摘要:
A vapor-grown-carbon-fiber-containing dispersion containing vapor grown carbon fiber having a fiber diameter of and an aspect ration of 5 to 15,000, a resin soluble in an organic solvent, and an organic solvent having an ET value of 45 or less, which value is a solvent parameter calculated from the absorption spectrum of pyridinium-N-phenol betaine, wherein (1) lumps of the carbon fiber are partially disintegrated to thereby allow individual filaments of the carbon fiber to be present as dispersed or (2) the carbon fiber is present such that carbon fiber lumps having a diameter of 40 μm or less and separated individual carbon fiber filaments are intermingled; a production method of the dispersion; vapor-grown-carbon-fiber-containing resin composite material obtained by the method; and electroconductive material and thermal conductive material using the resin composite material. The present invention enables to prepare a resin solution wherein vapor grown carbon fiber is uniformly dispersed and to easily obtain electroconductive material and thermal conductive material from the dispersed solution.
摘要:
A toughened thermoplastic polymer composition comprising (a) 1-30 weight percent of a polar toughening agent compatibilized with a polyphenol, and (b) 70-99 weight percent of at least one thermoplastic polymer, the above state percentages being based on the total weight of components (a) and (b) only.
摘要:
A fine carbon fiber having linearity, each fiber filament of the carbon fiber having a bending angle of 30° or less with respect to the longitudinal direction of the fiber filament, and including a hollow space extending along its axis, and having an outer diameter of 1 to 1,000 nm, an aspect ratio of 5 to 1,000, and a BET specific surface area of 2 to 2,000 m2/g, wherein the average interlayer distance (d002) of the carbon fiber at a (002) plane is 0.345 nm or less as measured by means of X-ray diffractometry, and the ratio of the peak height (Id) of the band at 1,341 to 1,349 cm−1 in a Raman scattering spectrum of the carbon fiber to that of the peak height (Ig) of the band at 1,570 to 1,578 cm−1 in the spectrum (Id/Ig) is 0.1 to 2. The fiber exhibits excellent dispersibility in a matrix.
摘要:
The present invention relates to a thermoplastic resin crystallization promoter comprising fine carbon fiber consisting of fiber filaments having a diameter of 0.001 μm to 5 μm and an aspect ratio of 5 to 15,000, a thermoplastic resin composition consisting of the fine carbon fiber and thermoplastic resin and comprising crystallized resin, and a production method thereof. The crystallization promoter comprising the fine carbon fiber of the present invention enables to crystallize even an amorphous resin, which has an irregular molecular structure and therefore is not crystallized, or which exhibits low crystallization degree and therefore is difficult to crystallize by means of a conventional crystallization promoter. The crystallization promoter provides a thermoplastic resin composition, which, when molded, exhibits improved strength and tribological characteristics and is further reinforced when mixed with a filler.
摘要:
There is provided a production method for a resin film according to which an application liquid raw material (polyaniline solution) does not gelate over a long period of time and a resin film can be stably produced. A production method for a resin film according to an embodiment of the present invention includes the step of heating and kneading a polyaniline in an emeraldine base state and a protonic acid to prepare a conductive resin composition.
摘要:
A thermally conductive film (10) includes a matrix (12) made of a resin and flaky filler particles (14) dispersed in the matrix (12). The flaky filler particles (14) each has a flaky filler body (16) made of boron nitride and a γ-ferrite coating (18) on the filler body (16), and are oriented in a through-thickness direction of the thermally conductive film (10). The resin is, for example, polyimide.
摘要:
The present invention relates to a method for producing a resin composition having a crystallized and orderly arranged structure. The method comprises kneading an amorphous thermoplastic resin with a resin crystallization promoter to form a mixture, wherein the resin crystallization promoter comprises vapor grown carbon fibers, each fiber filament of the carbon fibers having a diameter of 0.001 μm to 5 μm and an aspect ratio of 5 to 15,000, the fibers having undergone a graphitization at 1,500° C. or higher, and subsequently subjecting the mixture to annealing at a temperature of from 55° C. higher than the glass transition point of the resin to a temperature 75° C. higher than the glass transition point of the resin. The crystallization promoter and annealing provide a thermoplastic resin composition, which, when molded, exhibits improved strength and tribological characteristics.
摘要:
A porous material comprising vapor grown carbon fiber in an amount of 10 to 90 mass %, fiber filaments of the carbon fiber forming a three-dimensional network and having a diameter of 1 to 1,000 nm, an aspect ratio of 5 to 15,000, a specific surface area (by BET method) of 2 to 2,000 m2/g, and the ratio of the intensity of the peak at 1,360 cm−1 in a Raman scattering spectrum of the carbon fiber to that of the peak at 1,580 cm−1 in the spectrum(I1360/I1580) is 0.1 to 2.0, wherein the porosity of the porous material (V/V0) is 0.50 to 0.99 and a specific surface area is 5 to 1,000 m2/g; and a production method and use thereof. The vapor grow carbon fiber impregnated in the porous material of the present invention does not contain aggregates and a three-dimensional network is formed between the fiber filaments, wherein length of each of the fiber filaments is maintained. Therefore, the vapor grown carbon fiber enables to readily produce a composite material (porous material), in which even a small amount of addition of vapor grown carbon fiber can exhibit sufficient effect.