摘要:
The novel polymers of the present invention are prepared by reacting a heterocyclic nitrogen compound containing at least one --N(H)-- group in the ring, an aldehyde and amino-substituted polymer (e.g., an ethylene alpha-olefin interpolymer substituted by primary amino or secondary amino groups) to form an oil soluble Mannich base derivative useful as antioxidant additive in oleaginous compositions such as lubricating oils and fuels. Preferred heterocyclic nitrogen compound are azoles such as benzotriazoles and alkyl-substituted benzotriazoles. Preferred amino-substituted interpolymers comprise amino-substituted ethylene propylene norbornene terpolymers. The polymers of this invention are oil soluble and are useful as dispersants, viscosity index improver dispersants, and as antiwear and antioxidant additives in oleaginous compositions.
摘要:
The novel polymers of the present invention are prepared by graft polymerization of at least one aromatic nitrogen-containing monomer onto an amino-substituted polymer (e.g., an ethylene alpha-olefin interpolymer substituted by primary amino or secondary amino groups). Preferred aromatic nitrogen-containing moieties are illustrated by aniline, and preferred amino-substituted interpolymers comprise amino-substituted ethylene propylene norbornene terpolymers. The polymers of this invention are oil soluble and are useful as dispersant and antioxidant additives in oleaginous compositions and are further useful in electrical, textile and other applications.
摘要:
The novel polymers of the present invention are prepared by reacting a heterocyclic nitrogen compound containing at least one --N(H)-- group in the ring, an aldehyde and amino-substituted polymer (e.g., an ethylene alpha-olefin interpolymer substituted by primary amino or secondary amino groups) to form an oil soluble Mannich base derivative useful as antioxidant additive in oleaginous compositions such as lubricating oils and fuels. Preferred heterocyclic nitrogen compound are azoles such as benzotriazoles and alkyl-substituted benzotriazoles. Preferred amino-substituted interpolymers comprise amino-substituted ethylene propylene norbornene terpolymers. The polymers of this invention are oil soluble and are useful as dispersants, viscosity index improver dispersants, and as antiwear and antioxidant additives in oleaginous compositions.
摘要:
Polymers of olefin monomers and a substantially uniform concentration of carboxyl, hydroxyl, thio, amino, cabonyl and imino functional group-containing monomers. Polymers of olefin monomers and carboxyl, hydroxyl, thio, amino, carbonyl and imino functional group-containing monomers substantially devoid of halogen. Method for preparing polymers by reacting carboxyl, hydroxyl, thio, amino, carbonyl and imino functional group-containing monomers with non-halogenated organometallic compounds to form masked, functional group-containing monomers and polymerizing polymer chain monomers with the masked, functional group-containing monomers to produce a polymer chain. Method for forming masked, functional group-containing monomers by reacting carboxyl, hydroxyl, thio, amino, carbonyl and imino functional group-containing monomers with non-halogenated organometallic compounds. Masked, carboxyl, hydroxyl, thio, amino, carbonyl and imino functional group-containing monomers.
摘要:
By selecting the composition and intermolecular compositional distribution with respect to ethylene and diene content and the molecular weight and molecular weight distribution, ethylene-propylene-diene terpolymers can have both improved processing properties and compound vulcanizate physical properties. The lower molecular weight fractions of 10.sup.4 to about 5.times.10.sup.5 have at least 2 times the diene content of the higher molecular weight fractions and an ethylene content of 30-80 wt. %. The higher molecular weight fractions of 2.times.10.sup.5 to about 10.sup.7 have a higher ethylene content than the lower molecular weight fractions and are less than 90 wt. % ethylene.
摘要:
Polymer compositions for use as viscosity modifiers comprising at least two ethylene-based copolymer components are provided. The polymer composition comprises (a) a first ethylene-α-olefin copolymer and (b) a second ethylene-α-olefin copolymer. The first ethylene-α-olefin copolymer (a) has an ethylene content from about 60 to about 80 wt % and the second ethylene-α-olefin copolymer (b) has an ethylene content of less than about 60 wt %. The first ethylene-α-olefin copolymer (a) has a Melt Flow Rate Ratio (MFRR), defined as the ratio of the MFR measured at 230° C./21.6 kg and at 230° C./2.16 kg, of greater than 30 and optionally also has a Melt Flow Rate (MFR) of at least about 1.5 g/10 min, measured by ASTM D 1238 condition L (230° C./2.16 kg). The present disclosure is also directed to lubricant compositions comprising a lubricating basestock and a polymer composition of the present disclosure and is further directed to reducing gelation in the lubricant compositions.
摘要:
Disclosed herein is a nonwoven fabric comprising within the range of from 50 to 99 wt %, by weight of the composition, of a reactor grade propylene-α-olefin copolymer possessing within the range of from 5 to 35 wt %, by weight of the copolymer, of units derived from one or more of ethylene and/or C4 to C12 α-olefins; a melt flow rate (230° C./2.16 kg) within the range of from 500 to 7500 g/10 min; and a weight average molecular weight of less than 200,000; and a second polypropylene having a melting point, Tm, of greater than 110° C. and a melt flow rate (230° C./2.16 kg) within the range of from 20 to 7500 g/10 min; wherein the fabric has a CD Elongation value of greater than 50% (measuring the fabric of 35 g/m2 basis weight). The fabric described herein can be used in structures comprising one or more layers of the fabric described herein, and can include any number of other fabric layers made from other materials.
摘要:
Provided are ethylene-based copolymers, methods of preparing the same, lubricating oil compositions including the same, methods for preparing such lubricating oil compositions, and end uses for such ethylene-based copolymers and lubricating oil compositions. The ethylene-based copolymers may include less than about 80 wt. % of units derived from ethylene and one or more alpha-olefin comonomers having 3 to 20 carbon atoms. The ethylene-based copolymers have a melting peak (Tm), as measured by DSC, of 80° C. or less, and a polydispersity index of about 2.8 or less. In some embodiments, the ethylene-based copolymers have an intramolecular composition distribution of about 50 wt. % or less and/or an intermolecular composition distribution of about 50 wt. % or less.
摘要:
The present invention also discloses a heterogeneous blend composition comprising; a) from 1% to 99% by weight of the blend of a first polymer component comprising a copolymer of 5% to 35% by weight of the first polymer component consisting predominantly of alpha olefin derived units and 65% to 95% by weight of the first polymer component of propylene derived units having a crystallinity of 0.1% to about 25% from isotactic polypropylene sequences, a melting point of from 45° C. to 105° C., and wherein the Melt Flow Rate (MFR@230° C.) of the first polymer component is between 300 g/10 min to 5000 g/10 min b) from 1% to 99% by weight of the blend of a second polymer component comprising isotactic polypropylene and random copolymers of isotactic propylene, wherein the percentage of the copolymerized alpha-olefin in the copolymer is between 0.0% and 9% by weight of the second polymer component and wherein the second polymer component has a melting point greater than about 110° C., wherein the first polymer component has less than 1000 ppm of reaction products arising from the chemical reaction of a molecular degradation agent.
摘要:
Styrenic block copolymers are blended with propylene copolymers to provide polymeric compositions with an improved balance between processability and elasticity. The compositions have improved processability by facilitating the ease with which a rubbery material, usually difficult to melt process, can be processed at high line speeds, which in turn improves the formation of the composition into films or other articles, assisted by a desired level of melt elasticity, i.e., a high elastic extension and recovery.