Abstract:
An extrusion die (20) and method for co-extruding a first molten polymeric material and a second molten polymeric material. The die includes a first die portion (20), a second die portion and a shim separating the first die portion and the second die portion. The shim has a first side and a second side, the first side of the shim forming a boundary of the first die portion and defining a first die cavity (38), the second side of the shim forming a boundary of the second die portion and defining a second die cavity (40). A dispensing edge (36) is provided having a plurality of first and second extrusion openings, a plurality of first feed channels connecting the first die cavity to the first extrusion openings along the dispensing edge, and a plurality of second feed channels connecting the second die cavity to the second extrusion openings along the dispensing edge. The first and second extrusion openings arranged along the dispensing edge to provide an interfacial zone having portions of the first extrusion openings disposed between portions of the second extrusion openings. The die is used in an extrusion system and a method for making a multilayered article.
Abstract:
The present application is directed to adhesive articles and release liners. Namely, the present application is directed to an article comprising an adhesive layer with a structured surface. The structured surface comprises a first groove and a second groove recessed into the adhesive layer from a reference plane defined by the adhesive surface on either rim of the groove. In some embodiments, the second groove is contained within the first groove, and in other embodiments the grooves are separate. The first groove and the second groove have walls. The wall angle of the first groove with respect to the reference plane is non-zero and is smaller than the wall angle of the second groove with respect to the reference plane. The application is also directed to release liners for the adhesive article, wherein the surface of the release liner is the inverse of the adhesive surface.
Abstract:
Disclosed herein is a method of manufacturing a structured release liner. The method includes providing a base; providing a ridge-forming material; coating the ridge-forming material on the base; forming the ridge-forming material into at least one ridge using a coating bar having a profile; and solidifying the ridge-forming material. Coating the ridge-forming material on the base and forming the ridge-forming material into the at least one ridge using a coating bar may be carried out simultaneously.
Abstract:
A pressure sensitive adhesive composition comprising (a) a block copolymer composition comprising (i) a first component having a configuration of A-B, and (ii) a second component having a configuration of A-B-(B-A)n where n ranges from 1 to 20, wherein A is an alkenyl aromatic or arene hydrocarbon polymer and B is polybutadiene, and wherein the first component is present in an amount ranging from about 40 weight % to about 95 weight % based on a total weight of the block copolymer composition; (b) a polyphenylene oxide resin; and (c) a tackifier resin compatible with B.
Abstract:
Adhesive articles are prepared through the use of modified release liners. The modified release liners include a fracturable layer and a release surface partially covering the fracturable layer. The modified release liners may be prepared by selective coating of a release material onto the fracturable layer or by selective treatment of a release surface to expose portions of the fracturable layer. Upon removal of an adhesive layer adhered to the modified release liner, portions of the fracturable layer of the release liner adhere to the adhesive layer to form a modified adhesive layer.
Abstract:
The present application is directed to adhesive articles and release liners. Namely, the present application is directed to an article comprising an adhesive layer with a structured surface. The structured surface comprises a first groove and a second groove recessed into the adhesive layer from a reference plane defined by the adhesive surface on either rim of the groove. In some embodiments, the second groove is contained within the first groove, and in other embodiments the grooves are separate. The first groove and the second groove have walls. The wall angle of the first groove with respect to the reference plane is non-zero and is smaller than the wall angle of the second groove with respect to the reference plane. The application is also directed to release liners for the adhesive article, wherein the surface of the release liner is the inverse of the adhesive surface.
Abstract:
A pressure-sensitive adhesive comprises an elastomer having a partially oriented and partially crystallized elastomer component. Articles comprising the pressure-sensitive adhesive on a backing or substrate are also disclosed, as are methods of preparing the adhesive and the articles.
Abstract:
A solvent-free hot melt process, for preparing a non-thermosettable, pressure-sensitive adhesive from a tackified non-thermoplastic hydrocarbon elastomer. The process employs a continuous compounding device that has a sequence of alternating conveying and processing zones. The processing zones masticate and mix materials in them. Non-thermoplastic elastomers having high molecular weight may be readily compounded into adhesives in the process.
Abstract:
The present application is directed to a non-aqueous composition. The composition comprises a blend of an acidic copolymer derived from a first group of monomers comprising at least one acidic monomer, and a basic copolymer derived from a second group of monomers comprising at least one basic monomer. The basic copolymer may comprise an amide functionality. In some embodiments, the composition comprises an acidic (meth)acrylic copolymer having a Tg less than 0° C., which is derived from a first group of monomers comprising at least one acidic monomer, and a basic (meth)acrylic copolymer having a Tg less than 0° C., which is derived from a second group of monomers comprising at least one basic monomer. Additionally, the composition may comprise a minimum of 0.10 moles of acid/base pairs per kilogram of composition.
Abstract:
An adhesive composition includes a blend of a pressure sensitive adhesive and an additive. The pressure sensitive adhesive includes a (meth)acrylate polymer. The additive includes a copolymer with a vinyl polymeric backbone that includes at least one free radically polymerizable vinyl monomer A and at least one reinforcing comonomer B, wherein B is present at 0 to about 20% by weight of the copolymer, and a pendant polysiloxane monomer grafted to the backbone. The adhesive composition may optionally be crosslinked. The adhesive composition may be applied to a film to form a graphic article. These graphic articles may be applied to a substrate without liquid application aids.