-
公开(公告)号：US6099914A
公开(公告)日：2000-08-08
申请号：US401299
申请日：1999-09-23
申请人： Yasuki Yoshida , Setsuro Ogata , Masaharu Uno , Masashi Tanaka , Yoshinori Nishiki , Takayuki Shimamune , Hiroshi Inoue , Chiaki Iwakura
发明人： Yasuki Yoshida , Setsuro Ogata , Masaharu Uno , Masashi Tanaka , Yoshinori Nishiki , Takayuki Shimamune , Hiroshi Inoue , Chiaki Iwakura
CPC分类号： C01B3/0078 , C10G45/00 , C10G45/32 , C25B1/02 , C25B3/00 , C10G2300/4056 , C10G2300/42 , Y02E60/324
摘要： An electrolytic process and apparatus which can operate in a hydrogen reaction chamber at a hydrogen reaction rate corresponding to the increase in the rate of production of hydrogen accompanying the increase in the electrolysis rate and maintain the current efficiency at a very high value with respect to the electrolytic current for producing hydrogen and a process for the production of an electrode for this purpose. An electrolytic process is provided which comprises effecting electrolysis of an electrolytic solution in an electrolytic chamber separated from a reaction chamber by a hydrogen-storing metal member with one surface of the hydrogen-storing metal member as a cathode opposing an anode so that hydrogen thus produced is adsorbed by the hydrogen-storing metal member while allowing hydrogen thus adsorbed and a material to be treated to undergo continuous catalytic reaction in the reaction chamber on the other surface of the hydrogen-storing metal member to cause hydrogenation or reduction reaction by hydrogen thus adsorbed, wherein an electrolytic apparatus having a porous catalyst layer provided on the catalytic reaction surface of the hydrogen-storing metal member is used. The porous catalyst layer is obtained by reducing metal cations in an electroless plating solution by active hydrogen desorbed from a hydrogen-storing metal so that the hydrogen-storing metal is plated with the metal.
摘要翻译： 一种电解方法和装置，其可以在氢反应室中以氢反应速率操作，其伴随着电解速率的增加伴随着氢的生成速率的增加，并且将电流效率保持在非常高的值，相对于 用于生产氢的电解电流和用于生产电极的方法。 提供了一种电解方法，其包括通过储氢金属构件在与反应室分离的电解室中电解电解溶液，其中储氢金属构件的一个表面作为与阳极相对的阴极，从而产生氢 被吸氢金属部件吸附，同时允许被吸附的氢，并且被处理材料在储氢金属部件的另一个表面上的反应室中进行连续的催化反应，由此吸附氢气或还原反应 其中，使用具有设置在所述储氢金属构件的催化反应面上的多孔催化剂层的电解装置。 多孔催化剂层是通过从吸氢金属解吸的活性氢还原化学镀溶液中的金属阳离子而得到的，以使储氢金属镀金属。
-
92.发明授权Process and apparatus for the production of an aqueous solution of hydrogen peroxide 失效用于生产过氧化氢水溶液的方法和设备
公开(公告)号：US6045684A
公开(公告)日：2000-04-04
申请号：US60814
申请日：1998-04-16
CPC分类号： B01D61/44
摘要： An on-site process and apparatus for producing hydrogen peroxide at a high efficiency substantially from brine and oxygen-containing gas alone as raw materials while removing alkaline earth metals. Sea water concentrated by an electrodialytic apparatus 2 or the like as a raw material is supplied to an impurity removing apparatus 10 where caustic soda produced in an acid-alkali producing apparatus 11 at a subsequent stage and/or carbon dioxide gas is added to remove alkaline earth metals contained in sea water in the form of a hydroxide or carbonate precipitate. Separately, the acid-alkali producing apparatus 11 performs a salt separating operation to produce caustic soda which is then supplied to a hydrogen peroxide generator 28 to produce an alkaline aqueous solution of hydrogen peroxide.
摘要翻译： 一种现有的过程和装置，其以高效率生产基本上从盐水和含氧气体为原料的过氧化氢，同时除去碱土金属。 通过电渗析装置2等作为原料浓缩的海水被供给到杂质除去装置10中，在除去装置10中，在后续阶段的酸碱生产装置11中产生苛性钠和/或二氧化碳气体以除去碱 包含在海水中的以氢氧化物或碳酸盐沉淀形式的地球金属。 单独地，酸碱生产装置11进行盐分离操作以产生苛性钠，然后将其供应到过氧化氢发生器28以产生碱性过氧化氢水溶液。
-
公开(公告)号：US5980703A
公开(公告)日：1999-11-09
申请号：US53781
申请日：1998-04-02
申请人： Kuniaki Yamada , Seiichi Anzai , Masashi Tanaka , Takayuki Shimamune , Yoshinori Nishiki , Naoaki Sakurai , Naoya Hayamizu , Hiroshi Fujita
发明人： Kuniaki Yamada , Seiichi Anzai , Masashi Tanaka , Takayuki Shimamune , Yoshinori Nishiki , Naoaki Sakurai , Naoya Hayamizu , Hiroshi Fujita
CPC分类号： C02F1/469 , C02F1/4618 , C02F1/42 , C02F2001/46133 , C02F2001/46142 , C02F2001/46161 , C02F2103/04 , C02F2201/46115 , C02F2201/46125 , C02F2201/46195 , C02F9/00
摘要： An electrolytic cell for producing acidic water and alkaline water is disclosed. High-purity acidic water and high-purity alkaline water can be produced in a well balanced proportion from ultrapure water which is supplied in the minimum amount necessary for producing the desired acidic and alkaline waters using the minimum amount of electricity. The electrolytic cell includes an electrolytic acidic-water production unit 3 comprising an anode chamber 6 and an auxiliary cathode chamber 7 separated therefrom by a first ion-exchange membrane 5, and an electrolytic alkaline-water production unit 4 comprising a cathode chamber 10 and an auxiliary anode chamber 9 separated therefrom by a second ion-exchange membrane 8. Separately controllable power supplies are also provided for supplying power to each of the two units. The supply amount of pure water and the amount of electricity used can be fixed according to the desired amounts of acidic and alkaline waters. Thus, wasteful use of ultrapure water and electric power can be avoided.
摘要翻译： 公开了一种用于生产酸性水和碱性水的电解池。 高纯度酸性水和高纯度碱性水可以以超纯水的平衡比例生产，以最少的电量生产所需的酸性和碱性水所需的最小量。 电解池包括电解酸性水生产单元3，其包括由第一离子交换膜5与其隔开的阳极室6和辅助阴极室7;以及电解碱水生产单元4，其包括阴极室10和 辅助阳极室9由第二离子交换膜8分离。也提供了单独可控的电源，用于向两个单元中的每一个供电。 纯水的供给量和使用的电量可以根据所需量的酸性和碱性水而固定。 因此，可以避免浪费使用超纯水和电力。
-
公开(公告)号：US5965009A
公开(公告)日：1999-10-12
申请号：US839708
申请日：1997-04-15
CPC分类号： C02F1/4618 , C02F1/4674 , C02F2001/46138 , C02F2001/46185 , C02F2201/46115 , C02F2201/46185 , C02F2201/46195 , C02F2209/04 , C02F2209/06
摘要： A method of electrolytically producing acid water using an electrolytic cell partitioned by a cation-exchange membrane into an anode chamber and a cathode chamber. Chloride ion which generates hypochlorous acid by anodic oxidation is supplied to the cathode chamber without directly supplying chloride ion to the anode chamber. Part of the chloride ion permeates from the cathode chamber into the anode chamber through the cation-exchange membrane. The chloride ion which permeates through the cation-exchange membrane is present at the surface of an anode closely adhering to the cation-exchange membrane in the anode chamber or only in the vicinity of the anode, and is efficiently anodically oxidized to form hypochlorite ion. Also disclosed is an electrolytic cell for carrying out the method of electrolytically producing acid water.
摘要翻译： 使用由阳离子交换膜分隔成阳极室和阴极室的电解槽电解生成酸水的方法。 通过阳极氧化产生次氯酸的氯离子供应到阴极室，而不直接向阳极室供应氯离子。 部分氯离子通过阳离子交换膜从阴极室渗入阳极室。 渗透阳离子交换膜的氯离子存在于与阳极室中的阳离子交换膜紧密接触的阳极表面，或仅在阳极附近，阳极氧化形成次氯酸根离子。 还公开了一种用于实施电解生产酸性水的方法的电解池。
-
95.发明授权Gas-diffusion cathode and salt water electrolytic cell using the gas-diffusion cathode 失效使用气体扩散阴极的气体扩散阴极和盐水电解槽
公开(公告)号：US5879521A
公开(公告)日：1999-03-09
申请号：US922604
申请日：1997-09-03
CPC分类号： C25B9/08 , C25B11/035 , H01M4/8626
摘要： A gas-diffusion cathode disposed in contact with an ion-exchange membrane partitioning an electrolytic cell into an anode chamber and a cathode chamber, wherein at least one guide piece is disposed in the gas-diffusion cathode and a salt water electrolytic cell using the above-described gas-diffusion cathode. By using the above-described gas-diffusion cathode for salt water electrolysis, an aqueous caustic alkali solution formed descending in the direction of gravity in the cathode changes direction of movement by contact with a guide piece, whereby the decreased electrode performance resulting from the hindrance of the supply of raw material gas and the discharge of the gas formed caused by the retention of the descending caustic alkali solution is prevented and a large-sized electrolytic cell can be used without problems generally encountered in conventional electrolytic systems.
摘要翻译： 与将电解槽隔离成阳极室和阴极室的离子交换膜接触的气体扩散用阴极，其中，至少一个引导片设置在气体扩散阴极中，使用上述盐水电解池 描述的气体扩散阴极。 通过使用上述的用于盐水电解的气体扩散阴极，在阴极重力方向上下降的苛性碱水溶液通过与引导件接触而改变运动方向，由此产生的阻碍电极性能降低 的原料气体的供给和由下降的苛性碱溶液的保留引起的气体的排放被防止，并且可以使用大尺寸的电解池，而没有常规电解系统中通常遇到的问题。
-
公开(公告)号：US5626730A
公开(公告)日：1997-05-06
申请号：US442768
申请日：1995-05-17
CPC分类号： C25D17/12
摘要： An electrode structure containing an insoluble metal electrode which is used as an electrode for the electrolysis of an acidic aqueous solution under a high current density is disclosed. An elastic electroconductive material, containing an expanded metal, having formed thereon a corrosion-resistant electroconductive coating, is disposed between an electroconductive electrode substrate and an electrode having on the surface thereof a coating of an electrode material. They are fixed by a detachable fixing device from the surface of the electrode. The electrode can be exchanged when fixing the electrode structure to the electrolytic cell.
摘要翻译： 公开了一种含有不溶性金属电极的电极结构，其用作在高电流密度下电解酸性水溶液的电极。 在其上形成有耐腐蚀导电涂层的含有膨胀金属的弹性导电材料设置在导电电极基板和在其表面上具有电极材料的涂层的电极之间。 它们通过可拆卸的固定装置从电极的表面固定。 当将电极结构固定到电解槽时，可以更换电极。
-
公开(公告)号：US5607562A
公开(公告)日：1997-03-04
申请号：US321983
申请日：1994-10-12
申请人： Takayuki Shimamune , Isao Sawamoto
发明人： Takayuki Shimamune , Isao Sawamoto
IPC分类号： C25B1/30 , C02F1/42 , C02F1/461 , C02F1/467 , C02F1/78 , C25B1/13 , C25B9/00 , C25B9/08 , C25B15/08
CPC分类号： C02F1/4672 , C25B1/13 , C25B9/08 , C02F1/42 , C02F1/78 , C02F2001/46138 , C02F2001/46157 , C02F2201/46115 , C02F2201/4619 , C02F2201/46195 , C02F2201/782
摘要： An electrolytic ozone generator comprising anode chamber 3 and cathode chamber 4 partitioned by solid electrolyte 2, in which deionized water is electrolyzed in the cathode chamber while feeding air or oxygen-rich air to the cathode chamber through, for example, air holes 14. The air fed suppresses evolution of hydrogen gas thereby affording a saving of energy and eliminating the need a separate cooling mechanism. Furthermore, the air also decomposes ozone having entered the catholyte.
摘要翻译： 一种电解臭氧发生器，包括由固体电解质2分隔的阳极室3和阴极室4，其中在阴极室中电解去离子水，同时通过例如气孔14将空气或富氧空气供入阴极室。 空气供给抑制氢气的进化，从而提供能量的节省并且消除了单独的冷却机制的需要。 此外，空气还分解进入阴极电解液的臭氧。
-
公开(公告)号：US5545306A
公开(公告)日：1996-08-13
申请号：US353973
申请日：1994-12-06
申请人： Takayuki Shimamune , Yasuo Nakajima
发明人： Takayuki Shimamune , Yasuo Nakajima
CPC分类号： C25B11/0478 , C25B11/16
摘要： The present invention relates to a method of producing an electrolytic electrode containing the following steps: forming a lead plating layer on the surface of a metallic core material by using a lead electrolytic plating bath, where the metallic core material is the cathode; forming an .alpha.-lead dioxide layer on the lead plating layer by electrolysis using an alkaline bath containing a lead ion and using the core material as the anode; and forming a .beta.-lead dioxide layer on the .alpha.-lead dioxide layer by electrolysis using an aqueous lead nitrate solution and using the core material as the anode. The electrolytic electrode produced by the foregoing method is capable of electrolysis in an aqueous solution, in particular, in an aqueous corrosive solution containing fluorine ions.
摘要翻译： 本发明涉及一种生产电解电极的方法，包括以下步骤：通过使用铅电解电镀浴在金属芯材的表面上形成铅镀层，其中金属芯材料为阴极; 通过使用含有铅离子的碱性电解电解并使用芯材作为阳极，在铅镀层上形成α-二氧化碳层; 并通过使用硝酸铅水溶液的电解并使用芯材作为阳极在α-二氧化碳层上形成β-二氧化碳层。 通过上述方法制造的电解电极能够在水溶液中电解，特别是在含有氟离子的水性腐蚀性溶液中进行电解。
-
公开(公告)号：US5391280A
公开(公告)日：1995-02-21
申请号：US92437
申请日：1993-07-14
申请人： Takayuki Shimamune , Yasuo Nakajima
发明人： Takayuki Shimamune , Yasuo Nakajima
CPC分类号： C25B11/0478 , C25B11/16
摘要： The present invention relates to an electrolytic electrode comprising a metallic core material, a lead plating layer formed on the surface of the metallic core material, an .alpha.-lead dioxide layer formed on the surface of the lead plating layer, and a .beta.-lead dioxide layer formed on the .alpha.-lead dioxide layer. The present invention also relates to methods for the preparation thereof.
摘要翻译： 本发明涉及一种电解电极，包括金属芯材，形成在金属芯材表面上的铅镀层，形成在铅镀层表面上的α-二氧化碳层和β-二氧化碳 层形成在α-二氧化碳层上。 本发明还涉及其制备方法。
-
公开(公告)号：US5290415A
公开(公告)日：1994-03-01
申请号：US934229
申请日：1992-08-25
申请人： Takayuki Shimamune , Yasuo Nakajima
发明人： Takayuki Shimamune , Yasuo Nakajima
CPC分类号： C25B11/0484 , C25D17/10
摘要： An electrolytic electrode comprising a substrate made of a valve metal, an intermediate layer formed on a surface of the substrate containing an oxide of at least one metal selected from the group consisting of niobium, tantalum, titanium, and zirconium, and a coating layer formed on the intermediate layer containing an iridium-tantalum mixed oxide and platinum. In separate embodiments of the invention, the intermediate layer may contain platinum and/or a stabilizing layer formed on the coating layer containing an oxide of at least one metal selected from the group consisting of tin, titanium, tantalum, zirconium, and niobium.
摘要翻译： 一种电解电极，包括由阀金属制成的基板，在所述基板的表面上形成有包含选自铌，钽，钛和锆中的至少一种金属的氧化物的中间层和形成的涂层 在含有铱钽混合氧化物和铂的中间层上。 在本发明的单独实施例中，中间层可以含有形成在涂层上的含有选自锡，钛，钽，锆和铌中的至少一种金属的氧化物的铂和/或稳定层。
-
-
-
-
-
-
-
-
-
搜索结果
110 条记录 (耗时 0.045 秒)
