公开(公告)号：US11654422B2

公开(公告)日：2023-05-23

申请号：US16698558

申请日：2019-11-27

申请人： FURUKAWA ELECTRIC CO., LTD.

发明人： Takao Masuda ,  Yuta Nakasaka ,  Takuya Yoshikawa ,  Sadahiro Kato ,  Masayuki Fukushima ,  Hiroko Takahashi ,  Yuichiro Banba ,  Kaori Sekine

IPC分类号： B01J29/06 ,  B01J29/14 ,  B01J29/08 ,  B01J29/40 ,  B01J29/46 ,  B01J29/65 ,  B01J29/68 ,  B01J29/70 ,  B01J29/72 ,  B01J35/00 ,  B01J35/02 ,  B01J35/10 ,  B01J37/00 ,  B01J37/02 ,  B01J37/10 ,  C10G11/05 ,  C10G45/12 ,  B01J29/068 ,  B01J29/035 ,  B01J29/064 ,  B01J29/076 ,  B01J29/12 ,  B01J29/20 ,  B01J29/18 ,  B01J29/22 ,  B01J29/10 ,  B01J29/072 ,  B01J29/16 ,  B01J29/42 ,  B01J29/61 ,  B01J29/44 ,  B01J29/26 ,  B01J29/24 ,  B01J29/48 ,  B01J29/60 ,  B01J29/63 ,  B01J29/66 ,  B01J29/62 ,  B01J29/64 ,  B01J29/69 ,  B01J29/67 ,  B01J29/78 ,  B01J29/74 ,  B01J29/76

CPC分类号： B01J29/14 ,  B01J29/035 ,  B01J29/0352 ,  B01J29/0354 ,  B01J29/0356 ,  B01J29/0358 ,  B01J29/064 ,  B01J29/068 ,  B01J29/072 ,  B01J29/076 ,  B01J29/085 ,  B01J29/10 ,  B01J29/12 ,  B01J29/16 ,  B01J29/185 ,  B01J29/20 ,  B01J29/22 ,  B01J29/24 ,  B01J29/26 ,  B01J29/405 ,  B01J29/42 ,  B01J29/44 ,  B01J29/46 ,  B01J29/48 ,  B01J29/605 ,  B01J29/61 ,  B01J29/62 ,  B01J29/63 ,  B01J29/64 ,  B01J29/655 ,  B01J29/66 ,  B01J29/67 ,  B01J29/68 ,  B01J29/69 ,  B01J29/7007 ,  B01J29/7038 ,  B01J29/7057 ,  B01J29/7084 ,  B01J29/7088 ,  B01J29/7215 ,  B01J29/7269 ,  B01J29/7276 ,  B01J29/7415 ,  B01J29/7476 ,  B01J29/7615 ,  B01J29/7676 ,  B01J29/7815 ,  B01J29/7876 ,  B01J35/006 ,  B01J35/0013 ,  B01J35/0066 ,  B01J35/026 ,  B01J35/1057 ,  B01J35/1061 ,  B01J37/0018 ,  B01J37/0211 ,  B01J37/105 ,  C10G11/05 ,  C10G45/12 ,  B01J2229/126 ,  B01J2229/20 ,  B01J2229/32 ,  B01J2229/34 ,  C10G2300/70

摘要： To provide a structured catalyst for catalytic cracking or hydrodesulfurization that suppresses decline in catalytic activity, achieves efficient catalytic cracking, and allows simple and stable obtaining of a substance to be modified. The structured catalyst for catalytic cracking or hydrodesulfurization (1) includes a support (10) of a porous structure composed of a zeolite-type compound and at least one type of metal oxide nanoparticles (20) present in the support (10), in which the support (10) has channels (11) that connect with each other, the metal oxide nanoparticles (20) are present at least in the channels (11) of the support (10), and the metal oxide nanoparticles (20) are composed of a material containing any one or two more of the oxides of Fe, Al, Zn, Zr, Cu, Co, Ni, Ce, Nb, Ti, Mo, V, Cr, Pd, and Ru.

公开(公告)号：US20180194636A1

公开(公告)日：2018-07-12

申请号：US15741687

申请日：2016-07-05

申请人： Total Research & Technology Feluy ,  Centre National de la Recherche Scientifique (CNRS)

发明人： Xiaowei Cheng ,  Corine Gerardin ,  François Fajula ,  Laura Vaugon ,  Delphine Minoux ,  Jean-Pierre Dath

IPC分类号： C01B39/02 ,  C01B39/06 ,  C01B39/08 ,  C01B39/44 ,  C01B39/24 ,  B01J29/12 ,  B01J37/30

CPC分类号： C01B39/026 ,  B01J29/126 ,  B01J37/30 ,  B01J2229/126 ,  B01J2229/16 ,  B01J2229/183 ,  B01J2229/37 ,  B01J2229/38 ,  C01B39/06 ,  C01B39/08 ,  C01B39/24 ,  C01B39/445

摘要： A method to remove silica from a silica containing material characterized in that it comprises (i) contacting said silica containing material with a first metal ion carbonate, to obtain a first composition, and (ii) heating said first composition in a vessel at a temperature sufficient to increase the pressure above the atmospheric pressure in said vessel or at a pressure of at least 2 bara and at a temperature of at least 80° C., preferably 100° C. wherein said pressure is preferably autogeneously generated, wherein the total amount of water of said first composition originating from (a) the silica containing material and from (b) the first metal ion carbonate is greater or equal to 4 mol of water per mol of metal ion carbonate, and wherein the first composition obtained at step (i) is not a suspension in water and is under solid state at standard temperature and pressure (STP), before the performance of step (ii) and wherein said silica containing material is a zeolite

公开(公告)号：US20130296160A1

公开(公告)日：2013-11-07

申请号：US13938634

申请日：2013-07-10

申请人： UOP LLC

发明人： Laszlo T. Nemeth ,  Feng Xu

IPC分类号： B01J29/85

CPC分类号： B01J29/85 ,  B01J29/06 ,  B01J29/40 ,  B01J2229/123 ,  B01J2229/126 ,  B01J2229/32 ,  B01J2229/34 ,  B01J2229/42 ,  C01B39/026

摘要： Surface-modified zeolites and methods for preparing surface-modified zeolites are provided. A hybrid polymer formed from a silicon alkoxide and a metal alkoxide, a co-monomer, or both, is contacted with a zeolite suspension. The zeolite suspension comprises a sodium-, an ammonium-, or a hydrogen-form zeolite and a solvent. The hybrid polymer and zeolite suspension are contacted under conditions sufficient to deposit hybrid polymer on external surfaces of the zeolite to form a treated zeolite. Solvent is removed therefrom. The treated zeolite is dried and calcinated to form a dried and calcinated treated zeolite. Forming of the zeolite suspension and the contacting, removing, drying, and calcinating steps are provided in one selectivation sequence to produce a surface-modified zeolite from the ammonium-form zeolite and the hydrogen-form zeolite. If the dried and calcinated treated zeolite is a sodium-form zeolite, the sodium is exchanged with ammonium and then additionally dried and calcinated.

摘要翻译： 提供表面改性沸石和制备表面改性沸石的方法。 由硅醇盐和金属醇盐，共聚单体或两者形成的杂化聚合物与沸石悬浮液接触。 沸石悬浮液包含钠，铵或氢形式的沸石和溶剂。 混合聚合物和沸石悬浮液在足以在沸石的外表面上沉积杂化聚合物以形成经处理的沸石的条件下接触。 从中除去溶剂。 将经处理的沸石干燥并煅烧以形成经干燥和煅烧的处理的沸石。 沸石悬浮液的形成和接触，除去，干燥和煅烧步骤在一个选择序列中提供，以从铵型沸石和氢型沸石产生表面改性的沸石。 如果干燥和煅烧的经处理的沸石是钠型沸石，则钠与铵交换，然后另外干燥和煅烧。

公开(公告)号：US09895680B2

公开(公告)日：2018-02-20

申请号：US14134614

申请日：2013-12-19

申请人： BASF Corporation

发明人： Robert McGuire, Jr. ,  Gary M. Smith ,  Bilge Yilmaz

IPC分类号： B01J29/06 ,  C10G11/05 ,  B01J29/08 ,  C10G11/04 ,  C10G11/18 ,  B01J37/04 ,  B01J35/00 ,  B01J21/02 ,  B01J21/04 ,  B01J21/16 ,  B01J23/755 ,  B01J37/00 ,  B01J37/02

CPC分类号： B01J29/088 ,  B01J21/02 ,  B01J21/04 ,  B01J21/16 ,  B01J23/755 ,  B01J35/0006 ,  B01J37/0009 ,  B01J37/0045 ,  B01J37/0201 ,  B01J37/04 ,  B01J2229/126 ,  B01J2229/186 ,  B01J2229/26 ,  C10G11/04 ,  C10G11/05 ,  C10G11/18

摘要： Described are fluid catalytic cracking (FCC) compositions, methods of manufacture and use. FCC catalyst compositions comprise particles containing a non-zeolitic component and one or more boron oxide components. In embodiments, the FCC catalyst composition contains a zeolite component and optionally a rare earth component and a transition alumina. FCC catalytic compositions may comprise a first particle type containing one or more boron oxide components and a first matrix component mixed with a second particle type containing a second matrix component, and a zeolite. The FCC catalyst compositions can be used to crack hydrocarbon feeds, particularly resid feeds containing high V and Ni, resulting in lower hydrogen and coke yields.

公开(公告)号：US20150174559A1

公开(公告)日：2015-06-25

申请号：US14134600

申请日：2013-12-19

申请人： BASF Corporation

发明人： Gary M. Smith ,  Robert McGuire, JR. ,  Bilge Yilmaz

IPC分类号： B01J29/08 ,  C10G11/02

CPC分类号： B01J29/146 ,  B01J21/04 ,  B01J21/16 ,  B01J23/8472 ,  B01J29/088 ,  B01J35/0006 ,  B01J35/023 ,  B01J35/08 ,  B01J37/0009 ,  B01J37/0045 ,  B01J37/0201 ,  B01J37/04 ,  B01J37/28 ,  B01J2229/126 ,  B01J2229/186 ,  B01J2229/20 ,  B01J2229/26 ,  B01J2229/36 ,  C10G11/05 ,  C10G11/18

摘要： Described are fluid catalytic cracking (FCC) compositions, methods of manufacture and use. FCC catalyst compositions comprise catalytic microspheres containing a zeolite, a non-zeolitic component, and a rare earth component. The microspheres are modified with phosphorus. The FCC catalyst composition can be used to crack hydrocarbon feeds, particularly resid feeds containing high V and Ni, resulting in lower hydrogen and coke yields.

摘要翻译： 描述了流化催化裂化（FCC）组合物，制造和使用方法。 FCC催化剂组合物包含含有沸石，非沸石组分和稀土组分的催化微球。 微球用磷改性。 FCC催化剂组合物可用于裂解烃进料，特别是含有高V和Ni的渣油原料，导致较低的氢气和焦炭产率。

公开(公告)号：US08575055B2

公开(公告)日：2013-11-05

申请号：US12750250

申请日：2010-03-30

申请人： Laszlo Nemeth ,  Feng Xu

发明人： Laszlo Nemeth ,  Feng Xu

IPC分类号： B01J29/06

CPC分类号： B01J29/85 ,  B01J29/06 ,  B01J29/40 ,  B01J2229/123 ,  B01J2229/126 ,  B01J2229/32 ,  B01J2229/34 ,  B01J2229/42 ,  C01B39/026

摘要： Surface-modified zeolites and methods for preparing surface-modified zeolites are provided. A hybrid polymer formed from a silicon alkoxide and a metal alkoxide, a co-monomer, or both, is contacted with a zeolite suspension. The zeolite suspension comprises a sodium-, an ammonium-, or a hydrogen-form zeolite and a solvent. The hybrid polymer and zeolite suspension are contacted under conditions sufficient to deposit hybrid polymer on external surfaces of the zeolite to form a treated zeolite. Solvent is removed therefrom. The treated zeolite is dried and calcinated to form a dried and calcinated treated zeolite. Forming of the zeolite suspension and the contacting, removing, drying, and calcinating steps are provided in one selectivation sequence to produce a surface-modified zeolite from the ammonium-form zeolite and the hydrogen-form zeolite. If the dried and calcinated treated zeolite is a sodium-form zeolite, the sodium is exchanged with ammonium and then additionally dried and calcinated.

摘要翻译： 提供表面改性沸石和制备表面改性沸石的方法。 由硅醇盐和金属醇盐，共聚单体或两者形成的杂化聚合物与沸石悬浮液接触。 沸石悬浮液包含钠，铵或氢形式的沸石和溶剂。 混合聚合物和沸石悬浮液在足以在沸石的外表面上沉积杂化聚合物以形成经处理的沸石的条件下接触。 从中除去溶剂。 将经处理的沸石干燥并煅烧以形成经干燥和煅烧的处理的沸石。 沸石悬浮液的形成和接触，除去，干燥和煅烧步骤在一个选择序列中提供，以从铵型沸石和氢型沸石产生表面改性的沸石。 如果干燥和煅烧的经处理的沸石是钠型沸石，则钠与铵交换，然后另外干燥和煅烧。

公开(公告)号：US20120279901A1

公开(公告)日：2012-11-08

申请号：US13513385

申请日：2010-11-30

申请人： László Domokos ,  Wiebe Sjoerd Kijlstra ,  Lay Hwa Ong ,  Edward Julius Creyghton

发明人： László Domokos ,  Wiebe Sjoerd Kijlstra ,  Lay Hwa Ong ,  Edward Julius Creyghton

IPC分类号： C01B39/20 ,  C10G47/16 ,  B01J29/08

CPC分类号： C10G47/16 ,  B01J23/888 ,  B01J29/084 ,  B01J37/0201 ,  B01J37/0207 ,  B01J37/06 ,  B01J37/10 ,  B01J2029/081 ,  B01J2229/126 ,  B01J2229/16 ,  B01J2229/36 ,  B01J2229/37 ,  B01J2229/42 ,  C01B39/026 ,  C01B39/20 ,  C01B39/24 ,  C10G47/18 ,  C10G47/20

摘要： Disclosed is a process for the preparation of a faujasite zeolite. A starting zeolite of the faujasite structure having a silica to alumina ratio of from 4.5 to 6.5 and an alkali level of less than 1.5% wt is steam calcined to produce an intermediate zeolite. The intermediate zeolite is treated with an acidified solution having specificately defined characteristics.

摘要翻译： 公开了一种制备八面沸石的方法。 二氧化硅与氧化铝之比为4.5至6.5并且碱含量低于1.5重量％的八面沸石结构的起始沸石被蒸汽煅烧以产生中间沸石。 中间沸石用具有特定限定特征的酸化溶液处理。

公开(公告)号：US11655157B2

公开(公告)日：2023-05-23

申请号：US16698636

申请日：2019-11-27

申请人： NATIONAL UNIVERSITY CORPORATION HOKKAIDO UNIVERSITY ,  FURUKAWA ELECTRIC CO., LTD.

发明人： Takao Masuda ,  Yuta Nakasaka ,  Takuya Yoshikawa ,  Sadahiro Kato ,  Masayuki Fukushima ,  Kojiro Inamori ,  Hiroko Takahashi ,  Yuichiro Banba ,  Kaori Sekine

IPC分类号： B01J29/06 ,  C01B39/02 ,  B01J29/18 ,  B01J35/02 ,  B01J35/10 ,  B01J37/02 ,  B01J37/10 ,  B01J29/035 ,  B01J29/04 ,  B01J37/08 ,  B01J29/12 ,  B01J29/03 ,  B01J29/14 ,  B01J29/072 ,  B01J29/08 ,  B01J29/20 ,  B01J29/24 ,  B01J29/064 ,  B01J29/10 ,  B01J29/076 ,  B01J29/44 ,  B01J29/42 ,  B01J29/16 ,  B01J29/22 ,  B01J29/65 ,  B01J29/48 ,  B01J29/40 ,  B01J29/64 ,  B01J29/61 ,  B01J29/63 ,  B01J29/46 ,  B01J29/26 ,  B01J29/62 ,  B01J29/60 ,  B01J29/70 ,  B01J29/66 ,  B01J29/69 ,  B01J29/68 ,  B01J29/76 ,  B01J29/67 ,  B01J29/72 ,  B01J29/78 ,  B01J29/74 ,  B01J23/32 ,  B01J23/34 ,  B01J23/36 ,  B01J23/38 ,  B01J23/06 ,  B01J23/10 ,  B01J23/16 ,  B01J23/745 ,  B82Y30/00

CPC分类号： C01B39/026 ,  B01J23/06 ,  B01J23/10 ,  B01J23/16 ,  B01J23/32 ,  B01J23/34 ,  B01J23/36 ,  B01J23/38 ,  B01J23/745 ,  B01J29/035 ,  B01J29/0308 ,  B01J29/0352 ,  B01J29/0354 ,  B01J29/0356 ,  B01J29/0358 ,  B01J29/041 ,  B01J29/043 ,  B01J29/044 ,  B01J29/064 ,  B01J29/072 ,  B01J29/076 ,  B01J29/085 ,  B01J29/10 ,  B01J29/12 ,  B01J29/14 ,  B01J29/16 ,  B01J29/18 ,  B01J29/185 ,  B01J29/20 ,  B01J29/22 ,  B01J29/24 ,  B01J29/26 ,  B01J29/405 ,  B01J29/42 ,  B01J29/44 ,  B01J29/46 ,  B01J29/48 ,  B01J29/605 ,  B01J29/61 ,  B01J29/62 ,  B01J29/63 ,  B01J29/64 ,  B01J29/65 ,  B01J29/655 ,  B01J29/66 ,  B01J29/67 ,  B01J29/68 ,  B01J29/69 ,  B01J29/70 ,  B01J29/7007 ,  B01J29/7038 ,  B01J29/7057 ,  B01J29/7088 ,  B01J29/7215 ,  B01J29/7276 ,  B01J29/7415 ,  B01J29/7476 ,  B01J29/7676 ,  B01J29/7815 ,  B01J29/7876 ,  B01J35/023 ,  B01J35/10 ,  B01J35/1057 ,  B01J37/0201 ,  B01J37/0207 ,  B01J37/08 ,  B01J37/10 ,  B01J2229/126 ,  B01J2229/18 ,  B01J2229/20 ,  B01J2229/22 ,  B01J2229/32 ,  B01J2229/34 ,  B01J2229/37 ,  B01J2229/38 ,  B01J2229/40 ,  B82Y30/00 ,  Y02P30/20 ,  Y02P30/40

摘要： A functional structural body that can realize a prolonged life time by suppressing the decrease in function and that can fulfill resource saving without requiring a complicated replacement operation is provided. A functional structural body includes a skeletal body of a porous structure composed of a zeolite-type compound; and at least one solid acid present in the skeletal body, the skeletal body has channels connecting with each other, and the solid acid is present at least in the channels of the skeletal body.

公开(公告)号：US09340734B2

公开(公告)日：2016-05-17

申请号：US13513385

申请日：2010-11-30

申请人： László Domokos ,  Wiebe Sjoerd Kijlstra ,  Lay Hwa Ong ,  Edward Julius Creyghton

发明人： László Domokos ,  Wiebe Sjoerd Kijlstra ,  Lay Hwa Ong ,  Edward Julius Creyghton

IPC分类号： C01B39/02 ,  C01B39/20 ,  C01B39/24 ,  C10G47/16 ,  B01J29/08 ,  B01J37/10 ,  B01J23/888 ,  B01J37/02 ,  B01J37/06 ,  C10G47/18 ,  C10G47/20

CPC分类号： C10G47/16 ,  B01J23/888 ,  B01J29/084 ,  B01J37/0201 ,  B01J37/0207 ,  B01J37/06 ,  B01J37/10 ,  B01J2029/081 ,  B01J2229/126 ,  B01J2229/16 ,  B01J2229/36 ,  B01J2229/37 ,  B01J2229/42 ,  C01B39/026 ,  C01B39/20 ,  C01B39/24 ,  C10G47/18 ,  C10G47/20

摘要： Disclosed is a process for the preparation of a faujasite zeolite. A starting zeolite of the faujasite structure having a silica to alumina ratio of from 4.5 to 6.5 and an alkali level of less than 1.5% wt is steam calcined to produce an intermediate zeolite. The intermediate zeolite is treated with an acidified solution having specificately defined characteristics.

摘要翻译： 公开了一种制备八面沸石的方法。 二氧化硅与氧化铝之比为4.5至6.5并且碱含量低于1.5重量％的八面沸石结构的起始沸石被蒸汽煅烧以产生中间沸石。 中间沸石用具有特定限定特征的酸化溶液处理。

公开(公告)号：US20150182953A1

公开(公告)日：2015-07-02

申请号：US14142444

申请日：2013-12-27

申请人： Rive Technology, Inc.

发明人： Ernest Senderov ,  Mohammad Ibrahim Qureshi

IPC分类号： B01J29/08

CPC分类号： B01J29/084 ,  B01J29/0308 ,  B01J29/041 ,  B01J29/06 ,  B01J29/08 ,  B01J29/18 ,  B01J29/40 ,  B01J29/50 ,  B01J29/65 ,  B01J29/7007 ,  B01J29/7015 ,  B01J29/7034 ,  B01J29/83 ,  B01J29/84 ,  B01J29/85 ,  B01J29/89 ,  B01J35/10 ,  B01J35/1057 ,  B01J35/1061 ,  B01J35/109 ,  B01J2029/081 ,  B01J2229/126 ,  B01J2229/16 ,  B01J2229/36 ,  B01J2229/37 ,  B01J2229/38 ,  C10G11/05 ,  C10G29/205 ,  C10G45/12 ,  C10G47/16 ,  C10G50/00

摘要： Methods for introducing mesoporosity into zeolite materials that employ an acid pretreatment step are provided. By utilizing a non-acidic chelating agent during the acid treatment step, the zeolite material can be pretreated with a strong acid, often in higher concentrations or over shorter contact times, than had previously been contemplated. The resulting acid-treated mesoporous materials retain desirable properties, including Si/Al, UCS, and total mesopore and micropore volume. The ability to use a stronger acid without damaging the zeolite material results in a less expensive process capable of producing mesoporous zeolite materials suitable for a wide range of uses.

摘要翻译： 提供了使用酸预处理步骤将沸石导入沸石材料的方法。 通过在酸处理步骤期间利用非酸性螯合剂，沸石材料可以预先用强酸预处理，通常浓度较高或接触时间较短，比预期的要好。 所得酸处理的介孔材料保持所需的性能，包括Si / Al，UCS和总中孔和微孔体积。 在不破坏沸石材料的情况下使用更强的酸的能力导致能够生产适合于广泛用途的介孔沸石材料的较便宜的方法。