公开(公告)号：US06242133B1

公开(公告)日：2001-06-05

申请号：US09333935

申请日：1999-06-16

申请人： Kikuko Kato ,  Masutaka Ouchi ,  Yohei Hirota ,  Teruhiko Imoto ,  Nobuyuki Higashiyama ,  Mamoru Kimoto ,  Shin Fujitani ,  Koji Nishio

发明人： Kikuko Kato ,  Masutaka Ouchi ,  Yohei Hirota ,  Teruhiko Imoto ,  Nobuyuki Higashiyama ,  Mamoru Kimoto ,  Shin Fujitani ,  Koji Nishio

IPC分类号： H01M458

CPC分类号： H01M4/622 ,  H01M4/242 ,  H01M4/62 ,  Y10T29/49115

摘要： A hydrogen-absorbing alloy electrode for an alkaline secondary battery. The electrode is prepared by adding a transition metal salt to a paste comprising a hydrogen-absorbing alloy powder and binder. The electrode improves charge-discharge cycle performance and high rate discharge capacity at low temperature of an alkaline secondary battery.

摘要翻译： 一种用于碱性二次电池的吸氢合金电极。 通过将过渡金属盐加入到包含吸氢合金粉末和粘合剂的糊料中来制备电极。 电极提高碱性二次电池的低温充放电循环性能和高放电容量。

公开(公告)号：US6007946A

公开(公告)日：1999-12-28

申请号：US881146

申请日：1997-06-24

申请人： Mutsumi Yano ,  Mitsuzo Nogami ,  Katsuhiko Shinyama ,  Kousuke Satoguchi ,  Mitsunori Tokuda ,  Ikuo Yonezu ,  Koji Nishio ,  Masao Inoue ,  Shin Fujitani

发明人： Mutsumi Yano ,  Mitsuzo Nogami ,  Katsuhiko Shinyama ,  Kousuke Satoguchi ,  Mitsunori Tokuda ,  Ikuo Yonezu ,  Koji Nishio ,  Masao Inoue ,  Shin Fujitani

IPC分类号： H01M4/32 ,  H01M4/52 ,  H01M4/24 ,  H01M4/26

CPC分类号： H01M4/32 ,  H01M4/52 ,  Y02P70/54

摘要： In the non-sintered nickel electrode for an alkaline storage battery according to the invention, a yttrium metal powder and/or a yttrium compound powder has been added to a particulate active material comprising composite particles each consisting of a nickel hydroxide core and a sodium-doped cobalt compound shell. Because the yttrium metal powder and/or yttrium compound powder inhibits the diffusion of cobalt into the nickel hydroxide core, the non-sintered nickel electrode of the invention exhibits a high utilization efficiency not only in an initial phase of charge-discharge cycling but over a long time of use. Moreover, because the yttrium metal powder and/or yttrium compound powder enhances the oxygen overpotential, the non-sintered nickel electrode for an alkaline storage battery according to the invention shows very satisfactory charge characteristics particularly at high temperatures.

摘要翻译： 在根据本发明的碱性蓄电池的非烧结镍电极中，将钇金属粉末和/或钇化合物粉末添加到包含复合颗粒的颗粒活性材料中，每个复合颗粒由氢氧化镍芯和钠 - 掺钴复合壳。 由于钇金属粉末和/或钇化合物粉末抑制钴扩散到氢氧化镍芯中，本发明的非烧结镍电极不仅在充放电循环的初始阶段中显示出高的利用效率， 使用时间长 此外，由于钇金属粉末和/或钇化合物粉末提高氧超电势，所以根据本发明的碱性蓄电池的非烧结镍电极显示出非常令人满意的充电特性，特别是在高温下。

公开(公告)号：US5932513A

公开(公告)日：1999-08-03

申请号：US166140

申请日：1998-10-02

申请人： Hiroshi Nakamura ,  Shin Fujitani ,  Yumiko Nakamura ,  Hiroshi Watanabe ,  Ikuo Yonezu ,  Takahiro Yonesaki ,  Kouichi Nishimura

发明人： Hiroshi Nakamura ,  Shin Fujitani ,  Yumiko Nakamura ,  Hiroshi Watanabe ,  Ikuo Yonezu ,  Takahiro Yonesaki ,  Kouichi Nishimura

IPC分类号： B01J20/28 ,  B22F1/00 ,  B22F9/02 ,  C01B3/00 ,  C22C32/00 ,  F17C11/00 ,  H01M8/06 ,  B01J20/02 ,  B22F3/02

CPC分类号： F17C11/005 ,  B22F1/0014 ,  B22F1/0059 ,  B22F9/023 ,  C01B3/0005 ,  C01B3/0057 ,  C01B3/0078 ,  C01B3/0084 ,  C22C32/0094 ,  H01M8/065 ,  B22F2998/00 ,  Y02E60/321 ,  Y02E60/327 ,  Y10S420/90 ,  Y10T428/13

摘要： A container packed with a mixture of powders classified respectively into two or at least three particle-size distribution groups which are different in average particle size, the powders comprising a hydrogen absorbing alloy singly or the combination of such an alloy and a substance not absorbing hydrogen. The mixture is at least 0.03 to not greater than 0.50 in the ratio d.sub.2 /d.sub.1 wherein d.sub.1 is the average particle size of the powder having the particle-size distribution of the largest average particle size, and d.sub.2 is the average particle size of the powder having the particle-size distribution of the second largest average particle size. The weight ratio of the powder to the total weight of the powders is greater when that powder has a particle-size distribution of larger average particle size. The weight ratio of the powder having the particle-size distribution of the second largest average particle size to the powder having the particle-size distribution of the largest average particle size is at least 0.2 to not greater than 0.8.

摘要翻译： 将分散有两种或至少三种平均粒度不同的粒度分布基团的粉末混合物填充的容器，该粉末包含单独的吸氢合金或这种合金与不吸收氢的物质的组合 。 混合物的比率d2 / d1为0.03以上，0.50以下，其中，d1为粒径分布最大的平均粒径的粉末的平均粒径，d2为粉末的平均粒径 具有第二大平均粒径的粒度分布。 当粉末具有较大平均粒度的粒度分布时，粉末与粉末的总重量的重量比较大。 具有第二最大平均粒径的粒度分布的粉末与具有最大平均粒径的粒度分布的粉末的重量比至少为0.2以上且0.8以下。

公开(公告)号：US5900558A

公开(公告)日：1999-05-04

申请号：US901193

申请日：1997-07-28

申请人： Hiroshi Nakamura ,  Shin Fujitani ,  Yumiko Nakamura ,  Hiroshi Watanabe ,  Ikuo Yonezu ,  Takahiro Yonesaki ,  Kouichi Nishimura

发明人： Hiroshi Nakamura ,  Shin Fujitani ,  Yumiko Nakamura ,  Hiroshi Watanabe ,  Ikuo Yonezu ,  Takahiro Yonesaki ,  Kouichi Nishimura

IPC分类号： B01J20/28 ,  B22F1/00 ,  B22F9/02 ,  C01B3/00 ,  C22C32/00 ,  F17C11/00 ,  H01M8/06 ,  C01B3/02 ,  C22C29/00

CPC分类号： F17C11/005 ,  B22F1/0014 ,  B22F1/0059 ,  B22F9/023 ,  C01B3/0005 ,  C01B3/0057 ,  C01B3/0078 ,  C01B3/0084 ,  C22C32/0094 ,  H01M8/065 ,  B22F2998/00 ,  Y02E60/321 ,  Y02E60/327 ,  Y10S420/90 ,  Y10T428/13

摘要： A container packed with a mixture of powders classified respectively into two or at least three particle-size distribution groups which are different in average particle size, the powders comprising a hydrogen absorbing alloy singly or the combination of such an alloy and a substance not absorbing hydrogen. The mixture is at least 0.03 to not greater than 0.50 in the ratio d.sub.2 /d.sub.1 wherein d.sub.1 is the average particle size of the powder having the particle-size distribution of the largest average particle size, and d.sub.2 is the average particle size of the powder having the particle-size distribution of the second largest average particle size. The weight ratio of the powder to the total weight of the powders is greater when that powder has a particle-size distribution of larger average particle size. The weight ratio of the powder having the particle-size distribution of the second largest average particle size to the powder having the particle-size distribution of the largest average particle size is at least 0.2 to not greater than 0.8.

公开(公告)号：US5496424A

公开(公告)日：1996-03-05

申请号：US131617

申请日：1993-10-05

申请人： Shin Fujitani ,  Hiroshi Nakamura ,  Hiroshi Watanabe ,  Ikuo Yonezu ,  Toshihiko Saito

发明人： Shin Fujitani ,  Hiroshi Nakamura ,  Hiroshi Watanabe ,  Ikuo Yonezu ,  Toshihiko Saito

IPC分类号： C01B3/00 ,  C22C19/03 ,  C22F1/10

CPC分类号： C22C19/03 ,  C01B3/0057 ,  Y02E60/327 ,  Y02P20/129 ,  Y10S420/90

摘要： A hydrogen absorbing alloy represented by the general formula R.sub.1-x A.sub.x (Ni.sub.5-y B.sub.y).sub.z wherein R is Mm (misch metal) or La, A is at least one element selected from the group consisting of Ce, Nd, Pr, Sm and Y, B is at least one element selected from the group consisting of Al, Sn, V, Cr, Mn, Fe, Co and Cu, 0.ltoreq.x.ltoreq.0.5, 0

摘要翻译： 由通式R1-xAx（Ni5-yBy）z表示的吸氢合金，其中R是Mm（稀土金属）或La，A是选自Ce，Nd，Pr，Sm和Y中的至少一种元素 ，B是选自Al，Sn，V，Cr，Mn，Fe，Co和Cu中的至少一种元素，0

公开(公告)号：US5366820A

公开(公告)日：1994-11-22

申请号：US20687

申请日：1993-04-12

申请人： Masaru Tsutsumi ,  Nobuyoshi Nishizawa ,  Tsukasa Itoh ,  Takaaki Matsubayashi ,  Takehiro Yonesaki ,  Koichi Satoh ,  Akio Furukawa ,  Ikuo Yonezu ,  Shin Fujitani ,  Kenji Nasako ,  Toshihiko Saito

发明人： Masaru Tsutsumi ,  Nobuyoshi Nishizawa ,  Tsukasa Itoh ,  Takaaki Matsubayashi ,  Takehiro Yonesaki ,  Koichi Satoh ,  Akio Furukawa ,  Ikuo Yonezu ,  Shin Fujitani ,  Kenji Nasako ,  Toshihiko Saito

IPC分类号： H01M8/04 ,  H01M8/06 ,  H01M8/18

CPC分类号： H01M8/065 ,  H01M8/04089

摘要： A fuel cell system for directly converting chemical energy of a fuel into electric energy electrochemically. A fuel cell has a cathode and an anode. A main hydrogen absorbing alloy supplies hydrogen gas to the anode of the fuel cell during steady-state operation of the system. An auxiliary hydrogen absorbing alloy originally having a higher hydrogen gas absorbing/desorbing equilibrium pressure than the main hydrogen absorbing alloy at an equal temperature supplies hydrogen gas to the anode until the equilibrium pressure of the main hydrogen absorbing alloy, which is supplied an exhaust gas from the fuel cell is equal to a hydrogen gas absorbing/desorbing equilibrium pressure of the auxiliary hydrogen absorbing alloy, the auxiliary hydrogen absorbing alloy receiving the hydrogen gas from the main hydrogen absorbing alloy during steady-state operation.

摘要翻译： 燃料电池系统，用于将燃料中的化学能直接转化成电能的电能。 燃料电池具有阴极和阳极。 主要的储氢合金在系统的稳态运行期间向燃料电池的阳极供应氢气。 原始具有比主吸氢合金高的氢气吸收/解吸平衡压力的辅助吸氢合金在等温下将氢气供给到阳极，直到主吸氢合金的平衡压力从 燃料电池等于辅助吸氢合金的氢气吸收/解吸平衡压力，辅助吸氢合金在稳态运行期间从主吸氢合金接收氢气。

公开(公告)号：US5096665A

公开(公告)日：1992-03-17

申请号：US475806

申请日：1990-02-06

申请人： Shin Fujitani ,  Ikuo Yonezu ,  Toshihiko Saito

发明人： Shin Fujitani ,  Ikuo Yonezu ,  Toshihiko Saito

IPC分类号： C01B3/00 ,  C22C16/00 ,  C22C22/00 ,  C22C30/00

CPC分类号： C22C16/00 ,  C01B3/0031 ,  C01B3/0047 ,  Y02E60/327 ,  Y10S420/90

摘要： Alloys having the composition Zr(Mn.sub.1-x Co.sub.x).sub.y Al.sub.z A.sub.w are formed by adding rare-earth metals such as La, Ce, and Mm and the like or V to a Zr-Mn-Co-Al quaternary alloy, where A is at least one of rare-earth metals such as La, Ce, Mm and the like or V, and the amount x of Co substituent is the range 0

公开(公告)号：US08253386B2

公开(公告)日：2012-08-28

申请号：US10934705

申请日：2004-09-07

申请人： Akira Kinoshita ,  Shingo Tode ,  Yasufumi Takahashi ,  Hiroyuki Fujimoto ,  Ikuro Nakane ,  Shin Fujitani

发明人： Akira Kinoshita ,  Shingo Tode ,  Yasufumi Takahashi ,  Hiroyuki Fujimoto ,  Ikuro Nakane ,  Shin Fujitani

IPC分类号： H02J7/00 ,  H03K17/28 ,  H01M4/13

CPC分类号： H02J7/0031 ,  H01M4/131 ,  H01M4/133 ,  H01M4/505 ,  H01M4/525 ,  H01M4/587 ,  H01M10/0525 ,  H01M10/0587 ,  H01M10/42 ,  H01M10/44 ,  H01M10/448 ,  H02J2007/004

摘要： Capacity degradation due to charge/discharge cycles is suppressed in either a non-aqueous electrolyte secondary cell provided with a positive electrode including, as a positive electrode active material, a lithium-transition metal complex oxide having a layered structure and containing at least Ni and Mn as transition metals, and a negative electrode containing a carbon material as a negative electrode active material and having a higher initial charge-discharge efficiency than that of the positive electrode, or an assembled battery having a plurality of cells each of which is the secondary cell. A control circuit incorporated in the secondary cell or the assembled battery, or in an apparatus using the secondary cell or the assembled battery, monitors the voltage of the secondary cell or each of the cells in the assembled battery so that the end-of-discharge voltage of each cell is 2.9 V or higher.

摘要翻译： 在具有正极的非水电解质二次电池中，由于充电/放电循环而导致的容量劣化被抑制，所述正极包括作为正极活性物质的具有层状结构且至少含有Ni的锂 - 过渡金属复合氧化物 Mn作为过渡金属，以及含有作为负极活性物质的碳材料并且具有比正极更高的初始充放电效率的负极，或具有多个电池的组电池，每个电池均为次级 细胞。 集成在二次电池或组电池中的控制电路，或者在使用二次电池或组电池的装置中，监视蓄电池中的二次电池或各电池的电压，使得放电终止 每个电池的电压为2.9V或更高。

公开(公告)号：US07767343B2

公开(公告)日：2010-08-03

申请号：US10563124

申请日：2005-02-18

申请人： Koji Abe ,  Kazuhiro Miyoshi ,  Yasufumi Takahashi ,  Hiroyuki Fujimoto ,  Akira Kinoshita ,  Shingo Tode ,  Ikuro Nakane ,  Shin Fujitani

发明人： Koji Abe ,  Kazuhiro Miyoshi ,  Yasufumi Takahashi ,  Hiroyuki Fujimoto ,  Akira Kinoshita ,  Shingo Tode ,  Ikuro Nakane ,  Shin Fujitani

IPC分类号： H01M4/58 ,  H01M6/16

CPC分类号： H01M10/0525 ,  H01M4/131 ,  H01M4/485 ,  H01M4/525 ,  H01M4/587 ,  H01M10/0567 ,  H01M10/0569 ,  H01M2010/4292 ,  H01M2300/0025

摘要： A nonaqueous electrolyte secondary battery including a negative electrode containing a graphite material as the negative active material, a positive electrode containing lithium cobalt oxide as a main component of the positive active material and a nonaqueous electrolyte solution, the battery being characterized in that the lithium cobalt oxide contains a group IVA element and a group IIA element of the periodic table, the nonaqueous electrolyte solution contains 0.2-1.5% by weight of a sulfonyl-containing compound and preferably further contains 0.5-4% by weight of vinylene carbonate.

摘要翻译： 包含含有作为负极活性物质的石墨材料的负极，含有钴酸锂作为正极活性物质的主要成分的正极和非水电解液的非水电解质二次电池，其特征在于，所述锂钴 氧化物含有元素周期表IVA族元素和IIA族元素，非水电解质溶液含有0.2-1.5重量％的含磺酰基化合物，优选还含有0.5-4重量％的碳酸亚乙烯酯。

公开(公告)号：US07682748B2

公开(公告)日：2010-03-23

申请号：US11656008

申请日：2007-01-22

申请人： Masanobu Takeuchi ,  Hiroyuki Fujimoto ,  Seiji Yoshimura ,  Shin Fujitani

发明人： Masanobu Takeuchi ,  Hiroyuki Fujimoto ,  Seiji Yoshimura ,  Shin Fujitani

IPC分类号： H01M4/58

CPC分类号： H01M4/131 ,  H01M4/485 ,  H01M4/525 ,  H01M4/5825 ,  H01M4/625 ,  H01M10/0525 ,  H01M10/0569

摘要： In a nonaqueous electrolyte secondary battery having a positive electrode containing a positive electrode active material, a negative electrode containing a negative electrode active material, and a nonaqueous electrolyte, as the positive electrode active material or as the negative electrode active material, a mixture containing molybdenum dioxide and lithium titanate in a weight ratio (molybdenum dioxide:lithium titanate) of 90:10 to 50:50 is used.

摘要翻译： 在具有含有正极活性物质的正极，含有负极活性物质的负极和非水电解质的非水电解质二次电池中，作为正极活性物质或负极活性物质，含有钼 二氧化钛和钛酸锂，重量比（二氧化钛：钛酸锂）为90:10〜50:50。