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    Process for the preparation of polymers containing N-O terminal groups
    12.
    发明授权
    Process for the preparation of polymers containing N-O terminal groups 有权
    制备含有N-O端基的聚合物的方法

    公开(公告)号：US06433100B1

    公开(公告)日：2002-08-13

    申请号：US09763432

    申请日：2001-02-22

    Applicant: Andreas Kramer ,  Andreas Mühlebach ,  François Rime

    Inventor： Andreas Kramer ,  Andreas Mühlebach ,  François Rime

    IPC: C08F830

    CPC classification number: C08F4/00 ,  C08F2/38

    Abstract: The invention relates to a process for the preparation of polymers containing N→O terminal groups and to compositions comprising polymers obtained by this process. The process comprises polymerizing by atom transfer radical polymerization (ATRP) an aliphatic monomer of oligomer containing ethylene groups in the presence of a polymerization initiator.

    Abstract translation: 本发明涉及制备含有N-末端基团的聚合物的方法和包含通过该方法获得的聚合物的组合物。 该方法包括在聚合引发剂存在下通过原子转移自由基聚合（ATRP）聚合含有乙烯基团的低聚物的脂族单体。

    Ruthenium and osmium catalysts
    13.
    发明授权
    Ruthenium and osmium catalysts 有权
    钌和锇催化剂

    公开(公告)号：US06306987B1

    公开(公告)日：2001-10-23

    申请号：US09446052

    申请日：1999-12-16

    Applicant: Paul Adriaan Van Der Schaaf ,  Andreas Hafner ,  Andreas Mühlebach

    Inventor： Paul Adriaan Van Der Schaaf ,  Andreas Hafner ,  Andreas Mühlebach

    IPC: C08F480

    CPC classification number: B01J31/181 ,  B01J31/1825 ,  B01J31/2265 ,  B01J31/2282 ,  B01J31/24 ,  B01J31/2404 ,  B01J2231/14 ,  B01J2231/543 ,  B01J2531/821 ,  B01J2531/825 ,  C07F15/0013 ,  C07F15/002 ,  C08G61/08

    Abstract: Disclosed is a compound of formula (I), and its use in preparing metathesis polymers of dicyclopentadiene and/or other strained cycloolefins in which Me is ruthenium or osmium; X1 and X2 independently of one another are anionic ligands, or X1 and X2 together are a bis-anionic ligand; Y is oxygen, sulfur or the groups —NR7— or —PR7—, where R7 is hydrogen or a substituent selected from the group C1-C6alkyl, C6-C13aralkyl, sulfonyl and —C(═O)Rs2 and Rs2 is hydrogen or a substituent selected from the group C1-C12alkyl, C2-C12alkenyl, C3-C12cycloalkyl, C3-C12cycloalkenyl, C2-C11heterocycloalkyl, C2-C11heterocycloalkenyl, C5-C12aryl, C1-C9heteroaryl, C6-C14aralkyl, C2-C13heteroaralkyl, C6-C14aralkenyl and C3-C13heteroaralkenyl; n is 0 or 1; L1 is tertiary phosphine; and L2 is a neutral e− donor ligand which is coordinated to the metal atom and is attached via the bridge group C* to the carbon atom of the carbene group if n is 0 and to Y if n is 1.

    Abstract translation: 公开了式（I）化合物及其用于制备Me是钌或锇的二环戊二烯和/或其它应变环烯烃的复分解聚合物; X1和X2彼此独立的是阴离子配体，或者X1和X2一起是双 - 阴离子配体; Y是氧，硫或基团-NR7-或-PR7-，其中R7是氢或选自C1-C6烷基，C6-C13芳烷基，磺酰基和-C（= O）Rs2和Rs2 是选自C 1 -C 12烷基，C 2 -C 12烯基，C 3 -C 12环烷基，C 3 -C 12环烯基，C 2 -C 11杂环烷基，C 2 -C 11杂环烯基，C 5 -C 12芳基，C 1 -C 9杂芳基，C 6 -C 14芳烷基，C 2 -C 13杂芳烷基，C 6 -C14链烯基和C3-C13杂碳烯基; n为0或1; L1为叔膦; L2为与金属原子配位并通过桥基C *连接至卡宾的碳原子的中性e-供体配体 如果n为0，则为组，如果n为1则为Y。

    Two-component catalyst for ROMP
    14.
    发明授权
    Two-component catalyst for ROMP 失效
    ROMP双组分催化剂

    公开(公告)号：US06204347B1

    公开(公告)日：2001-03-20

    申请号：US09376453

    申请日：1999-08-18

    Applicant: Andreas Hafner ,  Paul Adriaan Van Der Schaaf ,  Andreas Mühlebach

    Inventor： Andreas Hafner ,  Paul Adriaan Van Der Schaaf ,  Andreas Mühlebach

    IPC: C08F426

    CPC classification number: C08G61/08 ,  B01J31/1805 ,  B01J31/185 ,  B01J31/2295 ,  B01J31/24 ,  B01J31/2404 ,  B01J2231/14 ,  B01J2531/821

    Abstract: A catalyst system for the ring-opening metathesis polymerization, which consists of at least two components (a) and (b), wherein (a) is a ruthenium compound of formula I or II RuX2(L1)m(L2)n(L3)o(L4)p  (I), ARuX2(L1)r(L2)s  (II), wherein L1, L2, L3 and L4 are each independently of the other C1-C18alkylcyanide, C8-C24-aralkylcyanide, tertiary amine, tertiary phosphine which does not contain any secondary alkyl or cycloalkyl radicals bound to the phosphorus atom, or phosphite, X is halogen, A is arene, m, n, o and p are integers from 0 to 4, where 2≦m+n+o+p≦4, r and s are integers from 0 to 2, where 1≦r+s≦2, and (b) is a tertiary phosphine containing at least one secondary alkyl radical or cycloalkyl radical bound to the phosphorus atom, is particularly suitable for the polymerization of strained cycloolefins by the RIM process.

    Abstract translation: 一种用于开环易位聚合的催化剂体系，其由至少两种组分（a）和（b）组成，其中（a）是式I或II的钌化合物，其中L1，L2，L3和L4各自独立地为 不含任何与磷原子键合的仲烷基或环烷基的其它C1-C18烷基氰化物，C8-C24-芳烷基氰化物，叔胺，叔膦，或亚磷酸酯，X是卤素，A是芳烃，m，n，o和 p是从0到4的整数，其中2 <= m + n + o + p <= 4，r和s是从0到2的整数，其中1 <= r + s <= 2，（b） 含有至少一个与磷原子键合的仲烷基或环烷基的叔膦特别适用于通过RIM方法聚合应变的环烯烃。

    Coating compositions containing levelling agents prepared by nitroxyl mediated polymerisation
    17.
    发明授权
    Coating compositions containing levelling agents prepared by nitroxyl mediated polymerisation 有权
    含有通过硝酰基介导的聚合制备的流平剂的涂料组合物

    公开(公告)号：US07829643B2

    公开(公告)日：2010-11-09

    申请号：US10581137

    申请日：2004-12-01

    Applicant: Ralf Knischka ,  Clemens Auschra ,  Andreas Mühlebach ,  Sevgi Zeren

    Inventor： Ralf Knischka ,  Clemens Auschra ,  Andreas Mühlebach ,  Sevgi Zeren

    IPC: C08F2/00

    CPC classification number: C09D5/033 ,  C08L57/12 ,  C08L2201/00 ,  C09D7/47

    Abstract: The present invention relates to coating compositions containing a polymeric or copolymeric levelling agent, which has been prepared by nitroxyl-mediated polymerisation. Further aspects are a process for the preparation of smooth surface coatings and the use of said polymer or copolymer as levelling agent in coating compositions. Yet another aspect are specific ethylenically unsaturated monomer compositions from which copolymers can be obtained by atom transfer radical polymerisation or nitroxyl mediated polymerisation, which copolymers are useful as levelling agents in coating compositions. Still another aspect is the use of poly-tert.-butyl acrylate or poly-tert.butylmethacrylate as a levelling agent in powder coating compositions.

    Abstract translation: 本发明涉及包含通过硝酰基介导的聚合制备的聚合物或共聚物流平剂的涂料组合物。 另外的方面是制备光滑表面涂层的方法以及所述聚合物或共聚物作为涂料组合物中的流平剂的用途。 另一方面是特定的烯键式不饱和单体组合物，其可通过原子转移自由基聚合或硝酰基介导的聚合获得共聚物，该共聚物可用作涂料组合物中的流平剂。 另一方面是在粉末涂料组合物中使用聚丙烯酸叔丁酯或聚 - 叔丁基甲基丙烯酸酯作为流平剂。

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