公开(公告)号：US10683458B2

公开(公告)日：2020-06-16

申请号：US15707137

申请日：2017-09-18

Applicant: BASF Corporation

Inventor： Gary M. Smith ,  Robert McGuire, Jr. ,  Bilge Yilmaz

IPC: B01J21/02 ,  B01J21/16 ,  B01J29/06 ,  B01J29/08 ,  B01J35/00 ,  B01J37/00 ,  B01J37/04 ,  B01J37/06 ,  B01J37/28 ,  C10G11/04 ,  C10G11/18 ,  B01J37/08

Abstract: A method of cracking a hydrocarbon feed under fluid catalytic cracking conditions includes adding FCC compatible inorganic particles having a first particle type including one or more boron oxide components and a first matrix component into a FCC unit and adding cracking microspheres having a second particle type including a second matrix component, a phosphorus component and 20% to 95% by weight of a zeolite component into the FCC unit.

公开(公告)号：US20180010054A1

公开(公告)日：2018-01-11

申请号：US15707137

申请日：2017-09-18

Applicant: BASF Corporation

Inventor： Gary M. Smith ,  Robert McGuire, JR. ,  Bilge Yilmaz

IPC: C10G11/04 ,  B01J37/04 ,  B01J21/16 ,  B01J29/06 ,  B01J21/02 ,  B01J37/00 ,  B01J35/00 ,  B01J29/08 ,  C10G11/18 ,  B01J37/28 ,  B01J37/06

Abstract: A method of cracking a hydrocarbon feed under fluid catalytic cracking conditions includes adding FCC compatible inorganic particles having a first particle type including one or more boron oxide components and a first matrix component into a FCC unit and adding cracking microspheres having a second particle type including a second matrix component, a phosphorus component and 20% to 95% by weight of a zeolite component into the FCC unit.

公开(公告)号：US20170144137A1

公开(公告)日：2017-05-25

申请号：US15426843

申请日：2017-02-07

Applicant: BASF CORPORATION

Inventor： Gary M. Smith ,  Robert McGuire, JR. ,  Bilge Yilmaz

IPC: B01J29/14 ,  C10G11/18 ,  C10G11/05 ,  B01J37/28 ,  B01J37/02

CPC classification number: B01J29/146 ,  B01J21/04 ,  B01J21/16 ,  B01J23/8472 ,  B01J29/088 ,  B01J35/0006 ,  B01J35/023 ,  B01J35/08 ,  B01J37/0009 ,  B01J37/0045 ,  B01J37/0201 ,  B01J37/04 ,  B01J37/28 ,  B01J2229/126 ,  B01J2229/186 ,  B01J2229/20 ,  B01J2229/26 ,  B01J2229/36 ,  C10G11/05 ,  C10G11/18

Abstract: Described are fluid catalytic cracking (FCC) compositions, methods of manufacture and use. FCC catalyst compositions comprise catalytic microspheres containing a zeolite, a non-zeolitic component, and a rare earth component. The microspheres are modified with phosphorus. The FCC catalyst composition can be used to crack hydrocarbon feeds, particularly resid feeds containing high V and Ni, resulting in lower hydrogen and coke yields.

公开(公告)号：US11498054B2

公开(公告)日：2022-11-15

申请号：US16762472

申请日：2018-11-08

Applicant: BASF Corporation

Inventor： Gary M. Smith ,  Bilge Yilmaz

IPC: B01J23/10 ,  B01J29/06 ,  B01J35/08 ,  B01J35/10 ,  C10G11/05 ,  C10G11/18 ,  B01J21/16 ,  B01J35/02 ,  C10G25/00

Abstract: A metal trap for an FCC catalyst include pre-formed microspheres impregnated with an organic acid salt of a rare earth element.

公开(公告)号：US20150174560A1

公开(公告)日：2015-06-25

申请号：US14134614

申请日：2013-12-19

Applicant: BASF Corporation

Inventor： Robert McGuire, JR. ,  Gary M. Smith ,  Bilge Yilmaz

IPC: B01J29/08 ,  C10G11/04

CPC classification number: B01J29/088 ,  B01J21/02 ,  B01J21/04 ,  B01J21/16 ,  B01J23/755 ,  B01J35/0006 ,  B01J37/0009 ,  B01J37/0045 ,  B01J37/0201 ,  B01J37/04 ,  B01J2229/126 ,  B01J2229/186 ,  B01J2229/26 ,  C10G11/04 ,  C10G11/05 ,  C10G11/18

Abstract: Described are fluid catalytic cracking (FCC) compositions, methods of manufacture and use. FCC catalyst compositions comprise particles containing a non-zeolitic component and one or more boron oxide components. In embodiments, the FCC catalyst composition contains a zeolite component and optionally a rare earth component and a transition alumina. FCC catalytic compositions may comprise a first particle type containing one or more boron oxide components and a first matrix component mixed with a second particle type containing a second matrix component, and a zeolite. The FCC catalyst compositions can be used to crack hydrocarbon feeds, particularly resid feeds containing high V and Ni, resulting in lower hydrogen and coke yields.

Abstract translation: 描述了流化催化裂化（FCC）组合物，制造和使用方法。 FCC催化剂组合物包含含有非沸石组分和一种或多种氧化硼组分的颗粒。 在实施方案中，FCC催化剂组合物含有沸石组分和任选的稀土组分和过渡氧化铝。 FCC催化组合物可以包含含有一种或多种氧化硼组分的第一颗粒类型和与含有第二种基质组分的第二种颗粒类型和沸石混合的第一种基质组分。 FCC催化剂组合物可用于裂解烃进料，特别是含有高V和Ni的渣油进料，导致较低的氢气和焦炭产率。

公开(公告)号：US10525451B2

公开(公告)日：2020-01-07

申请号：US15861423

申请日：2018-01-03

Applicant: BASF Corporation

Inventor： Robert McGuire, Jr. ,  Gary M. Smith ,  Bilge Yilmaz

IPC: B01J29/06 ,  B01J29/08 ,  C10G11/04 ,  C10G11/05 ,  B01J29/18 ,  B01J29/40 ,  B01J29/70 ,  C10G11/18 ,  B01J37/04 ,  B01J35/00 ,  B01J21/02 ,  B01J21/04 ,  B01J21/16 ,  B01J23/755 ,  B01J37/00 ,  B01J37/02

Abstract: Described are fluid catalytic cracking (FCC) compositions, methods of manufacture and use. FCC catalyst compositions comprise particles containing a non-zeolitic component and one or more boron oxide components. In embodiments, the FCC catalyst composition contains a zeolite component and optionally a rare earth component and a transition alumina. FCC catalytic compositions may comprise a first particle type containing one or more boron oxide components and a first matrix component mixed with a second particle type containing a second matrix component, and a zeolite. The FCC catalyst compositions can be used to crack hydrocarbon feeds, particularly resid feeds containing high V and Ni, resulting in lower hydrogen and coke yields.

公开(公告)号：US20170362513A1

公开(公告)日：2017-12-21

申请号：US15264428

申请日：2016-09-13

Applicant: BASF Corporation

Inventor： Robert McGuire ,  Gary M. Smith ,  Bilge Yilmaz ,  Sven Serneels

IPC: C10G11/05 ,  C10G11/18 ,  B01J29/08 ,  B01J35/10

CPC classification number: C10G11/05 ,  B01J29/084 ,  B01J35/023 ,  B01J35/08 ,  B01J35/1009 ,  B01J35/1014 ,  B01J35/1019 ,  B01J2229/42 ,  C10G11/18 ,  C10G2300/205

Abstract: A zeolite fluid catalytic cracking catalyst is provided that passivates nickel and vanadium during catalytic cracking. The zeolite fluid catalytic cracking catalyst includes Y-faujasite crystallized in-situ from a metakaolin-containing calcined microsphere. The zeolite fluid catalytic cracking catalyst further includes an alumina-containing matrix obtained by calcination of a dispersible crystalline boehmite and a kaolin contained in the metakaolin-containing calcined microsphere, where the dispersible crystalline boehmite has a crystallite size of less than 500 Å. Also provided are a method of reducing contaminant coke and hydrogen yields and a method of catalytic cracking of heavy hydrocarbon feed stocks.

公开(公告)号：US20150175899A1

公开(公告)日：2015-06-25

申请号：US14134629

申请日：2013-12-19

Applicant: BASF Corporation

Inventor： Robert McGuire, JR. ,  Gary M. Smith ,  Bilge Yilmaz

IPC: C10G11/04

CPC classification number: C10G11/04 ,  B01J21/02 ,  B01J29/088 ,  B01J35/0006 ,  B01J37/0045 ,  B01J37/04 ,  B01J2229/186 ,  B01J2229/20 ,  B01J2229/42 ,  B01J2229/64 ,  C10G11/02 ,  C10G11/18

Abstract: Fluid catalytic cracking (FCC) processes are described, the processes utilizing one or more boron oxide components. Also described are FCC compositions and methods of manufacture. One or more boron oxide components on FCC compatible inorganic particles are added to a FCC unit to crack hydrocarbon feeds, resulting in lower hydrogen and coke yields.

Abstract translation: 流程催化裂化（FCC）方法描述了利用一种或多种氧化硼组分的方法。 还描述了FCC组合物和制造方法。 将FCC兼容的无机颗粒上的一种或多种氧化硼组分加入到FCC单元中以裂解烃进料，导致较低的氢气和焦炭产率。

公开(公告)号：US20130252802A1

公开(公告)日：2013-09-26

申请号：US13899816

申请日：2013-05-22

Applicant: BASF Corporation

Inventor： Xingtao Gao ,  David Stockwell ,  Gary M. Smith

IPC: B01J29/08

CPC classification number: B01J29/084 ,  B01J29/06 ,  B01J29/064 ,  B01J29/106 ,  B01J29/166 ,  B01J35/023 ,  B01J35/026 ,  B01J35/1066 ,  B01J37/0009 ,  B01J37/0045 ,  B01J37/0072 ,  B01J37/0215 ,  B01J2229/64 ,  C10G45/02 ,  C10G47/16 ,  C10G47/20 ,  C10G65/12 ,  C10G2400/02

Abstract: A zeolite-containing fixed bed catalyst is formed by pre-shaping a mixture of a reactive aluminum-containing component and a matrix component into pre-shaped particles, and contacting the pre-shaped particles with a reactive liquid containing a silicate for a sufficient time and temperature to form an in-situ zeolite within the pre-shaped particles. The contacting of the pre-shaped particles and the liquid is achieved such that there is relative movement between the pre-shaped particles and the liquid.

Abstract translation: 通过将含活性铝的组分和基质组分的混合物预成型为预成型颗粒并使预成型颗粒与含有硅酸盐的反应性液体接触足够的时间来形成含沸石的固定床催化剂 和温度以在预成形颗粒内形成原位沸石。 实现预形状颗粒和液体的接触，使得在预形状颗粒和液体之间存在相对运动。

公开(公告)号：US11759771B2

公开(公告)日：2023-09-19

申请号：US16771960

申请日：2018-12-14

Applicant: BASF CORPORATION

Inventor： Bilge Yilmaz ,  Gary M. Smith ,  Bethany Nicole Harkrider

IPC: B01J35/00 ,  B01J35/08 ,  B01J20/06 ,  B01J20/04 ,  B01J20/12 ,  B01J20/28 ,  B01J20/22 ,  B01J29/06 ,  B01J37/04 ,  B01J37/02 ,  C10G11/18 ,  C10G11/05 ,  C10G29/16

CPC classification number: B01J35/0006 ,  B01J20/041 ,  B01J20/06 ,  B01J20/12 ,  B01J20/223 ,  B01J20/28004 ,  B01J20/28021 ,  B01J29/06 ,  B01J35/08 ,  B01J37/0221 ,  B01J37/04 ,  C10G11/05 ,  C10G11/18 ,  C10G29/16 ,  C10G2300/205

Abstract: A metal trap for an FCC catalyst include pre-formed microspheres impregnated with a salt of calcium and/or magnesium and an organic acid salt of a rare earth element.