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    Coal liquefaction process with metal/iodine cocatalyst
    12.
    发明授权
    Coal liquefaction process with metal/iodine cocatalyst 失效
    煤液化过程与金属/碘助催化剂

    公开(公告)号：US4824558A

    公开(公告)日：1989-04-25

    申请号：US93376

    申请日：1987-09-04

    Applicant: Peter S. Maa ,  Lonnie W. Vernon ,  William E. Winter ,  Gopal H. Singhal

    Inventor： Peter S. Maa ,  Lonnie W. Vernon ,  William E. Winter ,  Gopal H. Singhal

    IPC: C10G1/08 ,  C10G45/00 ,  C10G45/04

    CPC classification number: C10G1/086

    Abstract: An improved process for hydroconverting carbonaceous material wherein the hydroconversion is accomplished in the presence of a sulfide of tin or tin and at least one metal selected from the Group of metals consisting of the Groups IV-B, V-A, VI-A, VII-A and Group VIII-A metals of the Periodic Table of the Elements and in the presence of iodine. The tin and any other metal may be added directly as the sulfide or as a soluble precursor that will either decompose or be converted to the sulfide. The iodine may be added directly as iodine, hydrogen iodine or as a precursor which will decompose to yield either iodine or hydrogen iodide. The hydroconversion is also accomplished in the presence of hydrogen. The tin sulfide when used either alone or in combination with a sulfide of at least one other metal selected from the Group of metals consisting of Groups IV-B, V-A, VI-A, VII-A and VIII-A of the Periodic Table of the Elements when used with iodine surprisingly increases the yield of gasoline boiling range product from the hydroconversion or liquefaction process. When tin sulfide is used in combination with at least one other metal sulfide, the increase in the yield of gasoline boiling range product is even more surprising.

    Abstract translation: 一种用于加氢转化碳质材料的改进方法，其中加氢转化是在锡或锡的硫化物和选自由IV-B，VA，VI-A，VII-A族组成的金属组中的至少一种金属存在下完成的 和元素周期表第VIII-A族金属和碘存在下。 锡和任何其他金属可以直接加入作为硫化物或作为可分解或转化为硫化物的可溶性前体。 碘可以直接加入碘，氢碘或作为前体分解，得到碘或碘化氢。 加氢转化也是在氢的存在下完成的。 当硫化锡单独使用或与至少一种选自由周期表IV-B族，VA，VI-A，VII-A和VIII-A族组成的金属组中的至少一种其它金属的硫化物组合使用时， 与碘使用时的元素令人惊讶地增加了来自加氢转化或液化过程的汽油沸点产物的产率。 当硫化锡与至少一种其他金属硫化物组合使用时，汽油沸点产物的产率增加更令人惊奇。

    Sour water treating process utilizing liquid membranes having a sulfonated polymer exterior oil phase
    13.
    发明授权
    Sour water treating process utilizing liquid membranes having a sulfonated polymer exterior oil phase 失效
    酸水处理工艺利用具有磺化聚合物外部油相的液膜

    公开(公告)号：US4064040A

    公开(公告)日：1977-12-20

    申请号：US682271

    申请日：1976-05-03

    Applicant: Gopal H. Singhal ,  Martin L. Gorbaty ,  Richard M. Minday ,  Norman N. Li

    Inventor： Gopal H. Singhal ,  Martin L. Gorbaty ,  Richard M. Minday ,  Norman N. Li

    IPC: B01D61/40 ,  C08J3/09 ,  B01D31/00 ,  B01D13/00

    CPC classification number: C08J3/09 ,  B01D61/40

    Abstract: This invention relates to novel liquid membrane formulations which are water-in-oil emulsions wherein the oil phase comprises a sulfonated polymer having a backbone which is substantially nonaromatic, for example, less than 10 mole % aromatic, and uses thereof in high temperature liquid membrane processes. The emulsions are useful in liquid membrane water treating processes, especially in water treating processes which are desirably run at high temperatures. In the most preferred embodiment, these compositions are used in a liquid membrane sour water treating process wherein a waste water stream containing ammonium sulfide is contacted with a liquid membrane emulsion, i.e. the emulsions of the instant invention, at conditions whereby ammonia permeates through the external phase of the emulsion into an acidic internal phase wherein it is converted to a nonpermeable form, e.g. ammonium ion, while H.sub.2 S is continuously stripped out of the waste water solution by means of an inert gas, e.g. steam. Processes of this sort are most effectivey carried out at temperatures greater than 80.degree. C. wherein the emulsions of the instant invention have excellent stability.

    Abstract translation: 本发明涉及新的液膜制剂，其是油包水乳液，其中油相包含具有基本上非芳香的主链的磺化聚合物，例如小于10摩尔％的芳香族，以及其在高温液体膜中的用途 过程。 乳液可用于液膜水处理方法，特别是在期望在高温下运行的水处理过程中。 在最优选的实施方案中，这些组合物用于液膜酸性水处理方法中，其中含有硫化铵的废水流与液体膜乳液接触，即本发明的乳液，其中氨渗透到外部 将乳液相转变成酸性内相，其中将其转化为不透气的形式，例如， 铵离子，而H2S通过惰性气体例如废水溶液连续地从废水溶液中排出。 蒸汽。 这种方法在大于80℃的温度下最有效地进行，其中本发明的乳液具有优异的稳定性。

    Regeneration of spent hydrodesulfurization catalyst with heteropoly acids
    15.
    发明授权
    Regeneration of spent hydrodesulfurization catalyst with heteropoly acids 失效
    用加氢脱硫催化剂与杂多酸再生

    公开(公告)号：US4272401A

    公开(公告)日：1981-06-09

    申请号：US059072

    申请日：1979-07-19

    Applicant: Raam R. Mohan ,  Gopal H. Singhal

    Inventor： Raam R. Mohan ,  Gopal H. Singhal

    IPC: B01J23/90 ,  B01J23/94 ,  C10G45/08 ,  B01J21/20 ,  B01J23/92 ,  C10G23/02

    CPC classification number: B01J23/90 ,  B01J23/94 ,  C10G45/08 ,  Y10S502/516

    Abstract: Contacting deactivated hydrodesulfurization catalyst, such as Co-Mo supported on alumina, with a heteropoly acid, such as molybdophosphoric acid or tungstosilicic acid, in pH range of about 1 to 3 and temperature range of about 20.degree. to 80.degree. C., results, before any coke is burned off the catalyst, in selective abstraction of vanadium and nickel, removal of sulfur, increase in surface area, and increase in pore volume of the catalyst. Subsequent cobalt doping of demetallized catalyst followed by calcination promotes decoking, additional sulfur removal and additional increase in surface area and pore volume. The process results in substantially complete regeneration of catalytic activity.

    Abstract translation: 接触失活的加氢脱硫催化剂，例如负载在氧化铝上的Co-Mo与杂多酸如钼磷酸或钨硅酸接触，pH范围为约1至3，温度范围为约20至80℃， 在任何焦炭烧掉催化剂之前，选择性地提取钒和镍，去除硫，表面积增加，催化剂孔体积增加。 后续的钴掺杂脱金属催化剂随后煅烧促进脱焦，额外的硫去除和额外的表面积和孔体积的增加。 该过程导致催化活性的基本上完全的再生。

    Novel liquid membrane formulations and uses thereof
    16.
    发明授权
    Novel liquid membrane formulations and uses thereof 失效
    新型液膜制剂及其用途

    公开(公告)号：US3959173A

    公开(公告)日：1976-05-25

    申请号：US492616

    申请日：1974-07-29

    Applicant: Norman N. Li ,  Gopal H. Singhal ,  Richard M. Minday ,  Martin L. Gorbaty

    Inventor： Norman N. Li ,  Gopal H. Singhal ,  Richard M. Minday ,  Martin L. Gorbaty

    IPC: B01D61/40 ,  C08J3/09 ,  B01J13/00

    CPC classification number: C08J3/09 ,  B01D61/40

    Abstract: The instant invention relates to novel liquid membrane formulations, i.e., emulsions, which comprise an aqueous interior phase and a water-immiscible exterior phase; said water-immiscible exterior phase comprising an ethylene vinyl acetate copolymer and a solvent for this polymer. These compositions may additionally contain a water insoluble surfactant to stabilize the emulsions. In the most preferred embodiment, the aqueous interior phase comprises a strong acid, for example from about 1 to 10 percent by weight sulfuric acid. These emulsions are useful in liquid membrane processes for the separation of dissolved components from aqueous solution. Emulsions of the instant invention are characterized as showing very low swelling when contacted with aqueous solutions, especially at higher temperatures and thus are especially effective for use in the treatment of sour water feed streams by the liquid membrane technique.

    Abstract translation: 本发明涉及新型液膜制剂，即乳液，其包含水性内相和水不混溶的外部相; 所述与水不混溶的外部相包含乙烯乙酸乙烯酯共聚物和用于该聚合物的溶剂。 这些组合物可另外含有水不溶性表面活性剂以稳定乳液。 在最优选的实施方案中，水性内相包含强酸，例如约1至10重量％的硫酸。 这些乳液可用于从水溶液中分离溶解组分的液膜方法。 本发明的乳液的特征在于当与水溶液接触时显示非常低的溶胀度，特别是在较高温度下，因此特别有效地用于通过液膜技术处理酸性水进料流。

    Catalytic process for hydroconversion of carbonaceous materials
    18.
    发明授权
    Catalytic process for hydroconversion of carbonaceous materials 失效
    碳质材料加氢转化催化过程

    公开(公告)号：US5064527A

    公开(公告)日：1991-11-12

    申请号：US608308

    申请日：1984-05-08

    Applicant: Gopal H. Singhal ,  Bobby L. Wilson ,  Edward H. Edelson ,  Michael A. Mikita

    Inventor： Gopal H. Singhal ,  Bobby L. Wilson ,  Edward H. Edelson ,  Michael A. Mikita

    IPC: C10G1/08

    CPC classification number: C10G1/086

    Abstract: An improved hydroconversion process for carbonaceous materials wherein a dihydrocarbyl substituted dithiocarbamate of a metal selected from any one of Groups IV-B, V-A, VI-A, VII-B, and VIII-A of the Periodic Table of Elements or a mixture thereof is used as a catalyst precursor. The improved process is effective for both normally solid and normally liquid carbonaceous materials and for carbonaceous materials which are either solid or liquid at the conversion conditions. The hydroconversion will be accomplished at a temperature within the range from about 500.degree. to about 900.degree. F., at a total pressure within the range from about 500 to 7000 psig and at a hydrogen partial pressure within the range from about 400 to about 5000 psig.

    Abstract translation: 含碳材料的改进的加氢转化方法，其中选自元素周期表第IV-B族，VA，VI-A，VII-B和VIII-A族中的任一种的金属的二烃基取代的二硫代氨基甲酸盐或其混合物是 用作催化剂前体。 改进的方法对于常规固体和常规含碳材料以及在转化条件下为固体或液体的碳质材料都是有效的。 加氢转化将在约500至约900°F范围内的温度下进行，总压力范围为约500至7000psig，氢分压为约400至约5000 psig

    Method for separating arsenic and/or selenium from shale oil
    19.
    发明授权
    Method for separating arsenic and/or selenium from shale oil 失效
    从页岩油中分离砷和/或硒的方法

    公开(公告)号：US4853110A

    公开(公告)日：1989-08-01

    申请号：US925676

    申请日：1986-10-31

    Applicant: Gopal H. Singhal ,  Daniel F. Ryan

    Inventor： Gopal H. Singhal ,  Daniel F. Ryan

    IPC: C10G29/10 ,  C10G45/00

    CPC classification number: C10G45/00 ,  C10G29/10

    Abstract: A process for removing arsenic and/or selenium from carbonaceous materials. The arsenic and/or selenium are separated by reaction with a metal oxide and/or metal sulfide which is itself derived from a metal complex, and organometallic compound and/or a metal salt of an organic acid which is soluble in said carbonaceous fluid and which either decomposes to the corresponding metal oxide and/or metal sulfide or which can be converted to the corresponding metal sulfide or metal oxide. The reaction of the metal oxide and/or metal sulfide with the arsenic and/or selenium is accomplished at a temperature within the range from about 300.degree. F. to about 800.degree. F. preferably from about 500.degree. F. to about 750.degree. F., most preferably from about 680.degree. F. to about 750.degree. F. and in either an inert or reducing atmosphere. Preferably, the conversion is accomplished in a reducing atmosphere and in the presence of molecular hydrogen.

    Abstract translation: 从含碳材料中除去砷和/或硒的方法。 通过与本身衍生自金属络合物的金属氧化物和/或金属硫化物以及可溶于所述碳质流体的有机金属化合物和/或有机酸的金属盐反应来分离砷和/或硒，并且其中 或分解成相应的金属氧化物和/或金属硫化物，或者可以转化为相应的金属硫化物或金属氧化物。 金属氧化物和/或金属硫化物与砷和/或硒的反应在约300°F至约800°F的温度范围内完成，优选约500°F至约750°F 最优选约680°F至约750°F，并且在惰性或还原气氛中。 优选地，转化在还原气氛中和在分子氢的存在下完成。

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