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    Semiconducting fused thiophene polymer ink formulation
    11.
    发明授权
    Semiconducting fused thiophene polymer ink formulation 有权
    半导体熔融噻吩聚合物油墨配方

    公开(公告)号：US09312044B2

    公开(公告)日：2016-04-12

    申请号：US14421240

    申请日：2013-08-20

    Applicant: Corning Incorporated

    Inventor： Mingqian He ,  James Robert Matthews

    IPC: C08G75/00 ,  H01B1/12 ,  C09D165/00 ,  C08G61/12 ,  C09D11/52 ,  H01B13/00 ,  H01L51/00 ,  H01L51/05

    CPC classification number: H01B1/127 ,  C08G61/126 ,  C08G2261/124 ,  C08G2261/1412 ,  C08G2261/3223 ,  C08G2261/3243 ,  C08G2261/344 ,  C08G2261/364 ,  C08G2261/92 ,  C09D11/52 ,  C09D165/00 ,  H01B13/0026 ,  H01L51/0007 ,  H01L51/0036 ,  H01L51/0558

    Abstract: A formulation including: an organic semiconducting polymer selected from the diketopyrrolopyrrole (DPP) and fused thiophene co-polymer structures of the formulas (I), (II), or combinations thereof, or salts thereof, in an amount of from 0.1 to 5 wt % based on the total weight of the formulation: formulas (I) and (II), respectively, where m is an integer from 1 to 2, n is an integer from 4 to 80, X and Y are independently selected from a divalent heteroaryl, such as a thiophene, R1, R2, R3, and R4 is each a hydrocarbylene substituent as defined herein, a first solvent is selected from a cyclic aliphatic in an amount of from 2 to 98 wt %; and a second solvent selected from an aromatic in an amount of from 98 to 2 wt %. Also disclosed are method of making and using the disclosed formulations, for example, for use in electronic devices.

    Abstract translation: 一种制剂，其包含：选自二酮吡咯并吡咯（DPP）和式（I），（II）的稠合噻吩共聚物结构或其组合或其盐的有机半导体聚合物，其量为0.1-5wt ％，分别为式（I）和（II），其中m为1至2的整数，n为4-80的整数，X和Y独立地选自二价杂芳基 ，例如噻吩，R 1，R 2，R 3和R 4各自为如本文所定义的亚烃基取代基，第一溶剂选自2-98重量％的环状脂族; 和选自98至2重量％的芳族化合物的第二溶剂。 还公开了制备和使用所公开的制剂的方法，例如用于电子装置。

    Doping of other polymers into organic semi-conducting polymers
    13.
    发明授权
    Doping of other polymers into organic semi-conducting polymers 有权

    公开(公告)号：US11283023B2

    公开(公告)日：2022-03-22

    申请号：US16620050

    申请日：2018-06-01

    Applicant: Corning Incorporated

    Inventor： Mingqian He ,  Yang Li ,  James Robert Matthews ,  Karan Mehrotra ,  Weijun Niu ,  Arthur Lawrence Wallace

    IPC: H01L51/00 ,  C08G61/12 ,  H01L51/05

    Abstract: Disclosed is a polymer blend comprising an organic semiconductor (OSC) polymer blended with an isolating polymer and method for making the same. The OSC polymer includes a diketopyrrolopyrrole fused thiophene polymeric material, and the fused thiophene is beta-substituted. The isolating polymer includes a non-conjugated backbone, and the isolating polymer may be one of polyacrylonitrile, alkyl substituted polyacrylonitrile, polystyrene, polysulfonate, polycarbonate, an elastomer block copolymer, derivatives thereof, copolymers thereof and mixtures thereof. The method includes blending the OSC polymer with an isolating polymer in an organic solvent to create a polymer blend and depositing a thin film of the polymer blend over a substrate. Also disclosed is an organic semiconductor device that includes a thin semiconducting film comprising OSC polymer.

    OPTICAL FIBER COATING COMPOSITIONS WITH HYDROGEN BONDING, NON-COVALENT BONDING, CROSS-LINKERS
    14.
    发明申请
    OPTICAL FIBER COATING COMPOSITIONS WITH HYDROGEN BONDING, NON-COVALENT BONDING, CROSS-LINKERS 审中-公开

    公开(公告)号：US20200017706A1

    公开(公告)日：2020-01-16

    申请号：US16437469

    申请日：2019-06-11

    Applicant: CORNING INCORPORATED

    Inventor： James Robert Matthews

    IPC: C09D133/14 ,  G02B6/10 ,  G02B1/14

    Abstract: An optical fiber coating composition comprising: one or more monomers forming a first polymer chain and a second polymer chain upon polymerization; and one or more hydrogen bonding cross-linkers including a first molecule that covalently bonds to the first polymer chain during the polymerization and a second molecule that covalently bonds to the second polymer chain during the polymerization. The first molecule includes a first functional group. The second molecule includes a second functional group. The first functional group and the second functional group hydrogen bond to form three or more hydrogen bonds during the polymerization. The first functional group and the second functional group both can be a ureidopyrimidinone functional group. The first molecule and the second molecule can both be a ureidopyrimidinone (meth)acrylate. The one or more monomers can be mono-acrylate monomers, and the optical fiber coating composition can lack any multi-acrylate monomers.

    SEMICONDUCTING FUSED THIOPHENE POLYMER INK FORMULATION
    17.
    发明申请
    SEMICONDUCTING FUSED THIOPHENE POLYMER INK FORMULATION 有权
    半导体聚合物聚合物油墨制剂

    公开(公告)号：US20150206616A1

    公开(公告)日：2015-07-23

    申请号：US14421240

    申请日：2013-08-20

    Applicant: Corning Incorporated

    Inventor： Mingqian He ,  James Robert Matthews

    IPC: H01B1/12 ,  H01B13/00

    CPC classification number: H01B1/127 ,  C08G61/126 ,  C08G2261/124 ,  C08G2261/1412 ,  C08G2261/3223 ,  C08G2261/3243 ,  C08G2261/344 ,  C08G2261/364 ,  C08G2261/92 ,  C09D11/52 ,  C09D165/00 ,  H01B13/0026 ,  H01L51/0007 ,  H01L51/0036 ,  H01L51/0558

    Abstract: A formulation including: an organic semiconducting polymer selected from the diketopyrrolopyrrole (DPP) and fused thiophene co-polymer structures of the formulas (I), (II), or combinations thereof, or salts thereof, in an amount of from 0.1 to 5 wt % based on the total weight of the formulation: formulas (I) and (II), respectively, where m is an integer from 1 to 2, n is an integer from 4 to 80, X and Y are independently selected from a divalent heteroaryl, such as a thiophene, R1, R2, R3, and R4 is each a hydrocarbylene substituent as defined herein, a first solvent is selected from a cyclic aliphatic in an amount of from 2 to 98 wt %; and a second solvent selected from an aromatic in an amount of from 98 to 2 wt %. Also disclosed are method of making and using the disclosed formulations, for example, for use in electronic devices.

    Abstract translation: 一种制剂，其包含：选自二酮吡咯并吡咯（DPP）和式（I），（II）的稠合噻吩共聚物结构或其组合或其盐的有机半导体聚合物，其量为0.1-5wt ％，分别为式（I）和（II），其中m为1至2的整数，n为4-80的整数，X和Y独立地选自二价杂芳基 ，例如噻吩，R 1，R 2，R 3和R 4各自为如本文所定义的亚烃基取代基，第一溶剂选自2-98重量％的环状脂族; 和选自98至2重量％的芳族化合物的第二溶剂。 还公开了制备和使用所公开的制剂的方法，例如用于电子装置。

    Boron ester fused thiophene monomers
    18.
    发明授权
    Boron ester fused thiophene monomers 有权
    硼酯稠合噻吩单体

    公开(公告)号：US09070882B2

    公开(公告)日：2015-06-30

    申请号：US14460649

    申请日：2014-08-15

    Applicant: CORNING INCORPORATED

    Inventor： Mingqian He ,  James Robert Matthews ,  Weijun Niu ,  Arthur Lawrence Wallace

    IPC: C07D495/14 ,  H01L51/00 ,  C07F5/02 ,  C07D495/22

    CPC classification number: C07F5/02 ,  C07D495/14 ,  C07D495/22 ,  C07F5/025 ,  C08G61/124 ,  C08G61/126 ,  C08G2261/1412 ,  C08G2261/3243 ,  C08G2261/344 ,  C08G2261/411 ,  C08L65/00 ,  H01L51/0036 ,  H01L51/0043 ,  H01L51/0053 ,  H01L51/0068 ,  H01L51/0074 ,  H01L51/008 ,  H01L51/0545 ,  H01L51/4253

    Abstract: A compound of formula (I), formula (II), or a combination thereof, and salts thereof is described. Each A may be independently an optionally substituted conjugated species or an optionally substituted aromatic species. Each R may be independently an optionally substituted C1-C40 linear alkyl chain, an optionally substituted branched alkyl chain, an optionally substituted alkyl chain containing heteroatoms, substituted alkyl chains, or H. Each R2 may be independently an optionally substituted C1-C40 linear alkyl chain, an optionally substituted branched alkyl chain, an optionally substituted alkyl chain containing heteroatoms, substituted alkyl chains, H, or part of a cyclic boronate ester with an other R2. Each n may be independently less than or equal to 3 and greater than or equal to 1. Each x may be independently less than or equal to 3.

    Abstract translation: 描述了式（I），式（II）化合物或其组合及其盐。 每个A可以独立地是任选取代的共轭物质或任选取代的芳族物质。 每个R可以独立地是任选取代的C 1 -C 40直链烷基链，任选取代的支链烷基链，任选取代的含有杂原子的烷基链，取代的烷基链或H.每个R 2可以独立地是任选取代的C 1 -C 40直链烷基 链，任选取代的支链烷基链，含有杂原子的任选取代的烷基链，取代的烷基链，H或具有另一个R 2的环状硼酸酯的一部分。 每个n可以独立地小于或等于3并且大于或等于1.每个x可以独立地小于或等于3。

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