公开(公告)号：US20190155154A1

公开(公告)日：2019-05-23

申请号：US15819349

申请日：2017-11-21

Applicant: International Business Machines Corporation

Inventor： Matthew Kelly ,  Mark Jeanson ,  Joseph Kuczynski

IPC: G03F7/032 ,  G03F7/028 ,  G03F7/038 ,  G03F7/039 ,  H01L21/48 ,  B23K35/22

Abstract: Disclosed herein are solder mask formulations that include a liquid photo imageable solution and a solution of functionalized diamondoids. Also disclosed are semiconductor fabrication methods that include applying a described solder mask formulation to a semiconductor device.

公开(公告)号：US10295354B2

公开(公告)日：2019-05-21

申请号：US15462969

申请日：2017-03-20

Applicant: INTERNATIONAL BUSINESS MACHINES CORPORATION

Inventor： Daniel J. Buvid ,  Eric J. Campbell ,  Tyler Jandt ,  Joseph Kuczynski

IPC: B60W30/18 ,  G01C21/34 ,  H04W4/021 ,  G08G1/127 ,  G08G1/056 ,  F16H59/74 ,  F16H63/48 ,  H04W4/02 ,  G08G1/00 ,  G01C21/36 ,  F16H63/40

Abstract: A computing device detects that an ignition switch of the vehicle was activated, wherein the vehicle includes a navigation device. The computing device requests a destination from the navigation device. The computing device interlocking, an operation of the vehicle based on determining that the destination is not valid.

公开(公告)号：US20190136136A1

公开(公告)日：2019-05-09

申请号：US15806423

申请日：2017-11-08

Applicant: International Business Machines Corporation

Inventor： Scott B. King ,  Brandon M. Kobilka ,  Joseph Kuczynski ,  Jason T. Wertz

IPC: C09K21/12 ,  C09K21/14 ,  C07F9/6561 ,  C08K5/5373 ,  C08K5/5313 ,  C09J11/06

Abstract: A levoglucosan-based flame retardant compound, a process for forming a flame retardant polymer, and an article of manufacture comprising a material that contains a levoglucosan-based flame retardant polymer are disclosed. The levoglucosan-based flame retardant compound has phosphorus-based flame retardant functional groups. The process for forming the flame retardant polymer includes providing a phosphorus-based flame retardant molecule, providing levoglucosan, chemically reacting the phosphorus-based flame retardant molecule and the levoglucosan derivative to form a levoglucosan-based flame retardant compound, and incorporating the levoglucosan-based flame retardant compound into a polymer to form the levoglucosan-based flame retardant polymer.

公开(公告)号：US10280269B2

公开(公告)日：2019-05-07

申请号：US15839130

申请日：2017-12-12

Applicant: International Business Machines Corporation

Inventor： Sarah K. Czaplewski ,  Joseph Kuczynski ,  Jason T. Wertz ,  Jing Zhang

IPC: C08J3/24 ,  C08C19/24 ,  C08L23/16 ,  C08F232/08 ,  C08F210/18 ,  C08F8/40 ,  C08F210/06 ,  C08G61/08 ,  C09K21/14 ,  C08K5/5313 ,  C08F214/02 ,  C08C19/28 ,  C08F4/659

Abstract: In an example, a process includes polymerizing a mixture that includes an ethylene monomer, a propylene monomer, and a diene monomer to form an ethylene-propylene-diene (EPDM) terpolymer using ring-opening metathesis polymerization (ROMP). The process further includes chemically reacting the EPDM terpolymer with a norbornene-based phosphinate cross-linking material to form a flame-retardant, cross-linked EPDM rubber.

公开(公告)号：US10278284B2

公开(公告)日：2019-04-30

申请号：US15247151

申请日：2016-08-25

Applicant: International Business Machines Corporation

Inventor： Eric J. Campbell ,  Joseph Kuczynski ,  Timothy J. Tofil

IPC: B29C35/02 ,  H05K1/02 ,  H05K1/03 ,  B29K105/08 ,  B29K105/16 ,  B29L31/34

Abstract: A composite material incorporates multi-compartment microcapsules that produce heat when subject to a stimulus such as a compressive force or a magnetic field. The stimulus ruptures an isolating structure within the multi-compartment microcapsule, allowing reactants within the multi-compartment microcapsule to produce heat from an exothermic reaction. In some embodiments, the composite material is a laminate used in the manufacture of multi-layer printed circuit boards (PCBs) and provides heat during the curing process of the multi-layer PCBs to ensure a consistent thermal gradient in the multi-layer product.

公开(公告)号：US10272663B2

公开(公告)日：2019-04-30

申请号：US15412210

申请日：2017-01-23

Applicant: International Business Machines Corporation

Inventor： Dylan J. Boday ,  Joseph Kuczynski ,  Robert E. Meyer, III

IPC: B29C67/00 ,  C09D4/06 ,  C09D133/14 ,  B33Y70/00 ,  B33Y10/00 ,  B33Y30/00 ,  C09D11/106 ,  C09D11/30 ,  B29C64/112 ,  B33Y50/02

Abstract: Thermally cross-linkable photo-hydrolyzable inkjet printable polymers are used to print microfluidic channels layer-by-layer on a substrate. In one embodiment, for each layer, an inkjet head deposits droplets of a mixture of hydrophobic polymer and cross-linking agent in a pattern lying outside a two-dimensional layout of the channels, and another inkjet head deposits droplets of a mixture of poly(tetrahydropyranyl methacrylate) PTHPMA (or another hydrophobic polymer which hydrolyzes to form a hydrophilic material), cross-linking agent, and a photoacid generator (PAG) in a pattern lying inside the two-dimensional layout of the channels. After all layers are printed, flood exposure of the entire substrate to UV radiation releases acid from the PAG which hydrolyzes PTHPMA to form hydrophilic poly(methacrylic acid) PMAA, thereby rendering the PTHPMA regions hydrophilic. The layers of these now-hydrophilic patterned regions together define the microfluidic channels. The cross-linking agent (e.g., triallyl isocyanurate TAIC) forms covalent cross-links between the two polymer phases.

公开(公告)号：US10266772B2

公开(公告)日：2019-04-23

申请号：US15584838

申请日：2017-05-02

Applicant: International Business Machines Corporation

Inventor： Brandon M. Kobilka ,  Joseph Kuczynski ,  Jacob T. Porter ,  Jason T. Wertz

IPC: C09K21/12 ,  C07C15/04 ,  C08K5/5337 ,  C08K5/5313 ,  C08K5/5317 ,  C07D317/12

Abstract: A flame-retardant vanillin-derived monomer, a process for forming a flame-retardant polymer, and an article of manufacture comprising a material that contains flame-retardant vanillin-derived monomer are disclosed. The flame-retardant vanillin-derived monomer can be synthesized from vanillin obtained from a bio-based source, and can have at least one phosphoryl or phosphonyl moiety with phenyl, allyl, epoxide, or propylene carbonate substituents. The process for forming the flame-retardant polymer can include reacting a vanillin derivative and a flame-retardant phosphorus-based molecule to form the flame-retardant vanillin-derived monomer, and then polymerizing the flame-retardant vanillin-derived monomer. The material in the article of manufacture can be flame-retardant, and contain the flame-retardant vanillin-derived monomer. Examples of materials that can be in the article of manufacture can include resins, plastics, adhesives, polymers, etc.

公开(公告)号：US10266771B2

公开(公告)日：2019-04-23

申请号：US15584753

申请日：2017-05-02

Applicant: International Business Machines Corporation

Inventor： Brandon M. Kobilka ,  Joseph Kuczynski ,  Jacob T. Porter ,  Jason T. Wertz

IPC: C09K21/12 ,  C07F9/08 ,  C12P7/22 ,  C12P7/26 ,  C08K5/5313 ,  C08K5/5317 ,  C08K5/5337

Abstract: A flame-retardant vanillin-derived molecule, a process for forming a flame-retardant resin, and an article of manufacture comprising a material that contains the flame-retardant vanillin-derived molecule are disclosed. The flame-retardant vanillin-derived molecule can be synthesized from vanillin obtained from a bio-based source, and can have at least one phosphoryl or phosphonyl moiety with phenyl, allyl, epoxide, propylene carbonate, or thioether substituents. The process for forming the flame-retardant resin can include reacting a vanillin derivative and a flame-retardant phosphorus-based molecule to form the flame-retardant vanillin-derived molecule, and binding the flame-retardant vanillin-derived molecule to a resin. The flame-retardant vanillin-derived molecules can also be bound to polymers. The material in the article of manufacture can be flame-retardant, and contain the flame-retardant vanillin-derived molecules. Examples of materials that can be in the article of manufacture can include resins, plastics, adhesives, polymers, etc.

公开(公告)号：US10266325B2

公开(公告)日：2019-04-23

申请号：US15175390

申请日：2016-06-07

Applicant: International Business Machines Corporation

Inventor： Brandon M. Kobilka ,  Joseph Kuczynski ,  Jacob T. Porter ,  Jason T. Wertz

IPC: B65D65/20 ,  C08F210/02 ,  C08F212/34 ,  B29C49/00 ,  G02B5/22 ,  G02B1/04 ,  C07C13/573 ,  B29K23/00 ,  B29K105/00 ,  B29L31/00

Abstract: A process of forming a polymer with a blue light absorber chemically bonded to a polymeric backbone of the polymer includes mixing one or more olefin monomers with one or more functionalized p-vinylstyrylanthracene monomers to form a mixture of reactants. The mixture includes less than 10 percent by weight of the one or more functionalized p-vinylstyrylanthracene monomers. The process also includes polymerizing the mixture to produce a polymer with one or more blue light absorption characteristics.

公开(公告)号：US10257940B2

公开(公告)日：2019-04-09

申请号：US15426696

申请日：2017-02-07

Applicant: International Business Machines Corporation

Inventor： Sarah K. Czaplewski ,  Joseph Kuczynski ,  Jason T. Wertz ,  Jing Zhang

IPC: H05K3/38 ,  H05K3/28 ,  H05K1/02 ,  H05K3/00 ,  H05K3/46 ,  C09D163/00 ,  H05K1/11

Abstract: In an example, a process for reversibly bonding a conformal coating to a dry film solder mask (DFSM) material is disclosed. The process includes applying a first conformal coating material to a DFSM material. The first conformal coating material includes a first functional group, and the DFSM material includes a second functional group that is different from the first functional group. The process also includes reversibly bonding the first conformal coating material to the DFSM material via a chemical reaction of the first functional group and the second functional group.