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210 条记录 (耗时 0.042 秒)

    Stabilization of Pygas for Storage
    92.
    发明申请
    Stabilization of Pygas for Storage 失效
    用于储存的Pygas的稳定化

    公开(公告)号：US20100162617A1

    公开(公告)日：2010-07-01

    申请号：US12345567

    申请日：2008-12-29

    申请人： James R. Butler

    发明人： James R. Butler

    IPC分类号： C10L1/18 ,  C07C49/303

    CPC分类号： C10G55/04 ,  C10G29/20 ,  C10G29/22 ,  C10G2300/104 ,  C10L1/1857 ,  C10L1/2222

    摘要： A method for stabilizing pyrolysis gasoline in storage involves adding an effective amount of a quinone methide compound to the pyrolysis gasoline. The quinone methide does not require oxygen for activity. Embodiments of the quinone methide do not contain nitrogen and will have a reduced tendency for ammonia production.

    摘要翻译： 在储存中稳定裂解汽油的方法包括向热解汽油中加入有效量的醌甲基化合物。 醌甲基化物质不需要氧气用于活性。 醌甲基化物的实施方案不含有氮并且具有降低的氨生产倾向。

    Process for Ethylbenzene Production
    93.
    发明申请
    Process for Ethylbenzene Production 有权
    乙苯生产工艺

    公开(公告)号：US20100081856A1

    公开(公告)日：2010-04-01

    申请号：US12568007

    申请日：2009-09-28

    申请人： James R. Butler

    发明人： James R. Butler

    IPC分类号： C07C2/66

    CPC分类号： C07C2/66 ,  C07C2529/70 ,  Y02P20/584 ,  C07C15/073

    摘要： A method of producing an alkylaromatic by the alkylation of an aromatic with an alkylating agent, such as producing ethylbenzene by an alkylation reaction of benzene, is disclosed. The method includes using an H-beta catalyst to minimize process upsets due to alkylation catalyst deactivation and the resulting catalyst regeneration or replacement. The H-beta catalyst can be used in a preliminary alkylation reactor that is located upstream of the primary alkylation reactor. The H-beta catalyst used in a preliminary alkylation reactor can reduce the deactivation of the catalyst in the primary alkylation reactor.

    摘要翻译： 公开了通过用烷基化剂烷基化烷基化制备烷基芳族化合物的方法，例如通过苯的烷基化反应制备乙苯。 该方法包括使用H-β催化剂来最小化由于烷基化催化剂失活和所得到的催化剂再生或置换导致的过程紊乱。 H-β催化剂可用于位于初级烷基化反应器上游的初步烷基化反应器。 在初步烷基化反应器中使用的H-β催化剂可以减少初级烷基化反应器中催化剂的失活。

    Using Excess Levels of Metal Salts to Improve Properties when Incorporating Polymers in Asphalt
    96.
    发明申请
    Using Excess Levels of Metal Salts to Improve Properties when Incorporating Polymers in Asphalt 审中-公开
    在沥青中加入聚合物时，使用过多的金属盐来改善其性能

    公开(公告)号：US20090149577A1

    公开(公告)日：2009-06-11

    申请号：US12369285

    申请日：2009-02-11

    申请人： James R. Butler ,  Paul J. Buras ,  William Lee

    发明人： James R. Butler ,  Paul J. Buras ,  William Lee

    IPC分类号： C08L95/00 ,  E01C7/26

    CPC分类号： C08L95/00 ,  C08L17/00 ,  C08L2207/24 ,  C08L2666/04 ,  C08L2666/08

    摘要： In methods of preparing asphalt and elastomeric polymer compositions such as polymer modified asphalt (PMA), it has been discovered that the compatibility can be improved by adding excess amounts of certain organic and inorganic metal salts beyond the proportions normally used. Suitable metal salts may be metal oxides that include, but are not necessarily limited to, zinc oxide, calcium oxide, and the like. The method of the invention also permits asphalt modified with other polymers such as ground tire rubber (GTR) to have improved compatibility. Additionally, the use of excess amounts of these metal salts helps control gel formation.

    摘要翻译： 在制备沥青和弹性体聚合物组合物如聚合物改性沥青（PMA）的方法中，已经发现通过加入超过通常使用的比例的过量的某些有机和无机金属盐可以改善相容性。 合适的金属盐可以是金属氧化物，其包括但不一定限于氧化锌，氧化钙等。 本发明的方法还允许用诸如磨碎轮胎橡胶（GTR）的其它聚合物改性的沥青具有改进的相容性。 另外，使用过量的这些金属盐有助于控制凝胶形成。

    Promotors for Controlling Acidity and Pore Size of Zeolite Catalysts for Use in Alkylation
    97.
    发明申请
    Promotors for Controlling Acidity and Pore Size of Zeolite Catalysts for Use in Alkylation 有权
    用于控制用于烷基化的沸石催化剂的酸度和孔径的促进剂

    公开(公告)号：US20080255397A1

    公开(公告)日：2008-10-16

    申请号：US12145127

    申请日：2008-06-24

    申请人： Kevin P. Kelly ,  James R. Butler

    发明人： Kevin P. Kelly ,  James R. Butler

    IPC分类号： C07C2/64 ,  B01J29/06

    CPC分类号： C07C2/66 ,  B01J29/061 ,  B01J29/7057 ,  B01J37/0009 ,  B01J2229/42 ,  C07C15/073

    摘要： A metal-modified alkylation catalyst including a metal/zeolite is provided where the metal is one or two selected from the group consisting of yttrium and a rare earth of the lanthanide series other than cerium. Where two metals are used, one may be Ce or La. The metal-promoted zeolite is useful as a molecular sieve aromatic alkylation catalyst for the production of ethylbenzene by the ethylation of benzene in the liquid phase or critical phase. An alkylation product is produced containing ethylbenzene as a primary product with the attendant production of heavier alkylated by-products of no more than 10-60 wt % of the ethyl benzene.

    摘要翻译： 提供了包含金属/沸石的金属改性烷基化催化剂，其中金属是选自钇和除了铈之外的镧系稀土稀土的一种或两种。 在使用两种金属的情况下，可以使用Ce或La，金属促进的沸石可用作通过苯在液相或临界相中乙基化生产乙苯的分子筛芳烃烷基化催化剂。 制备含有乙苯作为主要产物的烷基化产物，伴随着生产不超过乙苯的10-60重量％的较重烷基化副产物。

    Oxidative dehydrogenation of alkyl aromatic hydrocarbons
    98.
    发明申请
    Oxidative dehydrogenation of alkyl aromatic hydrocarbons 审中-公开
    烷基芳烃的氧化脱氢

    公开(公告)号：US20080166274A1

    公开(公告)日：2008-07-10

    申请号：US11650648

    申请日：2007-01-08

    申请人： James R. Butler

    发明人： James R. Butler

    IPC分类号： C07C15/44

    CPC分类号： B01J38/12 ,  B01J21/10 ,  B01J23/22 ,  B01J23/92 ,  C07C5/3332 ,  C07C2521/04 ,  C07C2521/06 ,  C07C2521/08 ,  C07C2523/02 ,  C07C2523/06 ,  C07C2523/12 ,  C07C2523/22 ,  C07C2529/89 ,  Y02P20/584 ,  C07C15/46

    摘要： Dehydrogenation processes and systems are described herein. In one embodiment, the process generally includes providing an alkyl aromatic hydrocarbon, providing a reaction zone including an oxidative dehydrogenation catalyst, introducing the alkyl aromatic hydrocarbon into the reaction zone, contacting the alkyl aromatic hydrocarbon with the oxidative dehydrogenation catalyst to form a vinyl aromatic hydrocarbon and withdrawing the vinyl aromatic hydrocarbon from the reaction zone. The process generally utilizes a catalyst to oil ratio that is at least 10:1.

    摘要翻译： 脱氢过程和系统在本文中描述。 在一个实施方案中，该方法通常包括提供烷基芳族烃，提供包括氧化脱氢催化剂的反应区，将烷基芳族烃引入反应区，使烷基芳族烃与氧化脱氢催化剂接触以形成乙烯基芳烃 并从反应区取出乙烯基芳族烃。 该方法通常使用至少10:1的催化剂与油的比例。

    Critical phase alkylation process
    100.
    发明授权
    Critical phase alkylation process 失效
    临界相烷基化方法

    公开(公告)号：US07268264B2

    公开(公告)日：2007-09-11

    申请号：US10269639

    申请日：2002-10-04

    申请人： James R. Butler ,  Kevin P. Kelly

    发明人： James R. Butler ,  Kevin P. Kelly

    IPC分类号： C07C2/68 ,  C07C15/12

    CPC分类号： C07C2/66 ,  C07C6/126 ,  C07C2529/70 ,  Y02P20/544 ,  C07C15/073

    摘要： A process for the production of ethylbenzene by the ethylation of benzene in the critical phase over a molecular sieve aromatic alkylation catalyst. An aromatic feedstock having a benzene content of at least 90 wt. % is supplied into a reaction zone into contact with a zeolite beta alkylation catalyst having a silica/alumina ratio within the range of 20-500, specifically 50-150. The alkylation catalyst is a zeolite beta specifically a lanthanum-modified zeolite beta. Ethylene is supplied to the reaction zone to provide a benzene/ethylene mole ratio of 1-15. The reaction zone is operated under conditions in which benzene is in the supercritical phase to produce an alkylation product containing ethylbenzene as a primary product with heavier alkylated by-products of no more than 60 wt. % of the ethylbenzene. The alkylation product is recovered from the reaction zone and supplied to a separation and recovery zone to separate ethylbenzene from a polyalkylated component including diethylbenzene. At least a portion of the polyalkylated component is supplied to a transalkylation reaction zone containing a molecular sieve transalkylation catalyst. The transalkylation reaction zone contains a zeolite Y catalyst and is operated under liquid phase conditions.

    摘要翻译： 通过在分子筛芳族烷基化催化剂上的临界相中苯的乙基化生产乙苯的方法。 苯含量至少为90wt。％的芳族原料。 将％加入到与二氧化硅/氧化铝比在20-500，特别是50-150范围内的沸石β烷基化催化剂接触的反应区中。 烷基化催化剂是沸石β特别是镧改性沸石β。 将乙烯供应至反应区以提供1-15的苯/乙烯摩尔比。 反应区在苯处于超临界阶段的条件下运行，以产生含有乙苯作为主要产物的烷基化产物，其中较重的烷基化副产物不超过60wt。 ％的乙苯。 将烷基化产物从反应区回收并供应至分离和回收区，以从包含二乙基苯的多烷基化组分分离乙苯。 将至少一部分多烷基化组分供应到含有分子筛烷基转移催化剂的烷基转移反应区。 烷基转移反应区含有沸石Y催化剂，并在液相条件下运行。