摘要:
Propylene terpolymers are prepared by polymerizing propylene, ethylene and an alpha-olefin selected from the group of C4-C8 alpha-olefins in the presence of a catalyst system obtained by contacting a solid catalyst component comprising a magnesium halide, a titanium compound having at least a Ti-halogen bond and at least two electron donor compounds one of which being present in an amount from 40 to 90% by mol with respect to the total amount of donors and selected from succinates and the other selected from 1,3 diethers, an aluminum hydrocarbyl compound, and optionally an external electron donor compound.
摘要:
A process and apparatus for producing olefin polymers are disclosed, comprising:a. polymerizing one or more olefins in the gas phase, in the presence of an olefin polymerization catalyst, whereby growing polymer particles flow along a cylindrically-shaped downward path in densified form under the action of gravity so as to form a densified bed of downward-flowing polymer particles b. allowing said polymer particles to flow through a restriction of the densified bed, such restriction being positioned in a restriction zone extending from the bed upward to a distance of 15% of the total height of the densified bed; and c. metering an antistatic agent through a feed line connected to the densified bed at a feed point being located in a feed zone extending from the top of the restriction upward, to a distance five times the diameter of the section of the densified bed above the restriction.
摘要:
A method for monitoring and controlling the polymerization in a polymerization vessel by using a camera viewing unit to (a) detect features of the polymer particles, or the particles' environment, (b) compare the features to pre-defined acceptable values of these features or the environment, and (c) if a variation from the pre-defined values is detected, act on process parameters to reduce or eliminate the variation.
摘要:
The present disclosure relates to a propylene ethylene 1-butene terpolymer wherein: (i) the content of ethylene derived units ranges from 1.1 wt % to 1.9 wt %, (ii) the content of 1-butene ranges from 5.0 wt % to 9.0 wt %, (iii) the melting point (Tm) of the non-nucleated terpolymer ranges from 125° C. to 137° C.; and (iv) the xylene soluble fraction at 25° C. is lower than 8.0 wt %.
摘要:
Propylene terpolymers are prepared by polymerizing propylene, ethylene and an alpha-olefin selected from the group of C4-C8 alpha-olefins in the presence of a catalyst system obtained by contacting a solid catalyst component comprising a magnesium halide, a titanium compound having at least a Ti-halogen bond and at least two electron donor compounds one of which being present in an amount from 40 to 90% by mol with respect to the total amount of donors and selected from succinates and the other selected from 1,3 diethers, an aluminum hydrocarbyl compound, and optionally an external electron donor compound.
摘要:
A terpolymer containing propylene, ethylene and 1-hexene wherein: (i) the content of 1-hexene derived units ranges from 1 wt % to 2.6 wt %; (ii) the content of ethylene derived units is higher than 0.7 wt % and fulfils the following relation (1): C2
摘要:
A polypropylene composition made from or containing:
A) from 76 wt % to 95 wt % of a propylene homopolymer having:
fraction soluble in xylene at 25° C. between 2.0 wt % and 4.5 wt %; and melt flow rate ranging from 60.0 to 110.0 g/10 min; and
B) from 5 wt % to 24 wt % of a copolymer of propylene and ethylene containing from 75 wt % to 90.0 wt % of ethylene derived units; wherein the polypropylene composition has content of ethylene derived units in the fraction soluble in xylene at 25° C. lower than the content of ethylene derived units of component B) and ranging from 51.0 wt % to 74.0 wt %; and at least two melting points, wherein the higher melting points ranges from 156.0° C. to 166.0° C. and the lower melting point ranges from 90.0° C. to 125.0° C.; wherein the sum of the amounts of component A) and B) being 100 wt %.
摘要:
A polypropylene composition made from or containing:
from 70 wt % to 90 wt % of a propylene 1-hexene copolymer containing from 1.0 wt % to 5.0 wt % of 1-hexene derived units and a polydispersity index (PI) between 9.2 and 21.3; and from 10 wt % to 30 wt % of a copolymer of propylene and ethylene containing from 45.0 wt % to 65.0 wt % of ethylene derived units; the sum A)+B) being 100.
摘要:
A propylene ethylene copolymer having: (i) an ethylene derived units content (C2) ranging from 2.0 wt % to 11.0 wt %, based upon the total weight of the copolymer; (ii)) a fraction soluble in xylene (Xs) at 25° C. (Xs) ranging from 7.1 wt % to 28.5 wt %, based upon the total weight of the copolymer; (iii) an intrinsic viscosity of the fraction soluble in xylene at 25° C. ranging from 3.2 dl/g to 5.6 dl/g; (iv) a melting point (Tm) higher than 140.0° C. and fulfilling the relation (I): Tm>155−1.4×C2 (I); and (v) a flexural modulus (TM) higher than 500 MPa and fulfilling the relation (II) TM>1900−285×C2+50×Xs (II).
摘要:
The present disclosure relates to a propylene ethylene copolymer comprising: an ethylene content of between 1.8 and 10.0% by weight; a molecular weight distribution (MWD), expressed in terms of Mw/Mn, greater than 4.0; a content of xylene soluble fraction (XS) and ethylene content (C2) that fulfills the following relationship: XS