公开(公告)号：US4663132A

公开(公告)日：1987-05-05

申请号：US713433

申请日：1985-03-19

申请人： Hans-Werner Schmidt ,  Walter Koch ,  Martin Hirsch ,  Karlheinz Rosenthal ,  Yilmaz Yetmen

发明人： Hans-Werner Schmidt ,  Walter Koch ,  Martin Hirsch ,  Karlheinz Rosenthal ,  Yilmaz Yetmen

IPC分类号： C01F7/04 ,  C01F7/47

CPC分类号： C01F7/04 ,  C01F7/473

摘要： In a method of processing contaminated sodium oxalate which becomes available in a separating stage succeeding the digestion of bauxite in accordance with the Bayer process, chemicals used in the digesting process are recovered in that moist sodium oxalate which has been separated is dried with the hot exhaust gases from a rotary kiln jointly with aluminum hydroxide or aluminum oxide hydrate and/or reactive alumina at a mole ratio of aluminum to sodium of at least 0.8 and the dried product is decomposed in said rotary kiln at a temperature of 780.degree. to 1000.degree. C. to form sodium aluminate. Suitably drying is effected by spray drying in direct contact with the exhaust gases of the rotary kiln and decomposition is effected at a temperature in the range from 850.degree. to 950.degree. C. and with an Al:Na ratio not in excess of 1.2.

摘要翻译： 在根据拜耳方法处理铝矾土消化后的分离阶段中可用的污染草酸钠的方法中，回收用于消化过程中的化学物质，将已分离的潮湿草酸钠用热排出物干燥 与氢氧化铝或氧化铝水合物和/或活性氧化铝一起以铝与钠的摩尔比为至少为0.8的来自回转窑的气体和所述干燥产物在所述回转窑中在780℃至1000℃的温度下分解 以形成铝酸钠。 通过与回转窑的废气直接接触的喷雾干燥来适当地干燥，并且在850℃至950℃的温度和不超过1.2的Al:Na比中进行分解。

公开(公告)号：US4643885A

公开(公告)日：1987-02-17

申请号：US713461

申请日：1985-03-19

申请人： Hans-Werner Schmidt ,  Walter Koch ,  Martin Hirsch ,  Karlheinz Rosenthal ,  Yilmaz Yetmen

发明人： Hans-Werner Schmidt ,  Walter Koch ,  Martin Hirsch ,  Karlheinz Rosenthal ,  Yilmaz Yetmen

IPC分类号： C01F7/04 ,  C01F7/16 ,  C01F7/47 ,  C07C51/42 ,  C07C55/06 ,  C07C55/07

CPC分类号： C01F7/04 ,  C01F7/473

摘要： In a method for processing contaminated sodium oxalate which becomes available in a separating stage succeeding the digestion of bauxite in accordance with the Bayer process, chemicals used in the digesting process are recovered in that the moist sodium oxalate which has been separated is dried with the hot exhaust gases from a fluidized bed, particularly a circulating fluidized bed, jointly with aluminum hydroxide or aluminum oxide hydrate and/or reactive alumina at a mole ratio of aluminum to sodium of at least 0.8 and the dried product is decomposed in said fluidized bed at a temperature of 780.degree. to 1000.degree. C. to form sodium aluminate. Suitably drying is effected by spray drying in direct contact with the exhaust gases of the fluidized bed and decomposition is effected at a temperature in the range from 850.degree. to 950.degree. C. and with an Al:Na mole ratio not in excess of 1.2.

摘要翻译： 在根据拜耳方法处理铝土矿消化后的分离阶段中可用的受污染的草酸钠的方法中，回收用于消化过程中的化学品，其中分离的湿草酸钠用热 来自流化床，特别是循环流化床的废气与氢氧化铝或氧化铝水合物和/或反应性氧化铝以铝至钠的摩尔比与至少为0.8一起，并且干燥产物在所述流化床中以 温度为780〜1000℃，形成铝酸钠。 通过与流化床的废气直接接触的喷雾干燥来适当干燥，并且在850℃至950℃的温度和不超过1.2的Al:Na摩尔比下进行分解。

公开(公告)号：US08802759B2

公开(公告)日：2014-08-12

申请号：US13254411

申请日：2010-03-09

申请人： Alexandre Terrenoire ,  Roelof Balk ,  Harm Wiese ,  Arno Tuchbreiter ,  Timothy Francis ,  Hans-Werner Schmidt ,  Andreas Bernet

发明人： Alexandre Terrenoire ,  Roelof Balk ,  Harm Wiese ,  Arno Tuchbreiter ,  Timothy Francis ,  Hans-Werner Schmidt ,  Andreas Bernet

IPC分类号： C08K5/20

CPC分类号： C09D7/63 ,  C08K5/20 ,  C09D133/14

摘要： The present invention relates to binders based on polymer dispersions and terephthalic bisamides with high water vapor transmission, and also to their use in formulations, especially for wood coatings.

摘要翻译： 本发明涉及基于聚合物分散体和具有高水蒸汽透过性的对苯二甲酸双酰胺的粘合剂，以及它们在制剂中的用途，特别是用于木器涂料。

公开(公告)号：US20110049501A1

公开(公告)日：2011-03-03

申请号：US12905112

申请日：2010-10-15

申请人： Markus BOLD ,  Christian Lennartz ,  Martina Prinz ,  Hans-Werner Schmidt ,  Mukundan Thelakkat ,  Markus Bäte ,  Christian Neuber ,  Wolfgang Kowalsky ,  Christian Schildknecht ,  Hans-Hermann Johannes

发明人： Markus BOLD ,  Christian Lennartz ,  Martina Prinz ,  Hans-Werner Schmidt ,  Mukundan Thelakkat ,  Markus Bäte ,  Christian Neuber ,  Wolfgang Kowalsky ,  Christian Schildknecht ,  Hans-Hermann Johannes

IPC分类号： H01L51/54 ,  C07F15/00

CPC分类号： H01L51/0085 ,  B01J31/2265 ,  B01J31/2273 ,  B01J2531/16 ,  B01J2531/17 ,  B01J2531/18 ,  B01J2531/57 ,  B01J2531/60 ,  B01J2531/70 ,  B01J2531/821 ,  B01J2531/822 ,  B01J2531/827 ,  B01J2531/828 ,  C07F15/0033 ,  C09B57/00 ,  C09B57/10 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1018 ,  C09K2211/1044 ,  C09K2211/1059 ,  C09K2211/18 ,  C09K2211/185 ,  H01L51/0081 ,  H01L51/5016 ,  H01L51/5096 ,  Y02P20/582

摘要： Use of transition metal complexes of the formula (I) in organic light-emitting diodes where: M1 is a metal atom; carbene is a carbene ligand; L is a monoanionic or dianionic ligand; K is an uncharged monodentate or bidentate ligand selected from the group consisting of phosphines; CO; pyridines; nitriles and conjugated dienes which form a π complex with M1; n is the number of carbene ligands and is at least 1; m is the number of ligands L, where m can be 0 or ≧1; o is the number of ligands K, where o can be 0 or ≧1; where the sum n+m+o is dependent on the oxidation state and coordination number of the metal atom and on the denticity of the ligands carbene, L and K and also on the charge on the ligands carbene and L, with the proviso that n is at least 1, and also an OLED comprising these transition metal complexes, a light-emitting layer comprising these transition metal complexes, OLEDs comprising this light-emitting layer, devices comprising an OLED according to the present invention, and specific transition metal complexes comprising at least two carbene ligands.

公开(公告)号：US20110049499A1

公开(公告)日：2011-03-03

申请号：US12901610

申请日：2010-10-11

申请人： Markus BOLD ,  Christian Lennartz ,  Martina Prinz ,  Hans-Werner Schmidt ,  Mukundan Thelakkat ,  Markus Bäte ,  Christian Neuber ,  Wolfgang Kowalsky ,  Christian Schildknecht ,  Hans-Hermann Johannes

发明人： Markus BOLD ,  Christian Lennartz ,  Martina Prinz ,  Hans-Werner Schmidt ,  Mukundan Thelakkat ,  Markus Bäte ,  Christian Neuber ,  Wolfgang Kowalsky ,  Christian Schildknecht ,  Hans-Hermann Johannes

IPC分类号： H01L51/54 ,  C07F15/00

CPC分类号： H01L51/0085 ,  B01J31/2265 ,  B01J31/2273 ,  B01J2531/16 ,  B01J2531/17 ,  B01J2531/18 ,  B01J2531/57 ,  B01J2531/60 ,  B01J2531/70 ,  B01J2531/821 ,  B01J2531/822 ,  B01J2531/827 ,  B01J2531/828 ,  C07F15/0033 ,  C09B57/00 ,  C09B57/10 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1018 ,  C09K2211/1044 ,  C09K2211/1059 ,  C09K2211/18 ,  C09K2211/185 ,  H01L51/0081 ,  H01L51/5016 ,  H01L51/5096 ,  Y02P20/582

摘要： Use of transition metal complexes of the formula (I) in organic light-emitting diodes where: M1 is a metal atom; carbene is a carbene ligand; L is a monoanionic or dianionic ligand; K is an uncharged monodentate or bidentate ligand selected from the group consisting of phosphines; CO; pyridines; nitriles and conjugated dienes which form a π complex with M1; n is the number of carbene ligands and is at least 1; m is the number of ligands L, where m can be 0 or ≧1; o is the number of ligands K, where o can be 0 or ≧1; where the sum n+m+o is dependent on the oxidation state and coordination number of the metal atom and on the denticity of the ligands carbene, L and K and also on the charge on the ligands carbene and L, with the proviso that n is at least 1, and also an OLED comprising these transition metal complexes, a light-emitting layer comprising these transition metal complexes, OLEDs comprising this light-emitting layer, devices comprising an OLED according to the present invention, and specific transition metal complexes comprising at least two carbene ligands.

摘要翻译： 在有机发光二极管中使用式（I）的过渡金属配合物，其中：M1是金属原子; 卡宾是卡宾配体; L是单阴离子或双阴离子配体; K是选自磷化氢的不带电荷的单齿或双齿配体; CO; 吡啶 腈和共轭二烯，形成＆pgr; 与M1复合; n是卡宾配体的数目，至少为1; m是配体L的数目，其中m可以是0或≥1; o是配体K的数目，其中o可以是0或≥1; 其中总和n + m + o取决于金属原子的氧化态和配位数以及配体卡宾，L和K的配位数，以及配体卡宾和L上的电荷，条件是n 包含这些过渡金属络合物的OLED，包含这些过渡金属络合物的发光层，包含该发光层的OLED，包含根据本发明的OLED的器件和特定的过渡金属络合物，其包含 至少两个卡宾配体。

公开(公告)号：US07858208B2

公开(公告)日：2010-12-28

申请号：US11575554

申请日：2005-09-20

申请人： Arnd Vogler ,  Valeri Pawlowski ,  Hans-Werner Schmidt ,  Mukundan Thelakkat ,  Markus Baete

发明人： Arnd Vogler ,  Valeri Pawlowski ,  Hans-Werner Schmidt ,  Mukundan Thelakkat ,  Markus Baete

IPC分类号： H01J1/63 ,  C07F9/28

CPC分类号： C07F1/005 ,  C08G73/00 ,  C09K11/06 ,  C09K2211/188 ,  H01L51/0059 ,  H01L51/0062 ,  H01L51/0077 ,  H01L51/5012 ,  H01L51/5096 ,  H05B33/14

摘要： The present invention relates to the use of copper(I) complexes of the formula I where X is nitrogen or a C—R group, R is alkyl or aryl, Ar is phenyl or naphthyl, each of which is optionally substituted by from one to three radicals selected from the group consisting of alkoxy, alkylthio, alkylamino, dialkylamino, alkoxycarbonyl, alkoxysulfonyl, halogen, cyano, carboxyl, hydroxysulfonyl and nitro, and the two optionally substituted phenyl or naphthyl radicals may be joined to one another by a chemical single bond via the carbon atoms in the α- and α′-position relative to the phosphorus atom, n is 1, 2 or 3, and Y is halogen, cyano, thiocyanato, alkoxy, aryloxy, alkylthio, arylthio, alkylamino, dialkylamino, arylamino or diarylamino, in organic light-emitting diodes (OLEDs), The present invention further relates to light-emitting layers which comprise at least one copper(I) complex of the formula I, to OLEDs which comprise at least one copper(I) complex of the formula I or an inventive light-emitting layer, and to stationary visual display units which comprise inventive OLEDs.Furthermore, the present invention relates to novel copper(I) complexes of the formula Ia and Ib where R, Ar and n are each as defined in formula I, Y in formula Ia is defined as cyano, thiocyanato, alkoxy, aryloxy, alkylthio, arylthio, alkylamino, dialkylamino, arylamino or diarylamino, and Y in formula Ib is defined as halogen, cyano, thiocyanato, alkoxy, aryloxy, alkylthio, arylthio, alkylamino, dialkylamino, arylamino or diarylamino.

摘要翻译： 本发明涉及式I的铜（I）络合物，其中X是氮或C-R基，R是烷基或芳基，Ar是苯基或萘基，其各自任选被一个 选自烷氧基，烷硫基，烷基氨基，二烷基氨基，烷氧基羰基，烷氧基磺酰基，卤素，氰基，羧基，羟基磺酰基和硝基的三个基团和两个任选取代的苯基或萘基可以通过化学单键彼此连接 通过相对于磷原子的α-和α'-位的碳原子，n是1,2或3，Y是卤素，氰基，氰硫基，烷氧基，芳氧基，烷硫基，芳硫基，烷基氨基，二烷基氨基，芳基氨基或 在有机发光二极管（OLED）中的二芳基氨基，本发明还涉及包含至少一种式I的铜（I）配合物的发光层与包含至少一种铜（I）络合物 公式I或者inve 发光层，以及包括本发明的OLED的固定的视觉显示单元。 此外，本发明涉及式Ia和Ib的新型铜（I）络合物，其中R，Ar和n各自如式I中所定义，式Ia中的Y定义为氰基，氰硫基，烷氧基，芳氧基，烷硫基， 氰基，氰硫基，烷氧基，芳氧基，烷硫基，芳硫基，烷氨基，二烷基氨基，芳基氨基或二芳基氨基。

公开(公告)号：US07790888B2

公开(公告)日：2010-09-07

申请号：US10555595

申请日：2004-04-30

申请人： Markus Bold ,  Peter Erk ,  Mairi Haddow ,  Ingolf Hennig ,  Hans-Werner Schmidt ,  Markus Baete ,  Mukundan Thelakkat

发明人： Markus Bold ,  Peter Erk ,  Mairi Haddow ,  Ingolf Hennig ,  Hans-Werner Schmidt ,  Markus Baete ,  Mukundan Thelakkat

IPC分类号： C07F15/00

CPC分类号： C07F15/0033

摘要： Process for preparing tris-ortho-metallated iridium complexes of the formula (I) where R1, R2, R3, R4, R5, R6 and X have the meanings given in the description, Ir complexes which can be prepared by the process of the invention, the use of the Ir complexes as emitter molecule in organic light-emitting diodes (OLEDs), a light-emitting layer comprising the Ir complexes, an OLED comprising this light-emitting layer and an apparatus comprising an OLED according to the present invention.

摘要翻译： 制备式（I）的三邻位金属化铱络合物的方法，其中R 1，R 2，R 3，R 4，R 5，R 6和X具有本说明书中给出的含义，可通过本发明方法制备的Ir配合物 ，在有机发光二极管（OLED）中使用Ir配合物作为发射体分子，包含Ir络合物的发光层，包含该发光层的OLED以及包含根据本发明的OLED的装置。

公开(公告)号：US20090318593A1

公开(公告)日：2009-12-24

申请号：US11992175

申请日：2006-09-21

申请人： Klaus Stoll ,  Kurt Hoffmann ,  Bruno Rotzinger ,  Hans-Werner Schmidt

发明人： Klaus Stoll ,  Kurt Hoffmann ,  Bruno Rotzinger ,  Hans-Werner Schmidt

IPC分类号： C08L23/06 ,  C08K5/05 ,  C08K5/20 ,  C08K5/1575 ,  C08L23/12

CPC分类号： C08K5/20 ,  C08K5/1575 ,  C08K7/02

摘要： A process for improving the flow properties of a melt containing a thermoplastic polymer, which comprises incorporating 0.005% to 0.5% by weight, relative to the weight of the thermoplastic polymer, of one or more additives selected from the group consisting of organic and inorganic compounds with needle-like morphology in their solid state into said thermoplastic polymer prior to or during melt processing.

摘要翻译： 一种用于改善含有热塑性聚合物的熔体的流动性能的方法，其包括相对于热塑性聚合物的重量掺入0.005重量％至0.5重量％的一种或多种选自有机和无机化合物的添加剂 在熔融加工之前或期间，其固态的针状形态进入所述热塑性聚合物。

公开(公告)号：US07479515B2

公开(公告)日：2009-01-20

申请号：US11703806

申请日：2007-02-07

申请人： Hans-Werner Schmidt ,  Paul Smith ,  Markus Blomenhofer

发明人： Hans-Werner Schmidt ,  Paul Smith ,  Markus Blomenhofer

IPC分类号： C08K5/20 ,  C07C233/64

CPC分类号： C08L53/02 ,  C08K5/20 ,  C08L23/10 ,  C08L51/003 ,  C08L53/00 ,  C08L55/02 ,  C08L101/00 ,  C08L2666/04 ,  C08L2666/24

摘要： A polypropylene composition containing the components a) a crystallizable polypropylene homopolymer, random copolymer, alternating or segmented copolymer, block copolymer or a blend of polypropylene with another synthetic polymer, and b) 0.001 to 5%, relative to the weight of component a), of a specific trimesic acid derivative.

摘要翻译： 含有组分的聚丙烯组合物a）可结晶聚丙烯均聚物，无规共聚物，交替或分段共聚物，嵌段共聚物或聚丙烯与另一种合成聚合物的共混物，和b）相对于组分a）的重量为0.001至5％ 的具体的均苯三酸衍生物。

公开(公告)号：US20080199731A1

公开(公告)日：2008-08-21

申请号：US11575554

申请日：2005-09-20

申请人： Arnd Vogler ,  Valeri Pawlowski ,  Hans-Werner Schmidt ,  Mukundan Thelakkat ,  Markus Bate

发明人： Arnd Vogler ,  Valeri Pawlowski ,  Hans-Werner Schmidt ,  Mukundan Thelakkat ,  Markus Bate

IPC分类号： H01J1/63 ,  C07F9/28

CPC分类号： C07F1/005 ,  C08G73/00 ,  C09K11/06 ,  C09K2211/188 ,  H01L51/0059 ,  H01L51/0062 ,  H01L51/0077 ,  H01L51/5012 ,  H01L51/5096 ,  H05B33/14

摘要： The present invention relates to the use of copper(I) complexes of the formula I where X is nitrogen or a C—R group, R is alkyl or aryl, Ar is phenyl or naphthyl, each of which is optionally substituted by from one to three radicals selected from the group consisting of alkoxy, alkylthio, alkylamino, dialkylamino, alkoxycarbonyl, alkoxysulfonyl, halogen, cyano, carboxyl, hydroxysulfonyl and nitro, and the two optionally substituted phenyl or naphthyl radicals may be joined to one another by a chemical single bond via the carbon atoms in the α- and α′-position relative to the phosphorus atom, n is 1, 2 or 3, and Y is halogen, cyano, thiocyanato, alkoxy, aryloxy, alkylthio, arylthio, alkylamino, dialkylamino, arylamino or diarylamino, in organic light-emitting diodes (OLEDs), The present invention further relates to light-emitting layers which comprise at least one copper(I) complex of the formula I, to OLEDs which comprise at least one copper(I) complex of the formula I or an inventive light-emitting layer, and to stationary visual display units which comprise inventive OLEDs.Furthermore, the present invention relates to novel copper(I) complexes of the formula Ia and Ib where R, Ar and n are each as defined in formula I, Y in formula Ia is defined as cyano, thiocyanato, alkoxy, aryloxy, alkylthio, arylthio, alkylamino, dialkylamino, arylamino or diarylamino, and Y in formula Ib is defined as halogen, cyano, thiocyanato, alkoxy, aryloxy, alkylthio, arylthio, alkylamino, dialkylamino, arylamino or diarylamino.

摘要翻译： 本发明涉及式I的铜（I）络合物，其中X是氮或CR基团，R是烷基或芳基，Ar是苯基或萘基，其各自任选被1-3个基团取代 选自烷氧基，烷硫基，烷基氨基，二烷基氨基，烷氧基羰基，烷氧基磺酰基，卤素，氰基，羧基，羟基磺酰基和硝基，并且两个任选取代的苯基或萘基可以通过化学单键经由 氰基，氰硫基，烷氧基，芳氧基，烷硫基，芳硫基，烷基氨基，二烷基氨基，芳基氨基或二芳基氨基，其中R 1，R 2， 在有机发光二极管（OLED）中，本发明还涉及包含至少一种式I的铜（I）络合物的发光层与包含至少一种式（I）的络合物 我还是一个 透气发光层，以及包括本发明的OLED的静止视觉显示单元。 此外，本发明涉及式Ia和Ib的新型铜（I）络合物，其中R，Ar和n各自如式I中所定义，式Ia中的Y定义为氰基，氰硫基，烷氧基，芳氧基，烷硫基， 氰基，氰硫基，烷氧基，芳氧基，烷硫基，芳硫基，烷氨基，二烷基氨基，芳基氨基或二芳基氨基。