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公开(公告)号：US4360453A
公开(公告)日：1982-11-23
申请号：US210885
申请日：1980-11-28
IPC分类号： B01J23/22 , B01J27/198 , C07C51/215 , C07C51/25 , B01J27/14
CPC分类号： C07C51/252 , B01J23/002 , B01J23/22 , B01J27/198 , C07C51/215 , C07C51/25 , B01J2523/00
摘要： The present invention provides a method for the preparation of oxidation catalysts containing mixed oxides of vanadium and phosphorus, which catalysts are particularly effective in the oxidation of n-butane, n-butenes, 1,3-butadiene or a mixture thereof with molecular oxygen or an oxygen-containing gas in the vapor phase to produce high yields of maleic anhydride with good selectivity. Vanadium phosphorus mixed oxide catalyst precursors prepared in solution in organic media are extracted from the organic media with water, with subsequent drying down to recover a precursor solid, or impregnation of a support with the aqueous solution.
摘要翻译： 本发明提供一种制备含有钒和磷的混合氧化物的氧化催化剂的方法，该催化剂在正丁烷，正丁烯，1,3-丁二烯或其与分子氧或其混合物的氧化中是特别有效的 气相中的含氧气体，以产生高产率的马来酸酐，具有良好的选择性。 在有机介质溶液中制备的钒磷混合氧化物催化剂前体用水从有机介质中萃取，随后干燥以回收前体固体，或用水溶液浸渍载体。
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公开(公告)号：US5185308A
公开(公告)日：1993-02-09
申请号：US696215
申请日：1991-05-06
申请人： William J. Bartley , Simon Jobson , Gordon G. Harkreader , Melanie Kitson , Michael F. Lemanski
发明人： William J. Bartley , Simon Jobson , Gordon G. Harkreader , Melanie Kitson , Michael F. Lemanski
IPC分类号： B01J31/04 , B01J23/44 , B01J23/52 , B01J23/54 , B01J23/58 , B01J31/28 , B01J37/02 , B01J37/03 , B01J37/06 , B01J37/16 , C07B61/00 , C07C67/05 , C07C67/055 , C07C69/15
CPC分类号： B01J23/44 , B01J23/52 , B01J23/58 , C07C67/055 , B01J35/008 , B01J37/0201 , B01J37/0205 , B01J37/03 , B01J37/06 , B01J37/16
摘要： A shell impregnated catalyst for use in the production of vinyl acetate from ethylene, acetic acid and an oxygen containing gas is provided. The catalyst has a productivity of greater than 661 grams of vinyl acetate per hour per liter of catalyst at 150.degree. C. and consists essentially of:(1) a catalyst support having a particle diameter from about 3 to about 7 mm and a pore volume of 0.2 to 1.5 ml per gram(2) palladium and gold distributed in the outermost 1.0 mm thick layer of the catalyst support particles, and(3) from about 3.5 to 9.5% by weight of potassium acetate.The catalyst is characterized by having a gold to palladium weight ratio in the range 0.60 to 1.25.
摘要翻译： 提供了用于从乙烯，乙酸和含氧气体生产乙酸乙烯酯的壳体浸渍催化剂。 催化剂在150℃下每小时催化剂具有大于661克乙酸乙烯酯的生产率，并且基本上由以下组成：（1）具有约3至约7mm的粒径的催化剂载体和孔体积 分布在最外层1.0mm厚的催化剂载体颗粒中的每克（2）钯和金为0.2至1.5ml，和（3）约3.5至9.5重量％的乙酸钾。 催化剂的特征在于金与钯的重量比在0.60至1.25的范围内。
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13.发明授权
公开(公告)号：US4350611A
公开(公告)日：1982-09-21
申请号：US252751
申请日：1981-04-10
IPC分类号： B01J27/198 , C07C51/215 , C07C51/25 , B01J27/14
CPC分类号： C07C51/252 , B01J23/002 , B01J27/198 , C07C51/215 , C07C51/25 , B01J2523/00
摘要： The present invention provides a process for the preparation of oxidation catalysts containing mixed oxides of vanadium and phosphorus, which catalysts are particularly effective in the oxidation of n-butane, n-butenes, 1,3-butadiene or a mixture thereof with molecular oxygen or an oxygen-containing gas in the vapor phase to produce high yields of maleic anhydride with good selectivity. A vanadium compound is introduced into an olefinic halogenated organic liquid medium, a phosphorus-containing compound is added to the medium, reduction of at least a portion of the vanadium to a +4 valence state is effected either prior to or subsequent to the addition of the phosphorus-containing compound, and the resulting vanadium-phosphorus oxide catalyst precursor is recovered, dried and calcined.
摘要翻译： 本发明提供了一种制备含有钒和磷的混合氧化物的氧化催化剂的方法，该催化剂在正丁烷，正丁烯，1,3-丁二烯或其与分子氧或其混合物的氧化中是特别有效的，或 气相中的含氧气体，以产生高产率的马来酸酐，具有良好的选择性。 将钒化合物引入烯烃卤代有机液体介质中，将含磷化合物加入到介质中，将至少一部分钒还原至+4价态可在添加之前或之后进行 含磷化合物和得到的钒 - 磷氧化物催化剂前体被回收，干燥并煅烧。
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公开(公告)号：US4115323A
公开(公告)日：1978-09-19
申请号：US843721
申请日：1977-10-19
IPC分类号： B01J27/00 , B01J27/10 , C07B61/00 , C07C17/00 , C07C17/156 , C07C17/25 , C07C21/06 , C07C67/00 , B01J23/80 , B01J23/60
CPC分类号： B01J27/10 , B01J27/00 , C07C17/156 , C07C17/25 , C07C21/06
摘要： The present invention relates to a novel catalyst for production of VCM containing a salt of rhodium or platinum, a salt of iron or copper, and a salt of zinc; impregnated on an alumina, titania, zirconia, silica, or silica alumina support.The catalyst can be employed in a fixed or fluid bed reactor to adiabatically produce vinyl chloride from a feed stream containing ethylene, a source of chlorine, a source of elemental oxygen, and, optionally, ethylene dichloride.
摘要翻译： 本发明涉及一种用于生产含有铑或铂盐，铁或铜盐和锌盐的VCM的新催化剂; 浸渍在氧化铝，二氧化钛，氧化锆，二氧化硅或二氧化硅氧化铝载体上。
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15.发明授权
公开(公告)号：US4544673A
公开(公告)日：1985-10-01
申请号：US585746
申请日：1984-03-30
IPC分类号： B01J23/86 , B01J23/887 , B01J23/888 , C07C1/04
CPC分类号： B01J23/868 , B01J23/8872 , B01J23/888 , C07C1/043 , C07C2523/72 , C07C2523/85 , C07C2523/885
摘要： Low molecular weight hydrocarbons are produced by contacting carbon monoxide and hydrogen at elevated temperatures and pressures with a catalyst comprising oxides of chromium, molybdenum and/or tungsten, copper, thorium or uranium and at least one alkali or alkaline earth metal. Catalysts are provided which are prepared by the procedure of adding an alkali or alkaline earth metal carbonate to an aqueous solution or slurry containing decomposable salts of thorium or uranium and copper chromate, copper tungstate and/or copper molybdate to form a precipitate. The precipitate is heated, neutralized, dried and thereafter calcined and reduced.
摘要翻译： 通过使含有铬，钼和/或钨，铜，钍或铀的氧化物和至少一种碱金属或碱土金属的催化剂在高温和高压下使一氧化碳和氢气接触来制备低分子量烃。 提供催化剂，其通过将碱金属或碱土金属碳酸盐添加到含有钍或铀和铬酸铜的可分解盐，铜酸铜和/或钼酸铜的水溶液或浆料中以形成沉淀物的方法制备。 将沉淀物加热，中和，干燥，然后煅烧并还原。
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16.发明授权Preparation of maleic anhydride from butane using fluidized vanadium-phosphorous-oxide containing catalysts 失效使用流化的含钒 - 氧化磷氧化物催化剂从丁烷制备马来酸酐
公开(公告)号：US4351773A
公开(公告)日：1982-09-28
申请号：US221670
申请日：1980-12-31
IPC分类号： C07D307/60 , B01J27/18 , B01J27/198 , C01B25/37 , C01B25/45 , C07B61/00 , C07C51/215
CPC分类号： B01J23/002 , B01J27/198 , C07C51/215 , B01J2523/00
摘要： A process is provided for the preparation of fluid bed oxidation catalysts containing the mixed oxides of vanadium and phosphorus, comprising the steps of preparing the catalyst precursor, comminuting the precursor, introducing the precursor into water to form an aqueous slurry and spray drying the slurry. The resulting microspheroidal particles are excellent fluid bed catalysts for the preparation of maleic anhydride from 4-carbon atom hydrocarbons.
摘要翻译： 提供了一种制备含有钒和磷的混合氧化物的流化床氧化催化剂的方法，包括制备催化剂前体，粉碎前体，将前体引入水中以形成含水浆料并喷雾干燥浆料的步骤。 所得微球颗粒是用于从4-碳原子烃制备马来酸酐的优异流化床催化剂。
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公开(公告)号：US5334751A
公开(公告)日：1994-08-02
申请号：US874947
申请日：1992-04-28
CPC分类号： C07C67/40
摘要： Disclosed is a process for making ethyl acetate which comprises reacting in a reaction zone ethyanol and molecular oxygen in the presence of a solid catalyst containing the elements and proportions indicated by the empirical formulaPd.sub.a M.sub.b TiP.sub.c O.sub.x (formula 1)where M is selected from Cd, Au, Zn, Tl, alkali metals and alkalineearth metals,a is from 0.0005 to 0.2b is from zero to 3ac is 0.5 to 2.5, andx is a value sufficient to satisfy the valence requirements ofthe other elements present, andwherein said catalyst contains crystalline TiP.sub.2 O.sub.7.
摘要翻译： 公开了一种制备乙酸乙酯的方法，其包括在含有元素的固体催化剂的存在下在反应区乙醇和分子氧中反应，并且经验式PdaMbTiPcOx（式1）所示的比例，其中M选自Cd，Au， Zn，Tl，碱金属和碱土金属，a为0.0005〜0.2b为0〜3ac为0.5〜2.5，x为足以满足其它元素的化合价要求的值，其中，所述催化剂 含有结晶TiP2O7。
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公开(公告)号：US4293498A
公开(公告)日：1981-10-06
申请号：US199148
申请日：1980-10-22
IPC分类号： C07D307/60 , B01J27/18 , B01J27/198 , C01B25/37 , C01B25/45 , C07B61/00 , C07C51/215 , C07C51/25
CPC分类号： C07C51/252 , B01J23/002 , B01J27/198 , C07C51/215 , C07C51/25 , B01J2523/00
摘要： The present invention provides a process for the preparation of oxidation catalysts containing mixed oxides of vanadium and phosphorus, which catalysts are particularly effective in the oxidation of n-butane, n-butenes, 1,3-butadiene or a mixture thereof with molecular oxygen or an oxygen-containing gas in the vapor phase to produce high yields of maleic anhydride with good selectivity. A vanadium compound is introduced into an olefinic halogenated organic liquid medium, a phosphorus-containing compound is added to the medium, reduction of at least a portion of the vanadium to a +4 valence state is effected either prior to or subsequent to the addition of the phosphorus-containing compound, and the resulting vanadium-phosphorus oxide catalyst precursor is recovered, dried and calcined.
摘要翻译： 本发明提供了一种制备含有钒和磷的混合氧化物的氧化催化剂的方法，该催化剂在正丁烷，正丁烯，1,3-丁二烯或其与分子氧或其混合物的氧化中是特别有效的，或 气相中的含氧气体，以产生高产率的马来酸酐，具有良好的选择性。 将钒化合物引入烯烃卤代有机液体介质中，将含磷化合物加入到介质中，将至少一部分钒还原至+4价态可在添加之前或之后进行 含磷化合物和得到的钒 - 磷氧化物催化剂前体被回收，干燥并煅烧。
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