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    Aromatic polyesters derived from 2,3-butanediol
    91.
    发明授权
    Aromatic polyesters derived from 2,3-butanediol 失效
    衍生自2,3-丁二醇的芳族聚酯

    公开(公告)号：US4600768A

    公开(公告)日：1986-07-15

    申请号：US789281

    申请日：1985-10-18

    Applicant: Winston J. Jackson, Jr. ,  Joseph J. Watkins

    Inventor： Winston J. Jackson, Jr. ,  Joseph J. Watkins

    IPC: C08G63/181 ,  C08G63/02

    CPC classification number: C08G63/181

    Abstract: Disclosed are polyesters derived from one or more aromatic dicarboxylic acids and a diol which includes at least 50 mol percent of 2,3-butanediol. The polyesters, prepared by the use of a tin catalyst, are high molecular weight polymers having an inherent viscosity of at least 0.4.

    Abstract translation: 公开了衍生自一种或多种芳族二羧酸的聚酯和包含至少50mol％的2,3-丁二醇的二醇。 通过使用锡催化剂制备的聚酯是具有至少0.4的特性粘度的高分子量聚合物。

    Polyesters and their manufacture from acids and glycol carbonates
    94.
    发明授权
    Polyesters and their manufacture from acids and glycol carbonates 失效

    公开(公告)号：US4521585A

    公开(公告)日：1985-06-04

    申请号：US509532

    申请日：1983-06-30

    Applicant: Joelle R. Thomsen ,  David R. Fagerburg

    Inventor： Joelle R. Thomsen ,  David R. Fagerburg

    IPC: C08G63/181 ,  C08G63/00

    CPC classification number: C08G63/181

    Abstract: Poly(ethylene terephthalate), poly(1,4-cyclohexanedicarboxylate), poly(ethylene isophthalate), poly(ethylene naphthalate), their copolymers with each other and with modifying aliphatic dicarboxylic acids, and substituted glycol repeat unit modifications thereof are produced from prepolymer (oligomer) obtained from the esterification of the acid or acids with ethylene carbonate or substituted ethylenecarbonate in the presence of one or more amines compounds selected from trialkylamines, tetraalkyldiamines, N-alkylated heterocyclic amines, and certain quaternary ammonium salts, employing certain mole ratios of ethylene carbonate and substituted ethylene carbonate to the diacid. The prepolymer is formed in an unusually short time and the final polyester of high I.V. exhibits improvement in such properties as desirable light color and low ether-glycol level.

    Polyisophthalate and copolymers thereof having reduced cyclic dimer content, and a process for making the same
    95.
    发明授权
    Polyisophthalate and copolymers thereof having reduced cyclic dimer content, and a process for making the same 失效
    具有降低的环状二聚体含量的聚邻苯二甲酸酯及其共聚物及其制备方法

    公开(公告)号：US4424337A

    公开(公告)日：1984-01-03

    申请号：US415304

    申请日：1982-09-07

    Applicant: Richard R. Smith ,  David W. Sartorelli

    Inventor： Richard R. Smith ,  David W. Sartorelli

    IPC: C08G63/00 ,  C08G63/12 ,  C08G63/181 ,  C08G63/20 ,  C08G63/78 ,  C08G63/82 ,  C08G63/22

    CPC classification number: C08G63/20 ,  C08G63/181 ,  C08G63/82

    Abstract: A polyisophthalate such as poly(ethylene isophthalate) and copolymers thereof having high intrinsic viscosities as well as reduced ring dimer of ethylene isophthalate, and a process for making the same. A protonic acid catalyst is utilized along with intrinsic viscosity modifying agents during preparation of the polyisophthalate. The polymers produced have very high clarity, improved oxygen and carbon dioxide barrier resistance, high glass transition temperature, as well as increased molecular weights. They are thus suitable for use as materials in packaging or forming containers, such as bottles.

    Abstract translation: 具有高特性粘度的聚（间苯二甲酸乙二醇酯）和其共聚物的聚间苯二甲酸酯以及间苯二甲酸乙二醇酯的还原环二聚体及其制备方法。 在制备聚间苯二甲酸酯期间使用质子酸催化剂以及特性粘度调节剂。 所生产的聚合物具有非常高的透明度，改善的氧气和二氧化碳屏障性，高玻璃化转变温度以及分子量的增加。 因此，它们适合用作包装或形成诸如瓶子的容器的材料。

    Modified polyethylene terephthalate molding material
    96.
    发明授权
    Modified polyethylene terephthalate molding material 失效
    改性聚对苯二甲酸乙二醇酯成型材料

    公开(公告)号：US4415727A

    公开(公告)日：1983-11-15

    申请号：US416746

    申请日：1982-09-10

    Applicant: Yuzo Toga ,  Toshio Shimada ,  Ichiro Okamoto

    Inventor： Yuzo Toga ,  Toshio Shimada ,  Ichiro Okamoto

    IPC: B65D1/00 ,  C08G63/00 ,  C08G63/181 ,  C08G63/183 ,  C08G63/02 ,  C08G63/70

    CPC classification number: C08G63/183

    Abstract: A modified polyethylene terephthalate molding material containing terephthalic acid as a major dicarboxylic acid component and ethylene glycol as a major glycol component, which contains 0.1 to 15 mol %, based on the total amount of said glycol component present, of 2-methyl-1,3-propanediol as part of said glycol component.

    Abstract translation: 含有对苯二甲酸作为主要二羧酸成分的改性聚对苯二甲酸乙二醇酯成型材料和乙二醇作为主要二醇成分，其含有0.1〜15摩尔％，以所述二醇成分的总量计，2-甲基-1， 3-丙二醇作为所述二醇组分的一部分。

    Siliconized polyether thermosetting coating compositions
    97.
    发明授权
    Siliconized polyether thermosetting coating compositions 失效
    硅化聚醚热固性涂料组合物

    公开(公告)号：US4412032A

    公开(公告)日：1983-10-25

    申请号：US372244

    申请日：1982-04-28

    Applicant: Joseph E. Gaske ,  Thomas H. Plaisance ,  Kazys Sekmakas

    Inventor： Joseph E. Gaske ,  Thomas H. Plaisance ,  Kazys Sekmakas

    IPC: C08G63/181 ,  C09D167/00 ,  C09D183/10 ,  C08L67/02

    CPC classification number: C09D167/00 ,  C08G63/181 ,  C09D183/10

    Abstract: Pigmented thermosetting organic solvent solution coating compositions are disclosed which cure to provide improved weather resistance. These coating compositions contain three resin components, as follows:(1) an essentially nonfunctional organic solvent-soluble silicone resin reaction product of a low molecular weight hydroxy functional polyether with an hydroxy or alkoxy-functional organic polysiloxane, said polyether having an average molecular weight in the range of 300 to 4000 and an hydroxy functionality of at least about 3, said polysiloxane being present in an amount of from 8% to 20% of the weight of the three resin components, and said polyether and said polysiloxane being combined in approximately stoichiometric proportions;(2) a reactive organic solvent-soluble essentially linear high molecular weight hydroxy functional polyester constituting the balance of the three resin components; and(3) from 3% to 15% of the three resin components of a heterocyclic aminoplast resin for curing the reactive polyester.Components 1 and 2 are compatible in the solution and at least partially incompatible in a film as the solvent evaporates, so that component 1 can concentrate at the surface to enhance the weather resistance.

    Abstract translation: 公开了固化以提供改善的耐候性的着色的热固性有机溶剂溶液涂料组合物。 这些涂料组合物包含三种树脂组分，如下：（1）低分子量羟基官能聚醚与羟基或烷氧基官能的有机聚硅氧烷的基本上无功能的有机溶剂可溶的有机硅树脂反应产物，所述聚醚具有平均分子量 在300至4000的范围内且羟基官能度为至少约3，所述聚硅氧烷的存在量为三种树脂组分重量的8％至20％，所述聚醚和所述聚硅氧烷大致合并 化学计量比 （2）构成三种树脂成分的平衡的反应性有机溶剂可溶性基本线性高分子量羟基官能聚酯; 和（3）用于固化反应聚酯的杂环氨基塑料树脂的三种树脂组分的3％至15％。 组分1和2在溶液中是相容的，并且随着溶剂蒸发而在膜中至少部分不相容，使得组分1可以集中在表面以增强耐候性。

    Thermotropic alkylaromatic copolyesters
    98.
    发明授权
    Thermotropic alkylaromatic copolyesters 失效
    热致烷基芳族共聚酯

    公开(公告)号：US4311824A

    公开(公告)日：1982-01-19

    申请号：US78719

    申请日：1979-09-25

    Applicant: Bernard Fayolle

    Inventor： Bernard Fayolle

    IPC: D01F6/86 ,  C08G63/00 ,  C08G63/16 ,  C08G63/181 ,  C08G63/19 ,  C08G63/199 ,  C08G63/672 ,  C08G63/682 ,  D01F6/84 ,  C08G63/40

    CPC classification number: C08G63/199 ,  C08G63/19 ,  C08G63/672 ,  C08G63/6826

    Abstract: High molecular weight thermotropic copolyesters are disclosed which can be shaped. These copolyesters consist or consist essentially of units of the formulae:(--O--X.sub.1 --O--).sub.a, (--O--X.sub.2 --O--).sub.b, (--O--X.sub.3 --O--).sub.c, --CO--Y--CO-- or --CO--Z--CO--,in which: X.sub.1 represents a monosubstituted para-phenylene radical; X.sub.2 represents an unsubstituted 1,4-phenylene radical; and X.sub.3 represents a disubstituted para-phenylene radical, a 4,4'-diphenylene radical or a p,p'-diphenylene ether radical, where 0.4.ltoreq.a.ltoreq.1, O.ltoreq.b.ltoreq.0.6, O.ltoreq.c.ltoreq.0.1 and a+b+c=1; Y represents a 1,4-cyclohexylene radical, a radical having two phenylene groups joined to one another by a single bond or an acyclic chain, or a divalent aromatic radical having at least two fused phenyl nuclei; and Z represents a radical --(CH.sub.2).sub.n --, in which 3.ltoreq.n.ltoreq.10, the molar ratio Z/Y+Z being between 0.2 and 0.5. These copolyesters may be made up into molded articles, threads, films, etc.

    Abstract translation: 公开了可以成形的高分子量热致变共聚酯。 这些共聚酯基本上由下式的单元组成：（-O-X1-O-）a，（ - O-X2-O-）b，（-O-X3-O-）c，-CO-Y- CO-或-CO-Z-CO-，其中：X1表示单取代的对 - 亚苯基; X2表示未取代的1,4-亚苯基; 并且X 3表示二取代的对亚苯基，4,4'-二亚苯基或者ap，p'-二亚苯基醚基，其中0.4≤i≤0.0，O =

    Copolyester from 1,4-butanediol and a dicarboxylic acid mixture
    100.
    发明授权
    Copolyester from 1,4-butanediol and a dicarboxylic acid mixture 失效
    共聚酯由1,4-丁二醇和二羧酸混合物组成

    公开(公告)号：US4166895A

    公开(公告)日：1979-09-04

    申请号：US905624

    申请日：1978-05-15

    Applicant: Lothar Buxbaum ,  Rolf Hugi

    Inventor： Lothar Buxbaum ,  Rolf Hugi

    IPC: C08G63/00 ,  C08G63/16 ,  C08G63/181 ,  C09J167/00 ,  C09J167/02 ,  C08G63/18

    CPC classification number: C09J167/02 ,  C08G63/16

    Abstract: Copolyesters formed from 1,4-butanediol and a dicarboxylic acid mixture of, relative to the polyester, 8-12 mol % of sebacic acid or of an amount equal by weight of a saturated aliphatic dicarboxylic acid having 6 to 36 C atoms, 26-32 mol % of terephthalic acid and 7.5 to 12 mol % of isophthalic acid are hot melt adhesives which are characterized by resistance to ageing even at elevated temperatures, good adhesive strength and a relatively high heat resistance of the bonded areas.

    Abstract translation: 相对于聚酯，由1,4-丁二醇和二羧酸混合物形成的共聚酯为8〜12摩尔％的癸二酸，或相当于6〜36个碳原子的饱和脂肪族二羧酸的重量，26〜 对苯二甲酸为32摩尔％，间苯二甲酸为7.5〜12摩尔％为热熔粘合剂，其特征在于即使在高温下也具有耐老化性，粘合强度好，粘合面积的耐热性较高。

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