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1.发明授权
公开(公告)号：US5169517A
公开(公告)日：1992-12-08
申请号：US561581
申请日：1990-08-02
申请人： Andre Buisson , Jean-Paul Euzen , Frederic Morel
发明人： Andre Buisson , Jean-Paul Euzen , Frederic Morel
摘要： Process for the treatment of a hydrocarbon fraction containing metals and comprising the following stages: (a) the said hydrocarbon fraction is treated in the presence of mean density particles (d.sub.o) under conditions for eliminating at least partly the metals contained therein and deposits of said metals on at least one fraction of said solid particles; (b) at least part of the solid particles from stage (a), whose mean density is (d.sub.i) is drawn off; (c) said solid particles from stage (b) are magnetohydrostatically separated by introducing said solid particles into a ferrofluid placed in a non-uniform magnetic field and creating a vertical magnetic field, whose intensity is adjusted in such a way that the apparent mean density (d.sub.af) of the ferrofluid permits the separation of said solid particles into at least one mean density fraction (d.sub.i) below said apparent mean density (d.sub.af) of the ferrofluid and into at least one mean density fraction (d.sub.s) above said mean apparent density (d.sub.af) of the ferrofluid and above the mean density (d.sub.1) of the solid particles drawn off in stage (b); (b) at least one fraction of said mean density solid particles (d.sub.s) is recovered; and (e) recycling takes place to stage (a) of at least one fraction of said mean density solid particles (d.sub.i). The solid particles preferably comprise particles of a catalyst and the treatment is e.g. a hydrotreatment.
摘要翻译： 用于处理含有金属的烃馏分并包括以下阶段的方法：（a）所述烃馏分在平均密度颗粒（do）的存在下处理，至少部分地除去其中所含的金属和所述 至少一部分所述固体颗粒上的金属; （b）平均密度为（di）的阶段（a）的至少一部分固体颗粒被除去; （c）来自阶段（b）的所述固体颗粒通过将所述固体颗粒引入放置在不均匀磁场中的铁磁流体中并且产生垂直磁场而磁静电分离，其强度被调节为使得表观平均密度 （daf）允许将所述固体颗粒分离成低于所述铁磁流体的表观平均密度（daf）的至少一个平均密度分数（di），并且至少一个平均密度分数（ds）高于所述平均表观密度 （daf），高于在阶段（b）中抽出的固体颗粒的平均密度（d1）; （b）回收至少一部分所述平均密度固体颗粒（ds）; 和（e）对所述平均密度固体颗粒（di）的至少一部分的阶段（a）进行再循环。 固体颗粒优选包含催化剂颗粒，并且处理是例如。 加氢处理。
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公开(公告)号：US5954950A
公开(公告)日：1999-09-21
申请号：US524631
申请日：1995-09-07
CPC分类号： C10G49/002
摘要： Intensive hydrofining of petroleum fractions wherein an at least partly together with hydrogen circulate in a given direction, in at least one reactor containing at least one fixed bed of a hydrofining catalyst in solid form, is characterized in that the reactor is equipped with at least one inlet pipe for the mixture of the petroleum fraction and hydrogen and at least one outlet pipe for the resultant hydrofined petroleum fraction, and that at least one static mixer is positioned upstream from said outlet of the hydrofined petroleum fraction.
摘要翻译： 石油馏分的强化加氢精制，其中至少部分与氢在给定方向循环，在至少一个含有至少一个固体床形式的加氢精制催化剂固定床的反应器中，其特征在于反应器配备有至少一种 用于石油馏分和氢气的混合物的入口管和用于所得加氢精制石油馏分的至少一个出口管，并且至少一个静态混合器位于加氢精炼馏分的出口的上游。
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公开(公告)号：US5658539A
公开(公告)日：1997-08-19
申请号：US506038
申请日：1995-07-24
CPC分类号： B01J8/12 , C10G35/12 , B01J2219/1925 , B01J2219/1943
摘要： An enclosure in which there circulates a moving bed of solid particles (for example a moving-bed catalytic reactor such as a reforming reactor), is delimited in the enclosure by at least one grill. In the enclosure a fluid passes through the bed in a direction different from that of the flow of the assembly of the particles and issues from the bed by way of at least one grill. Disposed in the thickness of said bed in an intermediate wall (grill) such as to distribute the thrust forces produced by the fluid on the particles in the zones of the bed which are delimited in that way. Jamming of the particles against the grill or grills is greatly reduced and the admissible fluid flow rate is then decreased.
摘要翻译： 在其中循环固体颗粒的移动床（例如移动床催化反应器例如重整反应器）的外壳通过至少一个格栅限定在外壳中。 在外壳中，流体沿与颗粒组件的流动不同的方向通过床，并通过至少一个格栅从床发出。 设置在中间壁（格栅）中的所述床的厚度上，以便将由流体产生的推力分配在以这种方式界定的床的区域中的颗粒上。 颗粒对格栅或烤架的干扰大大降低，然后允许的流体流速减小。
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公开(公告)号：US5047217A
公开(公告)日：1991-09-10
申请号：US288365
申请日：1988-12-22
申请人： Quang Dang Vu , Roland Huin , Jean-Paul Euzen
发明人： Quang Dang Vu , Roland Huin , Jean-Paul Euzen
CPC分类号： F28F3/025 , B01J8/025 , B01J8/0285 , F28D9/0006 , F28D9/0031 , B01J2208/0015 , B01J2208/022 , B01J2219/00085
摘要： The invention provides an apparatus for carrying out chemical reactions, in the presence of at least one catalyst, in at least one reaction zone equipped with heat exchanger plates which make it possible to control the temperature of the zone. The apparatus mainly comprises a reactor, at least one central distributor manifold, a plurality of distributor manifolds, at least one central receiver manifold, a plurality of receiver manifolds and a plurality of continuous and elongate hollow plates, preferably substantially perpendicular. The hollow plates can contain adjacent channels having one of the following shapes: square, rectangular, triangular, sinusoidal.
摘要翻译： 本发明提供了一种用于在至少一个装有热交换器板的反应区中的至少一种催化剂的存在下进行化学反应的装置，该反应区使得可以控制该区域的温度。 该装置主要包括反应器，至少一个中央分配器歧管，多个分配器歧管，至少一个中央接收器歧管，多个接收器歧管和多个连续和细长的中空板，优选地基本上垂直。 中空板可以包含具有以下形状之一的相邻通道：正方形，矩形，三角形，正弦形。
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5.发明授权Plate reactors for chemical syntheses under high pressure in gaseous phase and with heterogeneous catalysis 失效在高压下在气相和异相催化下进行化学合成的板式反应器
公开(公告)号：US4820495A
公开(公告)日：1989-04-11
申请号：US768780
申请日：1985-08-23
IPC分类号： B01J3/04 , B01J3/00 , B01J8/00 , B01J8/02 , B01J8/06 , C01C1/04 , C07C29/15 , C07C29/152 , C07C31/04 , B01J8/04
CPC分类号： C01C1/0417 , B01J8/0005 , B01J8/0242 , B01J8/0285 , C07C29/15 , B01J2208/0015 , B01J2208/022 , Y02P20/52
摘要： The invention relates to a process and to an apparatus for effecting chemical syntheses in gaseous phase, under pressure, in the presence of a solid catalyst, for instance for ammonia synthesis from hydrogen and nitrogen or for the synthesis of methanol or higher homolog alcohols from hydrogen and at least one carbon oxide.The reactor of substantially cylindrical shape contains a plurality of elongate compartments of parallelipiped shape, adjacent to each other, the adjacent walls of the compartments or the common walls of the adjacent compartments being gas-tight walls, said tight walls forming hollow plates wherein are provided channels for the flow of a fluid heat carrier flowing through said walls under a pressure substantially equal to the pressure to which are subjected the reaction gases.
摘要翻译： 本发明涉及一种在固体催化剂存在下，在压力下，在气相中进行化学合成的方法和装置，例如用于从氢和氮合成氨或从氢气合成甲醇或更高级的同系醇 和至少一种碳氧化物。 基本上圆柱形的反应器包含多个相互邻近的平行形状的细长隔间，隔室的相邻壁或相邻隔室的公共壁是气密壁，所述紧密壁形成中空板，其中提供 用于在基本上等于受到反应气体的压力的压力下流过所述壁的流体热载体的流动通道。
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6.发明授权Process for converting liquid or semi-liquid hydrocarbon charges to lighter fractions 失效将液体或半液体碳氢化合物装料转化为较轻馏分的方法
公开(公告)号：US4738769A
公开(公告)日：1988-04-19
申请号：US478428
申请日：1983-03-24
CPC分类号： B01J8/12 , C10G2400/20
摘要： A process for converting liquid or semi-liquid hydrocarbon charges to lighter fractions comprises a first step (a) heating droplets jets of the charge introduced into a pyrolysis chamber by surrounding them with parallel jets of hot solid particles, of relatively large size, of a heat carrier material, not substantially in contact with the droplet jets, so as to maintain a temperature of 700.degree.-1600.degree. C., and introducing a gas so as to obtain a pressure from 1 to 150 bars. A second step involves (b) separating the gaseous fraction from the solid particles. Thereafter (c) at least a portion of the solid particles are heated and fed back to step (a). The gaseous fraction is (d) cooled by means of a cold gas so as to recover light hydrocarbons therefrom.
摘要翻译： 将液体或半液体碳氢化合物装料转化成轻馏分的方法包括第一步骤（a）通过用相当大尺寸的热固体颗粒的平行射流包围引入到热解室中的电荷的液滴射流， 热载体材料，基本上不与液滴射流接触，以保持700〜-1600℃的温度，并引入气体以获得1至150巴的压力。 第二步涉及（b）从固体颗粒中分离气态馏分。 此后（c）将至少一部分固体颗粒加热并反馈到步骤（a）。 气态馏分（d）通过冷气体冷却，以从其中回收轻质烃。
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7.发明授权Device for following the variations in the composition of a flowing heterogeneous liquid mixture 失效用于跟踪流动的异质液体混合物的组成变化的装置
公开(公告)号：US4210015A
公开(公告)日：1980-07-01
申请号：US970306
申请日：1978-12-18
申请人： Jean-Paul Euzen , Patrick Scemama
发明人： Jean-Paul Euzen , Patrick Scemama
CPC分类号： G01N1/2035 , G01N33/2823
摘要： The device repeatedly samples a selected amount of liquid mixture and separates at least one liquid phase from the mixture. The amount of the separated liquid phase is plotted versus the corresponding amount of the sampled mixture. At least some of the sample is recycled.
摘要翻译： 该装置重复地对选定量的液体混合物进行取样，并从混合物中分离出至少一个液相。 将分离的液相的量相对于取样的混合物的相应量作图。 至少有一些样品被回收利用。
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8.发明授权
公开(公告)号：US5869541A
公开(公告)日：1999-02-09
申请号：US815987
申请日：1997-03-10
CPC分类号： C10G2/34 , B01J8/0453 , B01J8/0492 , C07C1/06
摘要： A process for the synthesis of essentially linear saturated C.sub.5.sup.+ hydrocarbons from a gas phase comprising synthesis gas is described. The process comprises circulation of an inert liquid phase and said gas phase in a reaction zone, in which the reaction zone is provided with at least one means for introducing gas and liquid phases, and at least one means for extracting the hydrocarbon phase formed by the Fischer-Tropsch reaction, and characterized in that the reaction zone comprises at least one mixing means. Preferably, at least one mixing means is a static mixer. An apparatus for carrying out the described process is also described.
摘要翻译： 描述了从包含合成气的气相合成基本上线性的饱和C 5+烃的方法。 该方法包括在反应区中循环惰性液相和所述气相，其中反应区设置有至少一种用于引入气相和液相的装置，以及至少一种用于提取由 费 - 托反应，其特征在于反应区包含至少一个混合装置。 优选地，至少一个混合装置是静态混合器。 还描述了用于执行所描述的过程的装置。
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公开(公告)号：US5712213A
公开(公告)日：1998-01-27
申请号：US493462
申请日：1995-06-22
申请人： Jean-Fran.cedilla.ois Joly , Eric Benazzi , Christian Marcilly , Jean-Paul Euzen , Alain Forestiere
发明人： Jean-Fran.cedilla.ois Joly , Eric Benazzi , Christian Marcilly , Jean-Paul Euzen , Alain Forestiere
IPC分类号： B01J27/053 , B01J27/30 , B01J37/00 , C07B61/00 , C07C2/58 , C07C9/16 , C10G35/04 , B01J20/34 , B01J38/56
CPC分类号： C07C2/58
摘要： The invention concerns a rejuvenation process for a solid catalyst for the alkylation of at least one isoparaffin by at least one olefin. The process is characterised in that the catalyst is rejuvenated in the reaction zone by circulating an isoparaffin-rich liquid fraction over the bed, said fraction originating from a zone for separating the reaction effluent extracted from the reaction zone.
摘要翻译： 本发明涉及用于至少一种烯烃烷基化至少一种异链烷烃的固体催化剂的再生方法。 该方法的特征在于，通过在床上循环富含异构烷烃的液体馏分，催化剂在反应区中再生，所述馏分源自用于分离从反应区提取的反应流出物的区域。
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10.发明授权Process and device for withdrawing solid particles and introducing a liquid charge at the lower portion of a contact zone 失效用于取出固体颗粒并在接触区的下部引入液体电荷的方法和装置
公开(公告)号：US4392943A
公开(公告)日：1983-07-12
申请号：US373183
申请日：1982-04-29
IPC分类号： C10G11/18 , B01J4/00 , B01J8/00 , B01J8/12 , C10G35/14 , C10G49/14 , C10G49/16 , C10B31/02 , C10B31/12
摘要： In a process for the catalytic treatment of hydrocarbon charges in the presence of hydrogen in a vertical reactor where the catalyst is introduced at the top and withdrawn at the bottom, countercurrently with the charge which is introduced at the bottom and discharged from the top. There is provided a flared funnel for the catalyst discharge having small perforations for the upward flow of the charge with the perforations of a size sufficiently small to prevent passage of the catalyst therethrough. These perforations are in association with injection tubes having orifices opening in the vicinity of the funnel wall, wherethrough at least a portion of the fluid charge is injected.
摘要翻译： 在催化处理在氢气存在下的氢气的方法中，其中催化剂在顶部引入并在底部引入，垂直反应器与底部引入并从顶部排出的电荷逆流反应。 提供了一种用于催化剂放电的扩口漏斗，其具有小的穿孔，用于电荷的向上流动，其中穿孔的尺寸足够小以防止催化剂通过其中。 这些穿孔与具有在漏斗壁附近开口的孔的注入管相关联，通过其中注入至少一部分流体进料。
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