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公开(公告)号：US20150174559A1
公开(公告)日：2015-06-25
申请号：US14134600
申请日：2013-12-19
Applicant: BASF Corporation
Inventor： Gary M. Smith , Robert McGuire, JR. , Bilge Yilmaz
CPC classification number: B01J29/146 , B01J21/04 , B01J21/16 , B01J23/8472 , B01J29/088 , B01J35/0006 , B01J35/023 , B01J35/08 , B01J37/0009 , B01J37/0045 , B01J37/0201 , B01J37/04 , B01J37/28 , B01J2229/126 , B01J2229/186 , B01J2229/20 , B01J2229/26 , B01J2229/36 , C10G11/05 , C10G11/18
Abstract: Described are fluid catalytic cracking (FCC) compositions, methods of manufacture and use. FCC catalyst compositions comprise catalytic microspheres containing a zeolite, a non-zeolitic component, and a rare earth component. The microspheres are modified with phosphorus. The FCC catalyst composition can be used to crack hydrocarbon feeds, particularly resid feeds containing high V and Ni, resulting in lower hydrogen and coke yields.
Abstract translation: 描述了流化催化裂化（FCC）组合物，制造和使用方法。 FCC催化剂组合物包含含有沸石，非沸石组分和稀土组分的催化微球。 微球用磷改性。 FCC催化剂组合物可用于裂解烃进料，特别是含有高V和Ni的渣油原料，导致较低的氢气和焦炭产率。
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公开(公告)号：US20240131497A1
公开(公告)日：2024-04-25
申请号：US18275006
申请日：2022-01-31
Applicant: BASF Corporation
Inventor： Toshiyuki Yokoi , Bilge Yilmaz , Chandrashekhar Kelkar , Christopher John Gilbert , Sungsik Park
CPC classification number: B01J29/08 , B01J29/40 , B01J29/7007 , B01J35/19 , B01J35/617 , B01J35/633 , B01J2229/183
Abstract: Disclosed herein is a YNU-5 zeolite and/or a phosphorus modified YNU-5 zeolite, methods of their preparation, and methods of their use in hydrocarbon conversion processes, e.g., as part of a catalyst component and/or as part of a catalyst composition. Catalyst components with YNU-5 zeolite and/or with phosphorus modified YNU-5 zeolites, their methods of preparation, and their methods of use suitable for petroleum refining applications (e.g., hydrocarbon conversion processes such as fluid catalytic cracking and hydrocracking) are described herein. Also disclosed herein are catalyst compositions, which include YNU-5 zeolites and/or phosphorus modified YNU-5 zeolites and catalyst components thereof along with at least one additional catalyst component.
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公开(公告)号：US11759771B2
公开(公告)日：2023-09-19
申请号：US16771960
申请日：2018-12-14
Applicant: BASF CORPORATION
Inventor： Bilge Yilmaz , Gary M. Smith , Bethany Nicole Harkrider
IPC: B01J35/00 , B01J35/08 , B01J20/06 , B01J20/04 , B01J20/12 , B01J20/28 , B01J20/22 , B01J29/06 , B01J37/04 , B01J37/02 , C10G11/18 , C10G11/05 , C10G29/16
CPC classification number: B01J35/0006 , B01J20/041 , B01J20/06 , B01J20/12 , B01J20/223 , B01J20/28004 , B01J20/28021 , B01J29/06 , B01J35/08 , B01J37/0221 , B01J37/04 , C10G11/05 , C10G11/18 , C10G29/16 , C10G2300/205
Abstract: A metal trap for an FCC catalyst include pre-formed microspheres impregnated with a salt of calcium and/or magnesium and an organic acid salt of a rare earth element.
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公开(公告)号：US11254878B2
公开(公告)日：2022-02-22
申请号：US16824061
申请日：2020-03-19
Applicant: BASF Corporation
Inventor： Robert McGuire , Gary Smith , Bilge Yilmaz , Sven Serneels
Abstract: A zeolite fluid catalytic cracking catalyst is provided that passivates nickel and vanadium during catalytic cracking. The zeolite fluid catalytic cracking catalyst includes Y-faujasite crystallized in-situ from a metakaolin-containing calcined microsphere. The zeolite fluid catalytic cracking catalyst further includes an alumina-containing matrix obtained by calcination of a dispersible crystalline boehmite and a kaolin contained in the metakaolin-containing calcined microsphere, where the dispersible crystalline boehmite has a crystallite size of less than 500 Å. Also provided are a method of reducing contaminant coke and hydrogen yields and a method of catalytic cracking of heavy hydrocarbon feed stocks.
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公开(公告)号：US20200224102A1
公开(公告)日：2020-07-16
申请号：US16824061
申请日：2020-03-19
Applicant: BASF Corporation
Inventor： Robert McGuire , Gary Smith , Bilge Yilmaz , Sven Serneels
Abstract: A zeolite fluid catalytic cracking catalyst is provided that passivates nickel and vanadium during catalytic cracking. The zeolite fluid catalytic cracking catalyst includes Y-faujasite crystallized in-situ from a metakaolin-containing calcined microsphere. The zeolite fluid catalytic cracking catalyst further includes an alumina-containing matrix obtained by calcination of a dispersible crystalline boehmite and a kaolin contained in the metakaolin-containing calcined microsphere, where the dispersible crystalline boehmite has a crystallite size of less than 500 Å. Also provided are a method of reducing contaminant coke and hydrogen yields and a method of catalytic cracking of heavy hydrocarbon feed stocks.
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Patent Agency Ranking
公开(公告)号：US10086367B2
公开(公告)日：2018-10-02
申请号：US15426843
申请日：2017-02-07
Applicant: BASF CORPORATION
Inventor： Gary M. Smith , Robert McGuire, Jr. , Bilge Yilmaz
IPC: B01J29/06 , B01J29/14 , B01J37/28 , B01J37/02 , C10G11/05 , C10G11/18 , B01J35/08 , B01J29/08 , B01J37/00
Abstract: Described are fluid catalytic cracking (FCC) compositions, methods of manufacture and use. FCC catalyst compositions comprise catalytic microspheres containing a zeolite, a non-zeolitic component, and a rare earth component. The microspheres are modified with phosphorus. The FCC catalyst composition can be used to crack hydrocarbon feeds, particularly resid feeds containing high V and Ni, resulting in lower hydrogen and coke yields.
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公开(公告)号：US09441167B2
公开(公告)日：2016-09-13
申请号：US14134629
申请日：2013-12-19
Applicant: BASF Corporation
Inventor： Robert McGuire, Jr. , Gary M. Smith , Bilge Yilmaz
CPC classification number: C10G11/04 , B01J21/02 , B01J29/088 , B01J35/0006 , B01J37/0045 , B01J37/04 , B01J2229/186 , B01J2229/20 , B01J2229/42 , B01J2229/64 , C10G11/02 , C10G11/18
Abstract: Fluid catalytic cracking (FCC) processes are described, the processes utilizing one or more boron oxide components. Also described are FCC compositions and methods of manufacture. One or more boron oxide components on FCC compatible inorganic particles are added to a FCC unit to crack hydrocarbon feeds, resulting in lower hydrogen and coke yields.
Abstract translation: 流程催化裂化（FCC）方法描述了利用一种或多种氧化硼组分的方法。 还描述了FCC组合物和制造方法。 将FCC兼容的无机颗粒上的一种或多种氧化硼组分加入到FCC单元中以裂解烃进料，导致较低的氢气和焦炭产率。
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公开(公告)号：US10525451B2
公开(公告)日：2020-01-07
申请号：US15861423
申请日：2018-01-03
Applicant: BASF Corporation
Inventor： Robert McGuire, Jr. , Gary M. Smith , Bilge Yilmaz
IPC: B01J29/06 , B01J29/08 , C10G11/04 , C10G11/05 , B01J29/18 , B01J29/40 , B01J29/70 , C10G11/18 , B01J37/04 , B01J35/00 , B01J21/02 , B01J21/04 , B01J21/16 , B01J23/755 , B01J37/00 , B01J37/02
Abstract: Described are fluid catalytic cracking (FCC) compositions, methods of manufacture and use. FCC catalyst compositions comprise particles containing a non-zeolitic component and one or more boron oxide components. In embodiments, the FCC catalyst composition contains a zeolite component and optionally a rare earth component and a transition alumina. FCC catalytic compositions may comprise a first particle type containing one or more boron oxide components and a first matrix component mixed with a second particle type containing a second matrix component, and a zeolite. The FCC catalyst compositions can be used to crack hydrocarbon feeds, particularly resid feeds containing high V and Ni, resulting in lower hydrogen and coke yields.
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公开(公告)号：US20170362513A1
公开(公告)日：2017-12-21
申请号：US15264428
申请日：2016-09-13
Applicant: BASF Corporation
Inventor： Robert McGuire , Gary M. Smith , Bilge Yilmaz , Sven Serneels
CPC classification number: C10G11/05 , B01J29/084 , B01J35/023 , B01J35/08 , B01J35/1009 , B01J35/1014 , B01J35/1019 , B01J2229/42 , C10G11/18 , C10G2300/205
Abstract: A zeolite fluid catalytic cracking catalyst is provided that passivates nickel and vanadium during catalytic cracking. The zeolite fluid catalytic cracking catalyst includes Y-faujasite crystallized in-situ from a metakaolin-containing calcined microsphere. The zeolite fluid catalytic cracking catalyst further includes an alumina-containing matrix obtained by calcination of a dispersible crystalline boehmite and a kaolin contained in the metakaolin-containing calcined microsphere, where the dispersible crystalline boehmite has a crystallite size of less than 500 Å. Also provided are a method of reducing contaminant coke and hydrogen yields and a method of catalytic cracking of heavy hydrocarbon feed stocks.
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公开(公告)号：US20150175899A1
公开(公告)日：2015-06-25
申请号：US14134629
申请日：2013-12-19
Applicant: BASF Corporation
Inventor： Robert McGuire, JR. , Gary M. Smith , Bilge Yilmaz
IPC: C10G11/04
CPC classification number: C10G11/04 , B01J21/02 , B01J29/088 , B01J35/0006 , B01J37/0045 , B01J37/04 , B01J2229/186 , B01J2229/20 , B01J2229/42 , B01J2229/64 , C10G11/02 , C10G11/18
Abstract: Fluid catalytic cracking (FCC) processes are described, the processes utilizing one or more boron oxide components. Also described are FCC compositions and methods of manufacture. One or more boron oxide components on FCC compatible inorganic particles are added to a FCC unit to crack hydrocarbon feeds, resulting in lower hydrogen and coke yields.
Abstract translation: 流程催化裂化（FCC）方法描述了利用一种或多种氧化硼组分的方法。 还描述了FCC组合物和制造方法。 将FCC兼容的无机颗粒上的一种或多种氧化硼组分加入到FCC单元中以裂解烃进料，导致较低的氢气和焦炭产率。
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