公开(公告)号：US5759229A

公开(公告)日：1998-06-02

申请号：US688194

申请日：1996-07-29

申请人： David Feitler

发明人： David Feitler

IPC分类号： B01J23/94 ,  B01J38/62 ,  B01J38/68 ,  C22B7/02 ,  C22B23/02 ,  C22B47/00 ,  B22F9/06

CPC分类号： B01J23/94 ,  B01J38/62 ,  B01J38/68 ,  C22B23/026 ,  C22B47/0009 ,  C22B7/02 ,  Y02P10/214 ,  Y02P10/224

摘要： A process for recovering valuable components of a residue from a stream of used catalyst, discharged from a plant for the liquid-phase, homogeneously catalyzed oxidation of alkylaromatic compounds under pressure, to produce polycarboxylic aromatic acids. The residue containing mainly cobalt (Co) and manganese (Mn) compounds is injected into a molten metal bath in combination with enough oxygen gas to convert essentially all carbon in the residue mainly to CO. The residue may also be sludge from a pond in which the residue is stored. The Co content of the molten metal is determined by how much of the Mn in the residue is to be rejected from the molten metal. The Mn rejected is distributed between a slag overlying the molten metal and the effluent which leaves the bath. In the slag, the Mn is trapped as manganese oxide (MnO); in the effluent Mn leaves as manganese dibromide (MnBr.sub.2). The alloy recovered is atomized to form a powder metal which is then reacted with acetic acid and hydrogen bromide to form the corresponding salts. Mn and bromine (Br) values from the slag and from the effluent are also recovered. Substantially pure Co may be recovered and exported, particularly if earthy residue from a sludge pond is processed to benefit the environment.

摘要翻译： 从用于液相的植物排出的用过的催化剂流中回收残余物的有价值组分的方法，在压力下均匀催化烷基芳族化合物的氧化，以产生多元羧酸芳族酸。 主要包含钴（Co）和锰（Mn）化合物的残渣与足够的氧气一起注入熔融金属浴中，将残余物中的所有碳基本上主要转化为CO，残渣也可以是来自池塘的污泥 残留物被储存。 熔融金属的Co含量由残留物中的Mn多少从熔融金属中排出来确定。 Mn排出物分布在熔融金属上的熔渣和离开熔池的流出物之间。 在炉渣中，锰被氧化为锰（MnO）; 在锰废水中Mn二溴化锰（MnBr2）。 回收的合金被雾化以形成粉末金属，然后与乙酸和溴化氢反应形成相应的盐。 来自渣和流出物的Mn和溴（Br）值也被回收。 大部分纯Co可以回收和出口，特别是如果来自污泥池的泥土残留物被处理以使环境受益。

公开(公告)号：US5302360A

公开(公告)日：1994-04-12

申请号：US990943

申请日：1992-12-14

申请人： Guenter Fernschild, deceased ,  Sarah Fernschild, heir

发明人： Guenter Fernschild, deceased ,  Sarah Fernschild, heir

IPC分类号： B01J27/32 ,  B01J38/00 ,  B01J38/68 ,  C01G30/00 ,  C07K14/725 ,  C07K16/00 ,  C07K16/42 ,  C12N5/16 ,  C12N15/00 ,  C12N15/85 ,  C12N15/87 ,  C12N15/90 ,  C22B7/00

CPC分类号： C07K14/7051 ,  B01J27/32 ,  B01J38/68 ,  C01G30/007 ,  C07K16/00 ,  C07K16/4266 ,  C12N15/00 ,  C12N15/85 ,  C12N15/87 ,  C12N15/90 ,  C12N5/163 ,  C22B7/009 ,  A01K2217/05 ,  Y02P10/214 ,  Y02P20/584

摘要： A method for working up antimony halide catalysts containing inactivating organic impurities having high boiling points, in which anhydrous antimony trichloride can be isolated in a technically simple manner. The antimony trichloride can be chlorinated to obtain antimony pentachloride which can be re-used as a catalyst in a fluorination process.

摘要翻译： 一种处理含有高沸点有机杂质的锑卤化物催化剂的方法，其中可以以技术上简单的方式分离无水三氯化锑。 可以将三氯化锑氯化以获得五氯化锑，其可以在氟化过程中再次用作催化剂。

公开(公告)号：US5132449A

公开(公告)日：1992-07-21

申请号：US569559

申请日：1990-08-20

申请人： Klaus Langerbeins ,  Ruediger Jelitte ,  Wolfgang Ruppert ,  Gerhard Emig ,  Otto Watzenberger ,  1

发明人： Klaus Langerbeins ,  Ruediger Jelitte ,  Wolfgang Ruppert ,  Gerhard Emig ,  Otto Watzenberger ,  1

IPC分类号： B01J27/188 ,  B01J27/198 ,  B01J27/199 ,  B01J27/28 ,  B01J38/12 ,  B01J38/48 ,  B01J38/68 ,  C07B61/00 ,  C07C51/377 ,  C07C57/04 ,  C07C69/54

CPC分类号： C07C51/377 ,  B01J23/002 ,  B01J27/188 ,  B01J27/198 ,  B01J27/199 ,  B01J27/285 ,  B01J38/68 ,  B01J2523/00 ,  Y02P20/584

摘要： The invention relates to the stabilization of the activity and/or the reactivation of molybdoheteropoly acid catalysts in vapor-phase oxidations, such as the oxidehydrogenation of isobutyric acid or its lower esters to methacrylic acid or its lower esters, by means of an oxidizing treatment of the catalyst in which compounds of catalyst constituents are added, at temperatures ranging from 200.degree. to 400.degree. C., with an oxygen-containing gas.The inventive activation measures can be carried out either during the catalytic vapor-phase reaction, such as oxihydrogenation in particular, or intermittently to alternate therewith, and optionally also physically separated in part from each other.

摘要翻译： 本发明涉及钼酸杂多酸催化剂在气相氧化中的活性和/或再活化的稳定性，例如通过氧化处理将异丁酸或其低级酯氧化成异丁酸或其低级酯的甲基丙烯酸或其低级酯 在200〜400℃的温度范围内加入催化剂成分的催化剂与含氧气体。 本发明的活化措施可以在催化气相反应期间进行，例如特别是氧化氢化，或者间歇地与其交替，也可以部分地彼此物理分离。

公开(公告)号：US4824814A

公开(公告)日：1989-04-25

申请号：US98911

申请日：1987-09-21

申请人： Frank J. Elvin ,  Jin S. Yoo

发明人： Frank J. Elvin ,  Jin S. Yoo

IPC分类号： B01J29/90 ,  B01J38/68 ,  C10G11/04 ,  C10G11/05 ,  B01J29/38 ,  B01J38/60 ,  B01J38/64

CPC分类号： B01J38/68 ,  B01J29/90 ,  C10G11/04 ,  C10G11/05 ,  Y10S502/516 ,  Y10S502/521

摘要： A process for treating a catalyst useful to promote the conversion of a substantially hydrocarbon feedstock containing at least one first metal at least a portion of which is deposited on the catalyst forming a first metal-containing catalyst, which process comprises:contacting the catalyst with at least one component of at least one second metal selected from the group consisting of antimony, tin, gallium, indium, zinc, tellurium and mixtures thereof to increase the second metal content of the catalyst, anddemetallizing the first metal-containing catalyst to provide a demetallized catalyst having a reduced first metal content.

摘要翻译： 一种用于处理催化剂的方法，所述催化剂用于促进包含至少一种第一金属的基本上烃原料的转化，其中至少一种第一金属的至少一部分沉积在形成第一含金属催化剂的催化剂上，该方法包括：使催化剂与 选自锑，锡，镓，铟，锌，碲及其混合物中的至少一种第二金属的至少一种组分以增加催化剂的第二金属含量，并使第一含金属催化剂脱金属化，以提供 脱金属催化剂具有降低的第一金属含量。