公开(公告)号：US4179406A

公开(公告)日：1979-12-18

申请号：US892369

申请日：1978-03-31

申请人： George J. Antos

发明人： George J. Antos

IPC分类号： B01J23/89 ,  C10G35/09 ,  B01J27/08 ,  B01J27/10

CPC分类号： B01J23/8953 ,  C10G35/09

摘要： Hydrocarbons are converted by contacting them at hydrocarbon conversion conditions with an acidic multimetallic catalytic composite comprising a combination of catalytically effective amounts of a platinum group component, a zinc component, a cobalt component, and a halogen component with a porous carrier material. The platinum group, zinc, cobalt, and halogen components are present in the multimetallic catalyst in amounts respectively, calculated on an elemental basis, corresponding to about 0.01 to about 2 wt. % platinum group metal, about 0.01 to about 5 wt. % zinc, about 0.05 to about 5 wt. % cobalt, and about 0.1 to about 3.5 wt. % halogen. These metallic components are uniformly dispersed throughout the porous carrier material in carefully controlled oxidation states such that substantially all of the platinum group metal is present therein in the elemental metallic state, substantially all of the catalytically available cobalt component is present in the elemental metallic state or in a state which is reducible to the elemental metallic state under hydrocarbon conversion conditions, or in a mixture of these states, while substantially all of the zinc is preferably present therein in an oxidation state above that of the elemental metal.

摘要翻译： 通过在碳氢化合物转化条件下与含有催化有效量的铂族组分，锌组分，钴组分和卤素组分与多孔载体材料的组合的酸性多金属催化复合物接触来转化碳氢化合物。 铂族，锌，钴和卤素组分分别以基于元素计算的量存在于多金属催化剂中，相当于约0.01至约2wt。 ％铂族金属，约0.01至约5wt。 ％锌，约0.05至约5wt。 ％钴，和约0.1至约3.5wt。 ％卤素。 这些金属组分以仔细控制的氧化态均匀地分散在整个多孔载体材料中，使得基本上所有的铂族金属存在于元素金属状态中，基本上所有催化可用的钴组分都以元素金属状态存在或 在碳氢化合物转化条件下还原为元素金属状态的状态下，或者以这些状态的混合状态，而基本上所有的锌优选以比元素金属高的氧化态存在。

公开(公告)号：US4169813A

公开(公告)日：1979-10-02

申请号：US886327

申请日：1978-03-13

申请人： John C. Hayes

发明人： John C. Hayes

IPC分类号： B01J23/62 ,  B01J23/656 ,  C10G35/09 ,  B01J27/08 ,  B01J27/10

CPC分类号： C10G35/09 ,  B01J23/62 ,  B01J23/624 ,  B01J23/6567

摘要： Hydrocarbons are converted by contacting them at hydrocarbon conversion conditions with an acidic multimetallic catalytic composite comprising a combination of catalytically effective amounts of a platinum or palladium component, a rhodium component, a rhenium component, a germanium component, and a halogen component with a porous carrier material. The platinum or palladium, rhodium, rhenium, germanium, and halogen components are present in the multimetallic catalyst in amounts respectively, calculated on a finished catalyst and elemental basis, corresponding to about 0.01 to about 2 wt. % platinum or palladium metal, about 0.01 to about 2 wt. % rhodium, about 0.01 to about 2 wt. % rhenium, about 0.01 to about 5 wt. % germanium, and about 0.1 to about 3.5 wt. % halogen. Moreover, these metallic components are uniformly dispersed throughout the porous carrier material in carefully controlled oxidation states such that substantially all of the platinum or palladium, rhenium and rhodium components are present therein in the elemental metallic state, and substantially all of the germanium component is present in an oxidation state above that of the elemental metal.

摘要翻译： 碳氢化合物通过在烃转化条件下与酸性多金属催化复合物接触而转化，所述酸性多金属催化复合材料包含催化有效量的铂或钯组分，铑组分，铼组分，锗组分和卤素组分与多孔载体的组合 材料。 铂或钯，铑，铼，锗和卤素组分分别以最终催化剂和元素计算的量存在于多金属催化剂中，相当于约0.01至约2重量％ ％铂或钯金属，约0.01至约2重量％ ％铑，约0.01至约2wt。 ％铼，约0.01至约5wt。 ％锗，和约0.1至约3.5重量％ ％卤素。 此外，这些金属组分在仔细控制的氧化状态下均匀地分散在整个多孔载体材料中，使得基本上所有的铂或钯，铼和铑组分都存在于元素金属状态中，并且基本上所有的锗组分都存在 处于比元素金属高的氧化态。

公开(公告)号：US4157989A

公开(公告)日：1979-06-12

申请号：US907240

申请日：1978-05-18

申请人： George J. Antos

发明人： George J. Antos

IPC分类号： B01J31/28 ,  B01J23/656 ,  B01J23/889 ,  B01J23/89 ,  C10G35/09 ,  B01J27/08 ,  B01J23/36 ,  B01J27/10

CPC分类号： B01J23/6567 ,  B01J23/8896 ,  B01J23/8986 ,  C10G35/09 ,  Y10S585/942

摘要： A novel superactive multimetallic hydrocarbon conversion catalytic composite comprises a combination of a catalytically effective amount of a pyrolyzed rhenium carbonyl component with a porous carrier material containing a uniform dispersion of a catalytically effective amount of a platinum group component which is maintained in the elemental metallic state. In a highly preferred embodiment, this novel catalytic composite also contains a catalytically effective amount of a halogen component. The platinum group component, pyrolyzed rhenium carbonyl component and optional halogen component are preferably present in the multimetallic catalytic composite in amounts, calculated on an elemental basis, corresponding to about 0.01 to about 2 wt. % platinum group metal, about 0.01 to about 5 wt. % rhenium and about 0.1 to about 3.5 wt. % halogen. A key feature associated with the preparation of the subject catalytic composite is reaction of a rhenium carbonyl complex with a porous carrier material containing a uniform dispersion of a platinum group metal maintained in the elemental state, whereby the interaction of the rhenium moiety with the platinum group moiety is maximized due to the platinophilic (i.e. platinum-seeking) propensities of the carbon monoxide ligand used in the rhenium reagent.

摘要翻译： 一种新型的超多活性多金属烃转化催化复合材料包括催化有效量的热解的铼羰基组分与多孔载体材料的组合，所述多孔载体材料含有维持在元素金属状态的催化有效量的铂族组分的均匀分散体。 在一个非常优选的实施方案中，该新型催化复合材料还含有催化有效量的卤素组分。 铂族组分，热解的铼羰基组分和任选的卤素组分优选以基于元素计算的量存在于多金属催化复合物中，相当于约0.01至约2重量％ ％铂族金属，约0.01至约5wt。 ％铼和约0.1至约3.5wt。 ％卤素。 与本发明催化复合材料的制备相关联的关键特征是羰基铑合金与保持元素状态的铂族金属均匀分散体的多孔载体材料的反应，由此铼部分与铂族的相互作用 部分由于铼试剂中使用的一氧化碳配体的铂嗜性（即铂寻求）倾向而最大化。

公开(公告)号：US4128596A

公开(公告)日：1978-12-05

申请号：US879571

申请日：1978-02-21

申请人： Clifford E. Smith ,  Hans D. Holtz

发明人： Clifford E. Smith ,  Hans D. Holtz

IPC分类号： B01J27/08 ,  B01J27/10 ,  C07C3/56

CPC分类号： B01J27/10 ,  B01J27/08

摘要： A catalytically active composition is provided that is an intercalate of graphite, aluminum halide, and a Group VA metal halide. A process for preparing an intercalate of graphite, aluminum halide, and a Group VA metal halide is also provided.

摘要翻译： 提供了催化活性组合物，其是石墨，卤化铝和VA族金属卤化物的插层。 还提供了制备石墨，卤化铝和VA族金属卤化物的插层的方法。

公开(公告)号：US4110251A

公开(公告)日：1978-08-29

申请号：US725584

申请日：1976-09-22

申请人： Alan Lauder ,  Elrey L. McCann, III

发明人： Alan Lauder ,  Elrey L. McCann, III

IPC分类号： B01D53/34 ,  B01D53/86 ,  B01J23/00 ,  B01J23/56 ,  B01J23/76 ,  B01J23/89 ,  B01J27/06 ,  C07C1/04 ,  C07C5/32 ,  C10G45/04 ,  B01J27/12 ,  B01J27/10

CPC分类号： C10G45/04 ,  B01D53/34 ,  B01D53/86 ,  B01J23/002 ,  B01J23/56 ,  B01J23/76 ,  B01J23/8933 ,  B01J27/06 ,  C07C1/043 ,  C07C5/321 ,  B01J2523/00 ,  Y10S502/525

摘要： Metal oxyhalides of the general formula ABO.sub.3-f X.sub.f having perovskite-type crystal structures in which A and B are each cations of at least one metal and a portion of the type B cations are catalytically active; X is fluoride or chloride; and f is about from 0.01 to 1.0; useful for the promotion of oxidation and reduction reactions, including those involved in the cleanup of exhaust gases of internal combustion engines.

摘要翻译： 具有其中A和B各自为至少一种金属的阳离子和B型阳离子的一部分的钙钛矿型晶体结构的通式ABO 3-f X f的金属卤氧化物具有催化活性; X是氟化物或氯化物; f约为0.01〜1.0; 可用于促进氧化还原反应，包括那些参与清理内燃机废气的工作。

公开(公告)号：US4107032A

公开(公告)日：1978-08-15

申请号：US737633

申请日：1976-11-01

申请人： Arthur Warren Chester

发明人： Arthur Warren Chester

IPC分类号： B01J8/26 ,  B01J29/06 ,  C10G11/05 ,  C10G11/18 ,  B01J8/24 ,  B01J27/10 ,  C10G23/04

CPC分类号： B01J29/061 ,  B01J8/26 ,  C10G11/05 ,  C10G11/182 ,  Y02P30/446

摘要： In a fluid catalytic cracking process for cracking hydrocarbons with a zeolitic cracking catalyst and in the absence of added hydrogen, the desired value of CO.sub.2 /CO in the flue gases from the regenerator is achieved by including in the catalyst a combustion-promoter metal such as platinum, palladium, rhodium, ruthenium, iridium, osmium or rhenium, and, additionally, contacting the catalyst with a metal-free chlorine or bromine compound.

摘要翻译： 在用沸石裂化催化剂裂化烃的流化催化裂解方法中，在没有添加氢气的情况下，来自再生器的烟气中CO 2 / CO的期望值通过在催化剂中包含助燃剂金属例如 铂，钯，铑，钌，铱，锇或铼，另外使催化剂与无金属的氯或溴化合物接触。

公开(公告)号：US4100058A

公开(公告)日：1978-07-11

申请号：US838266

申请日：1977-09-30

申请人： Lee Hilfman

发明人： Lee Hilfman

IPC分类号： B01J21/12 ,  B01J23/888 ,  C10G45/08 ,  C10G45/38 ,  C10G49/04 ,  C10G23/02 ,  B01J27/02 ,  B01J27/10

CPC分类号： C10G45/38 ,  B01J21/12 ,  B01J23/888 ,  C10G45/08 ,  C10G2400/08

摘要： A process for hydrotreating (hydroprocessing) hydrocarbons and mixtures of hydrocarbons utilizing a catalytic composite comprising a combination of a nickel component and a tungsten component with a silica-alumina carrier material wherein said carrier material is co-gelled silica-alumina consisting of from about 43 percent to about 57 percent by weight of alumina and from about 57 percent to 43 percent by weight silica and wherein said components are present in amounts sufficient to result in the composite containing, on an elemental basis, about 2 to about 10 percent by weight of the nickel component and about 8 to about 20 percent by weight of the tungsten component, in which process there is effected a chemical consumption of hydrogen. Key features of the subject composite are the criticality of the alumina content of the carrier material and the facility of using a co-gelled silica-alumina carrier material. The principal utility of the subject composite is in the hydrocracking of hydrocarbons. A specific example of the catalyst disclosed is a combination of nickel and tungsten with a co-gelled silica-alumina carrier material containing 50 weight percent alumina in amounts sufficient to result in the composite containing, on an elemental basis, about 7 to about 9 weight percent nickel and about 17 to about 19 weight percent tungsten. Other hydrocarbon hydroprocesses are directed toward the hydrogenation of aromatic nuclei, the ring-opening of cyclic hydrocarbons, desulfurization, denitrification, hydrogenation, etc.

摘要翻译： 使用包含镍组分和钨组分的组合的催化复合物与二氧化硅 - 氧化铝载体材料加氢处理（加氢处理）烃和烃的混合物的方法，其中所述载体材料是共聚凝胶的二氧化硅 - 氧化铝，由约43 百分比至约57重量％的氧化铝和约57重量％至43重量％的二氧化硅，并且其中所述组分的存在量足以导致所述复合材料在元素基础上含有约2至约10重量％ 镍组分和约8至约20重量％的钨组分，其中进行氢的化学消耗。 主题复合材料的主要特征是载体材料的氧化铝含量的关键性和使用共凝胶二氧化硅 - 氧化铝载体材料的设备。 主题复合材料的主要用途是加氢裂化烃类。 所公开的催化剂的具体实例是镍和钨与共凝胶二氧化硅 - 氧化铝载体材料的组合，其含有50重量％的氧化铝，其量足以导致复合材料在元素基础上含有约7至约9重量％ 的镍和约17至约19重量％的钨。 其他烃类加氢工艺涉及芳烃氢化，环状烃开环，脱硫，脱氮，氢化等。

公开(公告)号：US4069170A

公开(公告)日：1978-01-17

申请号：US750027

申请日：1976-12-13

申请人： Robert J. Blake ,  Guy W. Roy

发明人： Robert J. Blake ,  Guy W. Roy

IPC分类号： B01J27/10 ,  C07C17/15 ,  B01J27/06

CPC分类号： B01J27/10 ,  C07C17/15

摘要： Catalyst compositions comprising mixtures of salts of copper, potassium, didymium, lanthanum and magnesium are useful in the fluidized bed oxychlorination of aliphatic hydrocarbons. The catalyst composition loading is disposed on a suitable support media, preferably an alumina and does not cake or cause defluidization of the bed under start-up, operating, or shut-down conditions.

摘要翻译： 包含铜，钾，钕，镧和镁的盐的混合物的催化剂组合物可用于脂族烃的流化床氧氯化。 将催化剂组合物负载设置在合适的载体介质上，优选氧化铝，并且不会在启动，运​​行或停机条件下使床脱粘或引起床层流化。

公开(公告)号：US4055511A

公开(公告)日：1977-10-25

申请号：US666713

申请日：1976-03-15

申请人： Glenn R. Elion ,  Arthur E. Klink

发明人： Glenn R. Elion ,  Arthur E. Klink

IPC分类号： C07D277/20 ,  B01J23/88 ,  B01J23/887 ,  C07D277/32 ,  C07D277/56 ,  B01J27/10

CPC分类号： B01J23/8878 ,  C07D277/56

摘要： 4-Cyanothiazole is prepared by the catalytic vapor phase ammoxidation of .DELTA.3-4-methylthiazoline or 4-methylthiazole, using as catalyst a novel composition comprising a slurried chromium cobalt molybdate. The process affords high selectivity in the production of 4-cyanothiazole.

摘要翻译： 4-氰基噻唑通过DELTA 3-4-甲基噻唑啉或4-甲基噻唑的催化气相氨氧化制备，使用作为催化剂的包含浆状铬酸钼钴的新型组合物。 该方法在4-氰基噻唑的生产中提供高选择性。

公开(公告)号：US4046711A

公开(公告)日：1977-09-06

申请号：US699748

申请日：1976-06-24

申请人： George J. Antos

发明人： George J. Antos

IPC分类号： B01J23/62 ,  B01J27/13 ,  B01J37/02 ,  C10G35/09 ,  B01J27/08 ,  B01J23/14 ,  B01J27/10

CPC分类号： B01J23/624 ,  B01J37/0203 ,  C10G35/09

摘要： A method of catalyst manufacture wherein a common non-aqueous solution of a soluble platinum group metal compound and a halo-substituted germane is utilized to impregnate a porous high surface area carrier material, the impregnated carrier material being subsequently dried and calcined. The method of manufacture results in an improved hydrocarbon conversion catalyst, particularly with respect to catalytic reforming.

摘要翻译： 一种催化剂制备方法，其中使用常见的可溶性铂族金属化合物和卤代取代的锗烷的非水溶液来浸渍多孔高表面积载体材料，随后将浸渍的载体材料干燥和煅烧。 制造方法产生改进的烃转化催化剂，特别是在催化重整方面。