Thermographic recording material with improved image density and/or
image gradation upon thermal development
    91.
    发明授权
    Thermographic recording material with improved image density and/or image gradation upon thermal development 有权
    热成像记录材料,具有改善的图像密度和/或图像等级

    公开(公告)号:US6037114A

    公开(公告)日:2000-03-14

    申请号:US199924

    申请日:1998-11-25

    IPC分类号: G03C1/498

    CPC分类号: G03C1/49845 G03C1/4989

    摘要: A recording material exclusive of a thermal bleachable dye comprising a support and a thermosensitive element comprising an organic silver salt, an organic reducing agent therefor in thermal working relationship therewith and a binder, wherein the recording material further contains non-halide-ion-containing arylonium compound exclusive of compounds according to formula (I): ##STR1## wherein L.sub.a is a valence bond or a divalent or trivalent linking group, L.sub.2 is an alkylene group, each of R.sub.a and R.sub.b is a hydrogen atom or monovalent substituent group, M.sub.1 is an onium ion, R.sub.a and R.sub.b may form a ring taken together and D is an electron donative group of atoms, with the proviso that where D is a hydrazino group which is not a part of a semicarbazido group, no oxo group is substituted to the carbon atom which is directly attached to a nitrogen atom of the hydrazine; and a recording process therefor.

    摘要翻译: 不含热可漂白染料的记录材料,其包含载体和包含有机银盐的热敏元件,与其热加工关系的有机还原剂和粘合剂,其中所述记录材料还含有非卤化物离子的芳基 不包括根据式(I)的化合物的化合物:其中La是价键或二价或三价连接基团,L2是亚烷基,Ra和Rb各自为氢原子或一价取代基,M1为鎓离子 ,R a和R b可以形成一个环,D是原子的给电子基团,条件是其中D是不是一个氨基脲基的一部分的肼基,没有氧代基被碳原子取代 直接连接到肼的氮原子上; 及其记录过程。

    Thioheterocyclic near-infrared dyes
    92.
    发明授权
    Thioheterocyclic near-infrared dyes 失效
    硫杂环状近红外染料

    公开(公告)号:US5932740A

    公开(公告)日:1999-08-03

    申请号:US12699

    申请日:1998-01-23

    摘要: Disclosed is a novel near-infrared absorbing dye of formula: ##STR1## wherein X.sup.1, X.sup.2 independently represents --CR.sup.8 R.sup.9 --, --S--, --Se--, --NR.sup.10 --, --CH.dbd.CH-- or --O--;n is an integer of 2 or 3;R.sup.1 and R.sup.2 independently represent alkyl of 1 to 10 carbons or substituted alkyl of 1 to 10 carbons;R.sup.3 represents a ring chosen from a set consisting of aryl, substituted aryl, and a heterocyclic ring of a type present in photographic emulsions;R.sup.4, R.sup.5, R.sup.6 and R.sup.7 independently represent hydrogen, alkyl of 1-10 carbons, substituted alkyl of 1-10 carbons, R.sup.4 and R.sup.5 taken together or R.sup.6 and R.sup.7 taken together can represent atoms necessary to form a 5 or 6-membered aliphatic ring, an aromatic six-membered ring, an aromatic 10-membered ring, a substituted aromatic six-member ring or a substituted aromatic 10-member ring;R.sup.8, R.sup.9 independently represent alkyl of 1-10 carbons, substituted alkyl of 1-10 carbons, aryl of 6-10 carbons, or substituted aryl of 6-10 carbons; andR.sup.10 represents an alkyl of 1-10 carbons, substituted alkyl of 1-10 carbons, aryl of 6-10 carbons, or substituted aryl of 6-10 carbons;with the proviso that when R.sup.3 is phenyl or substituted phenyl and n=3, R.sup.1 or R.sup.2 is not an unsubstituted alkyl.

    摘要翻译: 公开了一种新型的近红外吸收染料,其结构式如下:其中X1,X2独立地表示-CR8R9-,-S-,-Se-,-NR10-,-CH = CH-或-O-; n为2或3的整数; R1和R2独立地表示1〜10个碳的烷基或1〜10个碳的取代烷基; R3表示选自由感光乳剂中存在的类型的芳基,取代的芳基和杂环组成的组的环; R4,R5,R6和R7独立地表示氢,1-10个碳的烷基,1-10个碳的取代的烷基,R4和R5一起或R6和R7一起可以表示形成5或6元脂肪族所需的原子 环,芳香族六元环,芳香族10元环,取代芳香族六元环或取代芳香族10元环; R8,R9独立地表示1-10个碳的烷基,1-10个碳的取代烷基,6-10个碳原子的芳基或6-10个碳的取代芳基; R 10表示1-10个碳的烷基,1-10个碳的取代烷基,6-10个碳原子的芳基或6-10个碳的取代芳基; 条件是当R3为苯基或取代苯基且n = 3时,R 1或R 2不是未取代的烷基。

    Thermographic imaging element
    93.
    发明授权
    Thermographic imaging element 失效
    热成像元件

    公开(公告)号:US5928855A

    公开(公告)日:1999-07-27

    申请号:US45017

    申请日:1998-03-20

    CPC分类号: G03C1/4989

    摘要: A thermographic imaging element comprises:(a) a support;(b) an imaging layer comprising:(i) a silver salt;(ii) a first reducing agent which has high activity with an activation energy of less than 10 Joules/sq.cm.;(iii) a second reducing agent which has low activity with an activation energy of greater than or equal to 10 Joules/sq. cm.; and(iv) a third reducing agent comprising a silicon compound containing at least one silicon-hydrogen bond.

    摘要翻译: 热成像成像元件包括:(a)支撑件; (b)成像层,包括:(i)银盐; (ii)具有活性能小于10焦耳/平方厘米的高活性的第一还原剂; (iii)具有低于10焦耳/平方的活化能的低活性的第二还原剂。 厘米。; 和(iv)包含含有至少一个硅 - 氢键的硅化合物的第三还原剂。

    Substantially non-photosensitive thermographic recording material with
improved stability and image-tone
    95.
    发明授权
    Substantially non-photosensitive thermographic recording material with improved stability and image-tone 失效
    具有改善的稳定性和图像色调的基本非感光性热敏记录材料

    公开(公告)号:US5854174A

    公开(公告)日:1998-12-29

    申请号:US856099

    申请日:1997-05-14

    IPC分类号: B41M5/32 G03C1/498 B41M5/30

    摘要: A substantially non-photosensitive recording material comprising a thermosensitive element comprising a substantially light-insensitive organic silver salt, an organic reducing agent therefor in thermal working relationship therewith, a compound with an unsaturated 5-membered heterocyclic ring consisting of nitrogen and carbon atoms with at least one of the nitrogen atoms having a hydrogen atom and none of the carbon atoms being part of a thione-group, the ring not being annulated with an aromatic ring system and the compound being exclusive of 1,2,4-triazole and substituted 1,2,4-triazole compounds, in reactive association with the substantially light-insensitive organic silver salt and the organic reducing agent and a binder, on a support; and a thermal image recording process therefor.

    摘要翻译: 一种基本上非感光的记录材料,其包含热敏元件,该热敏元件包含基本上不光敏的有机银盐,与其热加工关系的有机还原剂,具有由氮和碳原子组成的不饱和5元杂环的化合物, 至少一个氮原子具有氢原子,并且没有一个碳原子是硫酮基的一部分,该环未被芳环系统排列,该化合物不包括1,2,4-三唑和取代的1 ,2,4-三唑化合物,与基本上不光敏的有机银盐和有机还原剂和粘合剂反应,在载体上; 及其热图像记录处理。

    Thermal image forming process with improved slip performance therein
    96.
    发明授权
    Thermal image forming process with improved slip performance therein 失效
    热成像工艺,其中具有改善的滑动性能

    公开(公告)号:US5817598A

    公开(公告)日:1998-10-06

    申请号:US753793

    申请日:1996-11-29

    摘要: A thermal image forming process comprising the steps of: (i) bringing an outermost layer of a recording material comprising at least one thermosensitive element, comprising a substantially light-insensitive silver salt and a reducing agent therefor in thermal working relationship therewith, on a support into contact with a heat source; (ii) applying heat from the heat source imagewise to the recording material while maintaining mutual contact to but with relative movement between the recording material and the heat source; and (iii) separating the recording material from the heat source, characterized in that the dynamic frictional coefficient during the contact between the outermost surface of the recording material and the heat source has a maximum value of less than 0.3. The outermost layer in contact with the heat source may be the outermost layer of the thermosensitive element, a protective layer applied to the thermosensitive element or a layer on the opposite side of the support to the thermosensitive element.

    摘要翻译: 一种热成像方法,包括以下步骤:(i)使包含至少一种热敏元件的记录材料的最外层,其包含基本上不光敏的银盐和与其热处理关系的还原剂,在载体上 与热源接触; (ii)从记录材料和热源之间的相对移动保持相互接触而将成像的热源加热到记录材料; 和(iii)从热源分离记录材料,其特征在于,记录材料的最表面与热源之间的接触期间的动态摩擦系数具有小于0.3的最大值。 与热源接触的最外层可以是热敏元件的最外层,施加到热敏元件的保护层或与热敏元件的支撑体的相对侧上的层。

    Method for making an image by direct thermal imaging
    98.
    发明授权
    Method for making an image by direct thermal imaging 失效
    通过直接热成像制作图像的方法

    公开(公告)号:US5734411A

    公开(公告)日:1998-03-31

    申请号:US336311

    申请日:1994-11-08

    摘要: A method for making an image by means of a direct thermal imaging element, comprising on a support a thermosensitive layer incorporating an organic silver salt and a reducing agent contained in said thermosensitive layer and/or in other optional layers. The imaging element is imagewise heated by means of a thermal head having energizable heating elements. The activation of the heating elements is executed duty cycled pulsewise with the steps of preheating each heating element for a preheating time such that a preheat temperature in the imaging element is reached, which is just below the conversion temperature; selecting a pulse duty cycle such that a maximal density on the imaging element will be reached at the end of the maximal writing time; retrieving from a memory for each individual pixel an individual writing time related to a desired density on the imaging element; and energizing the heating elements with the selected pulse duty cycle for a time related to the retrieved individual writing time.

    摘要翻译: 一种用于通过直接热成像元件制作图像的方法,该方法包括在载体上,包含有机银盐和包含在所述热敏层中的还原剂的热敏层和/或其它可选层。 成像元件通过具有可激发加热元件的热​​敏头成像加热。 加热元件的激活以脉动方式执行,其步骤是预热每个加热元件预热时间,使得达到刚刚低于转换温度的成像元件中的预热温度; 选择脉冲占空比,使得在最大写入时间结束时将达到成像元件上的最大浓度; 从每个单独像素的存储器检索与成像元件上的期望密度相关的单独写入时间; 并且以所选择的脉冲占空比为加热元件通电一段与所检索的单独写入时间相关的时间。