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公开(公告)号：US4014785A
公开(公告)日：1977-03-29
申请号：US620966
申请日：1975-10-09
摘要： The instant invention relates to novel liquid membrane formulations, i.e., emulsions, which comprise an aqueous interior phase and a water-immiscible exterior phase; said water-immiscible exterior phase comprising an ethylene vinyl acetate copolymer and a solvent for this polymer. These compositions may additionally contain a water insoluble surfactant to stabilize the emulsions. In the most preferred embodiment, the aqueous interior phase comprises a strong acid, for example from about 1 to 10 percent by weight sulfuric acid. These emulsions are useful in liquid membrane processes for the separation of dissolved components from aqueous solution. Emulsions of the instant invention are characterized as showing very low swelling when contacted with aqueous solutions, especially at higher temperatures and thus are especially effective for use in the treatment of sour water feed streams by the liquid membrane technique.
摘要翻译： 本发明涉及新型液膜制剂，即乳液，其包含水性内相和水不混溶的外部相; 所述与水不混溶的外部相包含乙烯乙酸乙烯酯共聚物和用于该聚合物的溶剂。 这些组合物可另外含有水不溶性表面活性剂以稳定乳液。 在最优选的实施方案中，水性内相包含强酸，例如约1至10重量％的硫酸。 这些乳液可用于从水溶液中分离溶解组分的液膜方法。 本发明的乳液的特征在于当与水溶液接触时显示非常低的溶胀度，特别是在较高温度下，因此特别有效地用于通过液膜技术处理酸性水进料流。
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公开(公告)号：US3959173A
公开(公告)日：1976-05-25
申请号：US492616
申请日：1974-07-29
摘要： The instant invention relates to novel liquid membrane formulations, i.e., emulsions, which comprise an aqueous interior phase and a water-immiscible exterior phase; said water-immiscible exterior phase comprising an ethylene vinyl acetate copolymer and a solvent for this polymer. These compositions may additionally contain a water insoluble surfactant to stabilize the emulsions. In the most preferred embodiment, the aqueous interior phase comprises a strong acid, for example from about 1 to 10 percent by weight sulfuric acid. These emulsions are useful in liquid membrane processes for the separation of dissolved components from aqueous solution. Emulsions of the instant invention are characterized as showing very low swelling when contacted with aqueous solutions, especially at higher temperatures and thus are especially effective for use in the treatment of sour water feed streams by the liquid membrane technique.
摘要翻译： 本发明涉及新型液膜制剂，即乳液，其包含水性内相和水不混溶的外部相; 所述与水不混溶的外部相包含乙烯乙酸乙烯酯共聚物和用于该聚合物的溶剂。 这些组合物可另外含有水不溶性表面活性剂以稳定乳液。 在最优选的实施方案中，水性内相包含强酸，例如约1至10重量％的硫酸。 这些乳液可用于从水溶液中分离溶解组分的液膜方法。 本发明的乳液的特征在于当与水溶液接触时显示非常低的溶胀度，特别是在较高温度下，因此特别有效地用于通过液膜技术处理酸性水进料流。
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3.发明授权Sour water treating process utilizing liquid membranes having a sulfonated polymer exterior oil phase 失效酸水处理工艺利用具有磺化聚合物外部油相的液膜
公开(公告)号：US4064040A
公开(公告)日：1977-12-20
申请号：US682271
申请日：1976-05-03
摘要： This invention relates to novel liquid membrane formulations which are water-in-oil emulsions wherein the oil phase comprises a sulfonated polymer having a backbone which is substantially nonaromatic, for example, less than 10 mole % aromatic, and uses thereof in high temperature liquid membrane processes. The emulsions are useful in liquid membrane water treating processes, especially in water treating processes which are desirably run at high temperatures. In the most preferred embodiment, these compositions are used in a liquid membrane sour water treating process wherein a waste water stream containing ammonium sulfide is contacted with a liquid membrane emulsion, i.e. the emulsions of the instant invention, at conditions whereby ammonia permeates through the external phase of the emulsion into an acidic internal phase wherein it is converted to a nonpermeable form, e.g. ammonium ion, while H.sub.2 S is continuously stripped out of the waste water solution by means of an inert gas, e.g. steam. Processes of this sort are most effectivey carried out at temperatures greater than 80.degree. C. wherein the emulsions of the instant invention have excellent stability.
摘要翻译： 本发明涉及新的液膜制剂，其是油包水乳液，其中油相包含具有基本上非芳香的主链的磺化聚合物，例如小于10摩尔％的芳香族，以及其在高温液体膜中的用途 过程。 乳液可用于液膜水处理方法，特别是在期望在高温下运行的水处理过程中。 在最优选的实施方案中，这些组合物用于液膜酸性水处理方法中，其中含有硫化铵的废水流与液体膜乳液接触，即本发明的乳液，其中氨渗透到外部 将乳液相转变成酸性内相，其中将其转化为不透气的形式，例如， 铵离子，而H2S通过惰性气体例如废水溶液连续地从废水溶液中排出。 蒸汽。 这种方法在大于80℃的温度下最有效地进行，其中本发明的乳液具有优异的稳定性。
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公开(公告)号：US3969265A
公开(公告)日：1976-07-13
申请号：US482592
申请日：1976-06-24
CPC分类号： B01D61/40
摘要： This invention relates to novel liquid membrane formulations which are water-in-oil emulsions wherein the oil phase comprises a sulfonated polymer having a backbone which is substantially nonaromatic, for example, less than 10 mole % aromatic, and uses thereof in high temperature liquid membrane processes. The emulsions are useful in liquid membrane water treating processes, especially in water treating processes which are desirably run at high temperatures. In the most preferred embodiment, these compositions are used in a liquid membrane sour water treating process wherein a waste water stream containing ammonium sulfide is contacted with a liquid membrane emulsion, i.e., the emulsions of the instant invention, at conditions whereby ammonia permeates through the external phase of the emulsion into an acidic internal phase wherein it is converted to a nonpermeable form, e.g., ammonium ion, while H.sub.2 S is continuously stripped out of the waste water solution by means of an inert gas, e.g., steam. Processes of this sort are most effectively carried out at temperatures greater than 80.degree.C. wherein the emulsions of the instant invention have excellent stability.
摘要翻译： 本发明涉及新的液膜制剂，其是油包水乳液，其中油相包含具有基本上非芳香的主链的磺化聚合物，例如小于10摩尔％的芳香族，以及其在高温液体膜中的用途 过程。 乳液可用于液膜水处理方法，特别是在期望在高温下运行的水处理过程中。 在最优选的实施方案中，这些组合物用于液体膜酸性水处理方法中，其中含有硫化铵的废水流与本发明的液体膜乳液（即本发明的乳液）接触，其中氨渗透通过 乳状液的外相进入酸性内部相，其中将其转化为不渗透的形式，例如铵离子，同时通过惰性气体例如蒸汽将H 2 S连续地从废水溶液中排出。 这种方法在大于80℃的温度下最有效地进行，其中本发明的乳液具有优异的稳定性。
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公开(公告)号：US5294349A
公开(公告)日：1994-03-15
申请号：US925356
申请日：1992-08-04
CPC分类号： B01J31/0227 , B01J31/0217 , B01J31/0218 , B01J31/0225 , B01J31/226 , B01J31/26 , C10G1/00 , C10G1/006 , C10G1/086 , C10L9/02 , B01J2531/40 , B01J2531/50 , B01J2531/60 , B01J2531/70 , B01J2531/80
摘要： A process for hydroprocessing coal to hydrocarbon oils wherein coal is depolymerized at low temperatures by contacting finely divided coal with a hard acid and soft base. The depolymerized coal is then hydroprocessed to hydrocarbon oils by forming a mixture with a coal conversion catalyst or precursor thereof, and hydroprocessing the mixture at temperatures of from 250.degree. to 550.degree. C. and hydrogen partial pressures of from 2100 to 35000 kPa.
摘要翻译： 将煤加氢处理到烃油的方法，其中煤通过使细分散的煤与硬酸和软碱接触而在低温下解聚。 然后通过与煤转化催化剂或其前体形成混合物，然后将解聚的煤加氢处理成烃油，并在250-550℃的温度和2100〜35000kPa的氢分压下对该混合物进行加氢处理。
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公开(公告)号：US4824558A
公开(公告)日：1989-04-25
申请号：US93376
申请日：1987-09-04
CPC分类号： C10G1/086
摘要： An improved process for hydroconverting carbonaceous material wherein the hydroconversion is accomplished in the presence of a sulfide of tin or tin and at least one metal selected from the Group of metals consisting of the Groups IV-B, V-A, VI-A, VII-A and Group VIII-A metals of the Periodic Table of the Elements and in the presence of iodine. The tin and any other metal may be added directly as the sulfide or as a soluble precursor that will either decompose or be converted to the sulfide. The iodine may be added directly as iodine, hydrogen iodine or as a precursor which will decompose to yield either iodine or hydrogen iodide. The hydroconversion is also accomplished in the presence of hydrogen. The tin sulfide when used either alone or in combination with a sulfide of at least one other metal selected from the Group of metals consisting of Groups IV-B, V-A, VI-A, VII-A and VIII-A of the Periodic Table of the Elements when used with iodine surprisingly increases the yield of gasoline boiling range product from the hydroconversion or liquefaction process. When tin sulfide is used in combination with at least one other metal sulfide, the increase in the yield of gasoline boiling range product is even more surprising.
摘要翻译： 一种用于加氢转化碳质材料的改进方法，其中加氢转化是在锡或锡的硫化物和选自由IV-B，VA，VI-A，VII-A族组成的金属组中的至少一种金属存在下完成的 和元素周期表第VIII-A族金属和碘存在下。 锡和任何其他金属可以直接加入作为硫化物或作为可分解或转化为硫化物的可溶性前体。 碘可以直接加入碘，氢碘或作为前体分解，得到碘或碘化氢。 加氢转化也是在氢的存在下完成的。 当硫化锡单独使用或与至少一种选自由周期表IV-B族，VA，VI-A，VII-A和VIII-A族组成的金属组中的至少一种其它金属的硫化物组合使用时， 与碘使用时的元素令人惊讶地增加了来自加氢转化或液化过程的汽油沸点产物的产率。 当硫化锡与至少一种其他金属硫化物组合使用时，汽油沸点产物的产率增加更令人惊奇。
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7.发明授权Lubricating oil containing a mixed ligand metal complex and a metal thiophosphate 失效含有混合配体金属络合物和硫代磷酸金属的润滑油
公开(公告)号：US5055211A
公开(公告)日：1991-10-08
申请号：US404132
申请日：1989-09-07
申请人： Jacob J. Habeeb , Gopal H. Singhal
发明人： Jacob J. Habeeb , Gopal H. Singhal
IPC分类号： C07F7/00 , C10M137/10 , C10M159/18 , C10M163/00
CPC分类号： C10M159/18 , C07F7/003 , C10M137/10 , C10M163/00 , C10M2207/09 , C10M2219/068 , C10M2223/045 , C10M2227/09 , C10N2210/01 , C10N2210/02 , C10N2210/04 , C10N2210/05 , C10N2210/06 , C10N2210/07 , C10N2210/08 , C10N2240/02 , C10N2240/04 , C10N2240/042 , C10N2240/044 , C10N2240/046 , C10N2240/08 , C10N2240/10 , C10N2240/101 , C10N2240/102 , C10N2240/103 , C10N2240/104 , C10N2240/105 , C10N2240/106 , C10N2240/14
摘要： The addition of certain mixed ligand metal complexes and a metal thiophosphate to a lubricating oil results in a significant improvement in the anti-wear performance of the oil. Tin dithiocarbamate-ethoxyethylxanthate and zinc dialkyldithiophosphate are preferred additives.
摘要翻译： 将某些混合配体金属络合物和硫代磷酸金属添加到润滑油中导致油的抗磨损性能的显着改善。 二硫代氨基甲酸锡 - 乙氧基乙基黄原酸酯和二烷基二硫代磷酸锌是优选的添加剂。
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公开(公告)号：US4272401A
公开(公告)日：1981-06-09
申请号：US059072
申请日：1979-07-19
申请人： Raam R. Mohan , Gopal H. Singhal
发明人： Raam R. Mohan , Gopal H. Singhal
CPC分类号： B01J23/90 , B01J23/94 , C10G45/08 , Y10S502/516
摘要： Contacting deactivated hydrodesulfurization catalyst, such as Co-Mo supported on alumina, with a heteropoly acid, such as molybdophosphoric acid or tungstosilicic acid, in pH range of about 1 to 3 and temperature range of about 20.degree. to 80.degree. C., results, before any coke is burned off the catalyst, in selective abstraction of vanadium and nickel, removal of sulfur, increase in surface area, and increase in pore volume of the catalyst. Subsequent cobalt doping of demetallized catalyst followed by calcination promotes decoking, additional sulfur removal and additional increase in surface area and pore volume. The process results in substantially complete regeneration of catalytic activity.
摘要翻译： 接触失活的加氢脱硫催化剂，例如负载在氧化铝上的Co-Mo与杂多酸如钼磷酸或钨硅酸接触，pH范围为约1至3，温度范围为约20至80℃， 在任何焦炭烧掉催化剂之前，选择性地提取钒和镍，去除硫，表面积增加，催化剂孔体积增加。 后续的钴掺杂脱金属催化剂随后煅烧促进脱焦，额外的硫去除和额外的表面积和孔体积的增加。 该过程导致催化活性的基本上完全的再生。
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公开(公告)号：US5086027A
公开(公告)日：1992-02-04
申请号：US631303
申请日：1990-12-18
CPC分类号： B01J23/8993 , B01J37/086
摘要： A catalyst composition comprised of: about 0.005 to 5.0 wt. % noble metal, about 0.5 to 5 wt. % of at least one Group VIII metal, and about 3 to 18 wt. % of a Group VI metal, and a refractory support, wherein the noble metal is incorporated into the refractory support by use of a precursor represented by ML.sub.2 when the noble metal is Pt or Pd and ML.sub.3, when the noble metal is Rh or Ir, where M is the noble metal and L is a ligand selected from the dithiocarbamates, dithiophosphates, dithiophosphinates, xanthates, thioxanthates, and further wherein L has organo groups having a sufficient number of carbon atoms to render the noble metal complex soluble in oil.
摘要翻译： 催化剂组合物包含：约0.005至5.0wt。 ％贵金属，约0.5〜5wt。 ％的至少一种第Ⅷ族金属，和约3至18wt。 ％的VI族金属和耐火载体，其中当贵金属为Pt或者Pd和ML3时，当贵金属为Rh或Ir时，使用由ML2表示的前体将贵金属掺入耐火载体中， 其中M是贵金属，L是选自二硫代氨基甲酸盐，二硫代磷酸盐，二硫代磷酸盐，黄原酸盐，硫代黄酸盐的配体，并且其中L具有足够数目的碳原子的有机基团以使贵金属络合物可溶于油。
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10.发明授权
公开(公告)号：US4683316A
公开(公告)日：1987-07-28
申请号：US815604
申请日：1986-01-02
申请人： Gopal H. Singhal
发明人： Gopal H. Singhal
IPC分类号： C07C67/00 , C07C325/00 , C07C333/16 , C07F11/00
CPC分类号： C07F11/005
摘要： An improved process for preparing dihydrocarbyl substituted dithiocarbamates of molybdenum (VI) wherein an alkali metal ammonium or substituted ammonium salt of a dihydrocarbyl substituted dithiocarbamate is reacted with an alkali metal molybdate in the presence of an organic acid. The process is carried out in an inert atmosphere and within a relatively narrow range of temperatures. The dihydrocarbyl substituted dithiocarbamate of molybdenum (VI) may be recrystallized after preparation to increase its purity. The dihydrocarbyl substituted dithiocarbamate of molybdenum (VI) is produced at a temperature within the range from about -10.degree. C. to about +25.degree. C. at a pH during neutralization within the range from about 5.0 to about 8.0.
摘要翻译： 一种制备钼（Ⅵ）的二烃基取代二硫代氨基甲酸酯的改进方法，其中将碱金属铵或二烃基取代的二硫代氨基甲酸取代的铵盐与有机酸存在下的碱金属钼酸盐反应。 该方法在惰性气氛中并在相对较窄的温度范围内进行。 钼（VI）的二烃基取代的二硫代氨基甲酸盐在制备后可以重结晶以提高其纯度。 钼（VI）的二烃基取代的二硫代氨基甲酸盐在约-10℃至约+25℃的温度范围内，在中和期间的pH为约5.0至约8.0。
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