Method for preparing copolyestercarbonates and articles therefrom
    12.
    发明授权
    Method for preparing copolyestercarbonates and articles therefrom 有权
    共聚酯碳酸酯及其制品的制备方法

    公开(公告)号:US06538065B1

    公开(公告)日:2003-03-25

    申请号:US09916160

    申请日:2001-07-26

    CPC classification number: C08G63/64 Y10T428/31565

    Abstract: Block copolyestercarbonates substantially free of anhydride linkages linking at least two mers of the polymer chain may be prepared by a method which comprises the steps of: (A) preparing a hydroxy-terminated polyester intermediate in a molten reaction mixture comprising at least one 1,3-dihydroxybenzene moiety and at least one aromatic dicarboxylic acid diarylester under transesterification conditions, said polyester intermediate having a degree of polymerization of at least 4; and (B) conducting a reaction of said polyester intermediate with a carbonate precursor in a two-phase system comprising an aqueous phase and a water-immiscible organic solvent. Articles comprising the copolyestercarbonates are another aspect of the invention.

    Abstract translation: 可以通过包括以下步骤的方法制备基本上不含连接至少两个聚合物链的酸酐键的嵌段共聚酯碳酸酯:(A)在熔融反应混合物中制备羟基封​​端的聚酯中间体,其包含至少一种1,3 - 二羟基苯部分和至少一种芳族二羧酸二芳基酯,所述聚酯中间体的聚合度至少为4; 和(B)在包含水相和水不混溶的有机溶剂的两相体系中进行所述聚酯中间体与碳酸酯前体的反应。 包含共聚酯碳酸酯的制品是本发明的另一方面。

    Weatherable blends of polycarbonates with arylate polymers
    13.
    发明授权
    Weatherable blends of polycarbonates with arylate polymers 有权
    聚碳酸酯与芳基化聚合物的耐候性共混物

    公开(公告)号:US6143839A

    公开(公告)日:2000-11-07

    申请号:US152877

    申请日:1998-09-14

    CPC classification number: C08L69/00

    Abstract: Weatherability of polycarbonates, or of blends of polycarbonates with other polymers such as polyesters, is improved by incorporating therein a thermoplastic arylate polymer comprising units derived from a resorcinol or alkylresorcinol isophthalate-terephthalate. These units may be combined with units derived from a resorcinol or alkylresorcinol ester of a C.sub.4-12 aliphatic, alicyclic or mixed aliphatic-alicyclic dicarboxylic acid, such as sebacic acid.

    Abstract translation: 通过在其中加入包含衍生自间苯二酚或间苯二酚间苯二甲酸酯 - 对苯二甲酸酯的单元的热塑性芳基化合物聚合物来改善聚碳酸酯或聚碳酸酯与其它聚合物如聚酯的共混物的耐候性。 这些单元可以与衍生自C4-12脂族,脂环族或混合脂族 - 脂环族二羧酸如癸二酸的间苯二酚或烷基间苯二酚酯的单元组合。

    Process for preparing organosilanes
    18.
    发明授权
    Process for preparing organosilanes 失效
    制备有机硅烷的方法

    公开(公告)号:US5905150A

    公开(公告)日:1999-05-18

    申请号:US917968

    申请日:1997-08-27

    CPC classification number: C07F7/025 C07F7/1892

    Abstract: An improved process for preparing a nitrogen or oxygen containing organoalkoxysilane such as an isocyanurate or fumarate by reacting a haloalkylaikoxysilane such as a chloropropytrimethoxysilane and a reactant of either a cyanate or an ammonium salt of an organic acid of C1-C20 carbon atoms or a metal salt of an organic acid of C1-C20 carbon atoms or mixtures thereof to a reaction temperature of at least about 80.degree. C. to about 200.degree. C., the improvement is in carrying out the reaction in the presence of a guanidinium salt phase as a transfer catalyst such as hexaethylguanidinium chloride. The improved process also is reacted wherein the temperature increase from the exotherm reaction above the reaction temperature ranges from about 0.degree. C. to about 120.degree. C. A preferred metal cyanate is sodium cyanate.

    Abstract translation: 通过使卤代烷基烷氧基硅烷如氯丙基三甲氧基硅烷和C1-C20碳原子的有机酸的氰酸酯或铵盐的反应物或金属盐反应来制备含氮或氧的有机烷氧基硅烷如异氰脲酸酯或富马酸盐的改进方法 的C1-C20碳原子的有机酸或其混合物,反应温度为至少约80℃至约200℃,其改进在于在胍盐相存在下进行反应,为 转移催化剂如六乙基氯化胍。 改进的方法也被反应,其中在反应温度以上的放热反应的温度升高范围为约0℃至约120℃。优选的金属氰酸酯是氰酸钠。

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