公开(公告)号：US20120219482A1

公开(公告)日：2012-08-30

申请号：US13277419

申请日：2011-10-20

申请人： PETER ULRICH KOSS ,  STEPHEN A. BEDELL

发明人： PETER ULRICH KOSS ,  STEPHEN A. BEDELL

IPC分类号： B01D53/40 ,  B01D53/96 ,  B01D53/62

CPC分类号： C10L3/103 ,  B01D53/1406 ,  B01D53/1425 ,  B01D53/1456 ,  B01D53/1475 ,  B01D53/1487 ,  B01D2251/10 ,  B01D2251/506 ,  B01D2251/508 ,  B01D2252/103 ,  B01D2252/204 ,  B01D2256/24 ,  B01D2257/304 ,  B01D2257/306 ,  B01D2257/308 ,  B01D2257/40 ,  B01D2257/406 ,  B01D2257/504 ,  B01D2257/704 ,  B01D2257/708 ,  B01D2258/0283 ,  C10L3/104

摘要： Systems and process for volatile degradation removal from amine plant wash water are provided. The systems and processes include a separation device disposed within a water circulation loop and configured to continuously remove at least a portion of the volatile degradation products from the wash solutions. The separation device can be configured for stripping, distillation, and/or extraction of the volatile degradation products from at least a fraction of the spent wash water. Optionally, a chemical agent can be reacted with the volatile degradation products to form heat stable salts for subsequent removal.

摘要翻译： 提供了从胺植物洗涤水中去除挥发性降解的系统和方法。 该系统和方法包括设置在水循环回路内的分离装置，其被配置成从洗涤溶液中连续地除去至少一部分挥发性降解产物。 分离装置可以被配置用于从至少一部分废洗涤水中汽提，蒸馏和/或提取挥发性降解产物。 任选地，化学试剂可以与挥发性降解产物反应以形成热稳定的盐以便随后除去。

公开(公告)号：US20100012553A1

公开(公告)日：2010-01-21

申请号：US12448439

申请日：2007-12-21

申请人： John M. Griffin ,  Stephen A. Bedell ,  Clare M. Worley

发明人： John M. Griffin ,  Stephen A. Bedell ,  Clare M. Worley

IPC分类号： C10G29/04 ,  C09K3/00

CPC分类号： C09B47/065 ,  C10G29/06 ,  C10G2300/1096 ,  C10G2300/805 ,  C10G2300/807

摘要： The present invention relates to making tetra-sulfo iron-phthalocyanine by reacting sulfonated reactant(s) in the presence a boron-containing promoter. The present invention also relates to making tetra-sulfo iron phthalocyanine more tolerant to oxygen by combining the tetra-sulfo iron-phthalocyanine with a stabilizing amount of a complexing agent (e.g., a stabilizing amine) and/or contacting the tetra-sulfo iron-phthalocyanine with steam.

摘要翻译： 本发明涉及在含硼促进剂存在下使磺化反应物反应制备四磺基铁酞菁。 本发明还涉及通过将四磺基铁酞菁与稳定量的络合剂（例如稳定胺）组合和/或使四磺基铁 - 酞菁与络合剂接触，制备更耐氧的四磺基铁酞菁， 酞菁与蒸汽。

公开(公告)号：US5433934A

公开(公告)日：1995-07-18

申请号：US179882

申请日：1994-01-11

申请人： Dane Chang ,  Stephen A. Bedell ,  Larry H. Kirby

发明人： Dane Chang ,  Stephen A. Bedell ,  Larry H. Kirby

IPC分类号： B01D53/60 ,  B01D53/74 ,  B01D53/50 ,  B01D53/56

CPC分类号： B01D53/60

摘要： The simultaneous abatement of NO and SO.sub.2 in flue gas is provided by an absorption process and apparatus utilizing an absorbent composition comprising an aqueous solution of chelates and sulfite salt for NO abatement and amine SO.sub.2 absorbents such as piperazinones, morpholinones, piperidines, piperazines, piperazinediones, hydantoins, triazinones, pyrimidinones, oxazolidones, etc. for SO.sub.2 abatement. SO.sub.2 is thermally stripped from the spent absorbent and recovered. Metal chelates oxidized to an inactive state as a side-reaction are electrochemically reduced. An anionic exchange membrane in the electrochemical cell regenerates heat stable amine salt byproducts to be converted back to useable amine sorbent, and facilitates removal from the absorbent solution of other waste salts.

摘要翻译： 废气中NO和SO2的同时减少是通过吸收方法和装置来提供的，所述吸收方法和装置使用包含螯合物水溶液和亚硫酸盐用于NO消除的吸收剂组合物，以及胺SO 2吸收剂如哌嗪酮，吗啉酮，哌啶，哌嗪，哌嗪类， 乙内酰脲，三嗪酮，嘧啶酮，恶唑烷酮等，用于SO2消除。 SO2从废吸收剂中热剥离并回收。 氧化成非活性状态的金属螯合物作为副反应被电化学还原。 电化学电池中的阴离子交换膜再生热稳定的胺盐副产物以转化回可用的胺吸附剂，并且有助于从其它废盐的吸收剂溶液中除去。

公开(公告)号：US5096691A

公开(公告)日：1992-03-17

申请号：US295311

申请日：1989-01-09

申请人： Stephen A. Bedell

发明人： Stephen A. Bedell

IPC分类号： B01D53/52 ,  C01B17/05 ,  C10K1/10

CPC分类号： C10K1/10 ,  B01D53/52 ,  C01B17/05

摘要： H.sub.2 S abatement in geothermal drilling operations (e.g. drilling, flow testing and reworking) with a ferric aminocarboxylic acid chelating solution containing a stabilizer and an optional cationic polyelectrolyte catalyst which is injected in the blooie line of the well upstream of the separator. The stabilizer is a hydroxyl radical scavenger such as iodide, nitrite, amino acid, aliphatic aldehyde, sugar, ascorbate, formate and/or aryl sulfonic acid, and inhibits degradation the ferric aminocarboxylic acid complex.

摘要翻译： 使用含有稳定剂和任选的阳离子聚电解质催化剂的三价氨基羧酸螯合溶液来减少地热钻井操作（例如钻井，流动测试和重新加工）中的H2S，其被注入到分离器上游井的布线中。 稳定剂是羟基自由基清除剂，例如碘化物，亚硝酸盐，氨基酸，脂族醛，糖，抗坏血酸盐，甲酸盐和/或芳基磺酸，并且抑制三元羧酸复合物的降解。

公开(公告)号：US4960575A

公开(公告)日：1990-10-02

申请号：US359533

申请日：1989-06-01

申请人： Stephen A. Bedell ,  Larry H. Kirby

发明人： Stephen A. Bedell ,  Larry H. Kirby

IPC分类号： B01D53/52 ,  B01D53/14 ,  B01D53/77 ,  C01B17/50 ,  C01B17/62 ,  C01B17/64 ,  E21B43/34 ,  F03G7/04

CPC分类号： E21B43/34 ,  B01D53/52 ,  F03G7/04 ,  Y02C10/06 ,  Y02E10/10 ,  Y10S423/19

摘要： Geothermal steam is condensed with a sulfite solution to abate hydrogen sulfide. A portion of the hydrogen sulfide is converted in the condensation in the presence of soluble cationic polymeric catalysts to soluble sulfur compounds while avoiding elemental sulfur and carbonate formation. The remainder of the hydrogen sulfide is incinerated and the sulfur dioxide in the incinerator effluent is absorbed in an alkaline solution to form the sulfites for the geothermal steam condensation. By maintaining stoichiometric ratios, the hydrogen sulfide is substantially converted to soluble thiosulfate without the use of chelates, peroxides or makeup sulfites.

摘要翻译： 地热蒸汽与亚硫酸盐溶液冷凝以消除硫化氢。 一部分硫化氢在可溶性阳离子聚合物催化剂存在下转化为可溶性硫化合物，同时避免元素硫和碳酸盐形成。 将其余的硫化氢焚烧，焚化炉流出物中的二氧化硫被吸收在碱性溶液中，形成用于地热蒸汽冷凝的亚硫酸盐。 通过保持化学计量比，硫化氢基本上转化为可溶性硫代硫酸盐，而不使用螯合物，过氧化物或亚硫酸盐化妆品。

公开(公告)号：US4891205A

公开(公告)日：1990-01-02

申请号：US831969

申请日：1986-02-24

申请人： Stephen A. Bedell

发明人： Stephen A. Bedell

IPC分类号： B01D53/14 ,  B01D53/52 ,  B01D53/77 ,  C01B17/05 ,  C10K1/10

CPC分类号： C10K1/10 ,  B01D53/52 ,  C01B17/05

摘要： Soluble chemical compounds having a high affinity for hydroxyl radicals are effective stabilizers for chelating agents used in the hydrogen sulfide removal process. The stabilizers include aromatic compounds, bromide ions, iodide ions, cyanides, nitrites, amino acids, sugars, ascorbates, alcohols, polyols, aliphatic aldehydes, compounds having unsaturated carbon-carbon bonds, dimethyl sulfoxide, organic disulfides, alkyl amines, and formates. The aromatic compounds have the additional benefit of combining with hydroxyl radicals to form chelating agents.

摘要翻译： 对羟基自由基具有高亲和力的可溶性化合物是用于硫化氢去除方法中的螯合剂的有效稳定剂。 稳定剂包括芳族化合物，溴离子，碘离子，氰化物，亚硝酸盐，氨基酸，糖，抗坏血酸盐，醇，多元醇，脂族醛，具有不饱和碳 - 碳键的化合物，二甲基亚砜，有机二硫化物，烷基胺和甲酸盐。 芳族化合物具有与羟基自由基结合形成螯合剂的另外的益处。

公开(公告)号：US4623707A

公开(公告)日：1986-11-18

申请号：US807428

申请日：1985-12-10

申请人： Stephen A. Bedell ,  William M. Coleman, III ,  William R. Howell, Jr.

发明人： Stephen A. Bedell ,  William M. Coleman, III ,  William R. Howell, Jr.

IPC分类号： C08F10/00 ,  C08F4/02

CPC分类号： C08F10/00 ,  Y10S526/904

摘要： .alpha.-Olefins are polymerized in the presence of Ziegler-Natta catalysts which are polymer supported compounds or complexes of elements of the d-block transition metals, lanthanide or actinide series. An example of the polymer support is chloromethylated polystyrene-divinyl benzene copolymer covalently bonded to catechol. An example of the compound or complex of an element of the transition metal, lanthanide or actinide series is that which results when catechol which is covalently bonded to the polymer is contacted with titanium tetraisopropoxide.

摘要翻译： α-烯烃在齐格勒 - 纳塔催化剂存在下聚合，齐格勒 - 纳塔催化剂是聚合物负载的化合物或d-嵌段过渡金属，镧系元素或锕系元素的元素的络合物。 聚合物载体的实例是共价键合到儿茶酚上的氯甲基化聚苯乙烯 - 二乙烯基苯共聚物。 过渡金属，镧系元素或锕系元素的元素的化合物或络合物的实例是当与聚合物共价键合的儿茶酚与四异丙醇钛接触时产生的。

公开(公告)号：USH2287H1

公开(公告)日：2013-12-03

申请号：US13106227

申请日：2011-05-12

申请人： Frederic Vitse ,  Stephen A. Bedell

发明人： Frederic Vitse ,  Stephen A. Bedell

IPC分类号： C23F11/14

摘要： A structural low carbon steel in combination with and in contact with an aqueous MDEA solvent that includes as an amine-based chemical additive. When mixed with MDEA solvent to form a MDEA solution, the MDEA-based solution in contact with carbon steel reduces the corrosion rate of low carbon structural carbon steels having a carbon content greater than about 0.18% by weight is significantly reduced when the concentrations of CO2, O2 and heat stable salts (HSS) are controlled below critical amounts. The MDEA solution, when controlling the concentrations of CO2, O2 and HSS below critical amounts, suppresses the corrosion of carbon steel having a carbon content greater than about 0.18%. A smooth surface finish further suppresses the corrosion of the low carbon structural steel. When the CO2, O2 and HSS are maintained below critical values, a low carbon structural steel having a micropolished surface finish displayed improved corrosion resistance.

公开(公告)号：US20120251421A1

公开(公告)日：2012-10-04

申请号：US13354568

申请日：2012-01-20

申请人： STEPHEN A. BEDELL

发明人： STEPHEN A. BEDELL

IPC分类号： B01D53/62

CPC分类号： B01D53/62 ,  B01D53/1475 ,  B01D53/1493 ,  B01D2252/2041 ,  B01D2252/20415 ,  B01D2252/20426 ,  B01D2252/20431 ,  B01D2252/20447 ,  B01D2252/20489 ,  B01D2257/504 ,  B01D2258/0283 ,  Y02A50/2342 ,  Y02C10/04 ,  Y02C10/06

摘要： Acid gas purification processes for reducing nitrosamine precursor formation from a gas stream containing NOx, wherein the acid gas is selectively absorbed in an amine based wash solution comprising at least one secondary diamine. The processes generally include absorbing carbon dioxide from the gas stream containing NOx species with the amine-based wash solution comprising at least one secondary diamine to provide a carbon dioxide lean gas stream that is released into the surroundings, wherein absorbing the acid gas forms a rich amine solution; and regenerating the rich amine solution at an elevated temperature to release the carbon dioxide to form a regenerated lean amine solution, wherein absorbing and regenerating are configured to promote formation of carbamate species of at least one diamine.

摘要翻译： 用于从含有NO x的气流中还原亚硝胺前体形成的酸性气体净化方法，其中所述酸性气体被选择性地吸收到包含至少一种仲胺的基于胺的洗涤溶液中。 这些方法通常包括从含有NO x物质的气流中吸收二氧化碳，其中胺基洗涤溶液包含至少一种仲二胺以提供释放到周围环境中的贫二氧化贫气流，其中吸收酸性气体形成富 胺溶液; 以及在升高的温度下再生所述富胺溶液以释放所述二氧化碳以形成再生的贫胺溶液，其中吸收和再生被配置为促进形成至少一种二胺的氨基甲酸酯物质。

公开(公告)号：US5167941A

公开(公告)日：1992-12-01

申请号：US623313

申请日：1990-12-06

申请人： Stephen A. Bedell

发明人： Stephen A. Bedell

IPC分类号： B01D53/50

CPC分类号： B01D53/502

摘要： Inhibitors of oxidation of sulfites to sulfates in sulfur dioxide scrubbing solutions are disclosed. The inhibitors are cationic polyelectrolytes which are water soluble, have a molecular weight of at least 10,000 daltons and contain quaternary amine groups. The polyelectrolytes are preferably present at 1-3000 ppm in alkali solutions with which a sulfur dioxide containing gas stream is contacted. The scrubbing solutions contain amines such as piperazinones, morpholinones, piperidines, piperazines, piperazinediones, hydantoins, triazinones, pyrimidinones, oxazolidones, N-carboxymethyl ethylenediamines, etc.

摘要翻译： 公开了在二氧化硫洗涤溶液中将亚硫酸盐氧化成硫酸盐的抑制剂。 抑制剂是水溶性阳离子聚电解质，分子量至少为10,000道尔顿并含有季胺基。 聚电解质优选以1-3000ppm存在于与二氧化硫气流接触的碱溶液中。 洗涤溶液含有胺类，如哌嗪酮，吗啉酮，哌啶，哌嗪，哌嗪类，乙内酰脲，三嗪酮，嘧啶酮，恶唑烷酮，N-羧甲基乙二胺等。