公开(公告)号：US5055437A

公开(公告)日：1991-10-08

申请号：US528644

申请日：1990-05-24

申请人： Joseph A. Herbst ,  Hartley Owen ,  Paul H. Schipper

发明人： Joseph A. Herbst ,  Hartley Owen ,  Paul H. Schipper

IPC分类号： B01J29/08 ,  B01J29/40 ,  B01J29/80 ,  C10G11/05

CPC分类号： B01J29/80 ,  C10G11/05 ,  B01J2229/26 ,  B01J2229/42 ,  B01J29/084 ,  B01J29/40

摘要： A catalytic cracking catalyst mixture and process are disclosed. The mixture comprises (a) a cracking catalyst containing a matrix and a large pore molecular sieve and (b) separate additive catalysts comprising at least one of a shape selective paraffin cracking/isomerization zeolite and a shape selective aliphatic aromatization zeolite. An exemplary catalyst mixture comprises dealuminized zeolite Y, optionally containing rare earth elements in an alumina-rich matrix, an additive catalyst of HZSM-5 in a matrix, and an additional additive catalyst of gallium ZSM-5 in a matrix. The alumina-rich matrix of the cracking catalyst acts a a sodium and metals sink. The large pore molecular sieve catalyst cracks large hydrocarbons to lighter paraffins and olefins. The shape selective paraffin cracking/isomerization component cracks/isomerizes the paraffins produced by the large pore moleular sieve. The shape selective aliphatic aromatization catalyst converts light paraffins and olefins into aromatics. A single shape selective zeolite, e.g., ZSM-5 with a controlled amount of an aromatization component such as gallium, may promote both paraffin cracking/isomerization and aromatization. The additive catalysts have physical properties, e.g., size, shape, density and attrition resistance which are substantially the same as the cracking catalyst.

摘要翻译： 公开了催化裂化催化剂混合物和方法。 混合物包含（a）含有基质和大孔分子筛的裂化催化剂，和（b）分离的添加剂催化剂，其包含形状选择性石蜡裂化/异构化沸石和形状选择性脂肪族芳构化沸石中的至少一种。 示例性催化剂混合物包括脱铝沸石Y，任选地在富铝基质中含有稀土元素，基质中HZSM-5的添加剂催化剂和基质中的另外的镓ZSM-5的添加剂催化剂。 裂解催化剂的富含氧化铝的基体起钠和金属槽的作用。 大孔分子筛催化剂将大型烃裂解成较轻的链烷烃和烯烃。 形状选择性石蜡裂解/异构化组分裂解/异构化由大孔隙筛选产生的链烷烃。 形状选择性脂肪族芳构化催化剂将轻链烷烃和烯烃转化为芳族化合物。 具有受控量的芳构化成分如镓的单形选择性沸石，例如ZSM-5可以促进链烷烃裂解/异构化和芳构化。 添加剂催化剂具有与裂化催化剂基本相同的物理性质，例如尺寸，形状，密度和耐磨性。

公开(公告)号：US5053204A

公开(公告)日：1991-10-01

申请号：US500357

申请日：1990-03-28

申请人： Joseph A. Herbst ,  Hartley Owen ,  Paul H. Schipper

发明人： Joseph A. Herbst ,  Hartley Owen ,  Paul H. Schipper

IPC分类号： C10G11/18 ,  B01J8/08

CPC分类号： C10G11/18 ,  B01J2219/1942

摘要： A catalytic cracking process and apparatus operates with multiple feed injection points to a riser reactor with several enlarged regions. An elutriable catalyst mixture is used, comprising a conventionally sized cracking catalyst and a faster settling, shape selective additive cracking catalyst. Straight run naphtha, and a light, H.sub.2 -rich aliphatic stream are added to the base of a riser reactor. A resid feed is added higher up in the riser, with a gas oil and recycled heavy cycle oil and naphtha streams added even higher up in the riser. The riser has an elutriating base, and an elutriating upper portion, which increase residence time of the shape selective zeolite additive relative to the conventionally sized cracking catalyst.

摘要翻译： 催化裂化过程和装置用多个进料注入点操作到具有几个扩大区域的提升管反应器。 使用可洗涤催化剂混合物，其包含常规尺寸的裂化催化剂和较快沉降的形状选择性添加剂裂化催化剂。 将直馏石脑油和轻质富H2脂肪族物流加入提升管反应器的底部。 在提升管道中，残油饲料添加量更高，在提升管道中添加了更多的瓦斯油和回收的重质循环油和石脑油。 提升管具有淘洗基质和淘析上部，其相对于常规尺寸的裂化催化剂增加形状选择性沸石添加剂的停留时间。

公开(公告)号：US5043517A

公开(公告)日：1991-08-27

申请号：US428715

申请日：1989-10-30

申请人： James H. Haddad ,  Mohsen N. Harandi ,  Hartley Owen

发明人： James H. Haddad ,  Mohsen N. Harandi ,  Hartley Owen

IPC分类号： B01J29/40 ,  B01J29/90 ,  B01J38/30 ,  C07C2/12 ,  C10G11/18

CPC分类号： B01J38/30 ,  B01J29/90 ,  C07C2/12 ,  C07C2529/40 ,  Y02P20/584

摘要： Process for the continuous conversion of light olefin gas feed containing ethene, propene and butene to produce heavier hydrocarbons by contacting the light olefin feed in a fluidized bed reaction zone with a medium pore molecular sieve zeolite catalyst under oligomerization conditions to convert the light olefin feed to heavier hydrocarbons. The catalytic reaction causes the conversion of the light olefins to heavier hydrocarbons, the deposition of coke by-product on the catalyst and the absorption of hydrocarbon product on the catalyst. The deposited coke causes the partial deactivation of the catalyst. A portion of the partially deactivated catalyst containing deposited coke and absorbed hydrocarbon product is continuously withdrawn from the reaction zone and transferred to a catalyst stripping zone in which the catalyst is contacted with an inert stripping gas to remove the absorbed hydrocarbons from the catalyst. The stripped catalyst containing deposited coke is withdrawn from the stripping zone and transferred to a catalyst regeneration zone in which the catalyst is maintained in a fluidized bed and contacted with an oxygen containing gas to effect combustion of the coke and removal of the coke from the catalyst and regeneration of the catalyst. The regenerated catalyst containing a minor amount of residual carbon is withdrawn from the regeneration zone and introduced to the reaction zone and contacted with fresh light olefin feed. The careful control of the operating conditions in the regeneration zone provides removal of substantially all of the coke deposits at relatively low temperatures and an effluent flue gas with a low carbon monoxide content and low water content.

公开(公告)号：US5032251A

公开(公告)日：1991-07-16

申请号：US515930

申请日：1990-04-27

申请人： Hartley Owen ,  Paul H. Schipper

发明人： Hartley Owen ,  Paul H. Schipper

IPC分类号： B01J8/18 ,  C10G11/18

CPC分类号： B01J8/1863 ,  C10G11/182

摘要： A process and apparatus for achieving turbulent or fast fluidized bed regeneration of spent FCC catalyst in a bubbling bed regenerator having a stripper mounted over the regenerator and a stripped catalyst standpipe within the regenerator. A closed coke combustor vessel is added to the existing regenerator vessel, and spent catalyst is discharged into the coke combustor and regenerated in a turbulent or fast fluidized bed, and discharged up into a dilute phase transport which preferably encompasses, and is in a countercurrent heat exchange relationship with, the spent catalyst standpipe. Regenerated catalyst is discharged from the dilute phase transport riser, and collected in the bubbling dense bed surrounding the coke combustor. Catalyst may be recycled from the dense bed to the coke combustor for direct contact heat exchange. Catalyst coolers may be used on catalyst recycle lines to the coke combustor, or on the line returning regenerated catalyst to the cracking reactor.

摘要翻译： 一种用于在具有安装在再生器上的汽提塔和在再生器内的汽提催化剂立管的鼓泡床再生器中实现废FCC催化剂的湍流或快速流化床再生的方法和装置。 将封闭的焦炭燃烧器容器添加到现有的再生器容器中，并将废催化剂排放到焦炭燃烧器中并在湍流或快速流化床中再生，并排放到稀相转运中，该相传输优选包含并且处于逆流热 与废催化剂立管交换关系。 再生催化剂从稀相输送提升管排出，并收集在焦炭燃烧器周围的鼓泡致密床中。 催化剂可以从致密床再循环到焦炭燃烧器，用于直接接触热交换。 催化剂冷却器可用于到焦炭燃烧器的催化剂再循环管线上，或者在将再生的催化剂返回到裂化反应器的管线上。

公开(公告)号：US5026529A

公开(公告)日：1991-06-25

申请号：US297731

申请日：1989-01-17

申请人： Mohsen N. Harandi ,  Hartley Owen

发明人： Mohsen N. Harandi ,  Hartley Owen

IPC分类号： C07C1/20 ,  C10L1/02

CPC分类号： C10L1/023 ,  C07C1/20 ,  C07C2529/40

摘要： Improved operating techniques and apparatus for converting methanol or the like to intermediate olefins and etherification products, such as methyl t-butyl ether, by extracting crude methanol feedstock with an olefinic liquid hydrocarbon stream containing C.sub.4.sup.+ iso-olefins. The methanol extract phase is reacted under etherification conditions. The aqueous methanol raffinate stream is converted catalytically to olefins for recovery of C.sub.4.sup.+ olefinic liquid hydrocarbons useful as extraction solvent.A continuous system is provided for converting crude aqueous alcohol feedstock to olefinic hydrocarbons and octane enhancing ethers comprising: extractor means for contacting feedstock liquid containing water with a liquid hydrocarbon extraction stream to provide an extract liquid stream rich in alcohol and an aqueous raffinate stream lean in alcohol; catalytic reactor means for contacting the aqueous alcohol raffinate stream in a catalytic reaction zone with a crystalline acid zeolite catalyst at elevated temperature in an intermediate olefins production zone under process conditions to convert a major portion of alcohol to hydrocarbons; separation means to recover a gaseous stream rich in C.sub.3.sup.- hyrocarbons and a liquid stream comprising C.sub.4.sup.+ hydrocarbons; recycle means for contacting at least a portion of the liquid hydrocarbon stream from said separation means with crude alcohol feedstock in said extractor means; and etherification reactor means for contacting at least a portion of extracted alcohol and olefinic liquid hydrocarbon with etherification catalyst to produce an ether product stream.

摘要翻译： 通过用含有C4 +异烯烃的烯烃液体烃流提取粗甲醇原料，改进了将甲醇等转化成中间体烯烃和醚化产物如甲基叔丁基醚的操作技术和装置。 甲醇萃取相在醚化条件下反应。 将甲醇萃余水流催化转化为烯烃，以回收可用作萃取溶剂的C4 +烯烃液体烃。 提供连续系统用于将粗含水醇原料转化为烯烃和辛烷增强醚，包括：萃取器装置，用于使含有水的原料液体与液体烃萃取物流接触，以提供富含醇的萃取液体流和稀有的含水萃余液流 醇; 催化反应器装置，用于在催化反应区中的含水醇萃余液流与结晶酸沸石催化剂在高温下在中间烯烃生产区中在工艺条件下使大部分醇转化成烃; 分离装置用于回收富含C 3 - 碳氢化合物的气态物流和包含C4 +烃的液体物流; 用于使来自所述分离装置的液体烃流的至少一部分与所述提取器装置中的粗醇原料接触的再循环装置; 和醚化反应器装置，用于使至少一部分提取的醇和烯烃液态烃与醚化催化剂接触以产生醚产物流。

公开(公告)号：US5011592A

公开(公告)日：1991-04-30

申请号：US554309

申请日：1990-07-17

申请人： Hartley Owen ,  Paul H. Schipper

发明人： Hartley Owen ,  Paul H. Schipper

IPC分类号： B01J38/12 ,  C10G11/18

CPC分类号： C10G11/182

摘要： A process for controlled, multi-stage regeneration of FCC catalyst is disclosed. A modified high efficiency catalyst regenerator, with a fast fluidized bed coke combustor, dilute phase transport riser, and second fluidized bed regenerates the catalyst in at least two stages. The primary stage of regeneration is in the coke combustor, at full CO oxidation conditions. The second stage of catalyst regeneration occurs in the second fluidized bed, at partial CO combustion conditions. The process permits regeneration of spent FCC catalyst while minimizing NOx exmissions and achieving significant reduction of SOx.

摘要翻译： 公开了FCC催化剂的受控多级再生方法。 改进的高效催化剂再生器，具有快速流化床焦炭燃烧器，稀相输送提升管和第二流化床，至少在两个阶段中再生催化剂。 在完全CO氧化条件下，再生的主要阶段是在焦炭燃烧器中。 催化剂再生的第二阶段在部分CO燃烧条件下发生在第二流化床中。 该过程允许废催化剂催化剂的再生，同时最大程度地减少氮氧化物的排放并实现SO x的显着降低

公开(公告)号：US5002915A

公开(公告)日：1991-03-26

申请号：US358095

申请日：1989-05-30

申请人： Mohsen N. Harandi ,  Hartley Owen

发明人： Mohsen N. Harandi ,  Hartley Owen

IPC分类号： C10G50/00 ,  C10G57/02 ,  F02B3/06

CPC分类号： C10G57/02 ,  C10G50/00 ,  F02B3/06

摘要： A process for regenerating solid particulate catalyst used in fixed bed hydrocarbon conversion processes, such as the shape selective zeolite conversion of olefins to gasoline and diesel fuel. Regeneration is achieved using a portion of a flue gas stream to regenerate catalyst and preheat feedstock. Economies in equipment and operation are realized by employing a once-through configuration for the regenerator gas stream.

摘要翻译： 用于再生固定颗粒催化剂的方法，其用于固定床烃转化方法，例如烯烃形式选择性沸石转化成汽油和柴油燃料。 使用一部分烟道气再生催化剂并预热原料来实现再生。 设备和操作的经济可以通过采用一次直流配置来实现再生器气流。

公开(公告)号：US4988653A

公开(公告)日：1991-01-29

申请号：US292272

申请日：1988-12-30

申请人： Joseph A. Herbst ,  Hartley Owen ,  Paul H. Schipper

发明人： Joseph A. Herbst ,  Hartley Owen ,  Paul H. Schipper

IPC分类号： B01J29/08 ,  B01J29/40 ,  B01J29/80 ,  C10G11/05 ,  C10G11/18

CPC分类号： B01J29/80 ,  C10G11/05 ,  C10G11/18 ,  B01J2229/26 ,  B01J2229/42 ,  B01J29/084 ,  B01J29/40

摘要： A catalytic cracking catalyst mixture and process are disclosed. The mixture comprises (a) a cracking catalyst containing a matrix and a large pore molecular sieve and (b) separate particles of additive catalyst comprising at least one of a shape selective paraffin cracking/isomerization zeolite and a shape selective aliphatic aromatization zeolite. An exemplary catalyst mixture comprises dealuminized zeolite Y, optionally containing rare earth elements, in an alumina rich matrix and an additive catalyst of HZSM-5, and gallium ZSM-5 in a matrix. The alumina matrix of the cracking catalyst acts as a sodium and metals sink. The large pore molecular sieve catalyst cracks large hydrocarbons to lighter paraffins and olefins. The shape selective paraffin cracking/isomerization component cracks the paraffins produced by the large pore molecular sieve. The shape selective aliphatic aromatization catalyst converts light paraffins and olefins into aromatics. A single shape selective zeolite, e.g., ZSM-5 with a controlled amount of an aromatization component such as gallium, may promote both paraffin cracking/isomerization and aromatization. The additive catalyst is separable by physical means from the cracking catalyst, preferably by elutriation.

摘要翻译： 公开了催化裂化催化剂混合物和方法。 该混合物包含（a）含有基质和大孔分子筛的裂化催化剂，和（b）包含形状选择性石蜡裂解/异构化沸石和形状选择性脂肪族芳构化沸石中的至少一种的添加剂催化剂的分离颗粒。 示例性的催化剂混合物包括任选地含有稀土元素的脱铝沸石Y，富铝基质和HZSM-5的添加剂催化剂和基体中的镓ZSM-5。 裂化催化剂的氧化铝基体用作钠和金属沉。 大孔分子筛催化剂将大型烃裂解成较轻的链烷烃和烯烃。 形状选择性石蜡裂解/异构化组分裂解由大孔分子筛产生的链烷烃。 形状选择性脂肪族芳构化催化剂将轻链烷烃和烯烃转化为芳族化合物。 具有受控量的芳构化成分如镓的单形选择性沸石，例如ZSM-5可以促进链烷烃裂解/异构化和芳构化。 添加剂催化剂可通过物理方法与裂化催化剂分离，优选通过淘析。

公开(公告)号：US4968401A

公开(公告)日：1990-11-06

申请号：US211611

申请日：1988-06-27

申请人： Mohsen N. Harandi ,  Hartley Owen

发明人： Mohsen N. Harandi ,  Hartley Owen

IPC分类号： C10G57/00

CPC分类号： C10G57/00

摘要： A paraffinic feedstream is aromatized in an FCC external catalyst cooler by contacting the paraffinic feedstream with hot regenerated cracking and additive catalysts.

摘要翻译： 通过使链烷烃进料流与热再生裂化和添加剂催化剂接触，在FCC外部催化剂冷却器中将石蜡原料流芳构化。

公开(公告)号：US4927522A

公开(公告)日：1990-05-22

申请号：US292206

申请日：1988-12-30

申请人： Joseph A. Herbst ,  Hartley Owen ,  Paul H. Schipper

发明人： Joseph A. Herbst ,  Hartley Owen ,  Paul H. Schipper

IPC分类号： C10G11/18

CPC分类号： C10G11/18 ,  B01J2219/1942

摘要： A catalytic cracking process and apparatus operates with multiple feed injection points to a riser reactor with several enlarged regions. An elutriable catalyst mixture is used, comprising a conventionally sized cracking catalyst and a faster settling, shape selective additive cracking catalyst. Straight run naphtha, and a light, H.sub.2 -rich aliphatic stream are added to the base of a riser reactor. A resid feed is added higher up in the riser, with a gas oil and recycled heavy cycle oil and naphtha streams added even higher up in the riser. The riser has an elutriating base, and an elutriating upper portion, which increase residence time of the shape selective zeolite additive relative to the conventionally sized cracking catalyst.

摘要翻译： 催化裂化过程和装置用多个进料注入点操作到具有几个扩大区域的提升管反应器。 使用可洗涤催化剂混合物，其包含常规尺寸的裂化催化剂和较快沉降的形状选择性添加剂裂化催化剂。 将直馏石脑油和轻质富H2脂肪族物流加入提升管反应器的底部。 在提升管道中，残油饲料添加量更高，在提升管道中添加了更多的瓦斯油和回收的重质循环油和石脑油。 提升管具有淘洗基质和淘析上部，其相对于常规尺寸的裂化催化剂增加形状选择性沸石添加剂的停留时间。