Waterless dye composition and method of use thereof for coloring
thermoplastic articles
    111.
    发明授权
    Waterless dye composition and method of use thereof for coloring thermoplastic articles 失效
    无水染料组合物及其用于着色热塑性制品的方法

    公开(公告)号:US4581035A

    公开(公告)日:1986-04-08

    申请号:US669354

    申请日:1984-11-08

    申请人: Robert B. Wilson

    发明人: Robert B. Wilson

    摘要: A waterless dye composition for apparel and other thermoplastic articles comprises a triglyceride fat or oil of the formula ##STR1## wherein acyl, acyl' and acyl" each are saturated or unsaturated substituted or unsubstituted linear alkanoyl of an even number of carbon atoms from 10-30 carbon atoms and an organic colorant.The composition can further contain one or more of:A. an aromatic polyester of the formula C.sub.6 H.sub.z' -(COOR.sub.1).sub.z, wherein z is 3, 4,5, or 6; z' is 6-z and R.sub.1 is higher alkyl;B. a cycloaliphatic diester of the formula ##STR2## wherein R is substituted or unsubstituted straight or branched chain alkyl of 4-20 carbon atoms, polyoxyalkylene of the formula HO(C.sub.x H.sub.y O).sub.n C.sub.x H.sub.y --or phosphated polyoxyalkylene of the formula(HO).sub.2 P(.dbd.O)O(C.sub.x H.sub.2x O).sub.n C.sub.x H.sub.2x or a salt thereof, wherein (C.sub.x H.sub.2x O).sub.n is (CH.sub.2 CH.sub.2 O).sub.n, (C.sub.3 H.sub.6 O).sub.n or (CH.sub.2 CH.sub.2 O).sub.p --(C.sub.3 H.sub.6 O).sub.q, n is 2-22, and the sum of p+q is n; orC. a bisterephthalate ester of an alkylphenylpolyoxyethanol.A process for coloring apparel or other articles, fabricated from polyester, polyamide, polyurethane, acrylic, halogenated polyolefin or epoxy plastic, comprises exposing an article to the foregoing compositions, maintained at a temperature between 100.degree. C. and the temperature at which the plastic is degraded, for a time adequate to achieve the desired degree of coloration.

    摘要翻译: 用于服装和其它热塑性制品的无水染料组合物包含甘油三酯脂肪或下式的油:其中酰基,酰基和酰基各自为饱和或不饱和的取代或未取代的直链烷酰基,其偶数碳原子为10 -30碳原子和有机着色剂。 所述组合物可以进一步含有一种或多种:A.式C 6 H 6' - (COOR 1)z的芳族聚酯,其中z为3,4,5或6; z'为6-z,R 1为高级烷基; B.式(Ia)的脂环族二酯,其中R是取代或未取代的4-20个碳原子的直链或支链烷基,式HO(C x H y O)n C x H y的聚氧化烯或式(HO)2 P的磷酸化聚氧化烯 = O)O(C x H x O)n C x H 2 x或其盐,其中(C x H 2 x O)n为(CH 2 CH 2 O)n,(C 3 H 6 O)n或(CH 2 CH 2 O)p - (C 3 H 6 O)q,n为2-22, + q是n; 或C.一种烷基苯基聚氧乙醇的对苯二甲酸酯。 用于着色由聚酯,聚酰胺,聚氨酯,丙烯酸,卤化聚烯烃或环氧树脂制成的服装或其他制品的方法包括将制品暴露于前述组合物,保持在100℃至塑料的温度 在一段时间内降解,达到所需的着色程度。

    Method for dyeing of fibers in the presence of quaternary
alkoxyalkylammonium retarding or leveling agent
    112.
    发明授权
    Method for dyeing of fibers in the presence of quaternary alkoxyalkylammonium retarding or leveling agent 失效
    在季烷氧基烷基铵阻滞剂或流平剂存在下染色纤维的方法

    公开(公告)号:US4579560A

    公开(公告)日:1986-04-01

    申请号:US628250

    申请日:1984-07-06

    CPC分类号: D06P1/66 Y10S8/922 Y10S8/927

    摘要: Novel quaternary alkoxyalkylammonium compounds of the formula 1 ##STR1## in which R denotes C.sub.8 -C.sub.20 --, preferably C.sub.12 -C.sub.18 --, alkyl or C.sub.8 -C.sub.20 --, preferably C.sub.12 -C.sub.18 --, alkenyl, R.sub.1, R'.sub.1 and R".sub.1, which can be identical or different, denote methyl, ethyl or benzyl and at least one of the radicals R.sub.1, R'.sub.1 and R".sub.1 denotes a group of the formula --(C.sub.S H.sub.2S O).sub.x H,R.sub.2 and R.sub.3, which can be identical or different, denote methyl, ethyl or benzyl,a denotes 0 or 1, b denotes 0 or 1, of which either a or b has to be=1, m denotes 0 or 1, n denotes 2 or 3, p denotes 1, 2 or 3, S denotes 2 or 3, x denotes 1, 2, 3 or 4, and A denotes a halide, methosulfate, ethosulfate or methophosphate ion. These compounds are used as retarders and leveling agents in the dyeing of polyacrylonitrile and acid-modified polyester fibers.

    摘要翻译: 其中R表示C 8 -C 20 - ,优选C 12 -C 18 - 烷基或C 8 -C 20 - ,优选C 12 -C 18 - 烯基,R 1,R'1和R“'的新型季烷氧基烷基铵化合物, 1,其可以相同或不同,表示甲基,乙基或苄基,并且基团R1,R'1和R'1中的至少一个表示式 - (CSH 2 SO)x H,R 2和R 3的基团,其可以 相同或不同,表示甲基,乙基或苄基,a表示0或1,b表示0或1,其中a或b必须= 1,m表示0或1,n表示2或3,p表示 1,2或3,S表示2或3,x表示1,2,3或4,A表示卤化物,甲基硫酸盐,乙二硫酸盐或甲基磷酸根离子。 这些化合物在聚丙烯腈和酸改性聚酯纤维的染色中用作缓凝剂和流平剂。

    Overprinting of dye colored poly(vinyl chloride) resins
    113.
    发明授权
    Overprinting of dye colored poly(vinyl chloride) resins 失效
    染色聚(氯乙烯)树脂套印

    公开(公告)号:US4536184A

    公开(公告)日:1985-08-20

    申请号:US550828

    申请日:1983-11-14

    申请人: Thomas D. Ryan

    发明人: Thomas D. Ryan

    摘要: The invention is directed to overprinting a poly(vinyl chloride) resin substrate whose surface, or portion thereof, is colored by solvent soluble dye or by way of a mass solvent soluble dye, with a coloring agent made up of a liquid halogenated hydrocarbon solvent having 1-4 carbon atoms, pigment dispersed in said halohydrocarbon solvent, and a film former, dissolved in said halohydrocarbon solvent, consisting essentially of (a) acrylic resin or (b) a combination of acrylic resin and chlorinated polyolefin, at least 50% by weight of acrylic resin; and heat treating said overprinted substrate to adhere said film former and associated pigment.

    摘要翻译: 本发明涉及一种聚(氯乙烯)树脂基材,其表面或其部分由溶剂可溶性染料或通过溶剂可溶性染料着色,由着色剂组成,该着色剂由液态卤代烃溶剂组成, 1-4个碳原子,分散在所述卤代烃溶剂中的颜料和成膜剂,其溶解在所述卤代烃溶剂中,基本上由(a)丙烯酸树脂或(b)丙烯酸树脂和氯化聚烯烃的组合组成,至少50% 丙烯酸树脂重量; 并对所述叠印的基底进行热处理以粘附所述成膜剂和相关颜料。

    Fluid formulations of oxidation dyes for mineral oil products, fats and
waxes
    116.
    发明授权
    Fluid formulations of oxidation dyes for mineral oil products, fats and waxes 失效
    用于矿物油产品,脂肪和蜡的氧化染料的流体配方

    公开(公告)号:US4378969A

    公开(公告)日:1983-04-05

    申请号:US260273

    申请日:1981-05-06

    IPC分类号: C09B53/02 C09B67/44 D06P3/00

    CPC分类号: C09B67/0083 C09B53/02

    摘要: Fluid formulations of oxidation dyes, which are obtained by oxidizing a compound of the general formula I ##STR1## where R.sup.1 is unsubstituted or hydroxy-, C.sub.1 -C.sub.8 -alkoxy- or C.sub.1 -C.sub.8 -alkanoyloxy-substituted C.sub.2 -C.sub.13 -alkyl,R.sup.2 is hydrogen or unsubstituted or hydroxy- or C.sub.1 -C.sub.8 -alkoxy-substituted C.sub.1 -C.sub.13 -alkyl andX is hydroxyl, amino or ##STR2## in an organic solvent, are particularly suitable for dyeing mineral oil products, fats and waxes.

    摘要翻译: 氧化染料的流体制剂,其通过氧化通式I的化合物,其中R 1是未取代的或羟基,C 1 -C 8 - 烷氧基 - 或C 1 -C 8 - 烷酰氧基取代的C 2 -C 13 - 烷基, R2是氢或未取代的或羟基或C1-C8-烷氧基取代的C1-C13 - 烷基,X是羟基,氨基或有机溶剂中的“IMAGE”,特别适用于染色矿物油产品,脂肪和蜡。

    Monoazo compounds having a substituted thiazolium-5 diazo component
radical and a substituted 1,4-phenylene coupling component radical
    119.
    发明授权
    Monoazo compounds having a substituted thiazolium-5 diazo component radical and a substituted 1,4-phenylene coupling component radical 失效
    具有取代的噻唑鎓-5重氮组分基团和取代的1,4-亚苯基偶联组分基团的单偶氮化合物

    公开(公告)号:US4314817A

    公开(公告)日:1982-02-09

    申请号:US177016

    申请日:1980-08-11

    CPC分类号: C09B44/20 Y10S8/927

    摘要: Compounds of the formula ##STR1## in which R is --CH.sub.3, --C.sub.2 H.sub.5, --CH.sub.2 CH.sub.2 OH, --CH.sub.2 CH(OH)CH.sub.3 or --CH.sub.2 CH.dbd.CH.sub.2 ;R.sub.1 is --H or --CH.sub.3 ;R.sub.2 is --H or --CH.sub.3 ;R.sub.3 is --OCH.sub.3 or --OC.sub.2 H.sub.5 ;R.sub.4 is --H, --CH.sub.3, --C.sub.2 H.sub.5, n- or i- C.sub.3 H.sub.7, --CH.sub.2 CH.sub.2 OH or --CH.sub.2 CH.dbd.CH.sub.2 ;R.sub.5 is --H, --CH.sub.3, --C.sub.2 H.sub.5, n- or i- C.sub.3 H.sub.7 or R.sub.3 and R.sub.5 together with the N-atom to which R.sub.5 is attached and ring B form the group ##STR2## wherein R.sub.2 and R.sub.4 are as defined above, andR.sub.6 is --H or CH.sub.3 ; andA.sup..crclbar. is an anion,which are suitable for use as dyes, particularly for dyeing textile substrates comprising or consisting of homopolymers and copolymers of acrylomotrile or asymmetric dicyanoethylene, polyamides modified to contain acid groups and polyesters modified to contain acid groups and for leather, paper and plastics.

    摘要翻译: 其中R为-CH 3,-C 2 H 5,-CH 2 CH 2 OH,-CH 2 CH(OH)CH 3或-CH 2 CH = CH 2的式IMA化合物; R1是-H或-CH3; R2是-H或-CH3; R3是-OCH3或-OC2H5; R4是-H,-CH3,-C2H5,n或i-C3H7,-CH2CH2OH或-CH2CH = CH2; R 5是-H,-CH 3,-C 2 H 5,正或者C 3 H 7,或者R 3和R 5与与R 5连接的N-原子一起形成环B,其中R 2和R 4如上定义, 并且R6是-H或CH3; 和A( - )是一种阴离子,其适合用作染料,特别是用于染色纺织品基材,包括丙烯腈或不对称二氰基乙烯的均聚物和共聚物,或由改性含有酸基团的聚酰胺和经修饰以含有酸基团的聚酯 皮革,纸张和塑料。