公开(公告)号：US06435128B2

公开(公告)日：2002-08-20

申请号：US09824343

申请日：2001-04-02

Applicant: Jean Qiu ,  Joan M. Noyola ,  David J. Yarusso ,  Kevin R. Green

Inventor： Jean Qiu ,  Joan M. Noyola ,  David J. Yarusso ,  Kevin R. Green

IPC: G01K300

CPC classification number: G01K3/04

Abstract: A time-temperature indicator device provides a visually observable indication of the cumulative thermal exposure of an object. The device includes a substrate having a diffusely light-reflective porous matrix and a backing. The backing includes on its surface a viscoelastic indicator material for contacting the substrate and a barrier material for substantially inhibiting the lateral and longitudinal flow of viscoelastic indicator material between the substrate and the backing.

Abstract translation: 时间 - 温度指示器装置提供对物体的累积热暴露的视觉可见的指示。 该装置包括具有漫反射多孔基体和背衬的基底。 背衬在其表面上包括用于接触基底和阻挡材料的粘弹性指示剂材料，用于基本上抑制基材和背衬之间的粘弹性指示剂材料的横向和纵向流动。

公开(公告)号：USRE36855E

公开(公告)日：2000-09-05

申请号：US119825

申请日：1998-07-21

Applicant: Timothy D. Bredahl ,  Harold W. Leverty ,  Robert L. Smith ,  Richard E. Bennett ,  David J. Yarusso ,  Daniel C. Munson ,  George E. Cox

Inventor： Timothy D. Bredahl ,  Harold W. Leverty ,  Robert L. Smith ,  Richard E. Bennett ,  David J. Yarusso ,  Daniel C. Munson ,  George E. Cox

IPC: B29C47/02 ,  B29C47/06 ,  B29C47/10 ,  B29C47/40 ,  B29C47/50 ,  B29C71/02 ,  C08L21/00 ,  C09J5/08 ,  C09J7/02 ,  C08L23/00

CPC classification number: C09J5/08 ,  B29C47/0047 ,  B29C47/02 ,  B29C47/065 ,  B29C47/1063 ,  B29C47/1081 ,  B29C47/50 ,  C09J7/0214 ,  B29C47/0021 ,  B29C47/367 ,  B29C47/40 ,  B29C71/02 ,  B29K2023/22 ,  B29K2105/0005 ,  B29K2105/24 ,  C08L21/00 ,  C09J2421/00

Abstract: A solvent-free hot melt process, for preparing a non-thermosettable, pressure-sensitive adhesive from a tackified non-thermoplastic hydrocarbon elastomer. The process employs a continuous compounding device that has a sequence of alternating conveying and processing zones. The processing zones masticate and mix materials in them. Non-thermoplastic elastomers having high molecular weight may be readily compounded into adhesives in the process.

Abstract translation: 一种无溶剂的热熔融方法，用于从增粘的非热塑性烃弹性体制备不可热固的压敏粘合剂。 该方法采用具有交替输送和处理区序列的连续复合装置。 加工区在其中捏合和混合材料。 具有高分子量的非热塑性弹性体可以在该方法中容易地复合成粘合剂。

公开(公告)号：US20130101775A1

公开(公告)日：2013-04-25

申请号：US13521889

申请日：2011-01-20

Applicant: Kathleen A. Dennison ,  Bruce A. Nerad ,  David J. Yarusso ,  John A. Nielsen

Inventor： Kathleen A. Dennison ,  Bruce A. Nerad ,  David J. Yarusso ,  John A. Nielsen

IPC: B32B27/08 ,  B32B27/40 ,  C09J7/02

CPC classification number: B32B27/08 ,  B32B7/06 ,  B32B7/12 ,  B32B27/18 ,  B32B27/283 ,  B32B27/302 ,  B32B27/308 ,  B32B27/32 ,  B32B27/327 ,  B32B27/34 ,  B32B27/40 ,  B32B2250/05 ,  B32B2250/24 ,  B32B2270/00 ,  B32B2307/306 ,  B32B2307/308 ,  B32B2307/402 ,  B32B2307/41 ,  B32B2307/412 ,  B32B2307/414 ,  B32B2307/51 ,  B32B2307/514 ,  B32B2307/518 ,  B32B2307/54 ,  B32B2307/554 ,  B32B2307/58 ,  B32B2307/5825 ,  B32B2307/712 ,  B32B2307/714 ,  B32B2307/75 ,  B32B2405/00 ,  B32B2451/00 ,  B32B2519/00 ,  B32B2590/00 ,  B32B2605/00 ,  C09J7/20 ,  C09J7/40 ,  Y10T428/1452 ,  Y10T428/1476 ,  Y10T428/2848 ,  Y10T428/31551

Abstract: The present application is directed to a multilayer film The film comprises a thermoplastic receptor layer comprising a polyurethane, a thermoplastic core layer on the receptor layer comprising an acidic group or an anhydride group, and a thermoplastic primer layer on the core layer opposite the receptor layer comprising a nitrogen containing polymer. In some embodiments, the multilayer film includes additional layers. For example, an adhesive layer may be on the primer layer opposite the core layer. In another embodiment, a release layer is on the adhesive layer opposite the primer layer. In another embodiment, a liner layer is on the release layer opposite the adhesive layer.

Abstract translation: 本申请涉及多层膜该膜包括热塑性受体层，其包含聚氨酯，在包含酸性基团或酸酐基团的受体层上的热塑性核心层和与受体层相对的芯层上的热塑性底漆层 包含含氮聚合物。 在一些实施例中，多层膜包括另外的层。 例如，粘合剂层可以在与芯层相对的底漆层上。 在另一个实施方案中，剥离层位于与底漆层相对的粘合剂层上。 在另一个实施方案中，衬垫层位于与粘合剂层相对的剥离层上。

公开(公告)号：US07807754B2

公开(公告)日：2010-10-05

申请号：US11374236

申请日：2006-03-13

Applicant: Audrey A. Sherman ,  David J. Yarusso ,  Frank T. Sher

Inventor： Audrey A. Sherman ,  David J. Yarusso ,  Frank T. Sher

IPC: C08L33/08 ,  C08L43/04

CPC classification number: C08F265/04 ,  B33Y80/00 ,  C08F291/00 ,  C08L51/06 ,  C08L2666/02 ,  C08L2666/24 ,  C09J7/22 ,  C09J7/38 ,  C09J7/385 ,  C09J133/02 ,  C09J133/06 ,  C09J151/003 ,  C09J2433/00 ,  C09J2451/00 ,  Y10T428/31663 ,  Y10T428/31855 ,  Y10T428/31928

Abstract: An adhesive composition includes a blend of a pressure sensitive adhesive and an additive. The pressure sensitive adhesive includes a (meth)acrylate polymer. The additive includes a copolymer with a vinyl polymeric backbone that includes at least one free radically polymerizable vinyl monomer A and at least one reinforcing comonomer B, wherein B is present at 0 to about 20% by weight of the copolymer, and a pendant polysiloxane monomer grafted to the backbone. The adhesive composition may optionally be crosslinked. The adhesive composition may be applied to a film to form a graphic article. These graphic articles may be applied to a substrate without liquid application aids.

Abstract translation: 粘合剂组合物包括压敏粘合剂和添加剂的共混物。 压敏粘合剂包括（甲基）丙烯酸酯聚合物。 添加剂包括具有乙烯基聚合物主链的共聚物，其包含至少一种可自由基聚合的乙烯基单体A和至少一种增强共聚单体B，其中B以共聚物的0至约20重量％存在，以及侧链聚硅氧烷单体 嫁接到骨干。 粘合剂组合物可任选地交联。 粘合剂组合物可以施加到膜上以形成图形制品。 这些图形制品可以应用于没有液体施用辅助剂的基材。

公开(公告)号：US06872268B2

公开(公告)日：2005-03-29

申请号：US10167347

申请日：2002-06-11

Applicant: John R. David ,  Jeffrey O. Emslander ,  Danny L. Fleming ,  Michael R. Kesti ,  Larry A. Meixner ,  Frank T. Sher ,  Ronald S. Steelman ,  David J. Yarusso

Inventor： John R. David ,  Jeffrey O. Emslander ,  Danny L. Fleming ,  Michael R. Kesti ,  Larry A. Meixner ,  Frank T. Sher ,  Ronald S. Steelman ,  David J. Yarusso

IPC: B32B33/00 ,  B29C65/48 ,  B29L9/00 ,  B44C1/10 ,  C04B41/45 ,  C04B41/61 ,  C09J7/02 ,  C09J201/00 ,  C23C26/00 ,  G09F7/18 ,  G09F15/00 ,  G09F19/22 ,  B32B31/04

CPC classification number: B44C1/10 ,  B32B37/003 ,  C04B41/009 ,  C04B41/4503 ,  C04B41/61 ,  C09J7/38 ,  C09J2201/28 ,  C23C26/00 ,  Y10T156/1028 ,  C04B41/4515 ,  C04B2103/54 ,  C04B28/02

Abstract: Films are closely conformed to substrates by reducing the air pressure to a subatmospheric level in at least one airflow pathway that is present in the film or the substrate. The reduced air pressure enables the film to tightly contact the substrate in locations where protrusions or depressions on the substrate are present. The method is particularly useful for conforming film containing graphics to a variety of substrates such as the sides of semi-trailers or concrete block walls, even in instances where the semi-trailer sides include rivets and/or grooves and where the concrete block wall is relatively rough.

Abstract translation: 通过在存在于膜或基底中的至少一个气流路径中将空气压力降低到低于大气压的水平，薄膜紧密地与基底相一致。 降低的空气压力使膜能够在存在基板上的突起或凹陷的位置处紧密接触基板。 该方法对于使膜包含图形与各种衬底例如半挂车或混凝土块壁的侧面一致是特别有用的，即使在半挂车侧面包括铆钉和/或凹槽的情况下，以及混凝土阻挡壁 比较粗糙

公开(公告)号：US06630238B2

公开(公告)日：2003-10-07

申请号：US09880431

申请日：2001-06-13

Applicant: Patrick D. Hyde ,  Dennis L. Krueger ,  Felix P. Lau ,  Eumi Pyun ,  Robert W. Shipman ,  Pamela S. Tucker ,  Roy Wong ,  David J. Yarusso

Inventor： Patrick D. Hyde ,  Dennis L. Krueger ,  Felix P. Lau ,  Eumi Pyun ,  Robert W. Shipman ,  Pamela S. Tucker ,  Roy Wong ,  David J. Yarusso

IPC: B32B712

CPC classification number: A61L15/585 ,  C08L21/02 ,  C08L53/00 ,  C08L53/02 ,  C08L2205/16 ,  C08L2666/02 ,  C08L2666/04 ,  C08L2666/24 ,  C09J7/38 ,  C09J9/00 ,  C09J133/06 ,  C09J133/08 ,  C09J153/00 ,  C09J201/00 ,  C09J2201/606 ,  C09J2433/00 ,  Y10T428/28 ,  Y10T428/2852 ,  Y10T428/2878 ,  C08L33/04

Abstract: A pressure-sensitive adhesive comprising a blend of at least two components, wherein the first component is at least one pressure-sensitive adhesive and the second component is at least one thermoplastic material, wherein the components form a blended composition having more than one domain and, wherein one domain is substantially continuous (generally, the pressure-sensitive adhesive) and the other domain is substantially fibrillous to schistose (generally, the thermoplastic material). The second component can be (a) at least one thermoplastic elastomer, (b) at least one elastomer with a tackifying resin or (c) at least one elastomer.

Abstract translation: 一种压敏粘合剂，其包含至少两种组分的共混物，其中所述第一组分是至少一种压敏粘合剂，并且所述第二组分是至少一种热塑性材料，其中所述组分形成具有多于一个结构域的共混组合物， ，其中一个结构域基本上是连续的（通常为压敏粘合剂），另一个结构域基本上是纤维状的（通常是热塑性材料）。 第二组分可以是（a）至少一种热塑性弹性体，（b）至少一种具有增粘树脂的弹性体或（c）至少一种弹性体。

公开(公告)号：US5266400A

公开(公告)日：1993-11-30

申请号：US867277

申请日：1992-04-09

Applicant: David J. Yarusso ,  Daniel C. Munson

Inventor： David J. Yarusso ,  Daniel C. Munson

IPC: C09J7/02

CPC classification number: C09J7/0207 ,  C08L2312/00 ,  C09J2400/283 ,  C09J2421/00 ,  C09J2453/006 ,  Y10T428/2809 ,  Y10T428/2852 ,  Y10T428/2883 ,  Y10T428/2891

Abstract: A pressure sensitive tape comprising an electron beam radiation crosslinkable pressure sensitive adhesive on a radiation-degradable backing, the adhesive having been crosslinked by exposure to electron beam radiation in a fashion such that the dosage reduction through the adhesive layer is no greater than about 40%; the average dosage which is received by the backing is less than about 80% of that received by the adhesive, and a sufficient dose of beam energy has been provided to produce a gel content in the adhesive of at least about 20% by weight of the elastomer.

Abstract translation: 一种压敏胶带，其包含在辐射可降解背衬上的电子束辐射可交联压敏粘合剂，所述粘合剂通过暴露于电子束辐射而被交联，使得通过粘合剂层的剂量减少不大于约40％ ; 由背衬接受的平均剂量小于由粘合剂接收的平均剂量的约80％，并且已经提供足够量的束能以在粘合剂中产生至少约20重量％的粘合剂的凝胶含量 弹性体。

公开(公告)号：US08791207B2

公开(公告)日：2014-07-29

申请号：US12688476

申请日：2010-01-15

Applicant: Ronald S. Steelman ,  Michael P. Daniels ,  David J. Yarusso ,  Craig E. Hamer

Inventor： Ronald S. Steelman ,  Michael P. Daniels ,  David J. Yarusso ,  Craig E. Hamer

IPC: C08L33/24 ,  C08L33/02 ,  C09J133/24 ,  C09J133/02

CPC classification number: C09J133/02 ,  C08L33/02 ,  C08L33/24 ,  C08L2205/02 ,  C09J133/24

Abstract: The present application is directed to a non-aqueous composition. The composition comprises a blend of an acidic copolymer derived from a first group of monomers comprising at least one acidic monomer, and a basic copolymer derived from a second group of monomers comprising at least one basic monomer. The basic copolymer may comprise an amide functionality. In some embodiments, the composition comprises an acidic (meth)acrylic copolymer having a Tg less than 0° C., which is derived from a first group of monomers comprising at least one acidic monomer, and a basic (meth)acrylic copolymer having a Tg less than 0° C., which is derived from a second group of monomers comprising at least one basic monomer. Additionally, the composition may comprise a minimum of 0.10 moles of acid/base pairs per kilogram of composition.

Abstract translation: 本申请涉及非水组合物。 组合物包含衍生自包含至少一种酸性单体的第一组单体的酸性共聚物和衍生自包含至少一种碱性单体的第二组单体的碱性共聚物的共混物。 碱性共聚物可以包含酰胺官能团。 在一些实施方案中，组合物包含Tg小于0℃的酸性（甲基）丙烯酸共聚物，其衍生自包含至少一种酸性单体的第一组单体和具有 Tg小于0℃，其衍生自包含至少一种碱性单体的第二组单体。 另外，组合物可以包含每千克组合物至少0.10摩尔的酸/碱对。

公开(公告)号：US20100143654A1

公开(公告)日：2010-06-10

申请号：US12706262

申请日：2010-02-16

Applicant: Danny L. Fleming ,  Michael R. Kesti ,  John A. Nielsen ,  Richard L. Peloquin ,  Frank T. Sher ,  David J. Yarusso

Inventor： Danny L. Fleming ,  Michael R. Kesti ,  John A. Nielsen ,  Richard L. Peloquin ,  Frank T. Sher ,  David J. Yarusso

IPC: B32B3/30

CPC classification number: C09J7/403 ,  C09J7/10 ,  Y10S428/914 ,  Y10T156/1023 ,  Y10T428/14 ,  Y10T428/1471 ,  Y10T428/1476 ,  Y10T428/1486 ,  Y10T428/24479 ,  Y10T428/24612 ,  Y10T428/2486 ,  Y10T428/28 ,  Y10T428/2839

Abstract: The present application is directed to adhesive articles and release liners. Namely, the present application is directed to an article comprising an adhesive layer with a structured surface. The structured surface comprises a first groove and a second groove recessed into the adhesive layer from a reference plane defined by the adhesive surface on either rim of the groove. In some embodiments, the second groove is contained within the first groove, and in other embodiments the grooves are separate. The first groove and the second groove have walls. The wall angle of the first groove with respect to the reference plane is non-zero and is smaller than the wall angle of the second groove with respect to the reference plane. The application is also directed to release liners for the adhesive article, wherein the surface of the release liner is the inverse of the adhesive surface.

Abstract translation: 本申请涉及粘合剂制品和脱模衬垫。 即，本申请涉及包含具有结构化表面的粘合剂层的制品。 结构化表面包括第一凹槽和从由凹槽的任一边缘上的粘合剂表面限定的参考平面凹入粘合剂层的第二凹槽。 在一些实施例中，第二凹槽包含在第一凹槽内，而在其它实施例中凹槽是分开的。 第一槽和第二槽具有壁。 第一凹槽相对于参考平面的壁角不是零并且小于第二凹槽相对于参考平面的壁角。 该应用还涉及用于粘合剂制品的剥离衬垫，其中剥离衬垫的表面与粘合剂表面相反。

公开(公告)号：US20080078500A1

公开(公告)日：2008-04-03

申请号：US11537736

申请日：2006-10-02

Applicant: Frank T. Sher ,  David J. Yarusso ,  Brian E. Spiewak

Inventor： Frank T. Sher ,  David J. Yarusso ,  Brian E. Spiewak

IPC: B32B37/00

CPC classification number: B32B7/06 ,  B29C48/08 ,  B29C48/19 ,  B29C48/20 ,  B29C48/21 ,  B32B3/30 ,  B32B27/32 ,  C09J7/38 ,  C09J7/403 ,  C09J2201/28

Abstract: Disclosed herein is a method of manufacturing a structured release liner. The method includes providing an extrudable material; extruding the extrudable material through a die having a profile thereby forming a base and at least one rail. The rail has a height over the base of less than 100 micrometers. In other embodiments, a first and second extrudable material are provided and are extruded through the die to create a first layer and a second layer. The structured release liner may also be formed by extruding onto an existing substrate. Also disclosed herein is a method of forming a laminate construction comprising an adhesive layer and a backing.

Abstract translation: 本文公开了一种制造结构化释放衬垫的方法。 该方法包括提供可挤压材料; 通过具有轮廓的模具挤出可挤压材料，从而形成基部和至少一个轨道。 导轨的高度小于100微米。 在其它实施例中，提供第一和第二可挤出材料并通过模具挤出以形成第一层和第二层。 结构化释放衬垫也可以通过挤压到现有衬底上而形成。 本文还公开了形成包括粘合剂层和背衬的层压结构的方法。