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公开(公告)号：US5833936A
公开(公告)日：1998-11-10
申请号：US642000
申请日：1996-05-02
CPC分类号： B01J8/0015 , B01J8/02 , B01J8/0214 , B01J8/12 , C10G35/12 , B01J2208/00761 , B01J2208/021 , B01J2219/1925 , B01J2219/1943
摘要： A vessel, in which a chemical reaction is carried out in the presence of a catalyst, comprises a bed (4) of solid catalytic particles, delimited by at least one wall (1, 10, 11) and a base (2). The base comprises at least one gravity extraction device (3) for the particles and a succession of ridges and hollows forming pleats. The ridges and hollows are oriented towards the extraction device. This succession is advantageously formed by an assembly of facets, which are preferably trapezoidal. The invention has particular application to mobile bed reactors, in particular those used for catalytic reforming of petroleum cuts.
摘要翻译： 在催化剂存在下进行化学反应的容器包括由至少一个壁（1,10,11）和碱（2）限定的固体催化剂颗粒床（4）。 底座包括用于颗粒的至少一个重力提取装置（3）和形成褶皱的一连串脊和中空部。 脊和凹槽朝向提取装置定向。 该连续性有利地由小平面的组合形成，其优选是梯形的。 本发明特别适用于移动床反应器，特别是用于石油馏分催化重整的反应器。
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12.发明授权
公开(公告)号：US5169517A
公开(公告)日：1992-12-08
申请号：US561581
申请日：1990-08-02
申请人： Andre Buisson , Jean-Paul Euzen , Frederic Morel
发明人： Andre Buisson , Jean-Paul Euzen , Frederic Morel
摘要： Process for the treatment of a hydrocarbon fraction containing metals and comprising the following stages: (a) the said hydrocarbon fraction is treated in the presence of mean density particles (d.sub.o) under conditions for eliminating at least partly the metals contained therein and deposits of said metals on at least one fraction of said solid particles; (b) at least part of the solid particles from stage (a), whose mean density is (d.sub.i) is drawn off; (c) said solid particles from stage (b) are magnetohydrostatically separated by introducing said solid particles into a ferrofluid placed in a non-uniform magnetic field and creating a vertical magnetic field, whose intensity is adjusted in such a way that the apparent mean density (d.sub.af) of the ferrofluid permits the separation of said solid particles into at least one mean density fraction (d.sub.i) below said apparent mean density (d.sub.af) of the ferrofluid and into at least one mean density fraction (d.sub.s) above said mean apparent density (d.sub.af) of the ferrofluid and above the mean density (d.sub.1) of the solid particles drawn off in stage (b); (b) at least one fraction of said mean density solid particles (d.sub.s) is recovered; and (e) recycling takes place to stage (a) of at least one fraction of said mean density solid particles (d.sub.i). The solid particles preferably comprise particles of a catalyst and the treatment is e.g. a hydrotreatment.
摘要翻译： 用于处理含有金属的烃馏分并包括以下阶段的方法：（a）所述烃馏分在平均密度颗粒（do）的存在下处理，至少部分地除去其中所含的金属和所述 至少一部分所述固体颗粒上的金属; （b）平均密度为（di）的阶段（a）的至少一部分固体颗粒被除去; （c）来自阶段（b）的所述固体颗粒通过将所述固体颗粒引入放置在不均匀磁场中的铁磁流体中并且产生垂直磁场而磁静电分离，其强度被调节为使得表观平均密度 （daf）允许将所述固体颗粒分离成低于所述铁磁流体的表观平均密度（daf）的至少一个平均密度分数（di），并且至少一个平均密度分数（ds）高于所述平均表观密度 （daf），高于在阶段（b）中抽出的固体颗粒的平均密度（d1）; （b）回收至少一部分所述平均密度固体颗粒（ds）; 和（e）对所述平均密度固体颗粒（di）的至少一部分的阶段（a）进行再循环。 固体颗粒优选包含催化剂颗粒，并且处理是例如。 加氢处理。
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公开(公告)号：US4659455A
公开(公告)日：1987-04-21
申请号：US699376
申请日：1985-02-07
申请人： Didier Dall , Jean-Paul Euzen , Remy Patoux , Pierre Renard
发明人： Didier Dall , Jean-Paul Euzen , Remy Patoux , Pierre Renard
CPC分类号： B01J8/1872 , B01J8/003 , B01J8/085 , B01J8/12 , B01J8/44 , C10G35/12 , B01J2208/0084
摘要： The invention concerns a process for withdrawing catalyst, particularly from a moving bed.The device is characterized in that fins (4) (see FIG. 1A), shaped as corner-plates, are arranged, on a plate (6) which supports the catalyst bed radially around each vertical duct for catalyst withdrawal, so that the flow of catalyst particles converges towards the withdrawing ducts.The apparatus is useful for example in hydroconversion reactions, particularly in hydrotreatments of heavy oil cuts.
摘要翻译： 本发明涉及一种用于将催化剂，特别是从移动床抽出的方法。 该装置的特征在于，成形为角板的翅片（4）（参见图1A）布置在板（6）上，该板（6）围绕每个垂直管道径向地支撑催化剂床，用于催化剂取出，使得流动 的催化剂颗粒朝向排出管汇集。 该装置例如在加氢转化反应中是有用的，特别是在重油切割的加氢处理中。
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14.发明授权Plate reactors for chemical syntheses under high pressure in gaseous phase and with heterogeneous catalysis 失效在高压下在气相和异相催化下进行化学合成的板式反应器
公开(公告)号：US4544544A
公开(公告)日：1985-10-01
申请号：US555260
申请日：1983-11-25
IPC分类号： B01J3/04 , B01J3/00 , B01J8/00 , B01J8/02 , B01J8/06 , C01C1/04 , C07C29/15 , C07C29/152 , C07C31/04 , C01B3/12
CPC分类号： C01C1/0417 , B01J8/0005 , B01J8/0242 , B01J8/0285 , C07C29/15 , B01J2208/0015 , B01J2208/022 , Y02P20/52
摘要： The invention relates to a process and to an apparatus for effecting chemical syntheses in gaseous phase, under pressure, in the presence of a solid catalyst, for instance, for ammonia synthesis from hydrogen and nitrogen or for the synthesis of methanol or higher homolog alcohols from hydrogen and at least one carbon oxide.The reactor (8) of substantially cylindrical shape, (see FIG. 4) contains a plurality of elongate compartments (9) of parallelipiped shape, adjacent to each other, the adjacent walls of the compartments or the common walls of the adjacent compartments being gas-tight walls (1), said tight walls forming hollow plates wherein are provided channels for the flow of a fluid heat carrier flowing through said walls under a pressure substantially equal to the pressure to which are subjected the reaction gases.
摘要翻译： 本发明涉及一种在固体催化剂存在下，在压力下，在气相中进行化学合成的方法和装置，例如用于从氢和氮合成氨或用于合成甲醇或高级同系物的醇 氢和至少一种碳氧化物。 基本上圆柱形的反应器（8）（见图4）包含多个彼此相邻的平行形状的细长隔室（9），隔室的相邻壁或相邻隔室的公共壁是气体 （1），所述紧密壁形成中空板，其中提供的通道用于在基本上等于受到反应气体的压力的压力下流过所述壁的流体热载体的流动。
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公开(公告)号：US4187169A
公开(公告)日：1980-02-05
申请号：US885222
申请日：1978-03-10
摘要： Liquid and gas materials are reacted in the presence of a catalyst in a reactor of the dispersed bed type which comprises a plurality of superposed chambers through which the catalyst progressively drops, its rate of transfer from one chamber to another being controlled by injecting an auxiliary fluid into downcomers through which the catalyst is forced to pass.
摘要翻译： 液体和气体材料在催化剂存在下在分散床型反应器中反应，该反应器包括多个重叠室，催化剂通过该反应器逐渐下降，其通过注入辅助流体来控制从一个室到另一个室的转移速率 进入催化剂被迫通过的降液管。
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公开(公告)号：US5954950A
公开(公告)日：1999-09-21
申请号：US524631
申请日：1995-09-07
CPC分类号： C10G49/002
摘要： Intensive hydrofining of petroleum fractions wherein an at least partly together with hydrogen circulate in a given direction, in at least one reactor containing at least one fixed bed of a hydrofining catalyst in solid form, is characterized in that the reactor is equipped with at least one inlet pipe for the mixture of the petroleum fraction and hydrogen and at least one outlet pipe for the resultant hydrofined petroleum fraction, and that at least one static mixer is positioned upstream from said outlet of the hydrofined petroleum fraction.
摘要翻译： 石油馏分的强化加氢精制，其中至少部分与氢在给定方向循环，在至少一个含有至少一个固体床形式的加氢精制催化剂固定床的反应器中，其特征在于反应器配备有至少一种 用于石油馏分和氢气的混合物的入口管和用于所得加氢精制石油馏分的至少一个出口管，并且至少一个静态混合器位于加氢精炼馏分的出口的上游。
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17.发明授权Selective hydrogenation of hydrocarbon cuts containing monounsaturated and polyunsaturated hydrocarbons 失效含有单不饱和烃和多不饱和烃的烃馏分的选择氢化
公开(公告)号：US5817901A
公开(公告)日：1998-10-06
申请号：US524573
申请日：1995-09-07
IPC分类号： B01J8/00 , C07B61/00 , C07C5/05 , C07C7/167 , C07C9/02 , C07C9/14 , C07C9/22 , C10G45/32 , C10G45/44 , C10G70/02 , C07C5/03 , C07C5/08
摘要： A process for the selective hydrogenation of a fraction of hydrocarbons containing 2 to 20 carbon atoms and comprising monounsaturated olefinic hydrocarbons and/or aromatic compounds and at least one polyunsaturated hydrocarbon from the group formed by acetylenic compounds and dienes, in which the hydrocarbon fraction, which is at least partially in the liquid phase, circulates with hydrogen in a given direction in a reactor containing at least one fixed bed of a hydrogenation catalyst in the form of a divided solid, characterized in that said reactor is provided with at least one inlet conduit for a fluid mixture comprising said hydrocarbon fraction and hydrogen and at least one outlet conduit for the hydrogenated hydrocarbon fraction, and in that it comprises at least one static mixer upstream of said outlet for the hydrogenated hydrocarbon fraction.
摘要翻译： 一种含有2至20个碳原子的烃馏分的选择性氢化的方法，包括单不饱和烯烃和/或芳族化合物和至少一种由炔属化合物和二烯形成的基团中的多不饱和烃，其中烃馏分 至少部分地在液相中，在含有至少一种分解固体形式的氢化催化剂的固定床的反应器中，以给定方向在氢气中循环，其特征在于，所述反应器设置有至少一个入口导管 用于包含所述烃馏分和氢气的流体混合物和用于氢化烃馏分的至少一个出口导管，并且其包含在所述加氢烃馏分出口上游的至少一个静态混合器。
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公开(公告)号：US5772044A
公开(公告)日：1998-06-30
申请号：US508459
申请日：1995-07-28
CPC分类号： B07B13/003 , B07B1/06
摘要： An apparatus is provided for concentrating fine or broken particles to separate a particle stream into at least one stream which is concentrated in fine or broken particles and at least one stream with a reduced concentration of fine or broken particles. In addition to introduction and extraction structure, the apparatus includes at least two separator stages each comprising at least one funnel with an inclined or substantially vertical axis which opens upwardly, located beneath an inlet to collect the particles. The funnel is connected to at least one deflector which is directed downwardly to allow particles to flow under gravity and to form a bank of particles at the level of the funnel.
摘要翻译： 提供了一种用于浓缩精细或破碎的颗粒以将颗粒物流分离成至少一个流中的至少一个流，所述至少一个流被精细或破碎的颗粒和至少一个具有降低的细颗粒或破碎颗粒浓度的物流。 除了引入和提取结构之外，该装置还包括至少两个分离器级，每个分离器级包括至少一个漏斗，其具有向上开口的倾斜或基本上垂直的轴，位于入口下方以收集颗粒。 漏斗连接到至少一个导向器，该导流板被向下引导以允许颗粒在重力作用下流动并在漏斗的水平面上形成一束颗粒。
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19.发明授权Reactor and reaction method with internal heat control by hollow heat exchanger plates 失效中空换热板内部热控制的反应器和反应方法
公开(公告)号：US5035867A
公开(公告)日：1991-07-30
申请号：US296179
申请日：1989-01-12
申请人： Quang Dang Vu , Roland Huin , Jean-Paul Euzen
发明人： Quang Dang Vu , Roland Huin , Jean-Paul Euzen
CPC分类号： F28D9/0031 , B01J8/025 , B01J8/0285 , B01J8/0453 , B01J8/0496 , F28D9/0006 , F28F3/025 , F28F9/26 , B01J2208/0015 , B01J2208/022 , B01J2219/00085
摘要： The invention relates to an apparatus for carrying out chemical reactions in the presence of at least one catalyst, in at least one reaction zone equipped with heat exchanger plates allowing the temperature of the zone to be controlled. The apparatus mainly comprises a reactor (1), at least one central distributing manifold (6.1a), a plurality of distributing manifolds (6.2a), at least one central receiving manifold (6.5a), a plurality of receiving manifolds (6.4a), a plurality of connecting manifolds (6.6a) and a plurality of hollow, continuous, elongate plates (6.3a), each divided into two hollow half panels (6.3, 1a and 6.3, 2a). The plates are preferably substantially parallelepipedic and may contain adjacent channels having one of the following forms: square, rectangular, triangular, or sinusoidal.
摘要翻译： 本发明涉及一种用于在至少一个装有热交换器板的反应区域中，在至少一种催化剂存在下进行化学反应的装置，其允许控制该区域的温度。 该设备主要包括反应器（1），至少一个中央分配歧管（6.1a），多个分配歧管（6.2a），至少一个中央接收歧管（6.5a），多个接收歧管（6.4a） ），多个连接歧管（6.6a）和多个中空连续的细长板（6.3a），每个分成两个中空半板（6.3,1a和6.3,2a）。 板优选地基本上是平行六面体的，并且可以包含具有以下形式之一的相邻通道：正方形，矩形，三角形或正弦形。
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公开(公告)号：US4472264A
公开(公告)日：1984-09-18
申请号：US461413
申请日：1983-01-27
CPC分类号： C10G1/002 , B01J8/12 , C07C1/00 , Y10S585/943
摘要： Process for converting solid carbonaceous materials to methane, comprising (a) converting the carbonaceous material by means of a reducing gas at 300.degree.-500.degree. C. to a semi-oily phase adapted to be pumped and atomized, (b) heating falling droplets of said semi-oily phase to a temperature of 700.degree.-1600.degree. C. with hot solid particles in downward jets in the presence of reducing gas, under a presssure above 20 bars, (c) separating the solid particles of large size (d), heating them and feeding them back to step (b), (e) cooling the remaining fraction consisting of gas and solid particles of small size by means of a cold reducing gas and separating methane therefrom, and (f) treating the remaining solid phase of fine particles with oxygen and steam to produce a reducing gas fed back to steps (a) and (b).
摘要翻译： 将固体碳质材料转化成甲烷的方法，包括（a）将碳质材料通过300-500℃的还原气体转化成适于泵送和雾化的半油相，（b）加热滴液 的所述半油相在700〜1600℃的温度下，在还原气体存在下，在20巴以下的压力下，向下喷射热固体颗粒，（c）分离大尺寸固体颗粒（d ），加热它们并将其送回到步骤（b），（e）通过冷还原气体冷却由气体和小尺寸的固体颗粒组成的剩余部分并从其中分离甲烷，和（f）处理剩余的固体 用氧气和蒸汽将细颗粒的相分离，以产生反馈到步骤（a）和（b）的还原气体。
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