公开(公告)号：US20120162573A1

公开(公告)日：2012-06-28

申请号：US13393327

申请日：2010-08-26

Applicant: Kohsei Takahashi ,  Masanori Watanabe ,  Tetsuya Hanamoto ,  Masatsugu Masuda ,  Kenji Terashima

Inventor： Kohsei Takahashi ,  Masanori Watanabe ,  Tetsuya Hanamoto ,  Masatsugu Masuda ,  Kenji Terashima

IPC: G02F1/1335 ,  G02F1/13357

CPC classification number: C04B35/597 ,  C04B2235/3224 ,  C04B2235/767 ,  C09K11/7734 ,  G02F1/133514 ,  G02F1/133603 ,  G02F1/133609 ,  G02F1/133615 ,  G02F2001/133614 ,  H01L2224/32245 ,  H01L2224/48091 ,  H01L2224/48247 ,  H01L2224/48257 ,  H01L2224/48465 ,  H01L2224/73265 ,  H01L2924/00014 ,  H01L2924/00012 ,  H01L2924/00

Abstract: A liquid crystal display including a backlight and a filter, the backlight including a light-emitting device having a light-emitting element emitting blue light, and a green phosphor and a red phosphor absorbing a part of primary light emitted from the light-emitting element and emitting first secondary light and second secondary light, respectively, the green phosphor being a β-type SiAlON phosphor containing Eu and Al dissolved in a crystal of a nitride or an oxynitride having a β-type Si3N4 crystal structure, and the filter including filters for colors of red (R), green (G), blue (B) and yellow (Y), respectively, arranged in a plane for subpixels provided in each pixel of the liquid crystal display, which attains excellent color reproducibility (NTSC ratio) and high luminance, can be provided.

Abstract translation: 一种液晶显示器，包括背光源和滤光器，所述背光源包括具有发射蓝色光的发光元件的发光装置，以及绿色荧光体和红色荧光体，其吸收从所述发光元件发射的一次光的一部分 并且分别发射第一二次光和第二二次光，所述绿色荧光体是包含Eu和Al的SiAlON荧光体，所述Eu和Al溶解在具有“Si”型Si3N4晶体结构的氮化物或氮氧化物的晶体中，并且所述滤光器 包括设置在液晶显示器的每个像素中的子像素的平面中的分别用于红色（R），绿色（G），蓝色（B）和黄色（Y））的滤色器，其具有优异的色彩再现性（NTSC 比例）和高亮度。

公开(公告)号：US20120068595A1

公开(公告)日：2012-03-22

申请号：US13303907

申请日：2011-11-23

Applicant: Tetsuya HANAMOTO ,  Masatsugu Masuda ,  Kenji Terashima

Inventor： Tetsuya HANAMOTO ,  Masatsugu Masuda ,  Kenji Terashima

IPC: H01J1/63 ,  B32B5/16 ,  C09K11/80

CPC classification number: H01L33/502 ,  C01B21/0826 ,  C01P2004/54 ,  C01P2004/61 ,  C01P2006/60 ,  C04B35/597 ,  C04B2235/3224 ,  C04B2235/5296 ,  C04B2235/5436 ,  C04B2235/767 ,  C04B2235/9646 ,  C09K11/0883 ,  C09K11/7734 ,  H01L2224/48091 ,  H01L2224/48247 ,  H01L2224/48257 ,  H01L2224/73265 ,  H01L2924/181 ,  Y10T428/2982 ,  H01L2924/00014 ,  H01L2924/00012

Abstract: Provided is a phosphor particle group of divalent europium-activated oxynitride green light emitting phosphor particles each of which is a β-type SiAlON substantially represented by a general formula: EuaSibAlcOdNe, where 0.005≦a≦0.4, b+c=12, d+e=16, wherein 60% or more of the phosphor particle group is composed of the phosphor particles in which a value obtained by dividing a longer particle diameter by a shorter particle diameter is greater than 1.0 and not greater than 3.0. A high-efficiency and stable light emitting apparatus using a β-type SiAlON, which includes a light converter using the phosphor particle group, and a phosphor particle group therefor are also provided.

Abstract translation: 本发明提供一种二价铕活化氮氧化物绿色发光荧光体颗粒的荧光体颗粒，其各自为基本上由通式：EuaSibAlcOdNe表示的“SiAlON”，其中0.005≤n1E; a＆nlE; 0.4，b + c = 12， d + e = 16，其中，荧光体粒子群的60％以上由荧光体粒子构成，其中通过将更长的粒径除以更短的粒径而获得的值大于1.0且不大于3.0。 还提供了一种使用包含使用荧光体颗粒基团的光转换器和其荧光体粒子群的“SiAlON”的高效稳定的发光装置。

公开(公告)号：US07808012B2

公开(公告)日：2010-10-05

申请号：US12171946

申请日：2008-07-11

Applicant: Masatsugu Masuda ,  Kenji Terashima

Inventor： Masatsugu Masuda ,  Kenji Terashima

IPC: H01L33/00

CPC classification number: C09K11/7734 ,  C04B35/22 ,  C04B35/581 ,  C04B35/584 ,  C04B35/597 ,  C04B2235/3203 ,  C04B2235/3206 ,  C04B2235/3208 ,  C04B2235/3224 ,  C04B2235/3225 ,  C04B2235/3229 ,  C04B2235/3852 ,  C04B2235/5436 ,  C04B2235/767 ,  C09K11/0883 ,  C09K11/7721 ,  C09K11/7774 ,  H01L33/504 ,  H01L33/508 ,  H01L2224/45144 ,  H01L2224/48091 ,  H01L2224/48247 ,  H01L2224/48257 ,  H01L2924/181 ,  H05B33/14 ,  H01L2924/00012 ,  H01L2924/00014 ,  H01L2924/00

Abstract: A group of phosphor particles for a light-emitting device contains a plurality of types of phosphor particles having different emission peak wavelengths, while phosphor particles of a type having a relatively longer emission peak wavelength have a relatively larger median diameter as compared with phosphor particles of a type having a relatively shorter emission peak wavelength.

Abstract translation: 一组用于发光装置的荧光体颗粒包含具有不同发射峰值波长的多种类型的荧光体颗粒，而具有相对较长的发射峰值波长的荧光体颗粒与具有相对较大的发射峰值波长的荧光体颗粒相比，具有相对较大的中值粒径 具有相对较短的发射峰值波长的类型。

公开(公告)号：US20100176713A1

公开(公告)日：2010-07-15

申请号：US12668074

申请日：2008-06-18

Applicant: Tetsuya Hanamoto ,  Masatsugu Masuda ,  Kenji Terashima

Inventor： Tetsuya Hanamoto ,  Masatsugu Masuda ,  Kenji Terashima

IPC: H01J1/63 ,  C09K11/79

CPC classification number: H01L33/502 ,  C01B21/0826 ,  C01P2004/54 ,  C01P2004/61 ,  C01P2006/60 ,  C04B35/597 ,  C04B2235/3224 ,  C04B2235/5296 ,  C04B2235/5436 ,  C04B2235/767 ,  C04B2235/9646 ,  C09K11/0883 ,  C09K11/7734 ,  H01L2224/48091 ,  H01L2224/48247 ,  H01L2224/48257 ,  H01L2224/73265 ,  H01L2924/181 ,  Y10T428/2982 ,  H01L2924/00014 ,  H01L2924/00012

Abstract: Provided is a phosphor particle group of divalent europium-activated oxynitride green light emitting phosphor particles each of which is a β-type SiAlON substantially represented by a general formula: EuaSibAlcOdNe, where 0.0055≦a≦0.4, b+c=12, d+e=16, wherein 60% or more of the phosphor particle group is composed of the phosphor particles in which a value obtained by dividing a longer particle diameter by a shorter particle diameter is greater than 1.0 and not greater than 3.0. A high-efficiency and stable light emitting apparatus using a β-type SiAlON, which includes a light converter using the phosphor particle group, and a phosphor particle group therefor are also provided.

Abstract translation: 提供了一种二价铕激活的氮氧化物绿色发光荧光体颗粒的荧光体颗粒基团，其各自是基本上由通式：EuaSibAlcOdNe表示的“SiAlON”，其中0.0055和nlE; a＆nlE; 0.4，b + c = 12， d + e = 16，其中，荧光体粒子群的60％以上由荧光体粒子构成，其中通过将更长的粒径除以更短的粒径而获得的值大于1.0且不大于3.0。 还提供了一种使用包含使用荧光体颗粒基团的光转换器和其荧光体粒子群的“SiAlON”的高效稳定的发光装置。

公开(公告)号：US20080258602A1

公开(公告)日：2008-10-23

申请号：US11944052

申请日：2007-11-21

Applicant: Masatsugu MASUDA ,  Kenji TERASHIMA

Inventor： Masatsugu MASUDA ,  Kenji TERASHIMA

IPC: H01J1/62 ,  C01F17/00

CPC classification number: C09K11/7728 ,  B82Y30/00 ,  C01B21/0602 ,  C01B21/0821 ,  C01B21/0826 ,  C01P2002/52 ,  C01P2004/61 ,  C01P2004/62 ,  C01P2004/64 ,  C01P2006/60 ,  C04B35/581 ,  C04B35/584 ,  C04B35/597 ,  C04B35/6262 ,  C04B35/62807 ,  C04B2235/3208 ,  C04B2235/3224 ,  C04B2235/3418 ,  C04B2235/3852 ,  C04B2235/3865 ,  C04B2235/3873 ,  C04B2235/442 ,  C04B2235/5454 ,  C04B2235/766 ,  C04B2235/767 ,  C09K11/0883 ,  C09K11/7734 ,  F21K9/64 ,  G02F1/1336 ,  H01L33/32 ,  H01L33/502 ,  H01L33/504 ,  H01L33/507 ,  H01L2224/48247 ,  H01L2224/48257 ,  H01L2224/73265

Abstract: There are provided a phosphor which is a divalent europium-activated oxynitride phosphor substantially represented by General formula (A): EuaSibAlcOdNe, a divalent europium-activated oxynitride phosphor substantially represented by General formula (B): MIfEugSihAlkOmNn or a divalent europium-activated nitride phosphor substantially represented by General formula (C): (MIIl-pEup)MIIISiN3, having a reflectance of light emission in a longer wavelength region of visible light than a peak wavelength of 95% or larger, and a method of producing such phosphor; a nitride phosphor and an oxynitride phosphor which emit light efficiently and stably by the light having a wavelength ranging from 430 to 480 nm from a semiconductor light emitting device by means of a light emitting apparatus using such phosphor, and a producing method of such phosphor; and a light emitting apparatus having stable characteristics and realizing high efficiency.

Abstract translation: 提供了一种基本上由通式（A）表示的二价铕激活的氮氧化物荧光体的荧光体：Eu A a B b Al C a 基本上由通式（B）表示的二价铕激活的氮氧化物荧光体：MI Eu <<<<<<<<<<<<<<<<<<<<<<<<<<<<<<<<< 或二价铕激活的氮化物荧光体，其基本上由下式表示： 具有在可见光的较长波长区域中发光的反射率的通式（C）：（MII）1 P 95％以上的峰值波长，以及这种荧光体的制造方法; 通过使用这种荧光体的发光装置，从半导体发光元件利用具有430〜480nm波长的光有效且稳定地发光的氮化物荧光体和氮氧化物荧光体及其制造方法; 以及具有稳定特性并实现高效率的发光装置。

公开(公告)号：US5604396A

公开(公告)日：1997-02-18

申请号：US282454

申请日：1994-07-29

Applicant: Akio Watanabe ,  Shoji Naoki ,  Masaaki Tamatani ,  Fumiyasu Yanagisawa ,  Kenji Terashima

Inventor： Akio Watanabe ,  Shoji Naoki ,  Masaaki Tamatani ,  Fumiyasu Yanagisawa ,  Kenji Terashima

IPC: C09K11/02 ,  H01J61/42 ,  H01J61/46 ,  H01J61/44

CPC classification number: C09K11/025 ,  H01J61/42 ,  H01J61/46

Abstract: A luminescent material for a mercury discharge lamp comprises a phosphor material including phosphor particles for emitting a luminous flux upon excitation by ultraviolet radiation at 254 nm and a protective layer continuously formed on the phosphor particle with at least one metal oxide selected from the group consisting of MgO, Y.sub.2 O.sub.3, La.sub.2 O.sub.3, Sm.sub.2 O.sub.3, Gd.sub.2 O.sub.3, Dy.sub.2 O.sub.3, Ho.sub.2 O.sub.3, Er.sub.2 O.sub.3, Yb.sub.2 O.sub.3, Lu.sub.2 O.sub.3, CaO, ZrO.sub.2, SrO, BaO, .alpha.-Al.sub.2 O.sub.3 and BeO. A mercury discharge lamp has a luminescent layer coated with the luminescent material on the wall of the light transmissive bulb thereof.

Abstract translation: 用于汞放电灯的发光材料包括荧光体材料，其包括用于在254nm的紫外线辐射激发时发射光束的荧光体颗粒和在荧光体颗粒上连续形成的保护层，其中至少一种金属氧化物选自 MgO，Y2O3，La2O3，Sm2O3，Gd2O3，Dy2O3，Ho2O3，Er2O3，Yb2O3，Lu2O3，CaO，ZrO2，SrO，BaO，α-Al2O3和BeO。 汞放电灯在其透光灯泡的壁上具有涂覆有发光材料的发光层。

公开(公告)号：US20090014741A1

公开(公告)日：2009-01-15

申请号：US12171946

申请日：2008-07-11

Applicant: Masatsugu MASUDA ,  Kenji Terashima

Inventor： Masatsugu MASUDA ,  Kenji Terashima

IPC: H01L33/00 ,  C09K11/79

CPC classification number: C09K11/7734 ,  C04B35/22 ,  C04B35/581 ,  C04B35/584 ,  C04B35/597 ,  C04B2235/3203 ,  C04B2235/3206 ,  C04B2235/3208 ,  C04B2235/3224 ,  C04B2235/3225 ,  C04B2235/3229 ,  C04B2235/3852 ,  C04B2235/5436 ,  C04B2235/767 ,  C09K11/0883 ,  C09K11/7721 ,  C09K11/7774 ,  H01L33/504 ,  H01L33/508 ,  H01L2224/45144 ,  H01L2224/48091 ,  H01L2224/48247 ,  H01L2224/48257 ,  H01L2924/181 ,  H05B33/14 ,  H01L2924/00012 ,  H01L2924/00014 ,  H01L2924/00

Abstract: A group of phosphor particles for a light-emitting device contains a plurality of types of phosphor particles having different emission peak wavelengths, while phosphor particles of a type having a relatively longer emission peak wavelength have a relatively larger median diameter as compared with phosphor particles of a type having a relatively shorter emission peak wavelength.

Abstract translation: 一组用于发光装置的荧光体颗粒包含具有不同发射峰值波长的多种类型的荧光体颗粒，而具有相对较长的发射峰值波长的荧光体颗粒与具有相对较大的发射峰值波长的荧光体颗粒相比，具有相对较大的中值粒径 具有相对较短的发射峰值波长的类型。

公开(公告)号：US5289081A

公开(公告)日：1994-02-22

申请号：US798727

申请日：1991-11-27

Applicant: Masaaki Tamatani ,  Hidenori Ito ,  Akira Taya ,  Yoji Yuge ,  Kazuaki Nakagawa ,  Shigeru Ando ,  Kenji Terashima

Inventor： Masaaki Tamatani ,  Hidenori Ito ,  Akira Taya ,  Yoji Yuge ,  Kazuaki Nakagawa ,  Shigeru Ando ,  Kenji Terashima

IPC: C09K11/02 ,  H01J61/44 ,  H01J61/46

CPC classification number: H01J61/46 ,  C09K11/025 ,  H01J61/44

Abstract: A fluorescent lamp characterized in that the charging tendency of a phosphor used is positioned more negative side than that of metal oxides each having a metal ion electronegativity X.sub.i of 7.0 but more positive side than that of metal oxides each having a metal ion electronegativity X.sub.i of 11.8, that particles of the phosphor are charged positive and smaller than 3.0 .mu.C per gram when they are in contact with soda lime glass beads each having a particle size of 200-500 .mu.m, or that they are charged negative and larger than -0.5 .mu.C per gram when they are in contact with reduced iron powder having a particle size of 44-74 .mu.m.

Abstract translation: 一种荧光灯，其特征在于，使用的荧光体的充电趋势比金属离子电负载率Xi为7.0但比金属离子电负载率为11.8以上的金属氧化物的正极侧更具负极侧 当荧光体的颗粒与粒径为200-500（μm）的钠钙玻璃珠接触时，荧光体的颗粒被充电并且小于3.0（my）C /克，或者它们被负电和 当它们与粒度为44-74（my）m的还原铁粉接触时，其克数大于-0.5（my）C。

公开(公告)号：US09000664B2

公开(公告)日：2015-04-07

申请号：US13263053

申请日：2010-04-02

Applicant: Tetsuya Hanamoto ,  Masatsugu Masuda ,  Kenji Terashima ,  Hideyuki Emoto ,  Hironori Nagasaki

Inventor： Tetsuya Hanamoto ,  Masatsugu Masuda ,  Kenji Terashima ,  Hideyuki Emoto ,  Hironori Nagasaki

IPC: C09K11/64 ,  C09K11/78 ,  H01L33/50 ,  C09K11/77 ,  C09K11/08 ,  H05B33/14

CPC classification number: C09K11/7734 ,  C09K11/0883 ,  H01L33/502 ,  H05B33/14

Abstract: Provided is a phosphor particle group of divalent europium-activated oxynitride green light emitting phosphor particles each of which is a β-type SiAlON represented by a general formula: EuaSibAlcOdNe, where 0.005≦a≦0.4, b+c=12, d+e=16, wherein a mean value of a value obtained by dividing a longer particle diameter by a shorter particle diameter is not greater than 1.75. Also provided are a light emitting apparatus using the phosphor particle group in a light converter, and a liquid crystal display television using the light emitting apparatus. With these, a high-efficiency and stable light emitting apparatus using a β-type SiAlON, and a phosphor particle group therefor are provided.

Abstract translation: 提供了二价铕激活的氮氧化物绿色发光荧光体颗粒的荧光体颗粒组，每个都是由通式EuaSibAlcOdNe表示的“SiAlON”，其中0.005和nlE; a＆nlE; 0.4，b + c = 12，d + e = 16，其中通过将较长粒径除以更短粒径而获得的值的平均值不大于1.75。 还提供了在光转换器中使用荧光体粒子群的发光装置和使用该发光装置的液晶显示电视机。 利用这些，提供了使用“SiAlON”型的高效稳定的发光装置及其荧光体粒子群。

公开(公告)号：US20130037846A1

公开(公告)日：2013-02-14

申请号：US13655148

申请日：2011-04-05

Applicant: Masamichi Harada ,  Toyonori Uemura ,  Hiroshi Fukunaga ,  Hitoshi Matsushita ,  Kenji Terashima

Inventor： Masamichi Harada ,  Toyonori Uemura ,  Hiroshi Fukunaga ,  Hitoshi Matsushita ,  Kenji Terashima

IPC: C09K11/79 ,  C09K11/80 ,  H01L33/50

CPC classification number: C09K11/0883 ,  C09K11/7734 ,  H01L33/502 ,  H01L2224/48091 ,  H01L2224/48247 ,  H01L2224/48257 ,  H01L2224/73265 ,  H01L2924/181 ,  H01L2924/00014 ,  H01L2924/00012

Abstract: The present invention relates to a divalent europium-activated nitride red light emitting phosphor substantially represented by a general formula: (MI1-xEux)MIISiN3 (1) (in the formula (1), MI is an alkaline-earth metal element and represents at least one element selected from the group consisting of Mg, Ca, Sr, and Ba; MII is a trivalent metal element and represents at least one element selected from the group consisting of Al, Ga, In, Sc, Y, La, Gd, and Lu; and x is the number satisfying 0.001≦x≦0.10), in which the electrical conductivity of a supernatant liquid of the solution containing 10 parts by mass of pure water with respect to 1 part by mass of the red light emitting phosphor is not more than 10 mS/cm.

Abstract translation: 本发明涉及一种基本上由通式（MI1-xEux）MIISiN3（1）表示的二价铕活化氮化物红色发光荧光体（式（1）中，MI为碱土金属元素， 选自Mg，Ca，Sr和Ba中的至少一种元素; MII是三价金属元素，并且表示选自Al，Ga，In，Sc，Y，La，Gd中的至少一种元素， 和Lu; x是满足0.001＆nlE; x＆nlE; 0.10）的数量，其中相对于1质量份的红色发光荧光体，含有10质量份纯水的溶液的上清液的电导率 不超过10 mS / cm。