Cyclic compounds and the use thereof as light absorbers, light emitters, or complex ligands
    11.
    发明申请
    Cyclic compounds and the use thereof as light absorbers, light emitters, or complex ligands 审中-公开
    环化合物及其作为光吸收剂,光发射体或复合配体的用途

    公开(公告)号:US20050167637A1

    公开(公告)日:2005-08-04

    申请号:US10509944

    申请日:2003-04-04

    Abstract: The use of cyclic compounds of the formula (I) where n is a number in the range from 1 to 7, X-Y-Z, in each case independently of one another, is O—C═N, N═C—O, NR5—C═N, N═C—NR5, N+R52—C═N, N═C—N+R52, O—C═N+R5, N+R5═C—O, S—C═N+R5, N+R5═C—S, S—C═N, N═C—S, R1, R2 and R3 each independently are, for example, H or a substituent or corresponding heterocyclic compounds in which at least one group —CR1═, —CR2═, CR3═ is replaced by —N, R5 in each case independently are, for example, H or a substituent R7, in each case independently of one another, are H, C1-12-alkyl or C6-12-aryl, or metal complexes of the cyclic compounds or complexes of the cyclic compounds with mineral acids, chloride, sulfate, bisulfate, phosphate, hydrogen phosphate, nitrate, BF4− or methanesulfonate being present as opposite ions X− in the case of cationic cyclic structures, as light absorbers, materials for hole injection layers in OLEDs, light-emitting compounds in OLED, phase-transfer catalysts or synergistic agents for the dispersing of pigments or for optical data storage, is described.

    Abstract translation: 使用式(I)的环状化合物,其中n为1至7的数,XYZ在每种情况下彼此独立地为OCN,NCO,NR 5 -CN ,NC-NR 5,N + 5,...,5,...,...,N N + > 5 5 2,...,... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... > 5-CO,SCN +,...,5,...,...,...,... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ,NCS,R 1,R 2和R 3各自独立地为例如H或取代基或相应的杂环化合物,其中在 至少一个基团-CR 1, - CR 2 - , - CR 3 - 被-N,R 5, 在每种情况下,各自独立地是H或取代基R 7,在每种情况下彼此独立地为H,C 1-12 - 烷基或 C 6-12芳基或环状化合物的金属络合物或环状化合物与无机酸,氯化物,硫酸盐,硫酸氢盐,磷酸盐的络合物 在阳离子环状结构的情况下,作为阳离子环状结构存在,作为相反离子存在的磷酸根,硝酸根,BF 4 - 或 - 甲磺酸盐作为光 吸收剂,OLED中的空穴注入层的材料,OLED中的发光化合物,相转移催化剂或用于颜料分散或光学数据存储的协同剂。

    Multiple chromophores based on rylene
    13.
    发明授权
    Multiple chromophores based on rylene 有权
    基于二烯的多发色团

    公开(公告)号:US08501948B2

    公开(公告)日:2013-08-06

    申请号:US11996074

    申请日:2006-07-27

    Inventor: Martin Konemann

    Abstract: A rylene-based polychromophore of the general formula I in which the variables are each defined as follows: rylene is a radical of the formula which has been functionalized by at least one imide group, ester group or amide group and which may additionally be substituted by aryloxy, arylthio, hetaryloxy and/or hetarylthio; X is a rylenedicarboximide radical which absorbs at a different wavelength from the rylene radical, is bonded to the X radical in the peri-position via Y via a moiety —Y′-A-Y—, is bonded to the rylene radical and may likewise be substituted by aryloxy, arylthio, hetaryloxy and/or hetarylthio; A is a bridging member having at least one aromatic or heteroaromatic radical, the Y or Y and Y′ groups being bonded to the aromatic or heteroaromatic radical; Y is a moiety Y′ is a moiety where the moieties (i) and (ii) may be part of the ester groups of the rylene radical and the moieties (iii) are part of the imide groups of the rylene radical and the moieties (iv) are part of the amide groups of the rylene radical; R1 is hydrogen or C1-C18-alkyl, where the R1 radicals may be the same or different when they occur repeatedly; n is 1, 2 or 3; x is from 1 to 7.

    Abstract translation: 通式I的亚芳基多色荧光团,其中各变量各自定义如下:亚芳基是已经被至少一个酰亚胺基,酯基或酰胺基官能化并且可以另外被 芳氧基,芳硫基,杂芳氧基和/或杂芳硫基; X是在不同波长下从二芳基吸收的二甲酰亚胺基自由基通过Y经由Y-A'-AY-的键合在X位上的X基团键合到二芳基并且同样可以被取代 芳氧基,芳硫基,杂芳氧基和/或杂芳硫基; A是具有至少一个芳族或杂芳族基团的桥连构件,Y或Y和Y'基团键合到芳族或杂芳族基团; Y是部分Y'是其中部分(i)和(ii)可以是亚芳基的酯基的一部分的部分,并且部分(iii)是亚芳基的酰亚胺基团和部分( iv)是亚芳基的酰胺基团的一部分; R 1是氢或C 1 -C 18 - 烷基,其中当它们重复发生时,R 1基团可以相同或不同; n为1,2或3; x为1至7。

    VERFAHREN ZUR HERSTELLUNG VON MIT RYLENTETRACARBONSAEUREDIIMIDEN BESCHICHTETEN SUBSTRATEN

    公开(公告)号:US20090078312A1

    公开(公告)日:2009-03-26

    申请号:US12212199

    申请日:2008-09-17

    CPC classification number: C07D471/04

    Abstract: The present invention relates to a process for producing a substrate coated with rylenetetracarboximides, in which a substrate is treated with an N,N′-bisubstituted rylenetetracarboximide and the treated substrate is heated to a temperature at which the N,N′-bisubstituted rylenetetracarboximide is converted to the corresponding N,N′-unsubstituted compound. The present invention further relates to semiconductor units, organic solar cells, excitonic solar cells and organic light-emitting diodes which comprise a substrate produced by this process. The present invention further relates to a process for preparing N,N′-unsubstituted rylenetetracarboximides, in which the corresponding N,N′-bisubstituted rylenetetracarboximides are provided and heated to a temperature at which these compounds are converted to the corresponding N,N′-unsubstituted compounds.

    Abstract translation: 本发明涉及一种制备涂覆有四环四甲酰亚胺的基材的方法,其中用N,N'-二取代的三环四溴二酰亚胺处理基材,将处理过的基材加热至N,N'-二取代的四环四溴二酰亚胺 转化为相应的N,N'-未取代的化合物。 本发明还涉及半导体单元,有机太阳能电池,激子太阳能电池和有机发光二极管,其包括通过该方法制造的基板。 本发明进一步涉及制备N,N'-未取代的四环四甲酰亚胺的方法,其中提供相应的N,N'-二取代的四环四甲酰亚胺,加热至这些化合物转化为相应的N, 未取代的化合物。

    Terrylene and Quaterrylene Derivatives

    公开(公告)号:US20080255357A1

    公开(公告)日:2008-10-16

    申请号:US11913333

    申请日:2006-05-03

    Abstract: Rylene derivatives of the general formula I in which the variables are each defined as follows: X are joined to one another with formation of a six-membered ring to give a radical of the formula (a), (b) or (c) are both a —COOM radical; are both hydrogen or one of the two radicals is hydrogen and the other radical is halogen or a radical of the formula (d) Y are joined to one another with formation of a six-membered ring to give a radical of the formula (a) when one of the two X radicals is hydrogen and the other X radical is halogen or a radical of the formula (d) or when both X radicals are hydrogen or together are a radical of the formula (a), (b) or (c); are joined to one another with formation of a six-membered ring to give a radical of the formula (b) when one of the two X radicals is hydrogen and the other X radical is halogen or a radical of the formula (d) or when both X radicals are hydrogen or a —COOM radical or together are a radical of the formula (c); are joined to one another with formation of a six-membered ring to give a radical of the formula (c) when one of the two X radicals is hydrogen and the other X radical is halogen or a radical of the formula (d) or when both X radicals are hydrogen or a —COOM radical or together are a radical of the formula (c) which may be arranged in the cis or trans position to the other (c) radical; are both a —COOM radical when one of the two X radicals is hydrogen and the other X radical is halogen or a radical of the formula (d) or when both X radicals are hydrogen or a —COOM radical, M being different from hydrogen in the case that one X radical is a radical of the formula (d); are both hydrogen or one of the two radicals is hydrogen and the other radical is halogen or a radical of the formula (d) when both X radicals are hydrogen or one of the two X radicals is hydrogen and the other X radical is halogen or a radical of the formula (d); R are identical or different radicals: substituted or unsubstituted aryloxy, arylthio, hetaryloxy or hetarylthio; R′ is hydrogen; substituted or unsubstituted alkyl, cycloalkyl, aryl or hetaryl; A are each independently substituted or unsubstituted phenylene, naphthylene or pyridylene; M is hydrogen, ammonium or alkali metal cation; R″ are each independently hydrogen, alkyl, cycloalkyl, aryl or hetaryl, or are joined together with formation of a 5- to 7-membered, fused or unfused and substituted or unsubstituted ring comprising the two oxygen atoms and also the boron atom; R1 is hydrogen or alkyl, where the R1 radicals may be the same or different when they occur more than once; R2, R3 are each independently hydrogen; substituted or unsubstituted alkyl, aryl or hetaryl; m is 1 or 2; n is from 3 to 6 where m=1; is from 2 to 8 where m=2, and mixtures thereof.

    Substituted Rylene Derivatives
    17.
    发明申请
    Substituted Rylene Derivatives 有权
    取代的Rylene衍生物

    公开(公告)号:US20080167467A1

    公开(公告)日:2008-07-10

    申请号:US11994719

    申请日:2006-07-06

    CPC classification number: C07D493/06 C07D471/06 C08K5/0041 C08K5/3437

    Abstract: Rylene derivatives of the general formula I in which the variables are each defined as follows: Rylene is a polycyclic conjugated ring system which comprises at least one perylene unit may comprise heteroatoms as ring atoms, may be functionalized by moieties comprising —CO— groups and/or may bear further substituents other than the A radicals; A is a radical of the formula X is oxygen or sulfur; R are identical or different radicals: optionally substituted alkyl, cycloalkyl, aryl, hetaryl, —U-aryl where U is an —O—, —S—, —NR2—, —CO—, —SO— or —SO2— moiety, or C1-C12-alkoxy, C1-C6-alkylthio, —C≡CR2, —CR2═CR22, hydroxy, mercapto, halogen, cyano, nitro, —NR3R4, —NR3COR4, —CONR3R4, —SO2NR3R4, —COOR3 or —SO3R3; R′ are identical or different radicals: hydrogen or one of the R radicals; R2 is hydrogen or alkyl, where the R2 radicals may be the same or different when they occur more than once; R3, R4 are each independently hydrogen; optionally substituted alkyl, aryl or hetaryl; n is from 1 to 8.

    Abstract translation: 通式I的亚芳基衍生物各自定义如下:Rylene是多环共轭环系,其包含至少一个苝单元可以包含杂原子作为环原子,可以由包含-CO-基团和/ 或者可以承担除了A基团之外的其它取代基; A是式X的基团是氧或硫; R是相同或不同的基团:任选取代的烷基,环烷基,芳基,杂芳基,-U-芳基,其中U是-O - , - S - , - NR 2 - , - CO-, - SO - 或-SO 2 - 部分,或C 1 -C 12 - 烷氧基,C 1 -C -C≡CR2,-CR 2 -CR 2,2 - , - 羟基,巯基,卤素,氰基,硝基,-NR 3,R 4,-NR 3,COR 4, SO 2,SO 2,SO 2,SO 2,SO 3,SO 4,SO 2, >,-COOR 3或-SO 3 R 3; R'是相同或不同的基团:氢或R基团之一; R 2是氢或烷基,其中R 2个基团当它们不止一次出现时可以相同或不同; R 3,R 4各自独立地为氢; 任选取代的烷基,芳基或杂芳基; n为1至8。

    Method For Producing Perylene-3,4-Dicarboxylic Acid Imides
    18.
    发明申请
    Method For Producing Perylene-3,4-Dicarboxylic Acid Imides 有权
    生产苝-3,4-二羧酸酰亚胺的方法

    公开(公告)号:US20080114170A1

    公开(公告)日:2008-05-15

    申请号:US11718893

    申请日:2005-11-04

    CPC classification number: C07D221/18

    Abstract: A process for preparing perylene-3,4-dicarboximides which bear a sterically demanding substituent on the imide nitrogen atom by reacting a perylene-3,4:9,10-tetracarboxylic dianhydride with a sterically hindered primary amine in a substantially anhydrous reaction medium, which comprises undertaking the reaction in the presence of a tertiary amine, of a solvent based on a cyclic imine or amide and of a Lewis acid as a catalyst.

    Abstract translation: 通过在基本无水的反应介质中使苝-3,4:9,10-四羧酸二酐与空间位阻伯胺反应,制备在酰亚胺氮原子上具有空间要求取代基的苝-3,4-二甲酰亚胺的方法, 其包括在叔胺存在下进行基于环状亚胺或酰胺的溶剂和路易斯酸作为催化剂的反应。

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