摘要:
The present invention relates to an aqueous powder clearcoat dispersion comprising a solid pulverulent component A and an aqueous component B, where component A is a transparent powder coating material comprising a) at least one epoxy binder containing from 25 to 45% by weight, preferably from 25 to 35% by weight, of glycidyl-containing monomers, with or without a fraction of vinylaromatic compounds, preferably styrene, b) at least one crosslinking agent, preferably straight-chain, aliphatic dicarboxylic acids and/or carboxy-functional polyesters, and c) if desired, catalysts, auxiliaries, additives typical for transparent powder coating materials, such as devolatilizers, leveling agents, UV absorbers, free-radical scavengers, and antioxidants, and component B is an aqueous dispersion comprising a) at least one nonionic thickener and b) if desired, catalysts, auxiliaries, defoamers, wetting agents, antioxidants, UV absorbers, free-radical scavengers, biocides, small amounts of solvent, leveling agents, neutralizing agents, preferably amines, and/or water retention agents, and c) a dispersant medium in the form of a nonionic polyurethane dispersion.
摘要:
The present invention relates to a coating formulation for use in multicoat paint systems, which a) comprises as binder a water-dilutable polyurethane resin which has an acid number of from 10 to 60 and a number-average molecular weight of from 4000 to 25,000 and can be prepared by reacting with one another aa) a polyester—and/or polyether-polyol having a number-average molecular weight of from 400 to 5000 or a mixture of such polyester—and/or polyether-polyols, bb) a polyisocyanate or mixture of polyisocyanates, cc) a compound which has in the molecule at least one group which in reactive toward isocyanate groups and at least one group which is capable of forming anions, or a mixture of such compounds, and optionally dd) a hydroxyl—and/or amino-containing organic compound having a molecular weight of from 40 to 400, or a mixture of such compounds and at least partially neutralizing the resulting reaction product, and b) comprises pigments and/or fillers, the ratio of binder to pigment being between 0.5:1 and 1.5:1.
摘要:
The invention relates to a process for coating vehicle bodies in which an aqueous coating containing as the binder a combination of a water-dilutable polyurethane resin, a water-dilutable polyester resin and an aminoplast resin is employed as the stone-chip intermediate primer and/or filler.
摘要:
The invention relates to a process for the production of multicoat finishes, in which(1) an aqueous pigmented basecoat containing a waterthinnable polyurethane resin is applied to the substrate surface as basecoat,(2) a polymer film is formed from the coating applied in stage (1),(3) a transparent topcoat is applied to the basecoat obtained in this way and subsequently(4) the basecoat is baked together with the topcoat, and the water-thinnable polyurethane resin contains structural units of the formula ##STR1## X representing a divalent aromatic hydrocarbon radical and R.sup.1 and R.sup.2 representing an alkyl radical having 1 to 4 carbon atoms.
摘要:
Disclosed are pigmented coating compositions comprising at least one inorganic particle (N) having a primary particle size of 1 to 800 nm, at least one binder (B), at least one color and/or effect pigment (D), and one or more organic solvents (E), and at least one wax or one waxlike compound (W), wherein the inorganic particles (N) are at least partly modified with a stabilizer (S) which has groups (S1) which are able to interact with the surface of the inorganic particles (N), and one or more hydrophobic substructures. Also disclosed are processes for producing multicoat paint systems and also to the use thereof and also processes for enhancing the flop of multicoat paint systems by using the pigmented coating compositions.
摘要:
The present disclosure provides multicoat systems exhibiting ultraviolet (UV) stability after ultraviolet exposure and moisture exposure. The systems comprise at least one primer (G), at least one pigmented coating (P) disposed on a surface of the primer, and at least one ultraviolet (UV) absorber which has an absorption maximum of at least 370 nm. The pigmented coating (P) may be comprised of two or more coatings (P1), (P2) to (Pn). The multicoat systems may also comprise a transparent coating material (T) to form a transparent coating (K). The present multicoat systems demonstrate ultraviolet stability, reduced delamination of the pigmented coat from the primer and are available in a variety of shades for use in the finishing, refinishing and coating of component parts.The present disclosure also provides for a process for producing the multicoat system, and provides for the use of the system.
摘要:
A process for improving the intercoat adhesion in a multicoat paint system utilizing a primer coat, an aqueous basecoat, and a clearcoat, where the multicoat paint system has been produced by means of a wet-on-wet technique. The clearcoat is produced using a pseudoplastic powder clearcoat slurry prepared by a secondary dispersion process or a melt emulsification process. The aqueous basecoat material used to produce the aqueous basecoat comprises a dispersed graft copolymer whose particles are composed of a hydrophobic core of copolymerized olefinically unsaturated monomers and of a hydrophilic shell which comprises a polyurethane, wher said copolymer is prepared by free-radical (co)polymerization of the monomers in the presence of at least one polyurethane containing specially selected olefinically unsaturated groups.
摘要:
A hydrophilic or hydrophobic polyurethane having at least one olefinically unsaturated group selected from the group consisting of pendant olefinically unsaturated groups, terminal olefinically unsaturated groups, and mixtures thereo wherein the pendant olefinically unsaturated groups are sele consisting of pendant olefinically unsaturated groups which are attached to a cycloaliphatic group which represents a link in the polymer main chain and pendant olefinically unsaturated groups which are present as a double bond in a cycloolefinic group which constitutes a link in the polymer main chain, and the terminal olefinically unsaturated groups are selected from the group consisting of terminal olefinically unsaturated groups which are attached to a cycloaliphatic group which forms an endgroup of the polymer main chain and terminal olefinically unsaturated groups which are present as a double bond in a cycloolefinic structure which forms en endgroup of the polymer main chain.
摘要:
Self crosslinking polyurethane comprising lateral or terminal ethenylarylene groups, produced by reacting a polyurethane pre-polymer with an adduct, obtained by reacting an ethenylarylene mono-isocyanate with a compound containing hydroxyl groups or amino groups such that at least one group that is reactive to isocyanate remains in the adduct. Also, a self crosslinking graft copolymer containing at least one (meth)acrylate copolymer and at least one polyurethane produced by dispersing at least one self crosslinking olefinically unsaturated polyurethane comprising lateral or terminal ethenylarylene groups and blocked isocyanate groups in an aqueous medium and by radical copolymerization of a mixture of a monomer comprising at least one functional group that is reactive to isocyanate with a monomer that can be copolymerised with the mixture.
摘要:
The present invention relates to a method of coating substrates, preferably of metal, by cleaning the substrate surface, applying, if desired, an organic and/or inorganic pretreatment composition, applying a primer, applying a coating material by spraying, dipping, knifecoating, rollercoating or brushing, the coating material comprising an amine-modified epoxy resin and a crosslinking agent suitable for crosslinking.