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公开(公告)号：US5397457A
公开(公告)日：1995-03-14
申请号：US203185
申请日：1994-02-25
IPC分类号： C10G47/18
CPC分类号： C10G47/18
摘要： A hydrocarbon fraction, preferably in the kerosene boiling range containing a substantial proportion of C.sub.9 + hydrocarbons is contacted with an n-paraffin fraction, such as n-pentane, over a catalyst of acidic functionality, such as Pd/zeolite beta, under conditions of hydrocracking sufficient to convert the feed to lower boiling range materials of high octane number. The n-paraffin cofeed promotes isomerization and suppresses production of n-paraffins.
摘要翻译： 在氢化裂化条件下，在酸性官能团的催化剂如Pd /沸石β上，将含有大部分C 9+烃的烃馏分优选与正链烷烃馏分如正戊烷接触。 足以将进料转化为高辛烷值的较低沸点材料。 正链烷烃共进料促进异构化并抑制正链烷烃的生产。
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公开(公告)号：US5015364A
公开(公告)日：1991-05-14
申请号：US369169
申请日：1989-06-21
申请人： Mohsen N. Harandi
发明人： Mohsen N. Harandi
CPC分类号： C10G21/00 , C10G5/04 , C10G70/048 , C10G70/06
摘要： A process is disclosed for operating a refinery gas plant such as the unsaturated gas plant of a catalytic hydrocarbon conversion process that results in a reduction of the corrosive effect of acid gases on the gas plant vessels and equipment. The process comprises contacting acidic hydrocarbon feedstreams to an unsaturated gas plant separator zone with lean acid gas absorbing absorbent in an absorbtion zone comprising at least one liquid absorber bed and one vapor absorber bed. The liquid and vapor absorber beds are located upstream of the separator zone. The feedstreams to the gas plant comprise unstabilized, or wild, liquid gasoline and liquid and vapor output streams from the liquid-vapor separator for inter-stage wet gas compressor of the conversion process main fractionator. Accordingly, these feedstreams are deacidified before separation in the USGP deethanizer-absorber, sponge absorber, and debutanizer. This also eliminates the need for deacidification of the gas plant product stream.
摘要翻译： 公开了一种用于操作炼油厂气体设备（例如催化烃转化过程的不饱和气体装置）的方法，其导致酸性气体对气体装置容器和设备的腐蚀作用的降低。 该方法包括使酸性烃进料流与含有至少一个液体吸收剂床和一个蒸气吸收剂床的吸收区中的贫酸性气体吸收吸收剂的不饱和气体分离器区域接触。 液体和蒸汽吸收剂床位于分离器区域的上游。 来自气体设备的进料流包括来自转化过程主分馏器的级间湿气压缩机的液 - 气分离器的不稳定或野生液体汽油和液体和蒸气输出流。 因此，这些原料流在USGP脱乙烷吸收器，海绵吸收器和脱丁烷塔中分离之前是脱酸的。 这也消除了对气体工厂产品流的脱酸的需要。
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公开(公告)号：US5004852A
公开(公告)日：1991-04-02
申请号：US399182
申请日：1989-08-24
申请人： Mohsen N. Harandi
发明人： Mohsen N. Harandi
CPC分类号： C07C2/12 , C10G50/00 , C07C2529/40 , C07C2529/65 , C07C2529/70
摘要： Light aliphatic streams containing C.sub.4 - olefins are upgraded to C.sub.5 + gasoline in a two-stage process. In the first stage, olefins are oligomerized to C.sub.5 + olefinic gasoline. Unreacted light aliphatics including ethylene as well as light oligomerization byproducts are then charged to a second stage aromatization zone. Catalysts useful for both stages include medium pore zeolites.
摘要翻译： 含有C4-烯烃的轻质脂族物流在两阶段过程中升级为C5 +汽油。 在第一阶段，烯烃被低聚成C5 +烯烃汽油。 然后将包括乙烯在内的未反应的轻脂肪族以及轻质低聚副产物加入第二阶段芳构化区。 可用于两个阶段的催化剂包括中孔沸石。
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124.发明授权Hydrocarbon upgrading process and reaction section design with regenerated catalyst quench 失效碳氢化合物更新过程和反应段设计与再生催化剂淬火
公开(公告)号：US4956510A
公开(公告)日：1990-09-11
申请号：US322956
申请日：1989-03-14
申请人： Mohsen N. Harandi
发明人： Mohsen N. Harandi
IPC分类号： C10G35/14
CPC分类号： C10G35/14
摘要： Valuable product yield and catalyst useful life are improved by regenerating spent catalyst at temperatures below those maintained in the reaction zone. Relatively cold regenerated catalyst is then preheated and reactor effluent product is quenched by directly contacting the regenerated catalyst with hot reactor effluent product. The quenching step minimizes undesirable thermal cracking of valuable product to C.sub.2 -light gas. The process and apparatus are useful both in aromatization and dehydrogenation of aliphatic hydrocarbons.
摘要翻译： 通过在低于维持在反应区中的温度下再生废催化剂，可以改善产品产率和催化剂使用寿命。 然后将相对冷再生的催化剂预热，并通过将再生催化剂与热反应器流出物直接接触来猝灭反应器流出物。 淬火步骤使有价值产品对C2轻质气体的不期望的热裂化最小化。 该方法和装置在脂族烃的芳构化和脱氢中都是有用的。
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公开(公告)号：US4886925A
公开(公告)日：1989-12-12
申请号：US189450
申请日：1988-05-02
申请人： Mohsen N. Harandi
发明人： Mohsen N. Harandi
CPC分类号： C10G50/00 , C07C41/06 , C10G29/205 , C10L1/023 , C10L1/06 , Y02P20/125 , Y02P30/20
摘要： An integrated process is disclosed for the conversion of C.sub.2 + normal olefins into methyl tertiaryalkyl ethers and high octane gasoline. The process combines olefins interconversion with etherification and conversion of unreacted methanol and olefins in contact with acidic, shape selective metallosilicate zeolite catalyst.
摘要翻译： 公开了将C2 +正烯烃转化为甲基叔烷基醚和高辛烷值汽油的综合方法。 该方法将烯烃相互转化与醚化反应以及与酸性，形状选择性金属硅酸盐沸石催化剂接触的未反应的甲醇和烯烃的转化。
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公开(公告)号：US20110147267A1
公开(公告)日：2011-06-23
申请号：US12946317
申请日：2010-11-15
CPC分类号： C10G35/09 , B01J23/656 , B01J23/6567 , B01J23/94 , B01J23/96 , B01J38/02 , B01J38/06 , B01J38/10 , B01J38/16 , B01J38/44 , C10G35/085 , C10G35/24 , C10G2400/02
摘要： This invention relates to process for producing a reformate or gasoline product. The process involves a rapid cycle of reacting hydrocarbon feedstock to form the product and then regenerating the catalyst used in the reaction. The process can be carried out at relatively high liquid hourly space velocities and preferably at relatively low hydrogen to hydrocarbon ratios to produce a reformed product having relatively high liquid yield and hydrogen content.
摘要翻译： 本发明涉及重整产品或汽油产品的生产方法。 该方法涉及使烃原料反应形成产物，然后再生反应中使用的催化剂的快速循环。 该方法可以在相当高的液时空速下进行，优选在相对低的氢烃比下进行，以产生具有相对较高的液体产率和氢含量的重整产物。
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127.发明申请Crude oil blending to reduce organic-based fouling of pre-heat train exchangers and furnaces 审中-公开原油混合以减少预热交换器和炉子的有机物结垢公开(公告)号：US20080047874A1
公开(公告)日：2008-02-28
申请号：US11508251
申请日：2006-08-23
申请人： Glen B. Brons , Douglas S. Meyer , Mohsen N. Harandi , Praveen Duggal , Douglas P. Bryant , Rick Coy , Jack C. Dougherty
发明人： Glen B. Brons , Douglas S. Meyer , Mohsen N. Harandi , Praveen Duggal , Douglas P. Bryant , Rick Coy , Jack C. Dougherty
IPC分类号： C10G31/00
摘要： A high solvent power (HSP) crude oil is added to a blend of incompatible oils to proactively address the potential for fouling heat exchange equipment. The HSP component dissolves asphaltene precipitates before coking affects heat exchange surfaces. An HSP oil is also flushed through heat exchange equipment to remove any deposits and/or precipitates on a regular maintenance schedule before coking can affect heat exchange surfaces.
摘要翻译： 将高溶剂能（HSP）原油加入到不相容油的混合物中，以主动解决污染热交换设备的可能性。 在焦化影响热交换表面之前，HSP组分溶解沥青质沉淀物。 HSP油也通过热交换设备冲洗，以在定期维护计划之前去除任何沉积物和/或沉淀物，然后焦化可影响热交换表面。
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公开(公告)号：US5625113A
公开(公告)日：1997-04-29
申请号：US365334
申请日：1994-12-28
CPC分类号： C07C2/58 , C07C2/62 , C07C9/16 , C07C2527/054 , C07C2529/70
摘要： A process is disclosed for alkylating an isoparaffin with an olefin comprising the steps of:(a) reacting an isoparaffin having from 4 to 8 carbon atoms with an olefin having from 2 to 12 carbon atoms in a first alkylation reaction stage at temperature from about -40.degree. C. to about 500.degree. C. and overall isoparaffin:olefin feed weight ratio of from about 1:1 to about 250:1 with a solid alkylation catalyst comprising a synthetic porous crystalline material characterized by an X-ray diffraction pattern including values substantially as set forth in Table I of the specification and having a composition comprising the molar relationshipX.sub.2 O.sub.3 :(n)YO.sub.2,wherein n is less than about 35, X is a trivalent element and Y is a tetravalent element;(b) mixing the effluent from said first alkylation stage with additional olefin to evolve an intermediate stream having an isoparaffin:olefin weight ratio of from about 2:1 to about 100:1; and(c) reacting said intermediate stream in a second alkylation stage in the absence of intermediate fractionation with a liquid acid catalyst comprising H.sub.2 SO.sub.4 to produce C.sub.5 + alkylate.
摘要翻译： 公开了一种用烯烃烷基化异链烷烃的方法，该方法包括以下步骤：（a）使第一烷基化反应阶段中具有4至8个碳原子的异链烷烃与具有2至12个碳原子的烯烃反应， 40℃至约500℃，总异构链烷烃：烯烃进料重量比为约1:1至约250:1，其中固体烷基化催化剂包含合成多孔结晶材料，其特征在于X射线衍射图包括值 基本上如说明书的表I所述，并且具有包含摩尔关系X 2 O 3：（n）YO 2的组成，其中n小于约35，X是三价元素，Y是四价元素; （b）将来自所述第一烷基化阶段的流出物与另外的烯烃混合以产生具有约2:1至约100:1的异链烷烃：烯烃重量比的中间料流; 和（c）在不与中间分级分离的第二烷基化阶段中使所述中间物流与包含H 2 SO 4的液体酸催化剂反应，以产生C5 +烷基化物。
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公开(公告)号：US5552121A
公开(公告)日：1996-09-03
申请号：US296605
申请日：1994-08-29
CPC分类号： B01D53/74 , B01D53/68 , B01D53/685 , B01D2257/2047 , Y02C20/30
摘要： A system for containing and neutralizing a heavy vapor cloud from a potential source of hazardous vapor, such as HF from an HF alkylation unit, comprising a primary containment enclosure for containing and neutralizing a major portion of the vapor in the event of a leak, and a secondary fence line spaced from the primary enclosure for absorbing the vapor as the cloud passes therethrough.
摘要翻译： 用于从潜在的危险蒸汽源（例如来自HF烷基化单元的HF）中容纳和中和重的蒸气云的系统，包括用于在泄漏的情况下容纳和中和大部分蒸气的主容纳外壳，以及 与主壳体间隔开的辅助栅栏线，用于当云通过其中时吸收蒸气。
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公开(公告)号：US5396010A
公开(公告)日：1995-03-07
申请号：US106689
申请日：1993-08-16
摘要： A fluid catalytically cracked heavy naphtha containing a substantial proportion of preferably more than 90% C.sub.9 + hydrocarbons is contacted with a reformate heavy naphtha containing a substantial proportion of C.sub.9 + hydrocarbons and, optionally, a benzene-rich stream, over a catalyst of acidic functionality, preferably unsteamed ZSM-5, under transalkylation reaction conditions of temperature and pressure to produce a gasoline boiling range product, boiling below 300.degree. F., having a reduced sulfur content and an increased octane number. In one mode of operation the reformate is cascaded from the reformer as the conditions of reaction are compatible with the conditions established in the reformer.
摘要翻译： 将含有大部分优选大于90％C 9+烃的流体催化裂化重质石脑油与含有大部分C 9+烃和任选的富含苯的重整油重质石脑油在酸性官能团的催化剂上接触，优选 未蒸发的ZSM-5，在温度和压力的烷基转移反应条件下，产生沸点低于300°F的汽油沸点产物，硫含量降低，辛烷值增加。 在一种操作模式下，重整产物从重整器中级联，因为反应条件与重整器中确定的条件相符。
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