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    Process for making pen/pet blends and transparent articles therefrom
    11.
    发明授权
    Process for making pen/pet blends and transparent articles therefrom 失效
    制造笔/宠物混合物和透明制品的方法

    公开(公告)号：US06194536B1

    公开(公告)日：2001-02-27

    申请号：US09308787

    申请日：1999-07-23

    申请人： Steven L. Schmidt ,  Brian Lynch ,  Amit S. Agrawal

    发明人： Steven L. Schmidt ,  Brian Lynch ,  Amit S. Agrawal

    IPC分类号： C08G6302

    CPC分类号： C08G63/80 ,  B29B2911/1402 ,  B29B2911/14026 ,  B29B2911/14033 ,  B29B2911/1404 ,  B29B2911/1406 ,  B29B2911/14066 ,  B29B2911/1408 ,  B29B2911/14086 ,  B29B2911/14093 ,  B29B2911/14106 ,  B29B2911/14113 ,  B29B2911/14126 ,  B29B2911/14133 ,  B29B2911/1414 ,  B29B2911/14153 ,  B29K2067/00 ,  B29K2995/0025 ,  B29K2995/004 ,  C08L67/02 ,  Y10S264/917 ,  C08L2666/18

    摘要： The present invention relates to a process for controlling the change of intrinsic viscosity and transesterification during solid stating of a polyethylene terephthalate (PET) and polyethylene naphthalate (PEN) blend, with an effective amount of an alkylene glycol compound. The process enables the production of a copolymer based on predefined initial and final IV's and final transesterification level, by varying the solid-stating time and/or effective amount of alkylene glycol. In one embodiment, a relatively greater amount of post-consumer PET (e.g., 70%) having an IV of on the order of 0.72-0.73, is incorporated in the blend to provide a final IV on the order of 0.80-0.85, and a moderate, controlled level of transesterification; the blend is used to injection mold a sleeve layer of a preform. In another embodiment, a substantially transparent neck finish for a preform is made from a PEN/PET blend having an amount of alkylene glycol which enables substantial transesterification, without excessive increase in IV.

    摘要翻译： 本发明涉及一种用于控制聚对苯二甲酸乙二醇酯（PET）和聚萘二甲酸乙二醇酯（PEN）共混物固化时的特性粘度和酯交换的变化与有效量的亚烷基二醇化合物的方法。 该方法通过改变固化时间和/或有效量的亚烷基二醇，可以基于预定义的初始和最终IV和最终酯交换水平生产共聚物。 在一个实施方案中，将具有大约0.72-0.73的IV的相对较大量的消费后PET（例如，70％）掺入共混物中以提供大约0.80-0.85的最终IV，以及 中等，受控的酯交换水平; 该混合物用于注射成型预成型件的套筒层。 在另一个实施方案中，用于预成型件的基本上透明的颈部精加工由具有一定量的亚烷基二醇的PEN / PET共混物制成，其能够进行显着的酯交换，而不会过度增加IV。

    Method of forming two material three/five layer preform
    13.
    发明授权
    Method of forming two material three/five layer preform 失效
    形成两种材料三层/五层预成型件的方法

    公开(公告)号：US5032341A

    公开(公告)日：1991-07-16

    申请号：US436651

    申请日：1989-11-15

    申请人： Suppayan M. Krishnakumar ,  Thomas E. Nahill ,  Steven L. Schmidt ,  Wayne N. Collette

    发明人： Suppayan M. Krishnakumar ,  Thomas E. Nahill ,  Steven L. Schmidt ,  Wayne N. Collette

    IPC分类号： B29C45/16 ,  B29C49/22

    CPC分类号： B29C49/221 ,  B29C45/1643 ,  B29B2911/14053 ,  B29B2911/1406 ,  B29B2911/14066 ,  B29B2911/1408 ,  B29B2911/14093 ,  B29B2911/1412 ,  B29B2911/14126 ,  B29B2911/14153 ,  B29K2995/0067

    摘要： A plastic preform from which a plastic container is blow molded. The preform replaces a three layer preform by providing a preform which is of a five layer construction in the base forming portion thereof and wherein a secondary material which forms the core layer of the three layer preform construction is divided into an inner intermediate layer and an outer intermediate layer by a third injection of material. The third injected material is preferably the same material as the primary material which is first injected. This results in the reduction of the cost of the preform and also provides remaining in the injection nozzle a quantity of the last injected material which is the same as the first injected material for the following preform in the same preform injection mold cavity.

    摘要翻译： 一个塑料预成型件，一个塑料容器被吹塑成型。 预成型体通过在其基部形成部分中提供五层结构的预成型体来代替三层预制件，并且其中形成三层预成型结构的芯层的二次材料被分成内部中间层和外层 中间层通过第三次注射材料。 第三注入材料优选与首先注入的材料相同。 这导致预成型件的成本降低，并且在相同的预成型件注射模具腔中，在注射喷嘴中剩余的最后一次注射材料的数量与用于下一个预成型件的第一注射材料相同。

    ENHANCED OXYGEN-SCAVENGING POLYMERS, AND PACKAGING MADE THEREFROM
    16.
    发明申请
    ENHANCED OXYGEN-SCAVENGING POLYMERS, AND PACKAGING MADE THEREFROM 有权
    增强型氧气聚合物及其包装

    公开(公告)号：US20080153939A1

    公开(公告)日：2008-06-26

    申请号：US12022319

    申请日：2008-01-30

    申请人： Steven L. Schmidt ,  Brian Lynch ,  Keith Barker ,  Ronald Adams ,  Amit S. Agrawal

    发明人： Steven L. Schmidt ,  Brian Lynch ,  Keith Barker ,  Ronald Adams ,  Amit S. Agrawal

    IPC分类号： A23B7/00

    CPC分类号： B32B27/18 ,  A23L3/3436 ,  B32B27/08 ,  B32B27/32 ,  B32B27/34 ,  B32B27/36 ,  B32B33/00 ,  B32B2307/518 ,  B32B2439/70 ,  C08K3/08 ,  C08K5/098 ,  C08K2003/0843 ,  C08K2201/012 ,  Y10T428/1338 ,  Y10T428/1352 ,  Y10T428/1355 ,  Y10T428/1359 ,  Y10T428/1379 ,  C08L77/00

    摘要： Oxygen-scavenging polymers and packaging for holding oxygen-sensitive products. A heat treatment process has been found to significantly increase the oxygen-scavenging performance of the polymer. The enhanced scavenging polymer can be effectively incorporated into various packaging, including transparent multilayer containers for beer and juice. In one embodiment, a multilayer package made from the scavenger provides an actual reduction in oxygen content of a contents of the package, over a long period of time (e.g., 24 weeks). The package can be stored unfilled for an extended period (without significant loss of scavenging capability) and will scavenge substantially immediately upon filling with a liquid product. The package may incorporate a relatively low weight percentage of the scavenger, thus providing enhanced scavenging in a cost-effective manner.

    摘要翻译： 含氧清除聚合物和用于保存氧敏感产品的包装。 已经发现热处理工艺显着地提高了聚合物的清除氧气的性能。 增强的清除聚合物可以有效地结合到各种包装中，包括用于啤酒和果汁的透明多层容器。 在一个实施方案中，由清除剂制成的多层包装在长时间（例如24周）内提供包装内容物的氧含量的实际降低。 包装可以长时间储存​​（不会显着损失清除能力），并且在填充液体产品时将基本上立即清除。 包装可以包含相对较低重量百分比的清除剂，从而以成本有效的方式提供增强的清除。

    Process for making pen/pet blends and transparent articles therefrom
    17.
    发明授权
    Process for making pen/pet blends and transparent articles therefrom 失效
    制造笔/宠物混合物和透明制品的方法

    公开(公告)号：US06395865B2

    公开(公告)日：2002-05-28

    申请号：US09791361

    申请日：2001-02-23

    申请人： Steven L. Schmidt ,  Brian Lynch ,  Amit S. Agrawal

    发明人： Steven L. Schmidt ,  Brian Lynch ,  Amit S. Agrawal

    IPC分类号： C08G6302

    CPC分类号： C08G63/80 ,  C08L67/02 ,  C08L2666/18

    摘要： Process for controlling the change of intrinsic viscosity and transesterification during solid stating of a polyethylene terephthalate (PET) and polyethylene naphthalate (PEN) blend, with an effective amount of an ethylene glycol compound. The process enables the production of a copolymer based on predefined initial and final IV's and final transesterification level, by varying the solid-stating time and/or effective amount of ethylene glycol. In one embodiment, a relatively greater amount of post-consumer PET (e.g., 70%) having an IV of on the order of 0.72-0.73, is incorporated in the blend to provide a final IV on the order of 0.80-0.85, and a moderate, controlled level of transesterification; the blend is used to injection mold a sleeve layer of a preform. In another embodiment, a substantially transparent neck finish for a preform is made from a PEN/PET blend having an amount of ethylene glycol which enables substantial transesterification, without excessive increase in IV.

    摘要翻译： 用于控制聚对苯二甲酸乙二醇酯（PET）和聚萘二甲酸乙二醇酯（PEN）共混物固化期间的特性粘度和酯交换的变化与有效量的乙二醇化合物的方法。 该方法可以通过改变固体时间和/或有效量的乙二醇来制备基于预定义的初始和最终IV和最终酯交换水平的共聚物。 在一个实施方案中，将具有大约0.72-0.73的IV的相对较大量的消费后PET（例如，70％）掺入共混物中以提供大约0.80-0.85的最终IV，以及 中等，受控的酯交换水平; 该混合物用于注射成型预成型件的套筒层。 在另一个实施方案中，用于预成型件的基本上透明的颈部精加工由具有一定量的乙二醇的PEN / PET共混物制成，其能够进行实质的酯交换，而不会过多地增加IV。

    Transparent package with aliphatic polyketone oxygen scavenger
    18.
    发明授权
    Transparent package with aliphatic polyketone oxygen scavenger 失效
    透明包装与脂肪族聚酮氧清除剂

    公开(公告)号：US5952066A

    公开(公告)日：1999-09-14

    申请号：US958849

    申请日：1997-10-28

    申请人： Steven L. Schmidt ,  Wayne N. Collette ,  Ernest A. Coleman ,  Suppayan M. Krishnakumar

    发明人： Steven L. Schmidt ,  Wayne N. Collette ,  Ernest A. Coleman ,  Suppayan M. Krishnakumar

    IPC分类号： B32B27/28 ,  B65D1/02 ,  B65D81/26 ,  C08L67/02 ,  C08L101/00 ,  B65B55/19

    CPC分类号： C08L67/02 ,  B32B27/28 ,  B65D1/0215 ,  B65D81/266 ,  B65D81/267 ,  C08L101/00 ,  B29K2995/004 ,  Y10T428/1355 ,  Y10T428/1359 ,  Y10T428/1383 ,  Y10T428/31797

    摘要： A substantially transparent package or preform made of a polymer composition including an aliphatic polyketone as an oxygen scavenger having the formula ##STR1## where n is the number of repeating units and R is hydrogen, an organic side chain, or a silicon side chain. The aliphatic polyketone may be advantageously combined with other thermoplastic polymers to provide the desired injection molding and stretch blow molding characteristics for making substantially amorphous injection molded preforms and substantially transparent biaxially oriented polyester containers. A multilayer container package may be provided having a core layer of the oxygen scavenging composition, and inner and outer layers of polyethylene terephthalate (PET). The container may further include layers of a high-oxygen barrier polymer such as ethylene vinyl alcohol (EVOH). When filled with a liquid product including water, the water vapor from the product may permeate the inner and core layers to facilitate removal and consumption of entrapped oxygen by the core scavenging layer. The aliphatic polyketone provides a highly reactive oxygen scavenger which is made from low-cost monomers and which remains colorless during processing.

    摘要翻译： 由聚合物组合物构成的基本上透明的包装或预成型体，其包含具有下式的脂族聚酮作为除氧剂，其中n是重复单元的数目，R是氢，有机侧链或硅侧链。 脂族聚酮可以有利地与其它热塑性聚合物组合，以提供所需的注射成型和拉伸吹塑成型特性，用于制造基本上无定形的注射成型的预成型件和基本上透明的双轴取向的聚酯容器。 可以提供具有氧清除组合物的芯层和聚对苯二甲酸乙二醇酯（PET）的内层和外层的多层容器包装。 容器还可以包括高氧阻隔聚合物如乙烯乙烯醇（EVOH）的层。 当填充包括水的液体产物时，来自产品的水蒸气可以渗透内层和核层，以便于通过芯清除层去除和消耗夹带的氧。 脂肪族聚酮提供高活性氧清除剂，其由低成本单体制成，并且在加工过程中保持无色。