摘要:
The present invention relates to a process for preparing low-viscosity, allophanate-containing and NCO-free polyurethane prepolymers curable by actinic radiation, and to the products obtainable by this process. The prepolymers have residual monomer contents of less than 0.5% by weight and an NCO content of less than 1% by weight, and are prepared by a process in which A) diisocyanates, B) hydroxy-functional compounds containing groups which react with ethylenically unsaturated compounds on exposure to actinic radiation, and C) polyester, polyether or polycarbonate polyols having a functionality of at least 1.9 and a number-average molecular weight (Mn) of at least 1000 g/mol, D) optionally in the presence of a catalyst, are reacted to form NCO-group-containing prepolymers having radiation-curing groups, which are subsequently reacted E) optionally after addition of monofunctional isocyanates in the presence F) of an allophanatization catalyst to give allophanate-containing prepolymers, the ratio of NCO groups of the compounds from A) to the OH groups of the compounds from B) and C) being 1.45:1.0 to 1.1:1.0 and the ratio of the OH groups from B) to the OH groups from C) being 8.0:1 to 1.5:1.
摘要:
The present invention relates to a process for preparing low-viscosity reaction products of polyisocyanates containing activated groups which react, with polymerization, with ethylenically unsaturated compounds on exposure to actinic radiation.
摘要:
The invention relates to hybrid dispersions comprising nitrocellulose-polyurethanepolyurea particles (NC-PU dispersions) with accelerated drying behaviour as compared with the known systems, and also to their use in coating materials.
摘要:
The present invention relates to a process for preparing low-viscosity, allophanate-containing and NCO-free polyurethane prepolymers curable by actinic radiation, and to the products obtainable by this process. The prepolymers have residual monomer contents of less than 0.5% by weight and an NCO content of less than 1% by weight, and are prepared by a process in which A) diisocyanates, B) hydroxy-functional compounds containing groups which react with ethylenically unsaturated compounds on exposure to actinic radiation, and C) polyester, polyether or polycarbonate polyols having a functionality of at least 1.9 and a number-average molecular weight (Mn) of at least 1000 g/mol, D) optionally in the presence of a catalyst, are reacted to form NCO-group-containing prepolymers having radiation-curing groups, which are subsequently reacted E) optionally after addition of monofunctional isocyanates in the presence F) of an allophanatization catalyst to give allophanate-containing prepolymers, the ratio of NCO groups of the compounds from A) to the OH groups of the compounds from B) and C) being 1.45:1.0 to 1.1:1.0 and the ratio of the OH groups from B) to the OH groups from C) being 8.0:1 to 1.5:1.
摘要翻译:本发明涉及一种制备可通过光化辐射固化的低粘度,含有脲基甲酸酯和不含NCO的聚氨酯预聚物和通过该方法获得的产品的方法。 预聚物的残留单体含量小于0.5重量%,NCO含量小于1重量%,并且通过以下方法制备:A)二异氰酸酯,B)含有与烯属不饱和基团反应的基团的羟基官能化合物 化合物暴露于光化辐射,以及C)官能度为至少1.9,数均分子量(M N n N)至少为1000g / mol的聚酯,聚醚或聚碳酸酯多元醇,D )任选地在催化剂存在下反应以形成具有辐射固化基团的含有NCO基团的预聚物,其随后在式I化合物催化剂存在下加入单官能异氰酸酯后反应E),得到脲基甲酸酯 - 来自B)和C)的化合物的OH基的比例为1.45:1.0至1.1:1.0,并且B基中的OH基与OH基的比例 C)为8.0:1 至1.5:1。
摘要:
A device and a method for actuating an injector in a fuel-injection system of an internal combustion engine are described. Using a first calibration method and based on a control parameter, an injector parameter which characterizes the injection process is determined. Starting from this injector parameter, a first feature is determined for calibrating the injector. A second calibration method determines a second feature for calibrating the injector, based on an engine parameter. The first calibration method is monitored on the basis of the second feature.
摘要:
A method for operating an internal combustion engine in HCCI mode, including: a) sensing a profile of a measured variable of a variable in a combustion chamber of a cylinder; b) identifying combustion feature(s) of a combustion event in a first combustion cycle based on the profile; c) modeling a first value of a state variable at a defined point in time after the first combustion cycle and before a second subsequent combustion cycle based on the identified combustion feature(s); d) determining desired target values of combustion feature(s) of a combustion event in the second subsequent combustion cycle; e) modeling a second value of the state variable at the defined point in time based on the target values; and f) applying control to the internal combustion engine starting at the defined point in time as a function of the first and the second value of the state variable.
摘要:
The present invention relates to a process for preparing radiation-curing binders containing allophanate groups by reacting, at temperatures of ≦130° C., A) one or more compounds containing uretdione groups with B) one or more OH-functional compounds which contain groups which react, with polymerization, with ethylenically unsaturated compounds on exposure to actinic radiation (radiation-curing groups), C) optionally NCO-reactive compounds other than B), in the presence of D) a catalyst containing at least one zinc compound, to form allophanate groups by opening the uretdione ring. The present invention also relates to the binders obtained by the process of the invention and to coating compositions containing these binders.
摘要:
A method for regulating HCCI combustion of fuel in a reactor of an internal combustion engine is described in which a multivariable regulation is used, manipulated variable changes Δuk for the instantaneous regulating cycle k being determined on the basis of at least system deviations Δxk-1 and manipulated variable changes Δuk-1 of a preceding regulating cycle k−1.
摘要:
A process for the salt-free coagulation of polymer dispersions in a rotor/stator assembly is disclosed. The rotor/stator assembly includes a casing, a rotor shaft rotatably mounted within the casing, a rotor having a conical surface affixed to the rotor shaft, and a stator affixed to the casing and concentrically associated with the rotor. The conical surface faces a surface of the stator to form an adjustable shear gap, which is surrounded by an annular space. A polymer dispersion is fed into the assembly and conveyed through the shear gap. During this conveyance, the polymer dispersion is precipitated at a predetermined shear rate and a predetermined shear deformation. The polymer dispersion is discharged from the assembly through an outlet neck, and the assembly is flushed with water using one or more ports formed in at least one of a pipeline coupled to the axial feed neck, the stator, and the casing.
摘要:
A guide unit is provided for a height-adjustable cargo floor of a motor vehicle with a retaining part, to which a cargo floor can be fixed, and with a guide, along which the retaining part can be displaced from a lower position into an upper position. In addition, a spring element is provided for prestressing the retaining part into the topmost position. A motor vehicle is also provided with a height-adjustable cargo floor and at least one guide unit of the above-described type that is rigidly fixed to the vehicle.