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公开(公告)号：US4876228A
公开(公告)日：1989-10-24
申请号：US163191
申请日：1988-02-25
Applicant: Clarence D. Chang , Cynthia T-W Chu , Pochen Chu , Ralph M. Dessau , William E. Garwood , Guenter H. Kuehl , Joseph N. Miale , David S. Shihabi
Inventor： Clarence D. Chang , Cynthia T-W Chu , Pochen Chu , Ralph M. Dessau , William E. Garwood , Guenter H. Kuehl , Joseph N. Miale , David S. Shihabi
CPC classification number: B01J29/40 , B01J29/7007 , B01J2229/26 , B01J2229/36 , B01J2229/42 , B01J29/65 , B01J29/70
Abstract: A method is disclosed for modifying an aluminosilicate-containing inorganic solid having a predetermined ion exchange capacity and containing an extractable silica by contacting, in the absence of added organic nitrogen or organic phosphorous compound and added activating metal oxide, the porous solid with liquid water at a pH of at least 6, at a temperature of up to 370.degree. C. for about 1 to 100 hours, and recovering a crystalline solid having an ion exchange capacity greater than the starting inorganic solid.
Abstract translation: 公开了一种用于改变具有预定离子交换能力并含有可萃取二氧化硅的含铝硅酸盐的无机固体的方法，该方法在不加入有机氮或有机磷化合物和加入的活化金属氧化物的情况下，将多孔固体与液态水接触 pH至少为6，在高达370℃的温度下进行约1至100小时，并回收离子交换容量大于起始无机固体的结晶固体。
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公开(公告)号：US4855431A
公开(公告)日：1989-08-08
申请号：US457806
申请日：1983-01-13
Applicant: Clarence D. Chang , Patrick D. Perkins
Inventor： Clarence D. Chang , Patrick D. Perkins
IPC: C07D241/12
CPC classification number: C07D241/12
Abstract: The invention deals with a process for making a pyrazine from an aminoalkanol by passing it over a crystalline aluminosilicate zeolite having a silica to alumina ratio of at least 12 and a constraint index of 1 to 12 under conditions to dehydrate, dehydrogenate and cyclize it.
Abstract translation: 本发明涉及一种通过使二氧化硅与氧化铝之比至少为12且约束指数为1至12的结晶硅铝酸盐沸石在脱水，脱氢和使其环化的条件下将其从氨基烷醇制备吡嗪的方法。
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公开(公告)号：US4701313A
公开(公告)日：1987-10-20
申请号：US864746
申请日：1986-05-13
Applicant: Clarence D. Chang , Paul B. Weisz
Inventor： Clarence D. Chang , Paul B. Weisz
CPC classification number: B01J29/86 , C01B35/1009 , Y10S423/27
Abstract: The present invention relates to siliceous zeolite catalysts produced by a method which includes selecting an amount of aluminum framework species to be retained in a zeolite catalyst product, and use of a silicon substitution treatment to replace more reactive framework species used to control aluminum framework concentration. This technique substantially preserves the selected amount of the aluminum framework species. The zeolite product obtained has high reactivity and stability.
Abstract translation: 本发明涉及通过包括选择要保留在沸石催化剂产物中的铝骨架物质的量的方法制备的硅沸石催化剂，以及使用硅替代处理来替代用于控制铝骨架浓度的更多反应性骨架物质。 该技术基本上保留了选定量的铝框架物质。 获得的沸石产物具有高反应性和稳定性。
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公开(公告)号：US4620054A
公开(公告)日：1986-10-28
申请号：US787182
申请日：1985-10-15
Applicant: Clarence D. Chang , Joseph N. Miale
Inventor： Clarence D. Chang , Joseph N. Miale
Abstract: This invention relates to acid catalysis of organic compound feedstock, e.g. isomerization of xylenes, over catalyst material treated in a special way for increasing the acid catalytic activity thereof. In particular, a novel catalyst activation process is followed to enhance the alpha value of high-silica zeolite catalyst by contact with an ammoniacal solution of an alkali metal aluminate under appropriate conditions of time, temperature and pH.
Abstract translation: 本发明涉及有机化合物原料的酸催化，例如 在催化剂材料的异构化中，以特殊方式处理以增加其酸催化活性。 特别地，遵循新的催化剂活化方法，以通过在合适的时间，温度和pH条件下与碱金属铝酸盐的氨溶液接触来增强高硅石沸石催化剂的α值。
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公开(公告)号：US4605803A
公开(公告)日：1986-08-12
申请号：US787183
申请日：1985-10-15
Applicant: Clarence D. Chang , Joseph N. Miale
Inventor： Clarence D. Chang , Joseph N. Miale
Abstract: This invention relates to acid catalysis of organic compound feedstock, e.g. conversion of oxygenates to hydrocarbons, over catalyst material treated in a special way for increasing the acid catalytic activity thereof. In particular, a novel catalyst activation process is followed to enhance the alpha value of high-silica zeolite catalyst by contact with an ammoniacal solution of an alkali metal aluminate under appropriate conditions of time, temperature and pH.
Abstract translation: 本发明涉及有机化合物原料的酸催化，例如 在特定方式处理的催化剂材料中，含氧化合物转化为烃类，以增加其酸催化活性。 特别地，遵循新的催化剂活化方法，以通过在合适的时间，温度和pH条件下与碱金属铝酸盐的氨溶液接触来增强高硅石沸石催化剂的α值。
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Patent Agency Ranking146.发明授权Catalyst for methanol conversion by a combination of steaming and acid-extraction 失效通过蒸汽和酸萃取的组合进行甲醇转化的催化剂
公开(公告)号：US4579993A
公开(公告)日：1986-04-01
申请号：US643345
申请日：1984-08-22
Applicant: Emmerson Bowes , Clarence D. Chang , Richard F. Socha
Inventor： Emmerson Bowes , Clarence D. Chang , Richard F. Socha
IPC: C10G3/00 , B01J29/40 , B01J29/65 , B01J29/70 , C07B61/00 , C07C1/00 , C07C1/20 , C07C1/24 , C07C67/00
CPC classification number: B01J29/40 , C07C1/20 , B01J2229/26 , B01J2229/36 , B01J2229/37 , B01J2229/42 , B01J29/65 , B01J29/70 , C07C2529/40 , C07C2529/65 , C07C2529/70 , Y02P20/52 , Y02P30/20
Abstract: An improved catalyst for methanol conversion having enhanced stability is obtained by extruding a zeolite having a silica-to-alumina ratio of at least 12 and a Constraint Index within the approximate range of 1 to 12 with a silica matrix and thereafter subjecting the extrudate to both steaming and acid-extraction in order to enhance the stability thereof.
Abstract translation: 通过用二氧化硅基体挤出二氧化硅与氧化铝之比至少为12且约束指数在约1至12的约束指数之间的沸石，然后将挤出物同时进行两者，得到具有增强的稳定性的改进的甲醇转化催化剂 蒸汽和酸萃取，以提高其稳定性。
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公开(公告)号：US4579987A
公开(公告)日：1986-04-01
申请号：US733337
申请日：1985-05-13
Applicant: Clarence D. Chang , Joseph N. Miale
Inventor： Clarence D. Chang , Joseph N. Miale
CPC classification number: B01J29/40 , B01J2229/40 , B01J2229/42
Abstract: A process is provided for converting feedstock comprising paraffins, olefins or mixtures thereof to product comprising C.sub.5 + hydrocarbons over a catalyst comprising a high silica crystalline zeolite which has been treated by steps of calcining the crystalline material, contacting the calcined material with solid aluminum fluoride, and converting the aluminum fluoride contacted material to hydrogen form.
Abstract translation: 提供了一种方法，用于将包含链烷烃，烯烃或其混合物的原料转化为包含高二氧化硅结晶沸石的催化剂的包含C5 +烃的产物，该高二氧化硅结晶沸石已经通过煅烧结晶材料，煅烧材料与固体氟化铝接触的步骤，以及 将氟化铝接触的材料转化为氢形式。
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公开(公告)号：US4577048A
公开(公告)日：1986-03-18
申请号：US733340
申请日：1985-05-13
Applicant: Clarence D. Chang , Joseph N. Miale
Inventor： Clarence D. Chang , Joseph N. Miale
CPC classification number: B01J29/40 , B01J2229/40 , B01J2229/42
Abstract: A process is provided for converting feedstock aromatic compounds by alkylation, transalkylation, disproportionation and/or isomerization over a catalyst comprising a high silica crystalline zeolite which has been treated by steps of calcining the zeolite, contacting the calcined zeolite with solid aluminum fluoride, and converting the aluminum fluoride contacted zeolite to hydrogen form.
Abstract translation: 提供了一种通过在包含高二氧化硅结晶沸石的催化剂上进行烷基化，烷基转移，歧化和/或异构化来转化原料芳族化合物的方法，该高二氧化硅结晶沸石已经通过煅烧沸石的步骤进行处理，使煅烧的沸石与固体氟化铝接触， 氟化铝接触沸石形成氢。
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公开(公告)号：US4559315A
公开(公告)日：1985-12-17
申请号：US631687
申请日：1984-07-16
Applicant: Clarence D. Chang , Joseph N. Miale
Inventor： Clarence D. Chang , Joseph N. Miale
CPC classification number: B01J29/40 , B01J29/7007 , B01J2229/26 , B01J2229/36 , B01J2229/42
Abstract: The ion-exchange capacity and acid catalytic activity of a ZSM-5 type zeolite are increased by treatment of a physical mixture of the zeolite and an inorganic oxide with water in the presence of an alkali metal cation.
Abstract translation: ZSM-5型沸石的离子交换能力和酸催化活性通过在碱金属阳离子存在下处理沸石和无机氧化物的物理混合物与水而增加。
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公开(公告)号：US4554396A
公开(公告)日：1985-11-19
申请号：US651748
申请日：1984-09-18
Applicant: Clarence D. Chang , Cynthia T. W. Chu
Inventor： Clarence D. Chang , Cynthia T. W. Chu
IPC: C10G57/02 , B01J29/88 , C01B33/40 , C01B39/04 , C01B39/06 , C01B39/38 , C07C1/00 , C07C2/12 , C07C11/02 , C07C67/00 , C10G50/00 , C07C2/02
CPC classification number: C07C2/12 , B01J29/88 , C07C2529/88 , Y10S423/22
Abstract: A process for upgrading lower olefin to produce heavier hydrocarbons having a substantially linear molecular conformation comprising contacting olefinic feedstock under oligomerization conditions at reaction temperature and pressure favorable to formation of higher molecular weight aliphatic hydrocarbons with a shape selective medium pore acidic crystalline ferrosilicate zeolite catalyst having a major portion of zeolitic iron in tetrahedral coordination therein.
Abstract translation: 一种用于升级低级烯烃以生产具有基本上线性分子构象的较重烃的方法，包括在有利于形成较高分子量脂族烃的反应温度和压力的低聚条件下使烯烃原料与形状选择性中孔酸性结晶硅酸铝沸石催化剂接触， 在其中四面体配位的沸石铁的主要部分。
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