摘要:
Morphologically stable BCF yarns, and the methods and systems for making such BCF yarns are provided. More specifically, the BCF yarn is melt-spun, drawn and textured. The yarn texturizing includes a relatively low efficiency fluid jet texturizer, that is a fluid jet texturizer operating at a sufficiently low fluid jet velocity and a sufficiently high fluid jet temperature to obtain a yarn skein shrinkage of less than about 0.50 inch, more preferably about 0.25 inch or less. Most preferably, the BCF yarns are formed of nylon-6 and exhibit an alpha-crystalline content of less than about 45%, and usually between about 45% to about 55%.
摘要:
An inherently light- and heat-stabilized polyamide has at least one piperidine compound bonded to the backbone polymer chain and at least one 4-amino-2,2,6,6-tetramethylpiperidine compound bonded to the backbone polymer chain. The inherently light- and heat-stabilized polyamide may be used to form articles such as, for example, fibers, carpets, yarns, and textile fabrics.
摘要:
A spin pack for spinning synthetic fibers from two or more liquid polymer streams includes a supply for at least two polymer streams to the spin pack; a spinneret having extrusion orifices; and flow distribution plate sets. The flow distribution plate sets include at least one patterned plate having edges which define a substantially regular two-dimensional geometric shape, a substantially planar upstream surface, a substantially planar downstream surface and at least one flow distribution pattern stenciled therein by cutting through. For each patterned plate, at least one boundary plate stacked sealingly adjacent thereto and having edges which define a substantially regular geometric shape, a substantially planar upstream surface and a substantially planar downstream surface. The boundary plate has cut-through holes connecting the upstream surface with the downstream surface to form at least one flow-through channel to allow fluid flow through the patterned plate but otherwise is substantially solid.
摘要:
A spin pack for spinning synthetic fibers from two or more liquid polymer streams includes a supply for at least two discrete polymer streams without mixing with another discrete stream to the spin pack; a spinneret having extrusion orifices; and flow distribution plate sets. The flow distribution plate sets include at least one patterned plate having edges which define a substantially regular two-dimensional geometric shape, a substantially planar upstream surface, a substantially planar downstream surface and at least one flow distribution pattern stenciled therein by cutting through. For each patterned plate, at least one boundary plate stacked sealingly adjacent thereto and having edges which define a substantially regular geometric shape, a substantially planar upstream surface and a substantially planar downstream surface. The boundary plate has cut-through holes connecting the upstream surface with the downstream surface to form at least one flow-through channel to allow fluid flow through the patterned plate but otherwise is substantially solid.
摘要:
The end group content of polyamide in the solid state may be reduced by treating the polyamide with gas-phase acid, anhydride, or amine. Stain- or dye-resistant polyamide fibers can be made by reducing the number of amino end groups. Reduction in the number of carboxylic end groups reduces the rate of regeneration of starting monomers during extrusion.
摘要:
Bicomponent fibers of different cross-sections may be formed without changing the geometry of the spinneret orifices. More specifically, at least two polymers are co-melt-spun through an orifice of fixed geometry so as to achieve a bicomponent fiber having a desired cross-section. In order to change to a bicomponent fiber having a cross-section which is different, therefore, at least one of (1) the differential relative viscosity, (2) the relative proportions of the first and/or second polymers, and (3) the cross-sectional bicomponent distribution of the first and second polymers, is changed. In such a manner, therefore, a wide variety of bicomponent fibers having different cross-sectional geometries may be produced without changing the fixed geometry orifice through which the polymers are co-melt-spun. Thus, bicomponent fiber cross-sections may be "engineered" to suit a variety of needs without necessarily shutting down production equipment in order to change spinnerets. The bicomponent fibers are most preferably multilobal (e.g., trilobal) in which the core component is generally triangularly shaped.
摘要:
Novel bicomponent fibers have a polyamide domain and a contaminant-containing polymer domain which is embedded entirely within, and thereby completely surrounded by, the polyamide domain. The preferred bicomponent fibers have a sheath-core structure wherein the polyamide domain constitutes the sheath and the contaminant-containing polymer constitutes the core. Surprisingly, even though the core is formed of a contaminant-containing polymer (which is difficultly spinnable), the bicomponent fibers are readily spinnable and exhibit properties which are comparable in many respects to fibers formed from 100% polyamide. Preferably, the fibers are concentric sheath-core bicomponent fibers having an uncontaminated nylon-6 sheath and a core formed from nylon-6 having a relatively high level of contamination in the form of the cyclic dimer of caprolactam and/or nylon-6 derived from colored regenerated post-consumer nylon carpet fibers.
摘要:
Synthetic polymers are melt-mixed and spun from a mixture of respective first and second polymer melt flows. Specifically, the mixture of first and second polymer melt flows are mixed at a fluidic mixing device having a mixing intersection which receives the first and second polymer melt flows and discharges the mixture thereof respectively into at least one or another of multiple discharge ports fluid-connected with a respective spinning nozzle. The mixed flow of first and second polymer melt flows is controlled by diverting the first polymer melt so that it (i) entirely flows along a first flow path to responsively merge with the second polymer melt flow at the mixing intersection of the mixing device and thereby cause the mixed polymer flow to be discharged through the one discharge port, or (ii) entirely flow along a second flow path to responsively merge with the second polymer melt at the mixing intersection of the mixing device and thereby cause the mixed polymer flow to be discharged through the other discharge port. The mixed polymer flow thereby diverted is thus spun by one or another of the spinning nozzles, respectively.
摘要:
A process for manufacturing substantially 100% nylon 6 carpet provides a nylon 6 face yarn to a nylon 6 support means so that the yarn and the support means form a carpet having a face side which is displayed when the carpet is installed and a back that binds the face yarn to the support means wherein said binding is with molten or dissolved nylon 6.
摘要:
Fabric useful for processing into a fiber reinforced composite is made from multicomponent yarn having a thermoplastic matrix component of a first melting point if crystalline or a first softening point if not crystalline and a drawable, oriented, fibrous thermoplastic reinforcing component of a second melting point if crystalline or a second softening point if not crystalline, wherein said first melting or softening point is at least 5.degree. C. below said second melting or softening point.