Abstract:
A method of making a heterogenously supported catalyst useful in dimerization, oligomerization or polymerization is provided in which a catalyst precursor containing a metal and an aromatic group are alkylated onto an oligomeric support having at least one terminal unsaturated group by Friedel Crafts alkylation.
Abstract:
The invention relates to a method and an apparatus for providing information about printing plates to be manufactured for a new production of a printing press, wherein a use of at least one of said printing plates at the point of use thereof in the printing press is visualized on a display of a display apparatus, wherein several different positions exist at the point of use of the respective printing plate, each of said positions relating to one of several installation positions on a plate cylinder comprising the several installation positions and disposed in the printing press or relating to one of several storage positions of a printing plate magazine of the printing press comprising several storage positions, wherein by means of the display of the display apparatus simultaneously several different points of use in the printing press are displayed, wherein the display displays at which of the positions of a point of use comprising several positions a printing plate is to be provided, wherein the display additionally displays different states and/or properties with respect to at least one printing plate manufactured or to be manufactured and/or a position presently assumed by the respective printing plate on the transport path thereof to the printing press.
Abstract:
A method of making a heterogenously supported catalyst useful in dimerization, oligomerization or polymerization is provided in which a catalyst precursor containing a metal and an aromatic group are alkylated onto an oligomeric support having at least one terminal unsaturated group by Friedel Crafts alkylation.
Abstract:
The invention relates to a multinuclear metallocene catalyst of general formula (1); wherein Y and Y′ are the same or different and independently selected from a C1-20 linear hydrocarbyl group; C1-20 branched hydrocarbyl group; C1-20 cyclic hydrocarbyl group; a C1-30 aryl group and a C1-30 substituted aryl group; L and L′ are the same or different and each is an electron-donating group independently selected from the elements of Group 15 of the Periodic Table; Q and Q′ are the same or different and independently selected from hydrogen, a C1-30 alkyl group and a C1-30 aryl group; M″ is a metal selected from Group 3, 4, 5, 6, 7, 8, 9 and 10 elements and from lanthanide series elements of the Periodic Table; Z is selected from the group consisting of hydrogen; a halogen element; a C1-20 hydrocarbyl group; C1-20 alkoxy group and a C1-20 aryloxy group; B and B′ are the same or different and each is a half sandwich metallocene compound, with B being represented by Formula 2 and B′ being represented by Formula 3: W-M-Xx (Formula 2), W′-M′-X′x′, (Formula 3) wherein: W and W′ are the same or different and independently a ligand compound having a cyclo pentadienyl skeleton selected from the group consisting of cyclopentadienyl, substituted cyclopentadienyl, indenyl, substituted indenyl, fluorenyl and substituted fluorenyl; M and M′ are the same and each is independently selected from the group consisting of scandium; yttrium; lanthanoid series elements; titanium; zirconium; hafnium; vanadium; niobium; and tantalum; X and X′ are the same or different and each is selected from the group consisting of hydrogen; a halogen element; a C 1-20 hydrocarbyl group, C1-20 alkoxy group; and C1-20 aryloxy group; x and x′ are independently integers from 0 to 3; z is an integer from 1 to 5; n, n′ are independently 0 or 1, with 1≦(n+n′)≦2. The invention further relates to a method to prepare said multinuclear metallocene catalyst compound. The invention further relates to a catalyst system and to a process for the polymerisation of olefins.
Abstract:
A method and an apparatus are used for providing information about printing plates to be manufactured for a new production of a printing press. A point of use of at least one of the printing plates is visualized on a display. Several different positions exist at the point of use of each respective printing plate. Each may relate to one of several installation positions on a plate cylinder disposed in the printing press. These can also relate to storage positions of a printing plate magazine. Using the display, several different points of use in the printing area, for a particular printing plate, are displayed. The display depicts which one of the positions of use is to be provided. The display additionally depicts different states or properties of at least one printing plate. It may also depict a print location of a printing plate on a transport path.
Abstract:
Multinuclear catalyst complex comprising two or more active metal centres and at least one phenoxyimine compound and at least one substituted cyclopentadienyl, indenyl or fluorenyl derivative, each phenoxyimine compound being bonded to a cyclopentadienyl, indenyl or fluorenyl derivative forming a ligand framework, the cyclopentadienyl, indenyl or fluorenyl derivative being coordinated with one of the metal centres and the phenoxyimine compound being coordinated with an active metal centre other than the metal centre the cyclopentadienyl, indenyl or fluorenyl derivative is coordinated with, and wherein the phenoxyimine compound has the formula wherein R1 is hydrogen, alkyl, cycloalkyl, aryl or aralkyl; R2 is hydrogen, halogen, alkyl, cycloalkyl, aryl, O-alkyl or aralkyl; and R3 is alkyl, cycloalkyl, aryl or aralkyl, process for preparing a multinuclear catalyst composition comprising the steps of bonding a substituted phenoxyimine compound to a substituted cyclopentadienyl, indenyl or fluorenyl derivative to obtain a ligand framework and reacting at least one ligand framework with an active metal component and process for the polymerization of olefins, in particular of ethylene and optionally one or more other a-olefins, wherein said multinuclear catalyst is applied.
Abstract:
Fluorenyl-containing metallocenes are disclosed along with methods for making the metallocenes. Also disclosed are methods for using the metallocenes as polymerization catalysts. In addition, polymers resulting from such polymerizations are disclosed.
Abstract:
A catalyst comprising at least one metal selected from the group consisting of Group 8 metals, Group 9 metals, Group 10 metals and combinations thereof, an organic compound, and a solid acid and a method of making said catalyst is disclosed. The catalyst can be used in a hydrocarbon conversion process.