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    Oligomers and polymers containing sulfinate groups and method for the production thereof
    13.
    发明授权
    Oligomers and polymers containing sulfinate groups and method for the production thereof 有权
    含有亚磺酸盐基团的低聚物和聚合物及其制备方法

    公开(公告)号：US08030414B2

    公开(公告)日：2011-10-04

    申请号：US12324320

    申请日：2008-11-26

    Applicant: Thomas Haring ,  Jochen Kerres ,  Wei Zhang

    Inventor： Thomas Haring ,  Jochen Kerres ,  Wei Zhang

    IPC: C08F8/00 ,  C08F14/00 ,  C08F114/00 ,  C08F214/00

    CPC classification number: H01M6/181 ,  C08C19/02 ,  C08F8/04 ,  C08J5/2243 ,  C08J2381/00 ,  H01M8/1023 ,  H01M8/1025 ,  H01M8/1027 ,  H01M8/103 ,  H01M8/1032 ,  H01M8/1039 ,  H01M8/1072 ,  Y02P70/56

    Abstract: The invention relates to novel polymers or oligomers containing at least sulfinate groups (P—(SO2)nX, X=1-(n=1), 2-(n=2) or 3-(n=3) valent metal cation or H+ or ammonium ion NR4+ where R=alkyl, aryl, H), which are obtained by completely or partially reducing polymers or oligomers containing at least SO2Y-groups (Y═F, Cl, Br, I, OR, NR2 (R=alkyl and/or aryl and/or H), N-imidazolyl, N-pyrazolyl) by means of suitable reducing agents in a suspension or in a solution form.Polymer and polymer(blend)membranes which are obtained by further reacting the received sulfinated polymers, especially by alkylation of the sulfinate groups with mono- di- or oligo functional electrophiles. The invention further relates to methods for producing the sulfinated polymers and for further reacting the sulfinated polymers with electrophiles by S-alkylation.

    Abstract translation: 本发明涉及至少含有亚磺酸基团（P-（SO 2）n X，X = 1-（n = 1），2-（n = 2）或3-（n = 3）价金属阳离子或 H +或铵离子NR4 +，其中R =烷基，芳基，H），其通过完全或部分还原含有至少SO 2 Y基团（Y = F，Cl，Br，I，OR，NR 2（R = 和/或芳基和/或H），N-咪唑基，N-吡唑基），通过合适的还原剂以悬浮液或溶液形式存在。 聚合物和聚合物（共混物）膜，其通过进一步使所接收的磺化聚合物反应而获得，特别是通过亚硫酸酯基团与单 - 或寡功能亲电体的烷基化。 本发明还涉及用于生产硫化聚合物的方法，以及通过S-烷基化进一步使硫化聚合物与亲电体反应。

    Polymer Membranes
    14.
    发明申请
    Polymer Membranes 有权
    聚合物膜

    公开(公告)号：US20110027691A1

    公开(公告)日：2011-02-03

    申请号：US12850530

    申请日：2010-08-04

    Applicant: Jochen Kerres

    Inventor： Jochen Kerres

    IPC: B01D71/60 ,  B01D71/06 ,  C25B13/08 ,  H01M10/24 ,  H01M8/10 ,  C08J5/20

    CPC classification number: B01D67/0093 ,  B01D67/0011 ,  B01D67/0048 ,  B01D69/141 ,  B01D71/00 ,  B01D71/52 ,  B01D71/68 ,  B01D71/80 ,  B01D71/82 ,  B01D2323/08 ,  B01D2323/12 ,  B01D2323/26 ,  C08J5/2275 ,  C08J2379/06 ,  C25B13/04 ,  H01M8/1025 ,  H01M8/1027 ,  H01M8/103 ,  H01M8/1032 ,  H01M8/1041 ,  H01M8/1048 ,  H01M8/1074 ,  H01M8/1081 ,  H01M8/1088 ,  Y02P70/56

    Abstract: The invention relates to novel organic/inorganic hybrid membranes which have the following composition: a polymer acid containing —SO3H, PO3H2, —COOH or B(OH)2 groups, a polymeric ease (optional), which contains primary, secondary or tertiary amino groups, pyridine groups, imidazole, benzimidazole, triazole, benzotriazole, pyrazole or benzopyrazole groups, either in the side chain or in the main chain; an additional polymeric base (optional) containing the aforementioned basic groups; an element or metal oxide or hydroxide, which has been obtained by hydrolysis and/or sol-gel reaction of an elementalorganic and/or metalorganic compound during the membrane forming process and/or by a re-treatment of the membrane in aqueous acidic, alkaline or neutral electrolytes. The invention also relates to methods for producing said membranes and to various uses for membranes of this type.

    Abstract translation: 本发明涉及具有以下组成的新型有机/无机杂化膜：含有-SO 3 H，PO 3 H 2，-COOH或B（OH）2基团的聚合酸，聚合物易于（任选的），其含有伯，仲或叔氨基 基团，吡啶基，咪唑，苯并咪唑，三唑，苯并三唑，吡唑或苯并吡唑基团，在侧链或主链中; 含有上述碱性基团的另外的聚合物基（任选的） 通过元素或金属氧化物或氢氧化物，其通过在成膜过程中元素有机和/或金属有机化合物的水解和/或溶胶 - 凝胶反应和/或通过在酸性，碱性水溶液中再次处理而获得 或中性电解质。 本发明还涉及生产所述膜的方法和用于这种类型的膜的各种用途。

    Production Of Monomer, Oligomer And Polymer Phosphonic Acid Esters And Phosphonic And Sulphonic Acids By A Nucleophile Aromatic Substitution
    16.
    发明申请
    Production Of Monomer, Oligomer And Polymer Phosphonic Acid Esters And Phosphonic And Sulphonic Acids By A Nucleophile Aromatic Substitution 审中-公开
    通过亲核取代芳基取代单体，低聚物和聚合物膦酸酯和膦酸和磺酸的生产

    公开(公告)号：US20090221787A1

    公开(公告)日：2009-09-03

    申请号：US11995187

    申请日：2006-07-10

    Applicant: Thomas Haring ,  Jochen Kerres ,  Martin Hein ,  Frank Schonberger

    Inventor： Thomas Haring ,  Jochen Kerres ,  Martin Hein ,  Frank Schonberger

    IPC: C08G75/00 ,  C07C315/00 ,  C07F9/02 ,  C08G73/24

    CPC classification number: B01D71/52 ,  B01D71/66 ,  B01D71/68 ,  C07C303/02 ,  C07C317/22 ,  C07F9/3834 ,  C07F9/404 ,  C08F8/36 ,  C08F8/40 ,  H01M8/1025 ,  H01M8/1027 ,  H01M8/1032 ,  H01M8/1039 ,  H01M2300/0082 ,  Y02P70/56

    Abstract: The invention relates to producing monomer, oligomer and polymer non-fluorinated, partially fluorinated or perfluorinated sulphonic acids by reacting halogenated, low-molecular weight, oligomer or macromolecular arenes with (hydrogen) sulphites, dithionites, sulphides or other reducing sulfur salts, possibly by oxidising sulphur-containing arene intermediates which are formed at a sulphur oxidation degree less than +6 by means of appropriate oxidation agents with formation of corresponding sulphonate functional groups (sulphonic acid, sulfohalogenide, sulphonamide and sulphonic acid ester groups). The invention also relates to a method for producing monomer, oligomer or polymer non-halogenated, partially halogenated or perhalogenated phosphonic acid esters and the derivatives thereof (for example, a free phosphonic acid or a phosphonic acid salt) by a nucleophile aromatic substitution (Michaelis-Becker-reaktion, complete or partial substitution of halogenide functional groups by phosphate functional groups (phosphonic acid esters, phosphonic acid amides, phosphonic acids, phosphonic acid salts, phosphonic acid halogenides). Said invention also relates to a method for producing polymer or ionomer non-halogenated, partially halogenated or perhalogenated containing (CF2)xPO(OR)2— or (CF2)xSO2Me- or (CF2)xSO3Me- side chains, (wherein x=1-20, R=any organic radical, Me=any monovalent cation). A method for carrying out a nucleophile polycondensation of said functionalised (i.e. sulphonated, sulphonated or phosphonated) monomers into oligomers or polymers is also disclosed.

    Abstract translation: 本发明涉及通过卤代，低分子量，低​​聚物或大分子芳烃与（氢）亚硫酸盐，连二亚硫酸盐，硫化物或其它还原硫盐反应制备单体，低聚物和聚合物非氟化的，部分氟化的或全氟化的磺酸，可能通过 通过形成相应的磺酸盐官能团（磺酸，磺基卤化物，磺酰胺和磺酸酯基团）的合适的氧化剂，氧化含硫芳烃中间体，它们以小于+6的硫氧化度形成。 本发明还涉及通过亲核试剂芳香取代产生单体，低聚物或聚合物非卤代，部分卤化或全卤代膦酸酯及其衍生物（例如游离膦酸或膦酸盐）的方法（Michaelis - 磷酸酯官能团（膦酸酯，膦酸酰胺，膦酸，膦酸盐，膦酸卤化物）完全或部分取代卤化物官能团的方法本发明还涉及聚合物或离聚物的制备方法 （CF 2）x SO 2 Me-或（CF 2）x SO 3 Me侧链，（其中x = 1-20，R =任何有机基团，Me =任何 还公开了将所述官能化（即磺化，磺化或膦酸化）单体进行亲核物缩聚成低聚物或聚合物的方法。

    Oligomers and polymers containing sulfinate groups and method for the production thereof
    17.
    发明申请
    Oligomers and polymers containing sulfinate groups and method for the production thereof 审中-公开
    含有亚磺酸盐基团的低聚物和聚合物及其制备方法

    公开(公告)号：US20070185305A1

    公开(公告)日：2007-08-09

    申请号：US11602481

    申请日：2006-11-20

    Applicant: Thomas Haring ,  Jochen Kerres ,  Wei Zhang

    Inventor： Thomas Haring ,  Jochen Kerres ,  Wei Zhang

    IPC: C08G75/00

    CPC classification number: H01M6/181 ,  C08C19/02 ,  C08F8/04 ,  C08J5/2243 ,  C08J2381/00 ,  H01M8/1023 ,  H01M8/1025 ,  H01M8/1027 ,  H01M8/103 ,  H01M8/1032 ,  H01M8/1039 ,  H01M8/1072 ,  Y02P70/56

    Abstract: The invention relates to novel polymers or oligomers containing at least sulfonite groups (P—(SO2)nX, X=1−(n=1), 2−(n=2) or 3−(n=3) valent metal cation or H+ or ammonium ion NR4+ where R=alkyl, aryl, H), which are obtained by completely or partially reducing polymers or oligomers containing at least SO2Y-groups (Y═F, Cl, Br, I, OR, NR2 (R=alkyl and/or aryl and/or H), N-imidazolyl, N-pyrazolyl) by means of suitable reducing agents in a suspension or in a solution form. The invention also relates to polymers and polymer(blend) membranes which are obtained by further reacting the obtained sulfinated polymers, especially by alkylation of the sulfinate groups with mono- di- or oligo functional electrophiles. The invention further relates to methods for producing the sulfinated polymers and for further reacting the sulfinated polymers with electrophiles by S-alkylation.

    Abstract translation: 本发明涉及至少含有亚磺酸基团的新型聚合物或低聚物（X-1-（n = 1），2-（ n = 2）或3-（n = 3）价金属阳离子或H +或铵离子NR 4 +，其中R =烷基， 芳基，H），其通过完全或部分还原含有至少SO 2 Y基（YF，Cl，Br，I，OR，NR 2）的聚合物或低聚物而获得 （R =烷基和/或芳基和/或H），N-咪唑基，N-吡唑基），通过合适的还原剂以悬浮液或溶液形式。 本发明还涉及聚合物和聚合物（共混物）膜，其通过进一步使得到的硫化聚合物反应而获得，特别是通过亚磺酸基团与单 - 或寡官能亲电体的烷基化。 本发明还涉及用于生产硫化聚合物的方法，以及通过S-烷基化进一步使硫化聚合物与亲电体反应。

    Ionically and covalently cross-linked polymers and polymer membranes
    19.
    发明授权
    Ionically and covalently cross-linked polymers and polymer membranes 有权
    离子和共价交联的聚合物和聚合物膜

    公开(公告)号：US06767585B2

    公开(公告)日：2004-07-27

    申请号：US10275854

    申请日：2003-05-12

    Applicant: Jochen Kerres ,  Wei Zhang ,  Chy-Ming Tang

    Inventor： Jochen Kerres ,  Wei Zhang ,  Chy-Ming Tang

    IPC: B05D302

    CPC classification number: C08F8/44

    Abstract: The present invention relates to ionically and covalently cross-linked polymers and polymer membranes having recurrent units of the general formula (1), wherein Q is a link, oxygen, sulfur, (2) or (3) and the R radical is a divalent radical of an aromatic or heteroaromatic compound, and which are characterized in that a) R radical comprises at least partially substituents of general formula (4A), (4B), (4C), (4D), (4E), (4F), (4G) and/or (4H), b) R radical comprises at least partially substituents of the general formula (5A) and/or (5B) and/or the R radical is at least partially a group of the general formula (5C) and/or (5D) and c) the R radical comprises at least partially bridges of the general formula (6) linking at least to R radicals together, R1, R2, R3, R4, R5, M, X, Y, Z and m having the herein-mentioned meanings.

    Abstract translation: 本发明涉及具有通式（1）的复发单元的离子交换和共价交联的聚合物和聚合物膜，其中Q是连接，氧，硫，（2）或（3），R基是二价 芳族或杂芳族化合物的基团，其特征在于a）R自由基至少部分包含通式（4A），（4B），（4C），（4D），（4E），（4F）， （4G）和/或（4H），b）R自由基至少部分包含通式（5A）和/或（5B）的取代基和/或R基团至少部分为通式（5C ）和/或（5D）和c）R基团包含至少部分至少连接至R基团的通式（6）的桥，R 1，R 2，R 3，R 4，R 5，M，X，Y，Z 和m具有这里所述的含义。

    Acid-base polymer blends and their use in membrane processes
    20.
    发明授权
    Acid-base polymer blends and their use in membrane processes 有权
    酸基聚合物共混物及其在膜工艺中的应用

    公开(公告)号：US06759441B1

    公开(公告)日：2004-07-06

    申请号：US09647804

    申请日：2001-02-09

    Applicant: Jochen Kerres ,  Wei Cui

    Inventor： Jochen Kerres ,  Wei Cui

    IPC: C08J520

    CPC classification number: C08J5/2256 ,  B01D71/52 ,  B01D71/66 ,  B01D71/68 ,  B01D71/80 ,  C08J2381/06 ,  H01M8/1025 ,  H01M8/1027 ,  H01M8/103 ,  H01M8/1032 ,  H01M8/1044 ,  Y02E60/523 ,  Y02P70/56

    Abstract: The present invention relates to polymer blends and polymer blend membranes which consist of a polymeric sulfonic acid and of a polymer which contains primary, secondary or tertiary amino groups, which are prepared via mixing of a salt of the polymeric sulfonic acid with the polymer which contains primary, secondary or tertiary amino groups. The invention further relates to the use of polymer blend membranes in membrane fuel cells, polymer electrolyte membrane fuel cells (PEM fuel cells) or direct methanol fuel cells (DMFC), in membrane electrolysis, in aqueous or non-aqueous electrodialysis, in diffusion dialysis, in the perstractive separation of alkenes from alkene/alkane mixtures (here the membranes are in the SO3Ag form, where the Ag+ forms a reversible complex with the alkene (→facilitated transport)), in pervaporative separation of water from water/organics mixtures, or in gas separation.

    Abstract translation: 本发明涉及聚合物共混物和聚合物共混膜，其由聚合磺酸和含有伯，仲或叔氨基的聚合物组成，所述聚合物共聚物通过将聚合磺酸的盐与含有 伯，仲或叔氨基。 本发明还涉及聚合物共混膜在膜燃料电池，聚合物电解质膜燃料电池（PEM燃料电池）或直接甲醇燃料电池（DMFC）中）在膜电解中，在水性或非水电渗析中在扩散透析中的用途 在烯烃/烷烃混合物中烯烃的分离过程中（这里的膜是SO3Ag形式，其中Ag +与烯烃形成可逆复合物（ - >促进转运）），在水中从水中蒸发分离 /有机物混合物，或气体分离。

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