摘要:
A method for producing a composite of cubic boron nitride dispersed in a SiAlON ceramic. This method involves mixing silicon nitride nanoparticles, aluminum nitride nanoparticles, silica nanoparticles, calcium oxide nanoparticles, and cubic boron nitride microparticles to produce a mixture. The cubic boron nitride may be coated with nickel. The mixture is sintered to produce the composite, and this sintering may involve spark plasma sintering and/or sintering at a relatively low temperature. The composite may comprise a mixture of Ca-α-SiAlON and β-SiAlON ceramic reinforced by boron nitride in either or both cubic and hexagonal phases.
摘要:
There are provided a phosphor which is a divalent europium-activated oxynitride phosphor substantially represented by General formula (A): EuaSibAlcOdNe, a divalent europium-activated oxynitride phosphor substantially represented by General formula (B): MIfEugSihAlkOmNn or a divalent europium-activated nitride phosphor substantially represented by General formula (C): (MII1-pEup)MIIISiN3, having a reflectance of light emission in a longer wavelength region of visible light than a peak wavelength of 95% or larger, and a method of producing such phosphor; a nitride phosphor and an oxynitride phosphor which emit light efficiently and stably by the light having a wavelength ranging from 430 to 480 nm from a semiconductor light emitting device by means of a light emitting apparatus using such phosphor, and a producing method of such phosphor; and a light emitting apparatus having stable characteristics and realizing high efficiency.
摘要:
A sintered compact contains cubic sialon, β-sialon, and at least one of a first component and a second component. The first component is at least one element selected from the group consisting of iron, cobalt, nickel, and group 4 elements, group 5 elements, and group 6 elements of the periodic table. The second component is at least one compound containing at least one element selected from the group consisting of group 4 elements, group 5 elements, and group 6 elements and at least one element selected from the group consisting of carbon, nitrogen, and boron.
摘要:
The present invention provides a technique of improving wear resistance of a Sialon sintered body. The Sialon sintered body has a Sialon phase including at least a β-Sialon and a 12H-Sialon among an α-Sialon, the β-Sialon and the 12H-Sialon. A ratio of a second Sialon total content, which is a sum of the contents of the α-Sialon and the 12H-Sialon, to a first Sialon total content, which is a sum of contents of the α-Sialon, the β-Sialon and the 12H-Sialon, is greater than 20% and not greater than 55%, and a ratio of the content of the 12H-Sialon to the first Sialon total content is not less than 2% and not greater than 55%.
摘要:
α-sialon phosphor that is α-sialon represented by a general expression: (M)x(Eu)y(Si, Al)12(O, N)16 (where M is one or more types of elements selected from a group consisting of Li, Mg, Ca, and Y as well as lanthanide element (except for La and Ce) and including at least Ca), the α-sialon phosphor being structured so that an oxygen content is 1.2 mass % or less and primary particles constituting the α-sialon have a columnar shape. When the α-sialon phosphor receives ultraviolet rays or visible light having a wavelength from 250 to 500 nm as an excitation source, the α-sialon phosphor shows a fluorescent characteristic having a peak in a wavelength region from 595 to 630 nm.
摘要:
According to the invention, a highly crystalline α-sialon is synthesized to emit highly intense light and a white LED showing an excellent color rendering characteristic is provided by shifting emitted light to the short wavelength side (blue shift). Such an α-sialon is designed so as to be expressed by general formula (Lix, Cay, Euz) (Si12−(m+n)Alm+n) (OnN16−n) wherein the numerical ranges of x, y, z, m and n are respectively 0
摘要:
An α-sialon is offered which is represented by general formula: (M1)X(M2)Y(Si, Al)12(O, N)16 (wherein M1 represents one or more elements selected from the group which consists of Li, Mg, Ca, Y and lanthanoid (except La and Ce) and M2 represents one or more elements selected from the group which consists of Ce, Pr, Eu, Tb, Yb and Er and wherein 0.3
摘要:
A fluorophor comprising, as a main component, an α-type sialon crystal which contains at least an A element (wherein A represents one or more elements selected from among Mn, Ce, Pr, Nd, Sm, Eu, Tb, Dy, Er, Tm and Yb), an M element (wherein M represents one or more elements selected from among Li, Na, Mg, Ca, Y, La, Gd and Lu), Si, Al, oxygen and nitrogen, and is represented by the general formula: (Mx, Ay)(Si12−(m+n)Alm+n)(OnN16−n) (1) m=δM×x+δA×y (2) 0.2≦x≦2.4 (3) 0.001≦y≦0.4 (4) and 0.5×m
摘要:
A SiAlON phosphor represented by a general formula (1) Lup(Si, Al)12(O, N)16:Euq (1) wherein at least a main phase has an alpha SiAlON crystal structure; and 0.25≦p≦0.65.
摘要:
An insert includes a silicon nitride sintered body including β-Si3N4 as a main component, Mg, and a rare-earth element Re (Y, La, Ce, Er, Dy, Yb). A content of Mg in terms of MgO is 1.0-7.0 mol %, a content of Re in terms of an oxide thereof is 0.4-1.0 mol %, and a total content of Mg and Re is from 1.7 to less than 7.5 mol %. The insert has a graded composition in which oxygen content increases from a surface of the sintered body toward an inside thereof such that 0.8-1.5 mass % of oxygen is contained in a region of less than 0.5 mm inside from the surface, 1.1-2.3 mass % of oxygen is contained in a region of 0.5 mm or more inside from the surface, and a difference in oxygen content between the regions is 0.1-1.0 mass %.
摘要翻译:插入物包括以主要成分为主成分的Si 3 N 4作为主要成分的氮化硅烧结体,以及稀土元素Re(Y,La,Ce,Er,Dy,Yb)。 以MgO计的Mg含量为1.0〜7.0摩尔%,其氧化物的Re含量为0.4〜1.0摩尔%,Mg和Re的总含量为1.7〜小于7.5摩尔%。 插入物具有从烧结体的表面朝向内部氧含量增加的梯度组成,使得在表面内侧小于0.5mm的区域中含有0.8-1.5质量%的氧,1.1-2.3质量% 表面含有0.5%以上的氧含量,区域之间的氧含量差为0.1〜1.0质量%。