/04 , C08L83/08 , G02F1/15 , H01B1/12 , H01M6/18 , H01M10/052 , H01M10/0565 , C08G77/78
CPC分类号： H01M10/052 , C08G77/22 , C08G77/28 , H01B1/122 , H01M10/0565 , G02F1/1525
摘要： This invention has as its subject a basic organo-mineral proton conducting polymer, produced by copolymerization of three precursors:a precursor based upon a trialkoxysilane, onto which a methane sulphonamide group is grafted by means of an alkyl or aryl link,a "deprotonizing" precursor based upon a trialkoxysilane, onto which is grafted a group derived from a nitrogenous base, preferably an imidazoline group, by means of an alkyl or aryl link,a "plasticizing" and solvating precursor, having at least one urea group which is the product of a reaction between a primary mono-, di- or triamine D and a trialkoxysilane E onto which an isocyanate group has been grafted by means of an alkyl link.
摘要翻译： 本发明的主题为基本的有机 - 矿物质子导电聚合物，其通过三种前体的共聚产生：基于三烷氧基硅烷的前体，甲烷磺酰胺基团通过烷基或芳基键接枝在其上，“去质子化” 基于三烷氧基硅烷的前体，其上通过烷基或芳基键接受衍生自含氮碱，优选咪唑啉基的基团，具有至少一个作为产物的脲基的“增塑”和溶剂化前体 初级单 - ，二 - 或三胺D和三烷氧基硅烷E之间的反应，其上异氰酸酯基团已经通过烷基链接接枝。
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8.发明授权Monomers derived from perhalogenated sultones and polymers obtained from these monomers 失效衍生自全卤代磺内酯的单体和从这些单体获得的聚合物
公开(公告)号：US5721328A
公开(公告)日：1998-02-24
申请号：US452067
申请日：1995-05-26
申请人： Michel Armand , Jean-Yves Sanchez , Salime Sylla
发明人： Michel Armand , Jean-Yves Sanchez , Salime Sylla
IPC分类号： C07C303/38 , C07C311/02 , C07C311/03 , C07F7/08 , C07F7/12 , C08F28/00 , C08F28/02 , C08F30/08 , C08G65/14 , C08G65/22 , C08G65/337 , C08G79/02 , H01B1/12 , H01M4/60 , H01M6/18 , H01M8/10 , H01M10/052 , H01M10/0565 , C08F26/00
CPC分类号： H01M10/052 , C07C311/03 , C07F7/0834 , C08G65/14 , C08G65/22 , C08G65/226 , C08G65/337 , C08G79/02 , H01B1/122 , H01M10/0565 , H01M6/181 , H01M8/1027 , H01M8/103 , H01M8/1032 , H01M8/1039 , H01M8/1072 , Y02P70/56
摘要： The invention relates to monomers derived from perhalogenated sultones, to a process for their preparation, to the polymers obtained from the said monomers and to their use for the production of ion-conductive materials. The monomers are compounds corresponding to the formula A-CFX--SO.sub.2 Z in which A denotes one groups �sic! R.sup.3 --O--CF.sub.2 -- or R.sup.3 - or R.sup.1 R.sup.2 N--CO--; Z denotes F, Cl, --OSi(CH.sub.3).sub.3 or an ionic group, Z being other than F when A denotes R.sup.3 --O--CF.sub.2 -- or R.sup.3 -; X denotes F, Cl, H or R.sub.F, X being R.sub.F when A denotes R.sup.3 -; the radicals R.sup.1, R.sup.2 and R.sup.3 are chosen from polymerizable nonperfluorinated organic radicals; R.sub.F is chosen from perfluoroalkyl radicals and perfluoroaryl radicals. The polymers obtained from these monomers can be employed for the production of ion-conductive materials.
摘要翻译： 本发明涉及衍生自全卤代磺内酯的单体，其制备方法，从所述单体获得的聚合物及其用于生产离子导电材料的用途。 单体是对应于式A-CFX-SO 2 Z的化合物，其中A表示一个基团R 3 -O-CF 2 - 或R 3 - 或R 1 R 2 N-CO-; Z表示F，Cl，-OSi（CH3）3或离子基团，当A表示R3-O-CF2-或R3-时，Z不同于F; X表示F，Cl，H或RF，X表示当A表示R3-时为RF; 基团R1，R2和R3选自可聚合的非全氟化有机基团; RF选自全氟烷基和全氟芳基。 从这些单体获得的聚合物可用于制造离子传导材料。
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9.发明授权Monomers derived from perhalogenated sultones and polymers obtained from these monomers 失效衍生自全卤代磺内酯的单体和从这些单体获得的聚合物
公开(公告)号：US5459228A
公开(公告)日：1995-10-17
申请号：US391070
申请日：1995-02-21
申请人： Michel Armand , Jean-Yves Sanchez , Salime Sylla
发明人： Michel Armand , Jean-Yves Sanchez , Salime Sylla
IPC分类号： C07C309/07 , C07C309/09 , C07C309/10 , C07C309/17 , C07C309/82 , C07C309/84 , C07C311/02 , C07D303/22 , C07F7/08 , C07F7/18 , C08G65/14 , C08G65/22 , C08G65/32 , C08G65/334 , C08G65/337 , C08G79/02 , H01B1/12 , H01M6/18 , H01M8/10 , H01M10/052 , H01M10/0565 , C08G75/00 , C07C303/08 , C08J5/20
CPC分类号： H01M10/052 , C07C309/07 , C07C309/09 , C07C309/17 , C07C309/82 , C07C309/84 , C07F7/0834 , C07F7/1836 , C08G65/14 , C08G65/22 , C08G65/226 , C08G65/3346 , C08G65/337 , C08G79/02 , H01B1/122 , H01M10/0565 , H01M6/181 , H01M8/1027 , H01M8/103 , H01M8/1032 , H01M8/1039 , H01M8/1072 , Y02P70/56
摘要： The invention relates to monomers derived from perhalogenated sultones, to a process for their preparation, to the polymers obtained from the said monomers and to their use for the production of ion-conductive materials.The monomers are compounds corresponding to the formula A--CFX--SO.sub.2 Z in which A denotes one groups R.sup.3 O--CF.sub.2 -- or R.sup.3 -- R.sup.1 R.sup.2 N--CO--; Z denotes F, Cl, --OSi(CH.sub.3).sub.3 or an ionic group, Z being other than F when A denotes R.sup.3 O--CF.sub.2 -- or R.sup.3 --; X denotes F, Cl, H or R.sub.F, X being R.sub.F when A denotes R.sup.3 --; the radicals R.sup.1, R.sup.2 and R.sup.3 are chosen from polymerizable nonperfluorinated organic radicals; R.sub.F is chosen from perfluoroalkyl radicals and perfluoroaryl radicals.The polymers obtained from these monomers can be employed for the production of ion-conductive materials.
摘要翻译： 本发明涉及衍生自全卤代磺内酯的单体，其制备方法，从所述单体获得的聚合物及其用于生产离子导电材料的用途。 单体是对应于式A-CFX-SO 2 Z的化合物，其中A表示一个R 3 O-CF 2 - 或R 3 -R 1 R 2 N-CO-; Z表示F，Cl，-OSi（CH3）3或离子基团，当A表示R3O-CF2-或R3-时，Z不同于F; X表示F，Cl，H或RF，X表示当A表示R3-时为RF; 基团R1，R2和R3选自可聚合的非全氟化有机基团; RF选自全氟烷基和全氟芳基。 从这些单体获得的聚合物可用于制造离子传导材料。
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10.发明授权
公开(公告)号：US5446134A
公开(公告)日：1995-08-29
申请号：US84217
申请日：1993-07-08
IPC分类号： C07C317/04 , C07C317/18 , C07C317/24 , C07C317/28 , C07C317/34 , C07C317/36 , C07C317/42 , C07C317/44 , C07C317/48 , C07C323/65 , C07D207/32 , C07D207/335 , C07D207/444 , C07D311/66 , C07D311/72 , C07D311/80 , C07D311/82 , C07F9/44 , C07F17/02 , C09B11/24 , C09B69/04 , C09K9/02 , G02F1/15 , H01B1/12 , H01M4/60 , H01M6/16 , H01M6/18 , H01M8/02 , H01M8/10 , H01M10/052 , H01M10/0565 , C07D207/33 , C07D317/34
CPC分类号： C07D207/335 , C07C317/04 , C07C317/18 , C07C317/24 , C07C317/28 , C07C317/44 , C07C317/48 , C07C323/65 , C07D311/72 , C07D311/82 , C07F17/02 , C07F9/4407 , C09B11/24 , C09B69/045 , C09K9/02 , H01B1/122 , H01M10/052 , H01M10/0565 , H01M4/60 , H01M6/166 , H01M6/181 , H01M8/0289 , H01M8/10 , G02F1/1525 , Y02P70/56
摘要： Bis(perfluorosulphonyl)methanes, process for preparing same and uses thereof. The compounds of the invention are based on the formula (1/nM)+[(R.sub.F SO.sub.2).sub.2 CY].sup.- in which Y denotes an electron-attracting group chosen from --C.dbd.N and RZ groupings in which Z denotes a carbonyl grouping, sulphonyl grouping or a phosphonyl grouping and R denotes an organic monovalent grouping, M denotes a metal having valency n or an organic group capable of existing in the cationic form, R.sub.F denotes a perfluoroalkyl or perfluoroaryl grouping. Said compounds are especially useful in the production of electrochemical devices.
摘要翻译： 双（全氟磺酰基）甲烷，其制备方法及其用途。 本发明的化合物基于式（1 / nM）+ [（RFSO 2）2 C] - ，其中Y表示选自-C = N和RZ基团的吸电子基团，其中Z表示羰基基团，磺酰基 分组或膦酰基，R表示有机一价基团，M表示具有阳离子形式的化合价n的金属或有机基团，RF表示全氟烷基或全氟芳基。 所述化合物特别可用于生产电化学装置。
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