摘要:
The present invention relates to finely dispersed, low-viscosity polymer polyols which are stabilized in a novel manner and which are characterized by a high content of polystyrene or polystyrene copolymers. This invention also relates to the preparation of such polymer polyols, and their use for the preparation of polyurethane materials.
摘要:
Low-odor, higher molecular weight polyether polyols are produced by purifying the polyether polyols at temperatures of 110.degree. to 150.degree. C. and pressures of 10 to 70 hPa with the addition of 5 to 30% by weight of water, wherein the water is passed in finely divided form, with a droplet diameter of about 5 to 100.mu., through the polyether polyols to be purified for a time of metered addition of 1 to 5 hours.
摘要:
Stable, agglomerate-free, low-viscosity graft copolymer dispersions are prepared by the radical polymerization of 25 to 65% by weight of ethylenically unsaturated monomers in the presence of a base polyol, a macromer, a low-molecular weight regulator and, optionally, an organic solvent. The dispersions of this process are suitable as a polyol component for the production of polyurethane plastics by the isocyanate addition process.
摘要:
Compounds of the general formula ##STR1## in which n represents an integer from 2 to 6, preferably 2 or 3,m represents an integer from 1 to 6, preferably 1 to 3,R represents --C(CH.sub.3).sub.3 andX represents hydrogen or the group ##STR2## are used as core discoloration preventing agents in a process for the production of isocyanate-based foams.
摘要:
This invention relates to a process for the production of elastic, open-cell flexible slabstock polyurethane foams comprising reacting at an isocyanate index less than about 80 one or more polyisocyanates selected from the group tolylene diisocyanates, hexamethylene diisocyanate, and isophorone diisocyanate, with compounds containing at least two isocyanate-reactive hydrogen atoms and having a molecular weight of about 400 to about 10,000, in the presence of water as blowing agent in a quantity of about 5 to about 15 parts by weight for every 100 parts by weight of the isocyanate-reactive compound. The process may optionally include chain-extending and crosslinking agents containing at least two isocyanate-reactive hydrogen atoms and having a molecular weight of about 32 to about 399, and may optionally be carried out in the presence of other blowing agents, catalysts, auxiliaries, and additives.
摘要:
The present invention relates to a method for producing flexible polyurethane foams, wherein an isocyanate component (component B) is used which comprises polyether carbonate polyol, and to the isocyanate component itself. The invention also provides an NCO-terminated, urethane group-comprising prepolymer obtainable by reaction of one or more polyisocyanates (B1) with one or more polyether carbonate polyols.
摘要:
The present invention relates to a method for producing flexible polyurethane foams, wherein an isocyanate component (component B) which comprises fatty acid derivatives comprising hydroxyl groups is used as starting substance. The flexible polyurethane foams according to the invention have a bulk density according to DIN EN ISO 3386-1-98 in the range of ≧10 kg/m3 to ≦150 kg/m3, preferably ≧20 kg/m3 to ≦70 kg/m3, and in general their compressive strength according to DIN EN ISO 3386-1-98 is in the range of ≧0.5 kPa to ≦20 kPa (at 40% deformation and 4th cycle). The invention also provides an NCO-terminated prepolymer comprising urethane groups obtainable by reaction of one or more polyisocyanates (B1) with one or more fatty acid derivatives comprising hydroxyl groups (B2).
摘要翻译:本发明涉及柔性聚氨酯泡沫的制造方法,其中使用包含羟基的脂肪酸衍生物的异氰酸酯成分(B成分)作为原料。 根据本发明的柔性聚氨酯泡沫具有根据DIN EN ISO 3386-1-98的体积密度,范围> 10kg / m 3至@ 150kg / m 3,优选> = 20kg / m 3至@ 70kg / m3,并且一般来说,根据DIN EN ISO 3386-1-98的抗压强度在> = 0.5kPa至@ 20kPa(在40%变形和第四循环)的范围内。 本发明还提供了包含可通过一种或多种多异氰酸酯(B1)与一种或多种包含羟基(B2)的脂肪酸衍生物反应获得的氨基甲酸酯基团的NCO封端的预聚物。
摘要:
A continuous process for the preparation of highly stable, finely divided, low viscosity polymer polyols of small average particle size wherein in the first step an intermediate is prepared by reacting (1) a mixture of at least two ethylenically unsaturated monomers, preferably styrene and acrylonitrile, in a mixture comprising (2) a base polyol and (3) a macromer in the presence of (4) a free radical initiator, (5) a solvent having moderate chain transfer activity, and, optionally, (6) a reaction moderator at a temperature of at least 100.degree. C., such that the intermediate contains at least about 12% by weight of macromer, based on the weight of the base polyol and macromer, and a solids content of at least about 15% by weight and less than about 30% by weight, based on the weight of the base polyol, macromer and ethylenically unsaturated monomers. The intermediate, which functions as a seed for further polymerization, is then further reacted, in one or more stirred-tank reactors in series, in a mixture of at least two ethylenically unsaturated monomers, preferably styrene and acrylonitrile, in a base polyol and, optionally, a macromer, in the presence of solvent, initiator and a reaction moderator which are distributed among the remaining reactors.
摘要:
Process for the production of flexible polyurethane foams by reacting A) polyisocyanates or polyisocyanate prepolymers, with B) a specific blend of isocyanate-reactive compounds, C) water, D) optionally, blowing agents, E) optionally, activators, stabilizers and other per se known additives. The specific blend of isocyanate-reactive compounds B) comprises: i) at least one polyether polyol of a functionality of more than 2.5 to 6.0, ii) at least one polyether polyol of a functionality of 1.8 to less than 2.5, iii) at least one polyether polyol of a functionality of 1.8 to 6.0 having an EO content in the polyether chain of at least 50 wt. %. The flexible foams produced according to the present invention are characterized by moderate compressive strength at an elevated bulk density.
摘要:
A process for the production of stable, agglomerate-free, low viscosity graft copolymer dispersions through radical polymerization of ethylenically unsaturated monomers in the presence of a base polyol, a macromer, an enol ether of a specific formula, and optionally, an organic solvent. These enol ethers correspond to the general formula:A=CH--O--Rwherein:A represents a di-valent residue of the formula ##STR1## R represents an aliphatic hydrocarbon radical having 1 to 18 carbon atoms, a cycloaliphatic hydrocarbon radical having 5 to 10 carbon atoms, or a substituted or unsubstituted benzyl radical;andR' represents a hydrogen atom or an aliphatic hydrocarbon radical having 1 to 8 carbon atoms.