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    ADDITIVE FOR NON-AQUEOUS ELECTROLYTE AND SECONDARY BATTERY USING THE SAME
    11.
    发明申请
    ADDITIVE FOR NON-AQUEOUS ELECTROLYTE AND SECONDARY BATTERY USING THE SAME 有权
    添加非水电解质和使用相同的二次电池

    公开(公告)号：US20100099905A1

    公开(公告)日：2010-04-22

    申请号：US12649100

    申请日：2009-12-29

    Applicant: Yu Sin KIM ,  Hyeong Jin KIM ,  Hye Yun CHA ,  Ho Chun LEE

    Inventor： Yu Sin KIM ,  Hyeong Jin KIM ,  Hye Yun CHA ,  Ho Chun LEE

    IPC: C07C255/45

    CPC classification number: H01M10/0567 ,  H01M10/052 ,  H01M10/0569 ,  H01M10/4235

    Abstract: Disclosed is a compound represented by the following formula 1: wherein, each of R1˜R13 independently represents —H, —F, —Cl, —Br, —I, —OH, —SH, —COOH, —PO3H2, —NH2, —NO2, —O(CH2CH2O)nH (wherein, n is an integer of 1˜5), C1˜C12 alkyl group, C1˜C12 aminoalkyl group, C1˜C12 hydroxyalkyl group, C1˜C12 haloalkyl group, C2˜C12 alkenyl group, C1˜C12 alkoxy group, C1˜C12 alkylamino group, C1˜C12 dialkylamino group, C6˜C18 aryl group, C6˜C18 aminoaryl group, C6˜C18 hydroxyaryl group, C6˜C18 haloaryl group, C7˜C18 benzyl group, C7˜C18 aminobenzyl group, C7˜C18 hydroxybenzyl group, C7˜C18 halobenzyl group, or nitrile group (—CN); and at least one of R4˜R13 is nitrile group (—CN). A non-aqueous electrolyte comprising: (i) a lithium salt, (ii) a solvent, and (iii) a compound represented by formula 1; and a secondary battery comprising the non-aqueous electrolyte are also disclosed. When the compound represented by formula 1 is added to a non-aqueous electrolyte, it is possible to improve the safety of a secondary battery in an overcharged state.

    Abstract translation: 公开了由下式1表示的化合物：其中，R 1〜R 13各自独立地表示-H，-F，-Cl，-Br，-I，-OH，-SH，-COOH，-PO 3 H 2，-NH 2， -NO 2，-O（CH 2 CH 2 O）n H（其中n为1〜5的整数），C 1〜C 12烷基，C 1〜C 12氨基烷基，C 1〜C 12羟烷基，C 1〜C 12卤代烷基，C 2〜C 12烯基 基团，C 1〜C 12烷氧基，C 1〜C 12烷基氨基，C 1〜C 12二烷基氨基，C 6〜C 18芳基，C 6〜C 18氨基芳基，C 6〜C 18羟基芳基，C 6〜C 18卤代芳基，C 7〜C 18苄基， C 7〜C 18氨基苄基，C 7〜C 18羟基苄基，C 7〜C 18卤代苄基或腈基（-CN）; 并且R 4〜R 13中的至少一个为腈基（-CN）。 一种非水电解质，其包含：（i）锂盐，（ii）溶剂，和（iii）由式1表示的化合物; 还公开了包含非水电解质的二次电池。 当将由式1表示的化合物加入到非水电解质中时，可以提高过充电状态的二次电池的安全性。

    Non-aqueous electrolyte additive for improving safety and lithium ion secondary battery comprising the same
    12.
    发明申请
    Non-aqueous electrolyte additive for improving safety and lithium ion secondary battery comprising the same 有权
    用于改进安全性的非水电解质添加剂和包含该非水电解质添加剂的锂离子二次电池

    公开(公告)号：US20070134557A1

    公开(公告)日：2007-06-14

    申请号：US11651463

    申请日：2007-01-10

    Applicant: Hong-Kyu Park ,  Jeh-Won Choi ,  Yeon-Hee Lee ,  Young-Tack An ,  Hyeong-Jin Kim

    Inventor： Hong-Kyu Park ,  Jeh-Won Choi ,  Yeon-Hee Lee ,  Young-Tack An ,  Hyeong-Jin Kim

    IPC: H01M10/40 ,  C07C33/34

    CPC classification number: H01M10/4235 ,  H01M4/505 ,  H01M4/525 ,  H01M4/587 ,  H01M10/0567 ,  H01M2300/0025

    Abstract: The present invention relates to a non-aqueous electrolyte additive for improving safety and a lithium secondary battery comprising the same, and more particularly to a non-aqueous electrolyte additive that can improve cycle life and safety properties of a lithium ion secondary battery. According to the present invention, an organometallic compound represented by the Chemical Formula 1 is added to a non-aqueous electrolyte of a battery as an additive, and thus if a battery voltage is out of normal operation voltage range due to a short circuit and overcharge of a battery, etc., the non-aqueous electrolyte additive decomposes and a part of the decomposed additive polymerizes to form an insulating film on a cathode surface, and a part of the metal reacts with an insulating film formed on a cathode surface to improve thermal stability of the battery, thereby improving safety of the battery.

    Abstract translation: 本发明涉及一种用于提高安全性的非水电解质添加剂和包含该非水电解质添加剂的锂二次电池，更具体地说涉及一种能够改善锂离子二次电池的循环寿命和安全性能的非水电解质添加剂。 根据本发明，将由化学式1表示的有机金属化合物作为添加剂添加到电池的非水电解质中，因此如果由于短路和过充电而导致电池电压超出正常工作电压范围 的电池等，非水电解质添加剂分解，一部分分解添加剂聚合，在阴极表面形成绝缘膜，一部分金属与阴极表面形成的绝缘膜反应，从而提高 电池的热稳定性，从而提高电池的安全性。

    Nonaqueous electrolyte comprising oxyanion and lithium secondary battery using the same
    14.
    发明授权
    Nonaqueous electrolyte comprising oxyanion and lithium secondary battery using the same 有权
    包含氧阴离子和使用其的锂二次电池的非水电解质

    公开(公告)号：US08597826B2

    公开(公告)日：2013-12-03

    申请号：US11576084

    申请日：2005-12-07

    Applicant: Ho Chun Lee ,  Hyeong Jin Kim

    Inventor： Ho Chun Lee ,  Hyeong Jin Kim

    IPC: H01M6/04 ,  H01M6/16

    CPC classification number: H01M10/0567 ,  H01M4/38 ,  H01M4/525 ,  H01M10/05 ,  H01M10/052 ,  H01M10/0568 ,  H01M10/0569 ,  H01M10/4235

    Abstract: Disclosed is an electrolyte comprising: (a) an electrolyte salt; (b) a non-aqueous electrolyte solvent; and (c) a binary or multinary metal oxide salt. An electrochemical device comprising the same electrolyte is also disclosed. The metal oxide salt used in the electrolyte is dissolved in a non-aqueous solvent and generates oxyanions capable of improving corrosion resistance of metals. Therefore, the electrolyte prevents corrosion of metallic materials present in an electrochemical device, caused by extreme conditions, such as overcharge, overdischarge and high-temperature storage conditions, to which the device is exposed. Further, the electrolyte prevents degradation in the quality of an electrochemical device, caused by corrosion of metallic materials.

    Abstract translation: 公开了一种电解质，其包含：（a）电解质盐; （b）非水电解质溶剂; 和（c）二元或多元金属氧化物盐。 还公开了包含相同电解质的电化学装置。 将电解质中使用的金属氧化物盐溶解于非水溶剂中，生成能够提高金属耐蚀性的氧阴离子。 因此，电解液可以防止电极器件中存在的金属材料的腐蚀，这是由器件暴露于极端条件，如过充电，过放电和高温储存条件引起的。 此外，电解质防止由金属材料的腐蚀引起的电化学装置的质量下降。

    Lithium ion battery having an improved conserved property at a high temperature
    15.
    发明授权
    Lithium ion battery having an improved conserved property at a high temperature 有权
    在高温下具有改进的保存性能的锂离子电池

    公开(公告)号：US07846584B2

    公开(公告)日：2010-12-07

    申请号：US10559904

    申请日：2004-07-28

    Applicant: Seung-Don Choi ,  Hyeong Jin Kim

    Inventor： Seung-Don Choi ,  Hyeong Jin Kim

    IPC: H01M4/58

    CPC classification number: H01M10/0525 ,  H01M4/131 ,  H01M4/485 ,  H01M4/525 ,  H01M4/62 ,  H01M10/0567 ,  H01M10/0587 ,  H01M10/44

    Abstract: Disclosed are a cathode for a battery and a lithium ion battery. The cathode for a battery comprises a metal hydroxide having a large specific surface area as a cathode additive. The lithium ion battery comprises a cathode, an anode and a non-aqueous electrolyte, wherein the cathode comprises a metal hydroxide having a large specific surface area as a cathode additive. When a metal hydroxide having a large specific surface area is used as a cathode additive, excellent storage properties of a battery at a high temperature can be obtained, even if the metal hydroxide is used in a small amount.

    Abstract translation: 公开了一种用于电池和锂离子电池的阴极。 用于电池的阴极包括具有大比表面积的金属氢氧化物作为阴极添加剂。 锂离子电池包括阴极，阳极和非水电解质，其中阴极包括具有大比表面积的金属氢氧化物作为阴极添加剂。 当使用具有大比表面积的金属氢氧化物作为阴极添加剂时，即使使用少量的金属氢氧化物，也可以获得高温下的电池的优异的储存性。

    ANODE ACTIVE MATERIAL WITH IMPROVED ELECTROCHEMICAL PROPERTIES AND ELECTROCHEMICAL DEVICE COMPRISING THE SAME
    16.
    发明申请
    ANODE ACTIVE MATERIAL WITH IMPROVED ELECTROCHEMICAL PROPERTIES AND ELECTROCHEMICAL DEVICE COMPRISING THE SAME 有权
    具有改进的电化学性质的阳极活性材料和包含其的电化学装置

    公开(公告)号：US20090289219A1

    公开(公告)日：2009-11-26

    申请号：US12535207

    申请日：2009-08-04

    Applicant: Sung Kyun CHANG ,  Hyeong Jin KIM ,  Sang Hoon CHOY ,  Jeong Ju CHO

    Inventor： Sung Kyun CHANG ,  Hyeong Jin KIM ,  Sang Hoon CHOY ,  Jeong Ju CHO

    IPC: H01M4/04 ,  B05D5/12

    CPC classification number: H01M4/366 ,  H01M4/0402 ,  H01M4/0416 ,  H01M4/0471 ,  H01M4/133 ,  H01M4/1393 ,  H01M4/40 ,  H01M4/58 ,  H01M4/587 ,  H01M4/62 ,  H01M10/0525 ,  H01M10/058 ,  H01M2004/027

    Abstract: Disclosed is an anode active material, comprising: (a) a carbonaceous material; and (b) a carbide coating layer partially or totally formed on a surface of the carbonaceous material, the carbide coating layer comprising at least one element selected from the group consisting of metals and metalloids. An anode obtained by using the anode active material and an electrochemical device comprising the anode are also disclosed. The carbonaceous material comprises a coating layer of metal-/metalloid-carbide obtained by treating it at high temperature under inert atmosphere, wherein the coating layer has increased interfacial boding force to the carbonaceous material and thus shows minimized reactivity to lithium. The carbonaceous material as anode active material can minimize the irreversible anode capacity needed for the formation of an SEI film during the first charge/discharge cycle, thereby providing high capacity, high efficiency and significantly improved anode qualities.

    Abstract translation: 公开了一种阳极活性材料，其包含：（a）碳质材料; 和（b）部分或全部形成在所述碳质材料的表面上的碳化物涂层，所述碳化物涂层包含选自金属和准金属的至少一种元素。 还公开了通过使用阳极活性材料获得的阳极和包括阳极的电化学装置。 含碳材料包括通过在惰性气氛下在高温下处理而获得的金属/ /类金刚石碳化物的涂层，其中涂层对碳质材料具有增加的界面粘合力，因此显示出对锂的反应性最小化。 作为阳极活性材料的碳质材料可以使在第一充电/放电循环期间形成SEI膜所需的不可逆阳极容量最小化，从而提供高容量，高效率和显着改善的阳极质量。

    Method of manufacturing a superconducting magnesium diboride thin film
    17.
    发明授权
    Method of manufacturing a superconducting magnesium diboride thin film 失效
    制造超导二硼化镁薄膜的方法

    公开(公告)号：US07189425B2

    公开(公告)日：2007-03-13

    申请号：US10781644

    申请日：2004-02-20

    Applicant: Won nam Kang ,  Sung-ik Lee ,  Eun-mi Choi ,  Hyeong-jin Kim

    Inventor： Won nam Kang ,  Sung-ik Lee ,  Eun-mi Choi ,  Hyeong-jin Kim

    IPC: B05D5/12 ,  C23C14/00 ,  C23C16/00 ,  H01L39/24

    CPC classification number: H01L39/2487 ,  Y10T29/49014

    Abstract: A superconducting magnesium diboride (MgB2) thin film having c-axial orientation and a method and apparatus for fabricating the same are provided. The fabrication method includes forming a boron thin film on a substrate and thermally processing the substrate on which the boron thin film is formed along with a magnesium source and cooling the resulting structure. The superconducting magnesium diboride thin film can be used in a variety of electronic devices employing superconducting thin films, such as precision medical diagnosis equipment using superconducting quantum interface devices (SQUIDs) capable of sensing weak magnetic fields, microwave communications equipment used for satellite communications, and Josephson devices. Computer systems with 100 times greater computing speed can be implemented with the superconducting magnesium diboride thin film.

    Abstract translation: 提供了具有c轴取向的超导二硼化镁（MgB 2 N 2）薄膜及其制造方法和装置。 制造方法包括在基板上形成硼薄膜，并与镁源一起热处理形成有硼薄膜的基板，并冷却所得到的结构。 超导二硼化镁薄膜可用于使用超导薄膜的各种电子装置，例如使用能够感测弱磁场的超导量子接口装置（SQUID）的精密医疗诊断装置，用于卫星通信的微波通信设备和 约瑟夫森设备。 使用超导二硼化镁薄膜可以实现计算速度提高100倍的计算机系统。

    Poly(2-vinylpyridine)-b-poly(n-hexylisocyanate) amphiphilic coil-rod block copolymer and polymerization method thereof
    18.
    发明申请
    Poly(2-vinylpyridine)-b-poly(n-hexylisocyanate) amphiphilic coil-rod block copolymer and polymerization method thereof 审中-公开
    聚（2-乙烯基吡啶）-b-聚（正己基异氰酸酯）两亲性线性棒状嵌段共聚物及其聚合方法

    公开(公告)号：US20050215755A1

    公开(公告)日：2005-09-29

    申请号：US10993717

    申请日：2004-11-19

    Applicant: Jae-Suk Lee ,  Sang-Ho Han ,  Hyeong-Jin Kim ,  Yeong-Deuk Shin ,  Shashahar Samal

    Inventor： Jae-Suk Lee ,  Sang-Ho Han ,  Hyeong-Jin Kim ,  Yeong-Deuk Shin ,  Shashahar Samal

    IPC: C08G18/00 ,  C08F8/30 ,  C08F8/42 ,  C08F226/06 ,  C08F293/00 ,  C08F297/02 ,  C08G18/04 ,  C08G63/78 ,  C08L53/00

    CPC classification number: C08F297/02 ,  C08L53/00 ,  C08L2666/02

    Abstract: The present invention relates to a poly(2-vinylpyridine)-b-poly(n-hexylisocyanate) amphiphilic coil-rod block copolymer and a polymerization method thereof, more particularly to a poly(2-vinylpyridine)-b-poly(n-hexylisocyanate) amphiphilic coil-rod block copolymer polymerized by a process comprising synthesizing poly(2-vinylpyridine) having a narrow molecular weight distribution by living polymerization using potassium diphenylmethane (K-DPM) as initiator, adding sodium tetraphenylborate (NaBPh4) to replace the counter cation with a sodium ion (Na+) and adding n-hexylisocyanate and performing polymerization and a polymerization method thereof. According to the present invention, it is possible to control the molecular weight and the structure of each block of the copolymer. Therefore, coil-rod type amphiphilic block copolymers having a variety of structures can be obtained. The resultant block copolymer is a useful optical polymer material.

    Abstract translation: 本发明涉及聚（2-乙烯基吡啶）-b-聚（异己基异氰酸酯）两亲性线性棒状嵌段共聚物及其聚合方法，更具体地说涉及聚（2-乙烯基吡啶）-b-聚（n- 己基异氰酸酯）两亲性线棒嵌段共聚物，其通过包括通过使用二苯基甲烷（K-DPM）作为引发剂的活性聚合合成具有窄分子量分布的聚（2-乙烯基吡啶）的方法，加入四苯基硼酸钠（NaBPh 4 / SUB>）以用钠离子（Na + +）代替抗衡阳离子并加入正己基异氰酸酯并进行聚合及其聚合方法。 根据本发明，可以控制共聚物的每个嵌段的分子量和结构。 因此，可以获得具有各种结构的线棒型两亲嵌段共聚物。 得到的嵌段共聚物是有用的光学聚合物材料。

    Non-aqueous electrolyte additive for improving safety and lithium ion secondary battery comprising the same
    20.
    发明授权
    Non-aqueous electrolyte additive for improving safety and lithium ion secondary battery comprising the same 有权
    用于改进安全性的非水电解质添加剂和包含该非水电解质添加剂的锂离子二次电池

    公开(公告)号：US07901813B2

    公开(公告)日：2011-03-08

    申请号：US11651463

    申请日：2007-01-10

    Applicant: Hong-Kyu Park ,  Jeh-Won Choi ,  Yeon-Hee Lee ,  Young-Tack An ,  Hyeong-Jin Kim

    Inventor： Hong-Kyu Park ,  Jeh-Won Choi ,  Yeon-Hee Lee ,  Young-Tack An ,  Hyeong-Jin Kim

    IPC: H01M6/16 ,  C07C33/34 ,  C07C35/00

    CPC classification number: H01M10/4235 ,  H01M4/505 ,  H01M4/525 ,  H01M4/587 ,  H01M10/0567 ,  H01M2300/0025

    Abstract: The present invention relates to a non-aqueous electrolyte additive for improving safety and a lithium secondary battery comprising the same, and more particularly to a non-aqueous electrolyte additive that can improve cycle life and safety properties of a lithium ion secondary battery. According to the present invention, an organometallic compound represented by the Chemical Formula 1 is added to a non-aqueous electrolyte of a battery as an additive, and thus if a battery voltage is out of normal operation voltage range due to a short circuit and overcharge of a battery, etc., the non-aqueous electrolyte additive decomposes and a part of the decomposed additive polymerizes to form an insulating film on a cathode surface, and a part of the metal reacts with an insulating film formed on a cathode surface to improve thermal stability of the battery, thereby improving safety of the battery.

    Abstract translation: 本发明涉及一种用于提高安全性的非水电解质添加剂和包含该非水电解质添加剂的锂二次电池，更具体地说涉及一种能够改善锂离子二次电池的循环寿命和安全性能的非水电解质添加剂。 根据本发明，将由化学式1表示的有机金属化合物作为添加剂添加到电池的非水电解质中，因此如果由于短路和过充电而导致电池电压超出正常工作电压范围 的电池等，非水电解质添加剂分解，一部分分解添加剂聚合，在阴极表面形成绝缘膜，一部分金属与阴极表面形成的绝缘膜反应，从而提高 电池的热稳定性，从而提高电池的安全性。

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