Abstract:
Ion transport apparatus (e.g. an electrolytic eluent generator or a suppressor for ion chromatography) in which ions in a first chamber are transported to a liquid in second chamber through a wall comprising an ion exchange bead sealed in a bead seat. The wall is capable of transport ions but of substantially blocking bulk liquid flow.
Abstract:
A porous ion exchanger includes an open cell structure including interconnected macropores and mesopores whose average diameter is in a range of 1 to 1000 μm existing on walls of the macropores. Moreover, a total pore volume is in a range of 1 to 50 ml/g, ion exchange groups are uniformly distributed, and an ion exchange capacity is not less than 0.5 mg equivalent/g of dry porous ion exchanger. The porous ion exchanger can be used as an ion exchanger filled into a deionization module of an electrodeionization water purification device, solid acid catalyst, adsorbent, and filler for chromatography.
Abstract:
EDI apparatus for demineralizing a liquid flow is assembled in a housing having a cylindrical shape, and includes two metal electrodes, and one or more leafs, each leaf comprising a pair of selectively ion-permeable membranes arranged parallel to each other and spaced apart by spacing elements that allow liquid to flow in the interstitial space between membranes, thus forming an arrangement of dilute and concentrate cells in a desired flow configuration. Spacing elements between membranes, as well as between leaves, can be formed of inert polymer material, ion exchange beads, ion exchange fibers, a combination of two or more these elements, or a porous media incorporating one or more of such elements as an intrinsic part. An inner or central electrode and an outer or perimeter electrode establish a generally uniform and radially-oriented electrical or ionic current between the inner and the outer electrodes, across the helical flow spaces defined by the membrane/spacer windings. One or both electrodes may include a pocket, and the adjacent flow cells lie parallel to the electrode and free of shadowing and field inhomogeneity around a full circumference of the electrode. Flow paths within the helical cells are defined by barrier seals, which may form a path-lengthening maze, while unfilled cell regions may disperse or collect flow within a cell and define pressure gradients promote directional flows. Impermeable barriers between membranes further prevent the feed and concentrate flows from mixing. In various embodiments, seals along or between portions of the flow path may define a multi-stage device, may define separate feed and/or concentrate flows for different stages, and/or may direct the feed and concentrate flows along preferred directions which may be co-current, counter-current or cross-current with respect to each other within the apparatus.
Abstract:
A spiral wound module for the electrochemical desalination of aqueous salt-containing solutions, whose feeds (71) for solution to be desalinated and whose discharge (72) for desalinated water are mounted on side walls (31, 32) of the dilution chamber (3) of the module, permits an axial instead of tangential flow in the dilution chamber (3).
Abstract:
A spacer element (1) is disclosed having an integral screen for use in filled cell electrodialysis. The spacer (1) has a continuous portion (2) impermeable to flow and a screen (3) which spans a centrally-located flow treatment region that contains active treatment material, such as ion exchange beads. The screen (3) may perform a structural function, allowing operation at elevated pressure, and may also define a minimum gap between adjacent membranes and enhance mixing along the flow path and at cell boundaries. The spacer element (1) may be configured to enhance hydraulic filling of the cells, and cell architecture is readily implemented in a wide range of useful flow path geometries utilizing the screen spacer element (1).
Abstract:
Filter or filter-element designated for Modified Electro-Dialysis (MED) purposes characterized in that the filter or filter-element comprises a porous, ceramic, mainly uniform material with functional, preferably ion selective groups grafted onto the inner, porous surface of the ceramic body. The outer surface of the filter or filter-element may be completely or partly covered by layers of porous, ceramic membranes with a pore size of less than 1 μm and thickness less than 1 mm, and/or anion, cation or bipolar groups or membranes. The thickness of the filter-element is larger than 1 mm and has pores of size larger than 1 μm. The invention also relates to a method for the manufacture of such a filter either continuously by tape-casting, extruding, rolling or calendaring or single-bodied by casting, pressing or forging, of a paste containing a non-conductive, ceramic material. The body is then sintered and finally grafted with functional, preferably ion selective groups for one or more specific ions or groups of ions, onto the inner, porous surface of the ceramic body. Use of the filter or filter-element for filtering ions or complexes of heavy or precious metals from water is also claimed.
Abstract:
The present invention aims to provide electrode compartment structures in electrochemical liquid treatment equipments, which enable stable operation using pure water as an electrode compartment liquid requiring no concentration adjustment without adverse electrode reaction. The present invention relates an electrochemical liquid treatment equipment comprising ion exchange membranes between an anode and a cathode, which has an anode compartment defined by the anode and a cation exchange membrane and a cathode compartment defined by the cathode and an anion exchange membrane (12), each of the anode compartment and cathode compartment being packed with an ion exchanger (14) composed of a fibrous a material, each of the anode and cathode (11) being formed from a liquid- and gas-permeable and electrically conductive material, and the equipment also having an electrode compartment liquid flowing chamber (15) which is formed behind each of the anode and cathode.
Abstract:
The present invention generally relates to purification systems, and to sanitization and/or sealing of the purification system. The purification system includes an electrodeionization device which can comprise one or a plurality of stages. The electrodeionization device can be constructed with a resilient sealing member forming a water-tight seal between rigid thermally and dimensionally stable compartment spacers. The construction of the electrodeionization device may allow cycling of hot water and/or other liquids, which, in some cases, can improve efficiency and performance of the electrodeionization device. Moreover, the cycling of hot water and/or other liquids may be used to sanitize the electrodeionization device to at least a pharmaceutically acceptable condition and, preferably, in certain instances, to meet at least minimum requirements according to U.S. Pharmacopoeia guidelines by inactivating any microorganisms present within the electrodeionization device.
Abstract:
The present invention provides a method and apparatus for purifying effluent wastewater utilizing electrophoretic cross-flow filtration and electrode ionization. The method first comprises filtering the water in a cross-flow direction with a filter membrane in the presence of an electric field that is operative to drive suspended particles away from a surface of the filter membrane. The permeate containing dissolved solids is next passed through a mixture of at least one cation-exchange resin and at least one anion-exchange resin disposed between a cation-selective membrane and an anion-selective membrane in the presence of an electric field. The electric field drives cations in the permeate through the cation-selective membrane, and drives anions in the permeate through the anion-selective membrane, thereby to form deionized water. The apparatus includes cell modules adapted to be used in plate-and-frame or radial flow configurations.
Abstract:
Apparatus and method are disclosed for introducing ion exchange or other particulates into compartments of an already-assembled electrodeionization or comparable stack by modulating a flow of slurry into the compartments with slugs of gas such as air. The air propels liquid through the cells, scavenging ponded liquid so that the particulates (which are retained, e.g., by a strainer or obstruction, in compartment of the apparatus) are deposited as well-packed beds to fill the compartments. Pressurized air filling protocols may deliver discrete slugs of slurry between bursts of air, and the direction of filling may be periodically reversed to diminish particle bed non-homogeneities or settling gradients that arise during transport. The slugs of air may be applied in the direction of slurry flow, in the reverse direction, or both. Different slurries may be transported in a sequence to form layered and packed beds of enhanced utility. An apparatus of the invention has filled compartments of enhanced packing, and is ported or has its passages arranged so that ion exchange material may be filled, or may be replenished by a fluidized flow according to a method of this invention.