公开(公告)号：US10577492B2

公开(公告)日：2020-03-03

申请号：US15750772

申请日：2016-07-19

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： Andrea Felisati ,  Angelo Ferraro ,  Paola Massari ,  Marco Ciarafoni ,  Claudio Cavalieri ,  Roberto Pantaleoni

IPC: C08L23/14 ,  B32B27/08 ,  B32B27/32 ,  B32B7/04 ,  B32B27/16 ,  C08J5/18 ,  C08L23/16 ,  C08F210/06 ,  C08F4/649 ,  C08F4/642 ,  B29C55/12 ,  B29C48/08

Abstract: A polyolefin composition made from or containing: A) from 19 wt % to 50 wt % of a propylene ethylene copolymer having an ethylene derived units content ranging from 1.5 wt % to 6.0 wt; B) from 50 wt % to 81 wt % of a propylene ethylene 1-butene terpolymer having an ethylene derived units content ranging from 1.5 wt % and 6.0 wt % and 1-butene derived units content of between 4.8 wt % and 12.4 wt %; wherein the ratio C2 wt %/C4 wt % is between 0.22 and 3.0, where C2 wt % is the weight percent of ethylene derived units and C4 wt % is the weight percent of 1-butene derived units; the content of xylene soluble fraction at 25° C. is between 2 and 15 wt %; molecular weight distribution (MWD), expressed in terms of Mw/Mn, greater than 4.0; recoverable compliance at 200° C. having a maximum value between 800 and 1200 seconds, lower than 65×10−5 Pa−1.

公开(公告)号：US10221261B2

公开(公告)日：2019-03-05

申请号：US14346648

申请日：2012-09-17

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： Monica Galvan ,  Roberto Pantaleoni ,  Ofelia Fusco ,  Benedetta Gaddi ,  Andreas Neumann ,  Antonio Mazzucco ,  Gianni Collina ,  Gabriella Sartori

IPC: C08F210/06 ,  C08F10/06 ,  C08J5/18 ,  B01J31/02

Abstract: A process for the preparation of high purity propylene polymers carried out in the presence of a catalyst comprising the product obtained by contacting:(a) a solid catalyst component comprising Mg, Ti and at least a first internal electron donor compound (1ID) selected among the succinates and a second internal electron donor compound (2ID) selected among the 1,3-diethers, wherein the molar ratio of first internal donor over second internal donor 1ID:2ID is comprised between 4:6 and 9:1, with (b) an organo-aluminum compound, and optionally with (c) an external electron donor compound, said process being carried out at a temperature equal or higher than 78° C. and by employing a molar ratio of organo-aluminum compound over solid catalyst component (b):(a) of lower than 5.

公开(公告)号：US09752023B2

公开(公告)日：2017-09-05

申请号：US14358753

申请日：2012-11-07

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： Monica Galvan ,  Roberto Pantaleoni ,  Ofelia Fusco ,  Benedetta Gaddi ,  Andreas Neumann ,  Antonio Mazzucco ,  Gianni Collina ,  Marco Ciarafoni

IPC: C08L23/12 ,  C08F10/06

CPC classification number: C08L23/12 ,  C08F10/06 ,  C08F4/651 ,  C08F4/6543 ,  C08F2/00 ,  C08F210/16 ,  C08F210/06 ,  C08F2500/11 ,  C08F2500/12 ,  C08F2500/17 ,  C08F2500/21 ,  C08F2/001 ,  C08F110/06 ,  C08L23/16

Abstract: Preparing propylene polymer compositions comprising 50 to 90% by weight of a propylene (co)polymer, and 10 to 50% by weight of an ethylene copolymer. The polymerization process includes, in the presence of a catalyst system: (i) a first step of polymerizing propylene to produce the propylene (co)polymer; and (ii) a successive gas-phase polymerization step performed in the presence of the propylene (co)polymer, ethylene, and one or more α-olefins to produce the ethylene copolymer. The catalyst system contains the product obtained by contacting: (a) a solid catalyst component comprising at least two internal electron donor compounds, a succinate and a 1,3-diether; (b) an aluminum hydrocarbyl compound, and (c) optionally, an external electron donor compound.

公开(公告)号：US09181424B2

公开(公告)日：2015-11-10

申请号：US14349711

申请日：2012-10-05

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： Gisella Biondini ,  Marco Ciarafoni ,  Paola Massari ,  Roberto Pantaleoni

IPC: C08L23/00 ,  C08L23/10 ,  C08L23/06 ,  C08L23/14

CPC classification number: C08L23/14 ,  C08L23/142 ,  C08L2205/02 ,  C08L2205/025 ,  C08L2205/24 ,  C08L2314/02 ,  C08L2666/06

Abstract: Propylene polymer compositions comprising: A) from 70 wt % to 95 wt %, of a random copolymer of propylene with ethylene, containing from 1.5 wt % to 4.5 wt %, of ethylene derived units, having a content of fraction insoluble in xylene at 25° C. of not less than 93%; B) from 5 wt % to 35 wt %, of a copolymer of propylene with ethylene, containing from 7.0 wt % to 17.0 wt % of ethylene derived units; the sum A+B being 100; wherein the melt flow rate, MFR. (Melt Flow Rate according to ASTM 1238, condition L, i.e. 230° C. and 2.16 kg load) ranges from 40 g/10 min and 130 g/10 min; and wherein the relation (I) is fulfilled: 10

Abstract translation: 丙烯聚合物组合物，其包含：A）70重量％至95重量％的丙烯与乙烯的无规共聚物，其含有1.5重量％至4.5重量％的乙烯衍生单元，其含量在25℃不溶于二甲苯 ℃不低于93％; B）5重量％至35重量％的丙烯与乙烯的共聚物，其含有7.0重量％至17.0重量％的乙烯衍生单元; 总和A + B为100; 其中熔体流动速率MFR。 （根据ASTM 1238的熔体流动速率，条件L，即230℃和2.16kg负荷）为40g / 10min和130g / 10min; 并且其中满足关系式（I）：10

公开(公告)号：US20150191852A1

公开(公告)日：2015-07-09

申请号：US14408023

申请日：2013-06-13

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： Monica Galvan ,  Andreas Neumann ,  Roberto Pantaleoni ,  Antonio Mazzucco ,  Ofelia Fusco ,  Benedetta Gaddi ,  Gianni Collina

IPC: D01F6/06 ,  D04H3/016 ,  D04H3/007 ,  B29C47/00 ,  D04H3/16

Abstract: Fibers comprising a polypropylene obtainable by a process comprising the steps of: (i) polymerizing propylene in the presence of a catalyst system comprising the product obtained by contacting the following components: (a) a solid catalyst component comprising a magnesium halide, a titanium compound having at least a Ti-halogen bond and at least two electron donor compounds one of which being present in an amount from 40 to 90% by mol with respect to the total amount of donors and selected from succinates and the other being selected from 1,3 diethers, (b) an aluminum hydrocarbyl compound, and (c) optionally an external electron donor compound, to obtain a polypropylene precursor having a melt flow rate MFR1; (ii) subjecting the thus-obtained polypropylene precursor to visbreaking to obtain a visbroken polypropylene having a melt flow rate MFR2; (iii) spinning the visbroken polypropylene obtained in the previous step; wherein MFR2 is comprised between from 15 to 40 g/10 min, the ratio MFR2/MFR1 is comprised between 8 and 18, both MFR1 and MFR2 being measured according to ISO method 1133 (230° C., 2.16 kg).

Abstract translation: 包含聚丙烯的纤维包括以下步骤：（i）在催化剂体系存在下聚合丙烯，所述催化剂体系包含通过使以下组分接触获得的产物：（a）固体催化剂组分，其包含卤化镁，钛化合物 具有至少一个Ti-卤素键和至少两个电子给体化合物，其中一种以相对于供体总量为40-90％摩尔量存在，选自琥珀酸盐，另一种选自1， 3个二醚，（b）铝烃基化合物和（c）任选的外电子给体化合物，得到熔体流动速率MFR 1的聚丙烯前体; （ii）将由此获得的聚丙烯前体进行减粘裂化以得到熔体流动速率MFR 2的减粘裂化聚丙烯; （iii）纺丝上一步获得的耐磨破坏聚丙烯; 其中MFR 2在15至40g / 10min之间，MFR 2 / MFR 1的比率在8和18之间，MFR 1和MFR 2均根据ISO方法1133（230℃，2.16kg）测量。

公开(公告)号：US11708468B2

公开(公告)日：2023-07-25

申请号：US17275939

申请日：2019-09-04

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： Paola Massari ,  Claudio Cavalieri ,  Caroline Cathelin ,  Davide Tartari ,  Marco Ciarafoni ,  Roberto Pantaleoni

IPC: C08L23/16 ,  C08L23/20 ,  C08F210/08 ,  C08F210/02 ,  C08F210/06 ,  C08F210/16 ,  C08J5/18 ,  C08L23/14 ,  C08F2/00

CPC classification number: C08J5/18 ,  C08L23/14 ,  C08F2/001 ,  C08F210/02 ,  C08F210/06 ,  C08F210/08 ,  C08F210/16 ,  C08J2323/14 ,  C08J2423/14 ,  C08L23/16 ,  C08L23/20 ,  C08L2203/162 ,  C08L2205/025 ,  C08L23/16 ,  C08L23/20 ,  C08F2500/12 ,  C08F2500/34 ,  C08F2500/35 ,  C08F2500/36 ,  C08F2800/20

Abstract: A terpolymer compositions made from or containing:

A) From 80 wt % to 97 wt %; of a first propylene, ethylene, 1-butene terpolymer having:

i) the content of ethylene derived units ranging from 0.5 wt % to 3.2 wt %;
ii) the content of 1-butene derived units ranging from 7.2 wt % to 14.8 wt %; and


B) From 20 wt % to 3 wt %; of a second propylene, ethylene, 1-butene terpolymer having:

i) the content of ethylene derived units ranging from 0.5 wt % to 3.2 wt %;
ii) the content of 1-butene derived units ranging from 14.4 wt % to 26.5 wt %; and


the terpolymer composition having the melt flow rate, MFR, measured according to ISO 1133 at 230° C. with a load of 2.16 kg, ranging from 3.0 g/10 min to 20.0 g/10 min; the sum of the amounts of A) and B) being 100 wt %.

公开(公告)号：US10711080B2

公开(公告)日：2020-07-14

申请号：US16061164

申请日：2016-11-22

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： Claudio Cavalieri ,  Paola Massari ,  Michele Grazzi ,  Giampaolo Pellegatti ,  Roberto Pantaleoni

IPC: C08F210/06 ,  C08J5/18 ,  B32B27/08 ,  B32B27/32

Abstract: A propylene 1-hexene copolymer containing from about 5.5 to about 9.0% by weight, based upon the total weight of the copolymer, of 1-hexene derived units having: a) two melting temperature peaks in the DSC plot having a difference in height ranging from 0 to 5 mW; b) the higher melting temperature, measured by DSC, ranging from about 141.0° C. to about 151.0° C.; and c) Melt Flow Rate (MFR, measured according to ASTM D 1238, 230° C./2.16 kg) from about 3.5 to about 8.0 g/10 min.

公开(公告)号：US10604645B2

公开(公告)日：2020-03-31

申请号：US16064900

申请日：2016-11-28

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： Antonio Mazzucco ,  Gabriele Mei ,  Tiziana Caputo ,  Roberto Pantaleoni ,  Enrico Balestra ,  Maria Di Diego ,  Mara Destro ,  Riccardo Rinaldi

IPC: C08L23/12 ,  C08F2/00 ,  C08F2/38

Abstract: A process for the preparation of polyolefins carried out in the presence of an antistatic composition made from or containing:a) a compound of formula R—OH wherein R represents hydrogen or a linear or branched, saturated alkyl group having from 1 to 15 carbon atoms; andb) an oligomeric or polymeric organic compound having one or more terminal hydroxyl groups and a viscosity at 40° C. of at least about 20 mm2/sec (DIN 51562).

公开(公告)号：US09650458B2

公开(公告)日：2017-05-16

申请号：US14774591

申请日：2014-03-03

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： Monica Galvan ,  Andreas Neumann ,  Tiziana Caputo ,  Stefano Squarzoni ,  Antonio Mazzucco ,  Ofelia Fusco ,  Benedetta Gaddi ,  Gianni Collina ,  Gisella Biondini ,  Claudio Cavalieri ,  Roberto Pantaleoni

IPC: C08F210/06 ,  C08F4/646 ,  C08F4/649 ,  C08F4/654

CPC classification number: C08F210/06 ,  C08F4/6543 ,  C08F4/651 ,  C08F110/06 ,  C08F4/6492 ,  C08F210/16 ,  C08F210/08 ,  C08F2500/12 ,  C08F2500/26

Abstract: Propylene terpolymers are prepared by polymerizing propylene, ethylene and an alpha-olefin selected from the group of C4-C8 alpha-olefins in the presence of a catalyst system obtained by contacting a solid catalyst component comprising a magnesium halide, a titanium compound having at least a Ti-halogen bond and at least two electron donor compounds one of which being present in an amount from 40 to 90% by mol with respect to the total amount of donors and selected from succinates and the other selected from 1,3 diethers, an aluminum hydrocarbyl compound, and optionally an external electron donor compound.

公开(公告)号：US20140316069A1

公开(公告)日：2014-10-23

申请号：US14358753

申请日：2012-11-07

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： Monica Galvan ,  Roberto Pantaleoni ,  Ofelia Fusco ,  Benedetta Gaddi ,  Andreas Neumann ,  Antonio Mazzucco ,  Gianni Collina ,  Marco Ciarafoni

IPC: C08L23/12

CPC classification number: C08L23/12 ,  C08F10/06 ,  C08F4/651 ,  C08F4/6543 ,  C08F2/00 ,  C08F210/16 ,  C08F210/06 ,  C08F2500/11 ,  C08F2500/12 ,  C08F2500/17 ,  C08F2500/21 ,  C08F2/001 ,  C08F110/06 ,  C08L23/16

Abstract: A process for the preparation of propylene polymer compositions comprising from 50 to 90% by weight of a propylene (co)polymer fraction insoluble in xylene at 25° C., and from 10 to 50% by weight of an ethylene copolymer fraction soluble in xylene at 25° C., said process comprising: (i) a first step of polymerizing propylene in the optional presence of ethylene and/or C4-C10 alpha olefins, to produce a propylene (co)polymer being for at least 85% by weight insoluble in xylene at 25° C.; and (ii) a successive step, carried out in gas-phase, in the presence of the product coming from step (i), of copolymerizing a mixture of ethylene with one or more α-olefins CH2═CHR in which R is a hydrocarbon radical having 1-10 carbon atoms, to produce an ethylene copolymer; the process being carried out in the presence of a catalyst system comprising: the product obtained by contacting: (a) a solid catalyst component comprising a magnesium halide, a titanium compound having at least a Ti-halogen bond and at least two internal electron donor compounds one of which being present in an amount from 35 to 90% by mol with respect to the total amount of donors and being selected from succinates and the other being selected from 1,3-diethers, the total amount of internal electron donor compounds being lower than 14.0% by weight with respect to the total weight of the solid catalyst component; with (b) an aluminum hydrocarbyl compound, and optionally with (c) an external electron donor compound.

Abstract translation: 一种制备丙烯聚合物组合物的方法，其包含50至90重量％的在25℃下不溶于二甲苯的丙烯（共）聚合物部分和10至50重量％的可溶于二甲苯的乙烯共聚物部分 所述方法包括：（i）在乙烯和/或C 4 -C 10α-烯烃的任选存在下聚合丙烯以产生丙烯（共）聚合物至少85重量％的第一步骤 在25℃不溶于二甲苯。 和（ii）在来自步骤（i）的产物存在下，在气相中进行共聚合乙烯与一种或多种α-烯烃CH 2 = CHR的混合物的连续步骤，其中R是烃 具有1-10个碳原子的基团，以制备乙烯共聚物; 该方法在催化剂体系存在下进行，该催化剂体系包括：通过使（a）包含卤化镁的固体催化剂组分，至少具有Ti-卤素键的钛化合物和至少两个内部电子给体 其中一种相对于供体总量为35至90摩尔％，其中一种选自琥珀酸酯，另一种选自1,3-二醚，内给电子体化合物的总量为 相对于固体催化剂组分的总重量低于14.0重量％ 与（b）铝烃基化合物，和任选与（c）外电子给体化合物。